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Polymer Testing
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Product Performance
a r t i c l e i n f o a b s t r a c t
Article history: This work investigates the behavior under burst pressure testing of a pressure vessel liner.
Received 24 February 2011 The liner was produced with a polymer blend of 95 wt.% low linear density polyethylene
Accepted 10 April 2011 (LLDPE) and 5 wt.% of high density polyethylene (HDPE). The liner is to be used in an all–
composite carbon/epoxy compressed natural gas (CNG) shell, manufactured by the fila-
Keywords: ment winding process, with variable composite thickness. Experimental hydrostatic tests
Polymer blend
were conducted on reduced scale and actual liner models. Design and failure prediction of
Pressure vessels
the composite laminate shell and the polymeric liner were conducted based on Tsai-Wu
Composites
FEA and von Mises criteria, respectively, using commercial Finite Element Analysis (FEA)
Rotational molding software. Simulation and testing were both important in order to define adequate
production parameters for the polymeric liner so that it could be successfully used in
a composite pressure vessel.
Ó 2011 Elsevier Ltd. Open access under the Elsevier OA license.
0142-9418 Ó 2011 Elsevier Ltd. Open access under the Elsevier OA license.
doi:10.1016/j.polymertesting.2011.04.016
694 E.S. Barboza Neto et al. / Polymer Testing 30 (2011) 693–700
Table 2
Mechanical properties of aluminum 6061-T6.
(melt flow index: 0.38 g/10 min @190 C/5.00 kg; density:
0.952 g/cm3; yield strength: 26.0 MPa) were used. Both
polymers were supplied by BRASKEM S.A and cryogenically
micronized.
The specimens were extruded and injected in a Thermo
Scientific Hooke Minijet II injector, with injection pressure
of 200 bar and cylinder/mold temperature of 200 C/60 C.
The extrusion of the samples was performed in a single-
screw extruder (18 mm), Ciola/MEP-18 brand with two
heating zones. The mixtures were pelletized in an auto-
matic SEIBT shredder with ACS 300 frequency converter.
The fusion temperature of the samples was 190 C. The
blend composition was chosen based on previous studies
[8] in which density, crystallinity and melting temperature
of various blends were evaluated.
Fig. 2. Composite ply stacking sequence and fiber orientations on the actual cylinder wall.
Fig. 3. Typical results for the prototype liner: (a) Curve obtained during hydrostatic pressure testing, and (b) Visual aspect of the fracture region.
696 E.S. Barboza Neto et al. / Polymer Testing 30 (2011) 693–700
Fig. 4. Hydrostatic burst pressure for the prototype liner as a function of the wall thickness: Theoretical calculation using supplier data (A) or experimental data
(-), and comparison with actual burst pressure testing (:).
The parameter (a), defined in Eq. (2), may be used to generates an output subroutine comprised of structural
compare the burst pressure performance of cylinders of geometry and winding layout parameters, stress and strain
distinct sizes, in this case, the prototype and the actual along the fiber direction and also transverse to the fiber
cylinders [10]: direction. For the purpose of failure analysis, a subroutine
was written in Python to enable evaluation of the change of
D2 d2 mechanical properties due to failure criteria.
a ¼ (2) FEA simulations of the composite pressure vessel were
1:3D2 þ 0:4d2 conducted using ABAQUS/CAE 6.8 considering linear elastic
behavior of the polymeric liner and the carbon/epoxy
where D and d are the external and the internal diameters laminate. The mechanical behavior of the component was
of the polymeric liner, respectively. estimated based on: micromechanical models (strength of
material and elasticity approach) to predict the lamina
2.4. Finite element simulation procedure properties, classical laminate theory to predict laminate
properties; elasto-plastic behavior of the liner, von Mises
The wound composite modeler (WCM) Abaqus plug-in stress criterion for the liner and Tsai–Wu failure criterion
was used to model the carbon/epoxy layers, which for the composite laminate [11].
Fig. 5. Typical results for the actual liner: (a) Curve obtained during hydrostatic pressure testing, and (b) Visual aspect of the fracture region.
E.S. Barboza Neto et al. / Polymer Testing 30 (2011) 693–700 697
Fig. 6. Hydrostatic burst pressure for the actual liner as a function of the wall thickness: Theoretical calculation using supplier data (A) or experimental data (-),
and comparison with actual burst pressure testing (:).
