ANALYTICAL EXPLANATIONS

Practice Set 15 4. ( ) The angle of deviation 7. ( ) In case of sonometer

is the measure of angle between wire, (fundamental frequency)
1. ( ) The value of maximum incident ray and refracted or 1
current due to induced emf will be reflected ray measured in µ
1 df length
given by|i| = anti-clockwise sense.
R dt n1 : n2 : n3 = 1 : 2 : 3
No deviation occurs on interfaces 2 and 3
The flux linked with the ring due to as there is no change in medium. 1 1 1
solenoid is MI0 t . Also, the induced emf \ l1 : I2 : I3 = : : = 6: 3:2
However, deviation at interface 4 is same 1 2 3
(back emf) due to the inductance in the
as it was on interface 2 with only prism P. 110
ring is zero, because when \ l1 = ´ 6 = 60 cm
dl Q 11
current will be maximum , =0 1 2 4
dt 110
P 3 R l2 = ´ 3 = 30 cm
I d m I0 11
\ Current in the ring = ( M I0 t ) =
R dt R \ Bridges should be placed from A at
5. ( ) When a sphere is 60 cm and 90 cm.
2. ( ) We know that,
dropped in a liquid with density
GM G é4 ù 8. ( ) f1 = f for no rotation of bottom
g = = pR 3d ú greater than that of liquid, then
R2 R 2 ëê 3 û cylinder …(i)
after sometime sphere will attain a
where, d = mean density of the earth. constant velocity with viscous force FBD of top cylinder,
For planet,
G é4 ù is equal to the weight of sphere. N N
g¢= ´ pR ¢32d ú
( R ¢)2 êë 3 û When the sphere acquires terminal 30°
velocity, the upward viscous force equals
Given that, g = g ¢ the apparent weight in glycerine.
Therefore, Therefore, the magnitude of the viscous f f
G é4 ù G 4 force is (here r is the radius of the sphere)
Þ ´ pR 3d ú = ´ pR ¢3 (2d ) 30° 30°
R 2 êë 3 û ( R ¢)2 3 4
F = p r 3 ( x - y) g
æRö 3
Solving, we get R ¢ = ç ÷
è2 ø m æ yö Mg
= ( x - y) g º mg ç 1 - ÷
3. ( ) Bulk modulus, x è xø
2 N cos 30° + 2 f sin 30° = Mg …(ii)
Pressure
B= 6. ( ) Intensity at angle q is given by FBD of bottom cylinder (left one)
DV / V
I = I0 cos 2 q
Pressure
Þ DV = ´V [q is angle with normal] f
B
DV 10 8
1 \ Incident intensity = 9 ´ cos 2 45°
Þ = ´1= …(i)
V 160 ´ 10 9 16 ´ 10 2 9
=
W / cm2 30°
DV 2 f1
Now, = g × Dt = 3 a ( Dt )
V 9
Now, incident energy = ´ time ´ area N
[ coefficient of volume expansion 2 Mg
= 3 ´ coefficient of linear expansion] 9
DV = ´ 30 ´ 60 ´ 5
2 N sin 30° = f1 + f cos 30° ...(iii)
Þ = 3 ´ a ´ Dt …(ii)
V 81 ´ 1000 Solving Eqs. (i), (ii) and (iii), we get
From Eqs. (i) and (ii), we get = J
2 Mg
1 1 N=
Dt = ´ Since, surface is reflecting. 2
16 ´ 10 2 3 ´ 2.5 ´ 10-5 Mg
1 So, momentum transferred is f =
= = 8.3 ° C » 8 ° C 2u 2 (2 + 3 )
1.2 ´ 10-1 p=
c
TEST Edge Question based on 81000 1 9. ( ) Here, when body will
thermal stress and thermal p=2 ´ ´ detach itself from sphere, then
2 3 ´ 10 8
expansion can also be asked in the value of normal reaction will
examination. Students are advised = 2.7 ´ 10 -4 kg m / s become zero at that instant.
to study all concept related to At angle q, the body will have speed given
expansion and its proper Momentum, p = mv = 9 ´ 10 -4
by
application.
2.7 ´ 10 -4 1
Þ v = = 0.3 m / s mv 2 = loss of potential energy
9 ´ 10 -4 2
 14. ( ) When temperature of
R P3
an object like disc, ring etc., are
q h
R increased then its mass will move
q 90-q
P1 P2 apart and hence moment of inertia
1 increases.
mv 2 = mg ( R - R cos q)
2 Angular momentum of isolated rod would
= mgR (1 - cos q) remain constant. I1 w1 = I2 w 2, …(i)
v 2 = 2 gR (1 - cos q) ...(i) Now, moment of inertia of rod i .e., I µ l 2
Let the initial intensity of light is I0. So,
Forces acting on body are shown below intensity of light after transmission from Since rod is heated which would lead to
N I its expansion.
first polaroid = 0 .
