Subj

ect
:B.Tech.

NameofPaper
:CHEMI
STRY-
I

PaperCode:BS-
CH-
201

Ful
lMar
ks:70

Answeranyt
enf
rom Gr
.A,
anyt
hreeeachf
rom Gr
.BandGr
.Cquest
ions

Thequest i
onsareofequalv alue
Thefi
guresinthemar gi
nindicatefullmar
ks
Candi
dat
esar
erequi
redt
ogivet hei
ranswersintheirownwor dsasf
araspr
act
icabl
e
Gr
oup–A
(Mult
ipleChoiceTypeQuest i
ons)
Answeranyt enquestions

Sl
.No. Quest
ions Mar
ks

Or
derofat
omi
cradi
usf
or:
B,Al
,Ga,
In. 1
1.
(i
)
a)B<Al
<Ga<I
nb)B<Al
>Ga<I
nc)B<Al
>Ga>I
nd)B<Al
<Ga>I
n

Whi
choneoft
hef
oll
owi
ngi
smostwat
ersol
ubl
e?
(
ii
) 1
a)BeSO4 b)MgSO4 c)CaSO4 d)BaSO4

Whi
choft
hef
oll
owi
ngi
smostunst
abl
e
(
ii
i) 1
a)Fe(
CO)
5 b)Cr
(CO)
6 c)V(
CO)
6 d)Ni
(CO)
4

2+
Secondar
yval
encyof[
Ca(
EDTA)
] is
(
iv) 1
a)2 b)1 c)6 d)4

Sel
ect
ionr
uleforvi
brat
ional
transi
ti
onofdi
atomi
cmol
ecul
eas
har
monicosci
l
latori
s
(
v) 1
a)∆v=±1 b)∆v=±2 c)∆v=±3 d)al
l

Ar
omat
ic-
ali
phat
iccar
bon-
car
bonbondcanbef
ormedi
n
(
vi) a)Wurt
zreact
ionb)Fr
iedel
Craf
tsr
eact
ionc)Per
kinr
eact
iond)Et
ard 1
r
eact
ion
 PageNo.
:02

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Sl
.No. Quest
ions Mar
ks

Whi
choneoft
hef
oll
owi
ngi
sdi
spr
opor
ti
onat
ionr
eact
ion?

a)Baey
er-
Vil
l
igeroxi
dat
ionb)Oppenauerr
eact
ionc)Canni
zzar
o
(
vii
) 1
r
eact
ion

d)Cl
emensi
onr
educt
ion

HOMOofC2i
s
(
vii
i
) 1
a) σ2p b)π2p c)π*
2p
d)σ*
2p
z x x x

Whi
chonei
snott
her
mody
nami
cst
atef
unct
ion?
(
ix) 1
a)U b)G c)W d)S

Radi
ofr
equencyr
adi
ati
oni
srequi
redf
or
(
x) a)Rot
ati
onal b)NMR c)Vi
brat
ional
spect
roscopy d) 1
None

Hy
bri
dizat
ionofcar nCF3●r
boni adi
cal
is
(
xi) 1
a)sp b)sp2 c)sp3 d)sp3d

Whi
chonei
sIRact
ivemol
ecul
e?

(
xii
) a)O2 b)N2 c)CO2 d)H¬2 1
 PageNo.
:03

Gr
oup–B
(
ShortAnswerTypeQuest
ions)
Answeranythr
eequesti
ons

Sl
.No. Quest
ions Mar
ks

2.
(a) Howmanyel
ect
ronsar
ether
ein24Crwi
t n+l
h( )val
ueoff
our
? 2

Dr
awmol ecul
arener
gylev
eldi
agr
am f
orNO.Depi
ctt
hebondor
derand
(
b) 3
magnet
icbehavi
orofit
.

3.
(a) Repr
esentaf
uel
cel
landwr
it
edownt
hei
nvol
vedcel
lreact
ion. 2

Theemfoft
hecellZn/Zn2+(
0.1M)
//Cd2+(
C1)
/Cdhasbeenf oundtobe
0
(
b) 0.
331Vat298K.Calcul
atetheval
ueofC1?Gi enEZn /Zn=-
v 2+ 0.759V, 3
0
E
Cd2+/
=-
Cd
0.397V.

i
)Whatdoy oumeanbychemi
cal
shi
ft
?ii
)Howmanysi
gnal
doy
ou
4.
(a) 1+2
expectf
or2-met
hyl
but
aneinNMRspect
ra?

(
b) St
ateandexpl
ainLamber
t-Beer
slaw. 2
2- 2-
5.
(a) Ment
iont
hehy
bri
dizat
ionandshapeof[
Ni(
CN)
4] and[
Ni(
Cl)
4] 3
3+
Reddi
sh-vi
oletcol
orcompl
ex[
Ti(
H2O)
6] wheni
sheat
ed,
becomes
(
b) 2
col
orl
ess-explai
n.

