JEE MAINS MODEL PRACTICE TEST

GRAND TEST - 3
(KEY SHEET)

PHYSICS

01) 2 02) 1 03) 2 04) 4 05) 1

06) 4 07) 1 08) 3 09) 2 10) 1

11) 4 12) 4 13) 1 14) 1 15) 1

16) 3 17) 2 18) 3 19) 1 20) 3

21) 1 22) 2 23) 2 24) 4 25) 1

CHEMISTRY

26) 3 27) 2 28) 2 29) 1 30) 4

31) 3 32) 1 33) 3 34) 3 35) 1

36) 1 37) 1 38) 3 39)3 40)2

41) 1 42) 1 43) 2 44) 3 45) 3

46) 3 47) 1 48) 2 49) 1 50) 2

MATHEMATICS

51) 2 52) 3 53) 2 54) 4 55) 1

56) 2 57) 2 58) 2 59) 3 60) 2

61) 3 62) 2 63) 1 64) 3 65) 3

66) 4 67) 1 68) 1 69) 1 70) 1

71) 2 72) 3 73) 3 74) 2 75) 2

 PHYSICS HINTS & SOLUTIONS The resultant of these forces is,
01. Sol: Since the cross sectional area of the parts
GM  1
AN and NB are in the ratio 1 : 4 , the resistance Fres  2F  F1  a 2  2  2  .
 
per unit length will be in the ratio 4 : 1 and
therefore the potential gradient in the part NB
will be four times in the part AN i.e. 4V/m. Let
CN be x meter and ND be (0.2  x ) meter. The
F
potential difference across CD, 05. Sol. A B
V  1  x  (0.2  x)4  0.5  x  10 cm .
02. Sol. Since the positive terminal of battery is
connected to P-type of both diodes D1 and D2
so they are both forward biased. These For Block A: m1g  1F
diodes are replaced by with their forward
resistance as shown in figure. 20
20  0.1  F  F   200N
100
0.1

1 2
Frictional force on block A in upward direction
 F  0.1  200  20N
Block A exert a frictional force of 20 N on block
1V 20 B in downward direction.
20
 For block B:
 2F  m2g  1F  100  20  120N .
Total current I in the circuit 06. Sol. Speed changes due to electric field only.
1 1 Velocity along x axis due to electric field at time
I  amp and is,
100  10 110
qE
1 1 1 vx  t0 ,
I1  I2    amp . m
2 110 220
03. Sol. Total heat given to convert water into steam  qE 
2
2
at 120°C is Q  mL Net speed 2v 0  v 0   t
m 
Q  1  2.2  106 J  2.2  106 J
qE 3mv 0
The work done by the system against the  3v 0  t t .
m qE
surrounding is, W  pV
07. Sol. Conceptual/Basic Question.

W  (2  1.013  106 ) (0.824  0.001) J 0.167  106 J   D  330  30 

08. Sol. fAP      f    1400 Hz .
s  330  30 
U  Q  W  2.033  106 J .
09. Sol. The total elongation in the rod can be
04. Sol. The forces acting on unit mass are clearly computed by adding the elongations in three
shown in figure. parts individually.
M M 4F 4F 3F 3F

2F 2F

F    1   2   3
F1
M
m F L
4F  L / 4 3F  L / 2 2F  4
  
GM GM AY AY AY
F and F1 
a 2
( 2a)2 FL  3 1  3FL

AY 1  2  2   AY .
  Magnetic moment,
10. Sol: Displacement = Area under velocity – time
M  I  V  I  r2
plot
 5  105  3.14  (102 )2  (10  102 )  17.70 A  m2 .
1 1
 s  (4  2)  4  (4  2)  2  6m .
2 2    
15. Sol.   M  B    MBsin  4A  m2 .
2
3
11. Sol. FAC  I  Bsin120  IB (downward) 16. Sol. 42.5% of 30eV  12.75
2
 E 4  E1  0.85  ( 13.6)  12.75 eV
3
FAD  IB sin120  IB (upward) So it means electron has been transited from
2
ground state to 3rd excited state (n  4) . So
FDC  0 . the total number of unique wavelengths
12. Sol: Q  24  18  42 c 4  (4  1)
emitted are 6.
2
3 F
4 F 17.Sol: V  E  Ir
 6 c  6 c

 18 c  18  c  V  12  10  0.24  14.4 V
 24  c  24  c
2F Energy supplied
 16 F  16  F  VI  144  5 Whr  0.720 KWhr .
 