2 I
Therefore, I1 < I2 or 2 > 1
q q Intensity of light emitted from P3, I1
mg I w1 I
I1 = 0 cos 2 q Also, = 2 [from Eq. (i)]
2 w2 I1
N is normal reaction acting along radius
vector and mg is weight. Intensity of light transmitted from last w1
Þ > 1 Þ w1 > w 2
polariod, i.e. from w2
Centripetal force is given by
P2 = I1 cos 2( 90°- q)
Fc = ( mg cos q - N ) 15. ( ) Magnetic field due to
I0
mv 2 = cos 2 q × sin2 q infinitely long wire at a point near
Also, Fc = = 2 mg cos q – N ...(ii) 2
R one of its ends and at a
I I
So, using Eqs. (i) and (ii), we get = 0 (2 sin q cos q)2 = 0 sin2 2 q perpendicular distance R is given
8 8
m ´ 2 g (1 - cos q) = (mg cos q - N ) by
12. ( ) Suppose m is the mass of each piece m i
When body losses contact, then N = 0 flying off perpendicular to one another B= 0
So, 2 mg (1 - cos q) = mg cos q 4pR
with same speed u( = 30 m/s ). Then, 3m
z
Þ cos q = 2 / 3 is the mass of the third piece. Let v be the
Now, h = R cos q = 3 ´ 2 / 3 = 2 m velocity of the third piece.
mu i/2
10. ( ) Refraction at P, mu Ö2
sin 60°
= 3 y
sin r1 45º O
3mv sin q mu P i/2
1 (0, –a, 0)
Þ sin r1 = 135º i
2 q
3mv
Þ r1 = 30° x
3mv cos q
Magnetic field at the point P due to
According to conservation of linear m i
60° P current i along X-axis is 0 k, and due
momentum, we get 4pa
r1 3mv cos q = mu and 3mv sin q = mu i m i
3mv sin q mu to the current along Z-axis is 0 i
r2 Q Þ = 2 8pa
O r¢2 i2 3mv cos q mu The resultant field at P is
a Þ tan q = 1 or q = 45° 2
m 0i æ1ö 5 m 0i
Hence, 3mv cos 45° = mu 12 + ç ÷ =
3v 4pa è2 ø 8 pa
or =u
Since, r2 = r1 2 16. ( ) The maximum emf will be at mean
\ r2 = 30° Þ 30 m/s or v = 10 2 m/s position of oscillation.
Refraction at Q, (inclined at 135° with respect to From conservation of energy,
sin r2
=
1 direction of each one) mgl 1 æ ml 2 ö 2
\ (1 - cos a) = çç ÷w …(i)
sin i 2 3 13. ( ) Since, the body rolls without sliding. 2 2 è 3 ÷ø
Putting r2 = 30°, we obtain v 1
r and e = B wl 2 …(ii)
i 2 = 60° 2
Reflection at Q, w From Eqs. (i) and (ii), we get
a
r ¢2 = r2 = 30° a 3 3
e=Ba gl
\ a = 180° - ( r ¢2 + i 2 ) P 8
= 180° - ( 30° + 60° ) = 90°
17. ( ) Current at time t, in
11. ( ) No light is emitted from the second As rotation of the body must be in inductor is given by
polaroid, so P1 and P2 are perpendicular
to each other.
anti-clockwise sense, that means the
i = i0 ( 1 - e- t/ t ) , i0 is maximum
friction must act up the plane to produce
current.
an anti-clockwise torque.
 The current at time t is given by
26. ( ) This problem includes
e
i = i 0 (1 - e - t / t ), where, i 0 = B nomenclature of organic
R u
compound, Mannich reaction and
The charge passed through the battery a its optical activity. This problem
during the period t to t + dt is i dt . Thus, b
O can be answered by using
the total charge passed during 0 to t is
t t 2 ´ 2 ´ sin ( 60 - 30) nucleophilic addition reaction
Q= ò0 i dt = i0 ò0 (1 - e - t / t ) dt So, T =
g ´ cos 30°
followed by elimination and further
t nucleophilic addition reaction,
é e -t / t ù 4 ´ sin 30°
= i 0 êt - ú = including concept of umbrella
ë - 1 / t û0 3 inversion to deal optical activity.
10 ´
-1 2
= i 0 [t + t (e - 1)] = i 0 t / e Mannich reaction When formaldehyde
4
= = 023
. s and methyl amine are treated with phenyl
TEST Edge Question may also 10 3 methylketone, it produces b-amino
come in which capacitor is present 22. (5) FBD of given system is carbonyl compound. The reaction
in place of inductor. proceeds as
N
18. ( ) As, q = CV = C ( BvL ) = 80 mC H CH3 H
C O+ N C O
= constant m 2 kg
H H H
7 kg 4 kg H CH3
Magnetic force on electrons of the N
conducting rod PQ is towards Q. f m=0.50 H
Therefore, A is positively charged and B is H
(7+m) g (2+4) g
negatively charged.
