NOIDA INSTITUTE OF ENGINEERING & TECHNOLOGY, GREATER NOIDA

SEMESTER (EVEN)
UNIT:- II
ASSIGNMENT SHEET No. –2
Subject Name: - Chemical Engg. Thermodynamics
Course Coordinator:- Metali Sarkar Subject Code: - KCH 403
Checked &Return Date: - Submission Date: 6th April 2020

1. Briefly explain phase rule and Duhem’s Theorem.

2. Define bubble point and dew point in a VLE diagram.

3. At 300K and 1 bar, of a binary mixture V = 109.4 X 10 -6 – 16.8 X 10-6 x1 – 2.64 X 10-6 x12 m3/
mol.
Determine expression of V́ 1 and V́ 2 as a function of x1.
i) Numerical values for the pure component enthalpies V1 and V2.
∞ ∞
(ii) Numerical values for the partial molar enthalpies and V´1 and V´2 .

4. Prove that for a equilibrium multiphase system at same T and P, μαi =μiβ =…=μ πi .

5. Define Entropy. Prove that for entropy change in ideal gas,

T
ig dT P
∆ S=∫ C p −R ln
To T Po

6. Write a short note on Liquid-liquid equilibrium

7. Write a short note on Ternary liquid-liquid equilibrium.