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2 m0i
15. (1) I cm = mR 2 Magnetic field due to wire I = .
5 4pR
2 7 m0i
MR 2 + MR 2 = MR 2 Magnetic field due to wire III = .
I = Ian + MR2 = 4pR
5 5 m0 i
Magnetic field due to semiconductor arc II = .
4R
Magnetic field due to wire I and II
m0i m i m i
= Ä+ 0 = 0 Ä
4pR 4pR 2 pR
m0i m0i
Btotal = Barc – Bwires = – +
2 pR 4 R
m0 i é 2 ù m0 i é 2ù
= – +1 = 1–
4 R êë p úû 4 R êë p úû
Pointed away from page.
I = Ian + MR2
21. (2) [M] = k[F]a [T]b [V]c
2 5
= MR 2 + MR 2 = MR 2 [M1] = [M1 L1 T–2]a [T1]b [L1T–1]c = M a La + c T -2+ b -c
3 3
a = 1, b = 1, c = –1 \ [M] = [FTV–1]
16. (1) Here, centripetal force will be given by the gravita- Clearly, m0 is not a dimensionless quality.
tional force between the two particles.
22. (1) Velocity of light
Gm2 2 E E 9.3
= mw R c= ÞB= = = 3.1´10 -8 T
( 2 R )2 B c 3 ´ 10 8
Gm
Þ = w2
4 R3 23. (3)
Gm
Þ w=
4 R3
If the velocity of the two particles with respect to the
centre of gravity is v then v = wR
Gm Gm
v= 3
´R =
4R 4R
1
17. (4) yµ
q Using v 2 = u 2 + 2 gh
sin 4
2
at q = 0 Þ y ® ¥ v 2 - u 2 (80)2 - (20) 2
at q = p Þ y is a small finite value. Height, h = =
2g 2 ´10
I 6400 - 400
18. (3) v d = Here, I = 5.4A, n = 8.4 × 1028 per m3 = = 300 m
neA 20
A = 10–6m2, e = 1.6 × 10–19C 24. (1) Given:
5.4 Voltage in primary coil, VP = 200 V
\ vd = = 0.4 mm/s Current in primary coil, iP = 2 A
8.4 ´ 10 28 ´ 1.6 ´ 10 –19 ´ 10 –6
q1 r12 Voltage in secondary coil,Vs = 2000 V
19. (1) = [Let r1 and r2 be two different radii] The relation for the current in the secondary coil is
q 2 r22
Vs i p 2000 2 2 ´ 200
2 2 = Þ = = = 0.2 A
so, E1 = q1 . 4 pe0 r2 Þ q1 ´ r2 = 1 so E1 = E2 VP is 200 is 2000
E 2 4pe 0 r12 q2 q 2 r12 rL rL2
20. (3) 25. (2) R0 = =
A V
2
é Lù
r êL + ú
R' = ë
10 û = 121 R
0
V 100
= 1.21 R0
In streching, specific resistance remain unchanged.
FT - 01 3
1 1
(2) Number of O atoms = ´ NA ´ 2 p=Pµ
32 M
P2 > P1 > P3
1
(3) Number of Li atoms = ´ N A ´ 1 72. (3) Electron withdrawing group increases the acidic
7 character while electron donating group decreases the
acidic character. More the number of electron withdrawing
1
(4) Number of Ag atoms = ´ N A ´1 group, more will be acidic strength.
108 Order of acidic strength
59. (1) For (2), (3) and (4) we have to take mixture of alkyl
halides and hence many side products will also form along OH OH OH OH
with main products. NO2
60. (1) Prussian blue Fe 4 [Fe(CN) 6 ]3 is formed in > > >
Lassaigne test for nitrogen.