N = (7 + m) g
19. ( ) When a block is tied to a vertical H + CH3 H OH
spring, f = mN = 0.50 (7 + m) g C N C CH3
H H H N
For the blocks to remain at rest
Iminium salt H
6g £ 0.50 (7 + m) g
Unstretched O O
position 12 £(7 + m)
m m ³ 5 Þ mmin = 5kg CH3 OH CH2

x1 = mg/k A 23. (18) By law of conservation of

momentum,
Equilibrium v H CH3
m 400 ´ 20 + 4000 ´ 2.5 = -400 ´ 5+ 4000v 2 C N
position x ¢ = 2mg/k H H
B O
x2 = mg/k
v=0 Þ 8000 + 10000 + 2000 = 4000 v 2 CH3
m N
18 H
C Þ v 2 = 5 m/s = 5 ´ km/h =18 km/h
5
24. (2) Here, spring constant k for original (A)
So, at point C the KE of the block is zero.
spring is given by
Þ x ¢ = 2 x1 This compound is basic due to presence
So, ( F s ) ¢ = 2 ( F s )1 w = k ´9 of lone pair of N-atom.
(F ) ¢ w This compound is optically inactive,
Þ ( F s )1 = s k=
2 9 because N-atom is small and show rapid
20 As spring constant is inversely umbrella inversion, which is not detected
( F s )1 = w = = 10 N by polarimeter.
2 proportional to length, so spring constant
3
20. ( ) Projectile motion (without air for spring of 40 cm is k and that for N
2 N
resistance) has uniform acceleration
spring of 20 cm length = 3 k, spring Umbrella inversion
(acceleration due to gravity) but the
constant of combination of two shorter
vertical component of motion changes A can undergo aldol condensation due to
springs
due to gravity. presence of a-hydrogen.
3 9k 9
= k + 3k =; \ w = k( x ¢)
21. (0.23) The given question 2 2 2 27. ( ) This problem is based
is a case of projectile motion in 9 upon the concept of pH of buffer
9k = kx ¢ or x ¢ = 2 cm
inclined plane and time of flight. 2 solution.
25. (14) Frequency of 15th tuning fork is [salt]
2u sin ( a - b ) pH = pKa + log
T= . ( n - 14 ´ 3) [acid]
g cos b [C6H5 COO - ]
= 210 - 42 = 168 pH = pK a + log
We can use the formula, l 32 [C6H5 COOH]
2u sin ( a - b ) Path difference ( pr - 2 r ) = = = 16
T = 2 2 [C6H5 COO - ]
g cos b 4.7 = 4.4 + log
16 [C6H5 COOH]
r= = 14 cm
p -2
 [C6H5 COO - ] = - 20.0°). This change in optical volatile due to Intramolecular hydrogen
0.3 = log
[C6H5 COOH] properties of sucrose is called inversion bonding, while p-nitrophenol is less
of cane sugar. volatile due to intermolecular hydrogen
[C6H5 COO - ]
=2 bonding.
[C6H5 COOH] TEST Edge Hydrolysis of
different disaccharides are also OH
Let, volume of acid = V mL
0.2 ´ (300 - V ) asked including concept of
= 2 Þ V = 150 mL glycosidic linkage.
0.1 ´ V Intramolecular
30. ( ) For the given reaction, H-bonding
28. ( ) When NH3 is treated with acid it H
(CH3 ) 2 N2 ¾® C2H6 + N2 O
produces X O N
t = 0, 200 0 0 O O Intermolecular
H+
NH3 ¾® NH+4 t = t , 200- x x x N H H-bonding
[Z] [X ] O
When NH3 is treated with strong base 200 - x + x + x = 350 [Given] O
Base x = 150
NH3 ¾® NH2s
[Z] [Y ] 2.303 æp ö
k= log çç i ÷÷
Bond angles of X, Y, Z Bond angle of t è pf ø
molecule or ion can easily be understood 2.303 æ 200 ö
in terms of structure and Bent rule. k= log çç ÷÷ 32. ( ) All the isoelectronic elements do not
t è 200 - 150 ø belongs to same period.
Structure of NH +4 , NH 3, NH 2s
( Z) (Y ) 2.303 æ 200 ö e.g. Mg 2+ (having 10 e - s belong to 3rd
(X )
k= log ç ÷
H 20 è 50 ø period)
2.303 N3 - (having 10 e - s belong to 2 nd period)
N N k= ´ 2 log 2
N 20
H H H H 2.303 33. ( ) According to Graham’s law of
H H H H k= ´ 2 ´ 0.3010 effusion,
20
X Z Y rO2 nO2 M CH 4
0.693
4 bp 3bp + 1 lp 2 bp + 2 lp = = ´
10 rCH 4 nCH 4 M O2
Bond angle decreases as the number of = 6.93 ´ 10 -2 min-1 3 16 16 3
lone pair increases. = ´ ´ =
TEST Edge Similar problems 2 32 32 4 2
29. ( ) This problem can be having half life and quarter-life 34. ( ) Structure of X will be
solved by using the type of determination are also asked in JEE R R
glycosidic linkage, hydrolysis and Main. ½ ½
mutarotation. This problem HO ¾ Si ¾ O ¾ Si ¾ OH
involves conceptual mixing of 31. ( ) This problem is based ½ ½
hydrolysis of sucrose, glycosidic on conceptual mixing of chemical R R
linkage and mutarotation. property of phenol and separation Linear silicon
of products.