6.
(a) Showt
hatener
gyofapar
ti
cleconf
inedi
naboxofonedi
mensi
onal
box 3
ofl
engt
h‘l
’i
squant
ized.
 Theequi
li
bri
um constantsf
orareact
ionare2×104 at125oCand5×103
(
b) o 2
at25Crespect
ivel
y.Findst
andar
denthal
pyofreacti
on.

PageNo.
:04

Gr
oup–C
(
LongAnswerTy peQuest
ions)
Answeranythr
eequesti
ons

Sl
.No. Quest
ions Mar
ks

Cal
cul
atethev
aluesofabsor
pti
onmaxi
ma,
λmaxoft
hef
oll
owing
7.
(a) compoundusi
ng Woodwar
ds-Fi
eserr
ules: 2

Howdoy
oudi
sti
ngui
sht
hef
oll
owi
ngbyUV-
VISspect
ra

(
b) i
) ci
s-andt
ransci
nnami
caci
d(Ph-
CH=CH-
COOH) 2+2

i
i
) Et
hyl
eneandpr
opene.
?

Acetoneshowstwoabsor
pti
onmaximaat280nm and190nm i
nUV
(
c) spectr
a.I
denti
fyt
henatur
eofel
ect
roni
cexci
tat
ion.Whi
chonei
smore 3
i
ntense?

Whatdoyoumeanbyzer
opointenergy?I
ndent
if
ythef
oll
owing
(
d) 1+2
mol
ecul
esasMW orIRact
iveorboth:CO2,
HF,H2OandN2.

Whatisthedi
ffer
encebet
weenphosphor
escenceandf
luor
escence?
(
e) 3
Expl
ainwit
hdiagram.

8.
(a) Der
ivev
an’
tHof
fisot
her
m. 3

(
b) Har
dwat
ershoul
dnotbeusedasBoi
l
erFeedwat
er-why
? 2

(
c) Dr
awaf
lowdi
agr
am f
orwast
ewat
ert
reat
ment
. 4

(
d) Showt
hat
: []
∂G H
=-2
∂T TP T
3

Fi
ndentr
opychangeduri
ngmi
xi
ngof2mol N2at25OC,
NH3and3mol
(
e) 3
assumi
ngideal
behavi
or.

Drawpot
enti
alener
gycurveofbutaneasf
unct
ionofdi
hedr
alangl
e
9.
(a) 3
duri
ngt
herotat
ionaboutC2-
C3bond.

(
b) Car
ryoutt
hef
oll
owi
ngt
ransf
ormat
i anyt
ons.( hree) 6
 i
)Pr
openetoPropanol
.ii
)But
-2-
enetoacet
aldehy
de.i
v)But
-2-
enet
oci
s
-
but
an-
2,3-di
ol v)Ani
li
netoni
tr
obenzene

Whathappenswhen

(
c) i
) Gl
yoxal
ist
reat
edwi
thconc.NaOH 4

i
i
)Et
hyl
acet
oacet
atei
str
eat
edwi
thLi
AlH4

(
d) Pr
epar
ePar
acet
amol
from ni
tr
obenzene. 2

Sl
.No. Quest
ions Mar
ks

Defi
necompressi
bil
i
tyf
act
or(
Z).Pl
otZv
sP(
pressur
e)f
ori
deal
gas
10.
(a) 1+2
andalsoCO2gas.

ThevaluesofvanderWaal ’
sconstant‘
a’oft
wogasesAandBar e1.
39
(
b) and4.17atm.L2.
mol-2
r especti
vel
y.Whi
chgascanbeli
quef
iedeasi
ly
? 3
Canthisgasbeliquefiedbey ondit
scri
ti
calt
emper
atur
e?

(
c) Whati
stheusef
ulnessofEl
l
ingham di
agr
am? 2

Theemfofthecel
lPt,H2(
1at
m)/H+//
KCl(
1M),
Hg2Cl2(
s)/Hg(
Pt )i s0.52V
(
d) at298K.Cal
cul
atethepHoftheunknownsol
uti
on.GivenEOcalomel=0.
28 4
V.

(
e) Whatar
esof
taci
dsandsof
tbases? 3

11.
(a) Whi
choutofNH3andNF3hashi
gherdi
pol
emomentandwhy
? 2

Whatdoyoumeanbyef
fect
ivenucl
earchar
ge?Cal
cul
atei
tfor3d
(
b) 1+2
el
ect
ronofCr
.

Wr i
teashortnot
eoni)i
onexchangeresi
nmethodforr
emovalof
(
c) hardnessofwateri
i
)n-t
ypeandp-t
ypesemiconduct
ori
i
i)Di
elsAl
der 3×3
reacti
on

(
d) Whati
sthesi
gni
fi
canceoff
reeener
gy? 1