(–M) NO2
6NaCN + Fe2+ ¾® Na4[Fe(CN)6] + 2Na+ (Intra molecular (–1)
xH O NO2 H-bonding)
3Na4[Fe(CN)6] + 4Fe3+ ¾¾¾®
2
CH3
|
74. (2) H3C - C - CH 2 - CH = CH 2 NO2 OCH3
|
CH3 83. (1) Crystallization of sucrose solution. Entropy is a
This is the hydrocabon with 7 carbon atoms containing measure of randomness during the crystallisation of
a neopentyl and a vinyl group. sucrose solution liquid state is changing into solid state
75. (3) Molarity include volume thus with increase in hence entropy decreases.
temperature volume increases, hence molarity decreases DH fus
while in case of molality mass of solvent is taken, which is 84. (2) At Melting Point DSfus =
not affected by temperature. T
76. (3) The size of halogen atom increases from F to I hence DH 9.95 ´1000
bond length from C – F to C – I increases. ÞT= = = 278.7 K
DS 35.7
\ Bond enthalpy from CH3 – F to CH3 – I decreases. 85. (3) According to VSEPR theory.
77. (4) Given Kb = 1.0 × 10–12 86. (3) Reactions (1) and (2) are decomposition reactions.
[BOH] = 0.01 M [OH–] = ? Reaction (4) is displacement reaction, while reaction (3) is
B + + OH -
BOH an example of metal displacement reaction.
t =o c 0 0 DT f = K f ´ molality
teq c(1- x) cx cx 87. (2)
x ´ 1000
2 2 2 2 Þ 10 = 1.86 ´
c x cx 0.01x 92 ´ 600
Kb = = Þ 1.0 × 10–12 =
c(1 - x ) (1 - x) (1 - x ) Þ x = 296.8g » 297g
On calculation, we get, x = 1.0 × 10–5 88. (4) Due to inert pair effect, Pb(II) is more stable than
Now, [OH–] = cx = 0.01 × 10–5 = 1 × 10–7mol L–1 Pb(IV).
Sn(IV) is more stable than Sn(II).
é 1 ù
78. (4) hv = hv0 + mv 2 ú \ Pb(IV) is easily reduced to Pb(II) and can acts as an
ëê 2 û oxidising agent whereas Sn(II) is easily oxidised to Sn(IV)
or and can acts as a reducing agent.
1
hn = hn 0 + mv2 89. (1) CO : Neutral oxide
2 BaO : Basic oxide
1
mv2 = h ( n - n 0 ) = h Dn ...(i) Al2O3 : Amphoteric oxide
2
æ h h ö Cl2O7 : Acidic oxide
çl = ,\ v = ÷ 90. (1) According to molecular orbital theory as bond order
è mv ml ø
Substitute the value of v in equation (i) decreases stability of the molecule decreases
1 h2 Bond order =
1
(N b – N a )
m ´ 2 2 = h Dn
2 m l 2
h + 1
= Dn Bond order for O 2 = (10 - 5) = 2.5
2l 2 m 2
h 1
\ l= Bond order for O 2 = (10 - 6) = 2
2
2m Dn
- 1
79. (3) A – (ii), B – (iv), C – (i), D – (iii) Bond order for O 2 = (10 - 7) = 1.5
2
80. (1) Area under the p-V curve is maximum in the first
2- 1
option, which is equal to work done. Bond order for O2 = (10 - 8) = 1.0
2
81. (3) Si, Ge, As are metalloids and show properties in
hence the correct order is
between these of metals and non-metals.
O2+ > O2 > O2– > O22–
FT - 01 7
0.693 0.693
91. (3) k= = = 0.01 s -1 100. (2) (i) C H MgBr H SO , D
t1/2 69.35 ¾¾¾¾
2 5
¾® ¾¾¾®
2 4
O (ii) H2O OH
92. (4) Regular folding pattern of continuous portion of the (A) (B)
polypeptide chain. O
(1) O3
¾¾¾® + H
HgSO4 CH3MgBr Zn, H2O
93. (1) H2SO4 O
H2O (C)