Hydrolysis of sucrose Sucrose on 35. ( ) This problem is based
hydrolysis produces equimolar mixture of Students are advised to complete
on conceptual mixing of
D - ( + ) - glucose and D - ( - ) - fructose the chemical reaction first and then
substitution, elimination and
C12 H22 O11 + H2O ¾® C6H12O 6 use the appropriate method to
Diels-Alder reaction.
D - (+) - glucose separate the mixture of product,
+ C6H12O 6 using concept of hydrogen This reaction will complete through
D -( - )- fructose sequential nucleophlic substitution,
Glycosidic linkage In sucrose glycosidic bonding.
elimination and Diels-Alder reaction.
linkage exist between C 1 of glucose and Chemical properties of carbolic acid
Substitution reaction Cyclic halide
C 2 of fructose Carbolic acid is phenol. Phenol on
undergo substitution reaction on reaction
OH treatment with conc. HNO 3 and
with aq. KOH.
1 O conc.H 2SO 4 produces a mixture of
O H HOH C
H 5 2 H o-nitrophenol and p-nitrophenol. Elimination reaction The elimination of
4
H 1 2 5 water molecule from alcohol occurs in
OH H H HO OH OH OH
OH O + presence of acid.
OH conc. HNO3 NO2
3 2 3 4 conc. H2SO4 Diels-Alder reaction
H OH OH H +
When a conjugated diene and alkene are
a-D-glucose b-D-fructose
o-nitrophenol
heated, it undergoes 1, 4 addition to form
Solution of sucrose is dextrorotatory NO2 a cyclic product. This is known as
(specific rotation = ± 667
. °). When p-nitrophenol Diels-Alder reaction. The alkene used in
sucrose is hydrolysed if forms equimolar this process is known as dienophile.
Separation o-nitrophenol and
quantity of D-glucose and D-fructose. The
p-nitrophenol are separated by steam
solution of formed products is found to +
distillation method due to difference in
be levorotatory (specific rotation
boiling point. o-nitrophenol is steam
 The reaction sequence for the above reaction proceeds via carbocation
37. ( ) This problem is based
reaction is as follows (formed by heterolytic cleavage). The
on conceptual mixing of benzylic
Br OH product is a racemic mixture. The
bromination, benzylic oxidation
racemic mixture is equimolar mixture of d
and nucleophilic substitution
aq. KOH H+ and l-isomer. The formation of racemic
reaction. Use free radical
I II mixture is due to planar structure of
mechanism to complete the whole carbocation which allow frontal as well as
(B)
reaction sequence. backside attack.
Benzylic bromination Benzylic
SN 2 (bimolecular nucleophilic
+ bromination of toluene can be done by its
III substitution) reaction is a characteristic
treatment with NBS in CCl 4 occurs as
property of less hindered alkyl halide
follows
which proceeds through transition state.
O O CH 3
½
(C) CH 3 — C — CH 2 — Br
N Br N + Br
½
Step I is a simple nucleophilic CH 3
substitution reaction in which nucleophile
O O
OH - substitutes the Br. NBS
CH 3
Step II is a dehydration reaction which ½ Å
produces conjugated diene. ¾® CH 3 — C — C H 2 + Br s
H H
Step III is a Diels-Alder reaction in which ½
1, 3 hexadiene and cyclopentene reacts C H C CH 3
1°-carbocation
with each other to produce tricyclic Br
H H
product.
TEST Edge Similar questions with Rearrangement
Br
conceptual mixing of counting of
number of assymetric centre and
number of optically active isomers OH CH2 Br CH 3
may also be asked, so students are [X]
½
advised to study these. CH 3 — C — CH 2
Å
½
36. ( ) While solving this Benzylic oxidation This can be done by CH 3
problem, students are advised to treating toluene with SeO 2 . 3 °- carbocation

use the concept of enthalpy of CH3 OH

reaction. H 2 O, D
D H r = D H vap + BE SeO2
1 3 CH 3
N2 ( g ) + H2 ( g ) ¾® NH3 ( g )
2 2
Hence, the best reagent used for above ½
Let, binding energy of N ºº N is x CH 3 — C — CH 2 — CH 3
conversion is aq. KOH.
x 3 ½
- 46 = + ´ 436 - 3 ´ 393 \ [ X ] = aq . KOH OH
2 2 ( ±)
x = 958 TEST Edge In JEE Main. more (A)
Racemic mixture
N2H4 (l) ¾® N2 ( g ) + 2 H2 ( g ); problems of these type are also 2nd reaction in above question is believe
D Hr = - 50 kJ / mol asked including radical mechanism to occurs via SN 2 reaction. It is as follows
D Hr = [D Hvap (N2 H4 , l)+4 ´ Binding examples are ipso reaction.