8V
18. Sol: Let mass ‘m’ falls down by x so spring
extends by tx; which causes an extra tension
9 6 T in lowest string.
KQ  E  9  10  42  10  420 N / C
E .
r2 (30)2
13. Sol: The rate of loss of heat by the sphere is K
given by T/4

dQ
 A(T 4  T04 )
dt T/2
Where A is the surface area of the
sphere  4 r2 , with r  10cm  0.1m , T
T  327C  600K and T0  27C  300K . m

dQ x
Thus  5.67  108  4   (0.1)2  {(600)4  (300)4 }
dt

 866 Js1 .
Now dQ  msdT , where dT is the fall in T
temperature in time dt.   k(4x ) T  (16k)x
4
dQ dT dT Thus equation of motion of mass m is
 ms (or) 866  10  420  (or)
dt dt dt T  ma
dT 866 16k
  0.206C / s . a x
dt 4200 m
14. Sol. We know that,   o (1   ) Comparing with a  2 x

 4
16k
  1  6.3  10  1  500.6 We get  
o 4   107 m
Intensity of magnetisation,
 1 16k 2 k
f   .
I  H  500.6  1000  5  105 Am1 2 2 m  m
 dNB
19. Sol. Maximum angular magnification is  1N A  2NB
dt
achieved when the final image is formed at
the near point. Thus,   25 cm . The focal At t  t 0

1 1 1 1 dN B 3N0
length is f  m  10 cm . We have,    0 and NB 
10 v u f dt 2
1 1 1 3N0 1 4  
(or)    (or)  2N0 1e 1t0  2  0  t0  n  1  .
25cm u 10cm 2 1  3 2 
1 1 1 22. Sol: Point ‘P’ is outside the sphere A & B and
 
u 25 cm 10 cm (or), inside C. By applying principle of superposition
Potential at point P,
50
u cm  7.1 cm . Q1 Q2 Q3
7 V  
4  0 r 4  0 r 4  0 c .
20. Sol: We know work done by a gas is given by
the area under PV - curve or the area between 23. Sol. The forces acting on the ladder are shown
PV-curve and the volume axis. Generally we in figure.
take volume on x-axis while plotting PV-curve
N1 A
but in figure it is taken on y-axis thus the work
done is given by the shaded area shown in
figure. In this process volume of gas N2 53°
decreases thus work is done on the gas and it
is given as W
f
1 O
W    1.5  104  (2  5)  105  52.5 J C
2
For horizontal & vertical equilibrium, we get
3
V(m ) N1  f and N2  W

1 Taking torque about B, N1( AO)  W(CB)

2.5 104

W  sin53 4W 2W
2  N1  2  
1104 6 3
 cos53
The normal force by the floor is,
P(N/m2)
2 105 5 105
N2  W  (10kg) (10ms2 )  100 N
It is given that heat extracted in the process 200
is 70 cal thus The frictional force is, f  N1  N.
3
Q  70 cal  70  4.2 J  294 J
24. Sol. N x1  N 0e 10 t
Now from first law of thermodynamics, we
have Q  W  U (or) U  Q  W N x1 1 e 10t
N x 2  N 0e   t    t  e 9t
 ( 294)  ( 52.5)  241.5 J N x2 e e
Thus in the process internal energy of gas 1
decreases by 241.5 J.  9 t  1  t  .
9
1 2
A   B  C 25. Sol. y  (0.2 m) sin [kx  t]
t 0 2N0 N0
21. Sol.
t NA For x  0 , y  0.1 m
NB NC
 5
dN A  0.1  0.2sin( t)  t  or
 1N A 6 6
dt
 5  In (2), Fe 3 gets reduced to Fe 2
So t2  and t1 
6 6 In (3), I  gets oxidised to I2 .
2 1 In (4), KIO4 gets reduced from I7 to I5 .
t2  t1    1.9 ms .
3 3f
35. Sol. In O2 ( AsF6 ) , O2 has bond order 2.5. O2
CHEMISTRY HINTS & SOLUTIONS
has bond order 2.0.
26. Sol. If the potential tot he left of a given chemical
species is less than that to the right, the In KO2 , O2 has bond order 1.5.
species will undergo disproportionation. Higher the bond order, smaller is the bond
27. Sol. Equivalent of KMnO4  Equivalent of KHC2O 4 length. Hence, the order is O2 ( AsF6 )  O2  KO2 .
100 a 36. Sol.Thymine, also known as 5-methyluracil, is a
0.02  5  m  2 ––––––– (i) pyrimidine nucleobase. As the name implies,
1000 KHC2O4
thymine may be derived by methylation of
Equivalent of Ca(OH)2  Equivalent of KHC2O4 uracil at the 5th carbon.

