Name: Wandya Daniel

St#: 218057822

1. The separation between the innermost line of the P branch and the innermost line of the R
branch.
R=20 cm−1 P=20 cm−1
Therefore: 2 B=20 cm−1
2 B 20 cm−1 −1 −1
B= = =10 cm =1000 m
2 2
h (6.626 ×1 0−34 J s−1 )
i= = 2 =2.8× 10− 47 Kg m2
8 πBC 8 π (1000 m−1)(2.998× 10 8 m/ s)
M H × M Cl 10−3
The reduced mass: μ= ×
M H + M Cl N A
( 1.008 ) ( 34.97 ) 1 0−3
¿ ×
(1.008 )+ ( 34.97 ) ( 6.022 ×1 023 )
¿ 1.63 ×1 0−27 Kg
I
re=
√ μ
( 2.8 × 10−47 Kg m2 )
¿
√ ( 1.63× 1 0−27 Kg )
¿ 1.31× 10−10 m
¿ 1.31 A °
¿ 0.13 nm
−1 −1
2. The value fundamental vibration frequency V 0.1=2885 c m =288500 m
1 K
SinceV o .1 =
2 2 2
K=v 4 π c μ
2 πC
×
√
μ

¿¿
¿ 481.4 N m −1