energy (N — H ) CH3 CH3
Students are advised to understand
+ BE (N ¾ N)] - [BE (N ºº N) + 2 BE the concept of Markownikoff’s s +
SN 2
(H — H )] HO C—Br HO----C----Br
Let BE (N ¾ N) = y addition reaction and
anti-Markownikoff’s addition H H H H
- 50 = (18 + 4 ´ 393 + y)
reaction. Transition state
- ( 958 + 2 ´ 436)
- 50 = (1590 + y) - 1830 38. ( ) SnCl 2 + HgCl 2 ¾® SnCl 4 + Hg CH3
(XCl 2 ) ( YCl 2 ) ( XCl 4 ) (Y)
BE (N ¾ N) = 190 kJ/ mol
Heat 1 C—OH
HgO ¾¾® Hg + O2
TEST Edge Similar problems 410 ° C 2
including concept of enthalpy of H H
So, ore will be HgS, i.e. cinnabar. (B)
neutralisation are also asked, so Inversion of
students are advised to study these 39. ( ) SN 1 and SN 2 reaction SN 1 configuration
enthalpies very clearly. (unimolecular nucleophilic substitution)
 41. ( ) Reactions involved are: S Ni M i
40. ( ) This problem is based Mn =
NH4 Cl + Na 2HPO 4 S Ni
on conceptual mixing of (A )
nomenclature, preparation of ¾® NaNH4HPO 4 Weight average molecular mass ( M w )
Gilman’s reagent 1, 4 addition of Microcosmic salt S Ni M i 2
Mw =
a , b unsaturated carbonyl Heat S Ni M i
compound and optical activity. where, Ni = number of molecules,
NaPO 3
To complete the reaction, these ( B) M i = molecular mass.
+ MnO Heat Poly dispersity index (PDI) Ratio of
steps are followed:
Complete reaction involved in MnNa PO 4 weight average molecular mass and
preparation of Gilman reagent. (C ) number average molecular mass is
(Violet bead colour) known as PDI.
Now, perform 1, 4 attack of Gilman
42. ( ) DG = DG mix, DS = DS mix, Mw
reagent to substrate to yield product. PDI =
Gilman’s reagent DH = DHmix Mn
For an ideal solution, DHmix = 0, For natural polymer, PDI = 1
When CuCl and CH3 Li mixed together, it
produces Gilman’s reagent. DS mix > 0 and DG mix < 0. For synthetic polymer, PDI > 1
Mw
CH3 Li + CuCl ¾® (CH3 )2 CuLi 43. ( ) The extent of H-bonding is maximum \ >1
Mn
When Gilman reagent is treated with in H2O. In 15th group, BP of SbH 3 is
a, b unsaturated aldehyde or ketone, it maximum and minimum for PH3 . Mw > Mn
produces product through 1, 4 addition. TEST Edge Problems including
44. ( ) This problem is based
Structural formula of 6, 6-dimethyl numerical aspect of number
cyclohex-2-en-1-ol is on stoichiometry and electrolysis.
Students are advised to follow average molecular weight and mass
OH
these steps: average molecular weight are asked
frequently.
Calculate mole of Zn.
46. ( ) According to Freundlich adsorption
Then, use Faraday law of isotherm,
electrolysis to determine time of x 1
This molecule on reaction with MnO 2 log = log k + log p
undergoes oxidation to produce steady current to pass. m n
corresponding ketone as shown 100 On comparing, with equation straight line,
Moles of Zn = = 1.53 mol y = mx + c
OH O 65
1
1L of 1 M CuSO 4 solution contains 1 mol = tan 45° = 1
MnO2 of CuSO 4 . n
Þ log k = 0.60206
\ Zn + CuSO 4 ¾® ZnSO 4 + Cu
\ k = 4, n = 1
A Here CuSO 4 is the limiting reagent. x
\ = kp1/ n = 4 ´ 2 = 8
A further undergo reaction with \To deposit completely 1 mol of Cu, m
(CH3 ) 2 CuLi to give C through 1,4 addition. Electricity required = 2 ´ 96500 C TEST Edge In JEE Main question
O O Charge (Q ) 2 ´ 96500 related to adsorption isotherm at
Time, t = = s
Current ( l ) 1 low pressure and high pressure are
(CH3)2CuLi 2 ´ 96500 asked commonly. Students are
= h = 53.6 h
3600 advised to study the theory at
different condition.
