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Certificate of Analysis
Product Name: CYPERMETHRIN
PESTANAL, analytical standard
Product Number: 36128
Batch Number: BCCB1117
Brand: Sigma-Aldrich
CAS Number: 52315-07-8
Formula: C22H19Cl2NO3
Formula Weight: 416.30
Expiration Date: MAR 2024
Quality Release Date: 24 APR 2019

TEST SPECIFICATION RESULT

APPEARANCE (COLOR) COLORLESS TO YELLOW TO BROWN- VERY FAINT YELLOW
-YELLOW AND WHITE TO YELLOW

APPEARANCE (FORM) VISCOUS LIQUID OR SEMI-SOLID OR VISCOUS LIQUID

PASTE OR SOLID

PURITY (HPLC AREA %) ≥ 90.0 % 99.0 %

REFRACTIVE INDEX N20/D 1.5550 - 1.5750 1.5673
WATER ≤ 1.0 % 0.25 %
PROTON NMR SPECTRUM CONFORMS TO STRUCTURE CONFORMS

Dr. Claudia Geitner

Manager Quality Control
Buchs, Switzerland

Sigma-Aldrich warrants that at the time of the quality release or subsequent retest date this product conformed to the information contained in this publication. The current

specification sheet may be available at Sigma-Aldrich.com. For further inquiries, please contact Technical Service. Purchaser must determine the suitability of the product

for its particular use. See reverse side of invoice or packing slip for additional terms and conditions of sale.

Sigma-Aldrich Certificate of Analysis - Product 36128 Lot BCCB1117 Page 1 of 2

 36128 Cypermethrin

Lot Number: BCCB1117 Sample Name: T58339_003_LC

Dionex Ultimate 3000 RSLC

Pump : LPG-3400RS Injection Time: 21.03.19 17:43
Autosampler: WPS-3000 Processed By: Markus Urthaler
Detector: VWD-3400 Vial Number: GB3
Column: Supelco Ascentis Express C18, 2.7 um Column S/N: -
Column Dim.: 150 x 2.1 mm Sample Type: unknown
Mobile Phase: Injection Volume: 1.0 µl
%A : Acetonitrile Flow: 0.40 ml/min
%B : Methanol Column Temp. (°C): 40.0
%C : Water Run Time: 60.00 min
%D : Phosphoric acid 0.01M
Gradient : see Figure 1
Sample Prep.: 1 mg sample in 1 ml acetonitrile

100 T58339_003_LC UV_VIS_1

mAU WVL:210 nm

17* - 38.674
25.349
25.430
1 -- 25.054
- 25.812

Phosphoric acid 0.01M: 50.0 %

80
Isomer2
Isomer3
Isomer4
8*---Isomer

16* - 30.984
15* - 28.964

60
9*
10*
27.298
7*

27.405
14 -- 27.683
26.988

0.0
Water: 0.0 %
6 - 24.274
5 - 22.239

12*- -

100.0
13*

40
11*
4* - 17.859
3* - 9.849
2 - 8.868
1* - 7.695

20

Methanol: 50.0 %
Flow: 0.400 ml/min

min
-10
0.0 10.0 20.0 30.0 40.0 50.0 60.0

Figure 1: Zoomed Chromatogram

No. Ret.Time Peak Name Area Height Amount Rel.Area

min mAU*min mAU %
1 7.695 n.a. 0.05845 0.56208 n.a. 0.03
2 8.868 n.a. 0.18551 1.67324 n.a. 0.11
3 9.849 n.a. 0.04443 0.47058 n.a. 0.03
4 17.859 n.a. 0.12777 1.18748 n.a. 0.07
5 22.239 n.a. 0.34053 3.24461 n.a. 0.20
6 24.274 n.a. 0.31848 3.14410 n.a. 0.19
7 25.054 Isomer 1 36.18284 409.93792 n.a. 21.23
8 25.349 Isomer2 63.76459 689.82733 n.a. 37.42
9 25.430 Isomer3 25.84134 377.93576 n.a. 15.16
10 25.812 Isomer4 42.85738 484.39597 n.a. 25.15
11 26.988 n.a. 0.09510 1.14157 n.a. 0.06
12 27.298 n.a. 0.20198 2.38658 n.a. 0.12
13 27.405 n.a. 0.07936 1.07837 n.a. 0.05
14 27.683 n.a. 0.12575 1.43561 n.a. 0.07
15 28.964 n.a. 0.05607 0.79218 n.a. 0.03
16 30.984 n.a. 0.07345 1.12428 n.a. 0.04
17 38.674 n.a. 0.06040 1.20630 n.a. 0.04
Total: 170.41343 1981.54396 100.00
Table 1: Integration

Sigma-Aldrich Certificate of Analysis - Product 36128 Lot BCCB1117 Page 2 of 2