100 b O
0.05  2  m  1 ––––––– (ii)
1000 KHC2O4
H3C
Equation (i) ÷ Equation (ii) NH
2a  b .
28. Sol.
N O
OH OH OH H
Br
Br2/Cs2
273 K O O
HN HN

(i) CHC 3  NaOH

(Minor) 37. Sol. H3C CH3
Fe/Br2
H3C CH3
Br  
(ii) dil.HC (Major)

OH X Br
(o- and p- Bromophenol)
CHO
Electrophilic substitution takes place at
electron rich positions. The ring attached with
Y
–NH will have rich electron density due to
(Salicylaldehyde) resonance. As ortho-position is blocked, the
electrophile attacks the para-position.
29. Sol. Conceptual/Basic Question.
CH2  C  CH3 CH2C  O
30. Sol. Conceptual/Basic Question. I2 /OH
   CHI3
X is O O
Tf (K 4 [Fe(CN)]6 ) 5 38. Sol.
31. Sol.  .
Tf sugar 1 COOH
K 2Cr2O7 / H2SO4

1
32. Sol. t1/2  [Here a  P ]
a n1
o o
n1
39. Sol. X  Diamond , Y  1.54 A , Z  1.42 A .
880  364 
  n  2. 40. Sol. Conceptual/Basic Question.
410  170 
41. Sol.
33. Sol. Conceptual/Basic Question.
H
34. Sol.Oxidising nature of H2O 2 means it oxidises O 
O

AC  3
CH2  CH2OH
AC 3  CH2
other substance and itself gets reduced. In such CH2
CH2 CH2  AC 3
H2SO4 / 

reactions O2 is not evolved. CH  CH2

HO  CH  CH2  C
Ph

C CH2 HOC /H
 
In (1), MnO4 gets reduced from Mn7 to Mn2
NaOH
 
O
H
 o 0.059 PA 2  mB 2  2  m A
42. Sol. ECu/Cu2  ECu/Cu2  log [Cu2 ]    4.
2 PB mA mA
If log [Cu2 ]  0 i.e. [Cu2 ]  1
62 x
o
47. Sol. % of P    100
then ECu/Cu2  E 222 w
Cu/Cu2

62 2.6
OA  0.34 V  EoCu2 /Cu  EoCu/Cu2    100  45.38% .
222 1.6
 EoCu/Cu2  0.34 V 48. Sol. 2C 2  2H2O  4HC  O2

0.059 H  B.E. of (2  C  C )  (2  2  O  H)
Now, ECu/Cu2  0.34  log 0.1
(4  H  C )  (O  O)
2

0.059  2  242.8  4  464  4  431.8  442

 0.34  V.
2  172.4 kJ mol1 .
43. Sol.More reactive halogen can displace less
reactive halogen from its salt solution. F2 can  A   3eV
49. Sol. A  e 

displace C 2 , Br2 , I2 from their salt solutions 30 3  23 kcal

while C 2 can displace Br2 and I2 from NaBr  Energy released for conversion of 10 g
and NaI. Br2 can displace only I2 from NaI. 3  23
gaseous A into A  ions   10  23 kcal .
30
 2NaBr  I2 .
2NaI  Br2 
50. Sol.  rGo   rHo  T   r So