A C TEST Edge Students are advised
to solve the problems related to 47. ( ) The half reactions are,
The formation of C via 1, 4 addition is due
limiting reagent, stoichiometry and [Fe ( s ) ¾® Fe 2+ ( aq ) + 2e - ] ´ 2
to transfer of CH3 from less polar
Cu ¾ CH3 bond to less electropositive mole concept, which are asked in O 2( g ) + 4 H + + 4 e - ¾® 2 H 2O
position. JEE Main frequently. 2 Fe( s ) + O 2( g ) + 4 H + ¾® 2 Fe 2+ ( aq )
O
More electropositive
45. ( ) This problem involves + 2 H 2O( l )
position conceptual mixing of weight 0.059 (10 -3 )2
E = E° - log = 1.57 V
average molecular mass, number 4 (10 -3 )4 (0.1)
Less electropositive average molecular mass and
position 48. ( ) For zero order reaction,
polydispersity index.
dx x - x2
The product C contains assymatric carbon This problem can be solved by rate = =k = 1 = 2.0 ´ 10 -2
dt dt
hence product C is optically active. writing PDI in terms of number x1 - 0.5
O
average molecular mass and mass = 2.0 ´ 10 -2
25
average molecular mass. (Here, x1 = initial concentration)
Number average molecular mass ( M n )
# x1 - 0.5 = 0.5 = 0.5 + 0.5 = 1.0 M
49. ( ) Since, the external pressure is 1.0 atm, 53. ( ) Let the equation of the two lines are 57. ( ) Given that n1 = 5, x1 = 8, s12 = 18
the gas pressure is also 1.0 atm as piston is m1 ± m2
y - y1 = ( x - x1 ) n2 = 3, x2 = 8, s 22 = 24
movable. Out of this 1.0 atm, partial pressure 1 m1 m2
due to known compound is 0.68 atm. x12 = combined mean
These lines make angle of 45°.
Therefore, partial pressure of He 5 ´ 8 + 3 ´ 8 64
\ m1 = m2 = 1 = = =8
= 100
. - 0.68 = 0.32 atm 5+ 3 8
n(He) RT also these lines pass through the point
Combined variance
Volume = ( 3, 4).
p(H)
1± 1 n1 ( s12 + D12 ) + n2 ( s 22 + D22 )
\ y-4= ( x - 3) =
. ´ 0.082 ´ 273
01 1 1 n1 + n2
= =7L
0.32
Þ y = 4 or x = 3 where, D1 = x1 - x2, D2 = x2 - x12
50. ( ) MnO -4 used = 30.6 ´ 0.1 milimol Hence, the lines which make the triangle \ D1 = 8 - 8, D2 = 8 - 8 = 0
= 3.06 ´ 10 -3 mol are x - y = 2, y = 4, x = 3 5(18) + 3(24)
Combined variance =
2 mol MnO -4 = 5 mol H 2C 2O 4 × H 2O The intersection point of these lines are 5+ 3
90 + 72 162
( 6, 4), ( 3, 1) and ( 3, 4) = = = 20 .25
Thus, 3.06 ´ 10 -3 mol 8 8
\ Area of triangle is
MnO -4 = 7.65 ´ 10 -3 mol unreacted 6 4 1 58. ( ) We have, f( x) =
1
1 1- x
(H 2C 2O 4 × H 2O) taken 3 1 1 f(1) = ¥,
2
1.651 3 4 1 \ x = 1 is point of discontinuity.
= 1.53 ´ 10 -2 mol 1 x-1
108 1 If x ¹ 1, f[f( fx )] = =
= [½6 (1 - 4) - 4 ( 3 - 3) + 1 (12 - 3)½] 1
2 x
Used H 2C 2O 4 × H 2O by 1-
1 1 1- x
= (| - 18 - 0 + 9|] = ´ 9
MnO 2 = (1.53 ´ 10 -2 - 7.65 ´ 10 -3 ) 2 2 \ x = 0, 1 are points of discontinuity of
9 f [f ( x )]
= 7.650 ´ 10 -3
mol = square units
2 If x ¹ 0, x ¹ f [f ( fx )], then
1 mol H 2C 2O 4 × H 2O º 1 mol MnO 2 2 F ( n) + 1 1
54. ( ) Suppose that F ( n + 1) = f[f( fx )] = = x
\ 7.65 ´ 10 -3 mol H 2C 2O 4 × H 2O 2 x-1
1 1-
F ( n + 1) - F ( n) = x
= 7.65 ´ 10 -3 mol MnO 2 2 \ Point of discontinuity are 0 and 1.
= 7.65 ´ 10 -3 ´ 87 g pure MnO 2 Hence, given series is in AP with common 59. ( ) We know that the vectors are
1
= 0.6655g in 0.81g impure MnO 2 difference and first term being 2. coplanar if
2
a 1 1
\ Percentage of pure \ F (101) is 101 th term of an AP.
0.6655 1 b 1 =0
MnO 2 = ´ 100 = 82.16% 1 1 1 c
0.81 Hence, F(101) = 2 + (101 - 1)
2
51. ( ) Since, 2 < e < 3, 3 < p < 4 By C 2 - C1 and C 3 - C1, we get
= 2 + 50 = 52 a 1- a 1- a
and 3 < p2 - 6 < 4
55. ( ) Since any week day is possible for the D = 1 b-1 0 =0
\ The given determinant reduces to birthday of the person, so each person
1 0 c -1
2 3 3 has 7 choices.
