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Decline of Potential with Distance from Planar Colloid Surface

Potenti al in m V
Faraday Const C/mol 96485
Gas Constant J/mol K 8.314
Permittivity Water C/V.m 7E-10
POTENTIAL DECLINE
Layer T)
Counter-ion Conc mM/L 0.1 1 1 12
Counter-ion Val 1 1 3 10
Temperature K 300 300 300 8
Surface Potential mV 10 10 10 6
4
Kappa 1/m 3E+07 1E+08 3E+08 2
Deby Length m 3E-08 1E-08 3E-09 0
0 10 20
Dist from Co
Dist, nm c = 0.1 c = 1 mM,c = 1 mM, z = 3
0 10 10 10
2 9.3714 8.14389 5.40127
4 8.7822 6.6323 2.91738
6 8.2302 5.40127 1.57575
8 7.7128 4.39874 0.85111
10 7.2279 3.58229 0.45971
12 6.7735 2.91738 0.2483
14 6.3477 2.37588 0.13411
16 5.9487 1.93489 0.07244
18 5.5747 1.57575 0.03913
20 5.2243 1.28328 0.02113
22 4.8959 1.04509 0.01141
24 4.5881 0.85111 0.00617
26 4.2997 0.69313 0.00333
28 4.0294 0.56448 0.0018
30 3.7761 0.45971 0.00097
32 3.5387 0.37438 0.00052
34 3.3162 0.30489 0.00028
36 3.1078 0.2483 0.00015
38 2.9124 0.20221 8E-05
40 2.7293 0.16468 4E-05
42 2.5577 0.13411 2E-05
44 2.3969 0.10922 1E-05
46 2.2463 0.08895 7E-06
48 2.1051 0.07244 4E-06
50 1.9727 0.05899 2E-06
DOUBLE LAYER THEORY
Potenti al in m V

POTENTIAL DECLINE WITH DISTANCE (Double


Layer T)
12
c = 0.1
10 mM, z =
1
8
c=1
6 mM, z =
4 1
c=1
2 mM, z =
0 3
0 10 20 30 40 50
Dist from Colloid in nm
Decline of Potential with Distance from Spherical Colloid Surface DOUBLE LAYER TH

Potential in mV
Faraday Const C/mol 96485
Gas Constant J/mol K 8.314
Permittivity Water C/V.m 7.1E-10 POTENTIAL DECLI
Sphere (Double La
Counter-ion Conc mM/L 0.1 1 1 12
Counter-ion Val 1 1 3 10
Temperature K 300 300 300 8
Surface Potential mV 10 10 10
6
Radius of the Spherenm 10 10 10
4
Kappa 1/m 3.2E+07 1E+08 3E+08 2
Deby Length m 3.1E-08 1E-08 3E-09 0
0 10 20
Dist, nm c = 0.1 mc = 1 mM,c = 1 mM, z = 3 Dist from Collo
10 10 10 10
12 7.80947 6.78658 4.50106
14 6.27303 4.73736 2.08384
16 5.14385 3.3758 0.98485
18 4.28487 2.44374 0.47284
20 3.61396 1.79114 0.22985
22 3.07888 1.32608 0.11286
24 2.64489 0.98995 0.05588
26 2.28796 0.74419 0.02786
28 1.99097 0.56277 0.01397
30 1.74143 0.42776 0.00704
32 1.52996 0.32659 0.00357
34 1.34944 0.25033 0.00181
36 1.19435 0.19254 0.00093
38 1.06036 0.14855 0.00047
40 0.94402 0.11493 0.00024
42 0.84254 0.08914 0.00012
44 0.75369 0.06929 6E-05
46 0.6756 0.05398 3E-05
48 0.60675 0.04213 2E-05
50 0.54586 0.03294 9E-06
52 0.49187 0.02579 5E-06
54 0.44388 0.02023 2E-06
56 0.40112 0.01588 1E-06
58 0.36294 0.01249 7E-07
60 0.32879 0.00983 3E-07
DOUBLE LAYER THEORY

POTENTIAL DECLINE WITH DISTANCE For


phere (Double Layer T)
12
c = 0.1
10 mM, z =
8 1

6 c=1
mM, z =
4 1

2
0
0 10 20 30 40 50

Dist from Colloid Center in nm

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