Fig. 7. Comparison of experimental tensile testing results (conventional and real stress) and numerical simulation of the liner.
in Table 4). It can be noted that the measured burst pressure results of the numerical simulation and the experimental
lay within the range defined using syinf and syexp values. stress-strain curves, for engineering and true stress,
Fig. 5 shows the typical response of the actual liner (wall obtained during actual tensile testing. The numerical
thickness ¼ 12.5 mm) submitted to the hydrostatic pres- simulation results were closer to the true stress curve and
sure test. Macroscopic analysis of the specimen showed the maximum axial true stress was 21.1 MPa. Thus,
initial longitudinal (brittle) rupture at the center, followed comparison of the actual elastoplastic deformation curve
by transverse (ductile) rupture at the center and at the far and the results of the numerical simulation allowed vali-
left, reaching a maximum pressure of 1.63 MPa. Thus, the dation of the numerical FEA model using the experimen-
fracture behavior of the actual liner was similar to that tally determined seexp value.
found for the prototype. Table 6 shows the variation of the numerical von Mises
Fig. 6 shows the theoretical calculations of the stress in the central region of the actual liner, for distinct
maximum pressure for the actual liner as a function of the thicknesses, when the simulated maximum hydrostatic
wall thickness, along with the experimental hydrostatic pressure is reached. It can be observed that, in all cases, von
burst pressure test result. Eq. (1) was again applied using Mises stress varies within 20–21 MPa. Fig. 8 shows the
both the yield strength reported by the manufacturer and distribution of von Mises stress for the actual liner (thick-
the measured value. However, in this case, the pressure test ness: 13.9 mm) and it is possible to verify that the central
data showed better agreement with the theoretical values section of the liner is the weakest region. Also, the burst
obtained with the measured yield strength. pressure (1.84 MPa) was very close to the experimental
In order to compare the strength values obtained for the burst pressure obtained (1.86 MPa), as shown in Table 6.
prototype liner with those obtained for the actual size liner, The same was found for the 12.5 mm-thick liner, but the
which belong to distinct size scales, the proportionality 9.5 mm and the 15.3 mm-thick liners showed poorer
relation given by Eq. (2) was used [12]. Table 5 shows this agreement (18% and 17% error, respectively).
equivalence relation of pressures, allowing comparison of
the tensile strength of the prototype and the actual liners. It
can be seen that the pressures are very close when
analyzing similar ratios, i.e. 3.1:1 to 3.2:1 thickness ratio of Table 6
Simulated burst pressure and von Mises stress for the actual liner.
the prototype and the actual liners, referring to the 3.0/9.5
and 4.0/12.5 mm wall thickness samples. e Numerical Experimental
(mm)
Burst pressure von Mises stress Burst pressure
3.2. FE liner analysis (MPa) (MPa) (MPa)
9.5 1.23 20.8 1.50
In a preliminary study, the numerical simulation of 12.5 1.62 21.0 1.64
13.9 1.84 20.2 1.86
a tensile test was conducted to validate the physical
15.3 2.00 20.9 2.40
material model chosen for the simulation. Fig. 7 shows the
E.S. Barboza Neto et al. / Polymer Testing 30 (2011) 693–700 699
Fig. 8. Von Mises stress range found for the actual liner (13.9 mm thick).
Fig. 9. Composite carbon/epoxy simulation: (a) Tsai-Wu failure analysis - ply#2, sub laminate 1, and (b) deformation at the bottom dome.
700 E.S. Barboza Neto et al. / Polymer Testing 30 (2011) 693–700
3.3. FE composite shell analysis lay-up design (thickness and stacking angles and sequence)
proposed in this study.
The 40 filament wound composite shell for the
15.3 mm-thick liner was modeled according to the stacking
Acknowledgements
sequence previously shown in Fig. 2. Analysis was carried
out considering the Tsai-Wu failure criterion and the
The authors would like to thank FINEP, CNPq, CEFET-RS,
chosen inner pressure was 20.7 MPa, with a safety factor of
Braskem, Poplast, and Plastécnica for their support.
2.0.
Fig. 9a and b present the results of the FEA simulation
for 40.0 MPa inner liner pressure. The lowest strength ratio References
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