3 3 2 \ n (S ) = 7 ´ 7 ´ 7 ´ 7 ´ 7 = 7 5 Þ a ( b - 1) (c - 1) - (1 - a )
3 2 3 (c - 1) - (1 - a ) ( b - 1) = 0
We have to select two persons out of 5.
Dividing by (1 - a ) (1 - b ) (1 - c ), we get
= 2 ( 9 - 4) - 3 ( 9 - 6) + 3 ( 6 - 9) Other person can have birthday other a 1 1
= 10 - 9 - 9 = - 8 than sunday so they have 6 choices. + + =0
1- a 1- b 1- c
52. ( ) Here, the given function is n( E ) = 5C 2 ´ 6 ´ 6 ´ 6
1 1 -a
n ( E ) 5C 2 ´ 6 ´ 6 ´ 6 Þ + =
f ( x ) = x 3 + 3 ( a - 7 ) x 2 + 3 ( a 2 - 9) x - 2 1- b 1- c 1- a
P( E ) = =
Differentiating w.r.t x, we get n (S ) 75 1
Adding on both side, we get
f ¢ ( x ) = 3 [ x 2 + 2 ( a - 7 ) x + ( a 2 - 9)] 10 ´ 6 3 1- a
=
f ¢ ( x ) = 0 Þ x = 7 - a ± 58 - 14a 75 1 1 1
Þ + + =1
The maximum corresponds to the smaller 56. ( ) Let z1 = x1 + iy1 1 - a 1 - b 1- c
roots and z2 = z1 60. ( ) The curves are given as
7 - a - 58 - 14a > 0 z1 + z2 = z1 + z1 C1 : y = x 2
(7 - a )2 > 58 - 14a Þ a > 3 z1 + z2 = ( x1 + iy1 ) + ( x1 - iy1 ) C 2 : y = - x2
29 z1 + z2 = 2 x1
But 58 - 14 a ³ 0 Þ a £ æ 3ö
7 which is real. C 3 : y2 = 4 x - 3 = 4 ç x - ÷
è 4ø
 Since, ÐPAQ = ÐPBQ = a {angles in the 67. ( ) a £ a 3 is not true for all a Î R
same segment are equal}
\ not reflexive.
Þ PQAB is a cyclic quadrilateral 3
1 æ1ö
(1, 0) Also, For example 1£
/ ç ÷
2 è2 ø
3,0 Ð PAB = a (given)
a £ b3 Þ
/ b £ a 3 so not symmetric and
4 ÐPQB = a {angles in the same
segment} a £ b 3 and b £ c 3 does not imply a £ c 3,
Now, ÐPBQ = a = Ð PQB so not transitive. For example, take
Þ Ð ABQ = Ð AQB = 90° - a a = 10, b = 3, c = 2 .
Area of the required region, 68. ( ) 3a - 2 b + 5c = 0
Þ AB = AQ
k = 2 é ò x 2dx - ò 4x - 3ù
1 1
êë 0 3/ 4 úû Þ ABQ is an isosceles triangles. 3 2
a- b+c=0
AB BQ 5 5
é 1 é 3 ù ù
1
Also, =
ê é x3 ù ê 2 æ 4x - 3 ö2ú ú sin ( 90°- a ) sin2 a Therefore, ax + by + c = 0 always
k = 2 êê ú - ç ÷
3 ê3 è 4 ø ú ú Þ 2 AB sin a = B Q æ3 2ö
êë û0 ë û 3/ 4 úû passes through the point ç , - ÷.
ë AB 1 1 è 5 5ø
é 1 ù 1 1 Þ = = cosec a
k = 2 ê - 0ú - [1 - 0] = BQ 2 sin a 2
ë3 û 3 3 69. ( ) lim (log 2 2 x)log x 5
x ®1
1
64. ( ) Given that,
9 k is equal to 9 ´ = 3. dy y = lim (log 2 2 x - 1) × log x 5
3 = e x ®1
dx 2 y log y + y - x
61. ( ) Equations of given lines are = lim (log 2 2 x × log x 5 - log x 5)
dx 2 y log y + y - x
3x + y + 1 = 0 = e x ®1
dy y
and x + 3y + 1 = 0 æ log 2 5 log 2 5 ö
= lim çç log 2 2 x × - ÷
log 2 x log 2 x ÷ø
dx x
Equations of angle bisector = 2 log y + 1 - e x ®1 è
dy y
3x + y + 1 x + 3y + 1 é æ log 2 2 + log 2 x ö
=± dx x log 2 5 ù
Þ + = 2 log y + 1 = lim ê çç ÷÷ log 2 5 - ú
3 +1
2
12 + 3 2 dy y e x ®1 ëè log 2 x ø log 2 x û
æ 3x + y + 1ö æ x + 3y + 1ö It is linear equation in x and y. é log 5 + log 2 x log 2 5 - log 2 5 ù
ç ÷=± ç ÷ = lim ê 2
è 10 ø è 10 ø 1 ú
ò dy e x ®1 ë log 2 x û
a1 a2 + b1 b 2 = ( 3) (1) + (1) ( 3) IF = e = y y
= lim log 2 5 = elog 2 5
