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5s
3f
2p
First Part:
“Electron will first enter in those orbital which has the least value of n + l .”
Example:
Hence, electron will enter first in 3p orbital as its n+l value is less than n+l value of 3d.
Second Part:
“If the n+l value of two orbital are same then electron will first enter in that orbital which has least
value of n.”
Hence, electron will enter first in 3p orbital because its n value is less than that of 4s.