a1 a2 + b1 b 2 = 6 > 0 d e x ®1
( xy) = 2 y log y + y
dy
Bisectors of obtuse angle is 70. ( ) Here, x 2 + bx + c > 0 " x Î R
3x + y + 1 = x + 3y + 1 y2
xy = 2 ò y log ydy + +C
2x- 2y = 0Þ x - y = 0 2
n- 3 é y2 y2 ù y2
æ 1 ö Þ xy = 2 ê log y - ú+ +C
62. ( ) The given expression is ç x + ÷ ,
è x2 ø ë2 4û 2
n- 3
Þ xy = y 2 log y + C \ D<0
æ 1 ö
then the general term of ç x + 2 ÷ is Þ b 2 < 4ac
è x ø
65. ( ) r × ( 3 i - j + k ) = 1 and
k
n- 3 n- 3- k æ 1 ö Condition
tk + 1 = Ck x ç 2÷ r × ( i + 4 j - 2k ) = 2 are plane whose
Values Possible
èx ø of
2
<4 value of
n- 3
Þ tk + 1 = C k x n - 3 ( k + 1) normals are n1 = ( 3i - j + k ) and
1 1 < 4c c = 1, 2, 3, 4, 5, 6, 7, 8, 9
There is a term containing x , if 2r
n 2 = (i + 4 j - 2 k)
2 4 < 4c Þ c > 1 c = 2, 3, 4, 5, 6, 7, 8, 9,
n - 3 ( k + 1) = 2 r line will be perpendicular to n1 and n2
Þ n - 2 r = 3 ( k + 1), k Î N and line will be parallel to n1 ´ n2 9 < 4c Þ c >
9
3 c = 3, 4, 5, 6, 7, 8, 9
\ n - 2 r is a positive integral multiple of 3. \ n1 ´ n2 = ( 3 i - j + k ) ´ ( i + 4 j - 2 k )
4

63. ( ) From the below figure, = - 2 i + 7 j + 13 k 4 16 < 4c Þ c > 4 c = 5, 6, 7, 8, 9

B
1 25
66. ( ) cos q = x + 5 25 < 4 c Þ c > c = 7, 8, 9
a x 4
90–a x cos q = x 2 + 1
P 6 36 < 4 c Þ c > 9 Not possible
x 2 - x cos q - 1 = 0
a 7 - Not possible
For real x, cos 2 q - 4 (1) ( - 1) ³ 0
A a
cos q ³ 4 2
90–a a 8 - Not possible
Þ |cos q| > 2
9 - Not possible
Q Which is not possible
0 £|cos q | £ 1
 Number of favourable cases OA ¢ - OA + OB¢ - OB + OC ¢ - OC y + 3x + 2 = 0
= 9 + 8 + 7 + 5 + 3 = 32 = (OA ¢ + OB¢ + OC ¢) - (OA + OB + OC )
Total ways = 9 ´ 9 = 81 = 3 OG ¢ - 3 OG
0
= 3 (OG ¢ - OG ) = 3 GG ¢ (0, 7/2) =
32 5
\ Required probability = x–
81 KGG' = 3 GG' –2
3y
71. (3) Let the length of the side of cube is a, \ k=3
then coordinates of corner ( P ) opposite to (0, 5/3)
74. ( ) Number of ways of choosing 10
(–5/2, 0)
origin are ( a, a, a ). balls from infinite white, red, blue and
O (14, 0)
\Direction ratios of diagonal OP are green balls is equal to number of positive
integral solution of x + y + z + w = 10 (0, –2)
( a - 0, a - 0, a - 0) i .e., ( a, a, a ) i .e., 1, 1, 1
10 + 4 - 1 4y + x – 14 = 0
Since, a = 1, b = 1, g = 1 = C10 = 13
C10
\ a2 + b2 + g 2 = 1+ 1+ 1 13 ´ 12 ´ 11 ´ 10 ! é5 7ù
= = 286 \ b Îê , ú
10 ! ´ 3 ´ 2 ë3 2û
=3
75. (5) We can find the position of b on 5 7
72. ( ) Product of n consecutive positive So, m = and =
y-axis by ploting the line and their 3 2
integer is divisible by n.
é5 7ù
intersect on point on y-axis. \ [ m + n] = ê + ú
\greatest positive integer which divides ë3 2û
( k + 1) ( k + 2 )¼ ( k + 5) is b lie in y-axis and inside the triangle
é 10 + 21ù
5 ! = 5 ´ 4 ´ 3 ´ 2 ´ 1 = 120
formed by the line. =ê
5 7 ë 6 ûú
73. ( ) OA + OB + OC = 3 OG £b £ é 31ù
3 2 =ê ú =5
OA ¢ + OB¢ + OC ¢ = 3 OG ¢ ë6û
\ AA ¢ + BB ¢ + CC ¢