44. Sol. In (i) CH3 is major product while  30  300  0.1  0
 rGo  2.303 RT log K  K  1 .
MATHEMATICS HINTS & SOLUTIONS
CH2 is minor product according to 51. Sol. Conceptual/Basic Question.
52. Sol. Conceptual/Basic Question.
Saytzeff’s rule.
53. Sol. Conceptual/Basic Question.
45. Sol. 1) Cr3  3d3 configuration (t1,1,1 0,0
2g  e g ) ; 54. Sol. Conceptual/Basic Question.
2,1,1 0,0
Mn3  3d4 configuration (t2g  e g ) ; (V)  3d
5 55. Sol. cos x  tan y , cos y  tanz , cosz  tan x

configuration (t2,2,1 0,0

2g  e g ) . 1  cos2 y 1  tan2 z
cos2 x  tan2 y  
cos2 y tan2 z
2)  o  strength of ligand for same oxidation
state of central metal.    
3) In carbonylate anion, the metal has a greater   3
electron density to be dispersed, with the result 4 2 4
that M  C bonding in enhanced in strength.
4) [FeIII (CN)6 ]3 ; EAN  23  12  35 2  sec2 z 2  cot 2 x  cosz  tanx 
   sec z  cot x 
sec2 z  1 cot2 x  1  
[CoII (CN)6 ]4 ; EAN  25  12  37
2sin2 x  cos2 x 3sin2 x  1
[Ni(NH3 )6 ]2 ; EAN  26  12  38 .  1  sin2 x  
cos2 x  sin2 x 1  2sin2 x
w d
46. Sol. Using PV  RT or P  RT  1  3 sin2 x  2sin4 x  3sin2 x  1
m m
3 5
3 1.5  sin4 x  3 sin2 x  1  0  sin2 x 
For gas A PA   R  T ; PB  R T 2
mA mB
 2  x  2y  4  0 , 2x  2  2y  0 and
3  5  5 1
 sin2 x     [ sinx  1]
2 x2  y2  4  9
 2 
 x  2 , y  1  x  y  3 .
5 1  5 1 
 sin x   2    2sin18 dx
2  4  59. Sol.  sec  tan   sin   (sec   cos  )
d
[ 0  x  ]
dy
 10(sec10  tan   cos9  sin  )
56. Sol. AB  BC  2x ; BD  DC  x ; AD  5x d
x AD x 1  10tan  (sec10   cos10  )
  sin   
sin  sin 45 2 5x 10 dy
dy d 10(sec10   cos10  )
   ––––– (1)
x 1 dx dx
sec   cos 
sin    d
5x 5
2 20 20
Also, y  4  sec   cos   2  4
A x2  4 sec2   cos2   2  4
2
 (sec10   cos10  )2 1  dy 
   
(sec   cos  )2 100  dx 
2x
[From eq. (1)]
45°  k  100 .
B x D x C
60. Sol. (z  1)5  (z  1)5 –––––– (1)
For z  1 , eq. (1) can be written as
sin  2
 . 5
sin  1  z 1 2ki
  1  e , k I
 z 1 
cos(sinx )  cos x
57. Sol. lim
x 0 x4 z 1
  e2ki/5 , where k  2,  1, 1, 2
z 1
 sinx  x   x  sin x 
2sin   sin  
 2   2  [For k  0 , we get 1  1 ]
 lim 4
x 0 x If we denote this value of z by zk , then

 sinx  x   x  sinx  e2ki/5  1 eki/5  e  ki/5

2sin  sin  zk  
 2  sinx  x 2 e2ki/5  1 e ki/5  e ki/5
 lim   lim  
x 0 sinx  x x x 0 x  sinx
2 2  k 
 icot   , k  2,  1, 1, 2
 5 
x  x3 
x  x   .....  
 
2  3!   Roots of eq. (i) are  icot    ,  icot  2  .
1 1 5  5
 lim 2  2  .
x 0 x4 2  3! 6 61. Sol. There are 50 factors. So, the coefficient of
58. Sol. If ‘A’ is an orthogonal matrix, then AA T  I x 49  1  3  5  ...  99 .
50
 1 2 2  1 2 x   (1  99)  2500 .
1 2
Here, AA   2 1 2 2 1 2 
T

9 1 2 1 1
 x 2 y  2 2 y  62. Sol. (cot x )  3cot x  2cot x  6  0

 (cot1 x  3)(cot1 x  2)  0
 9 0 x  4  2y 
1 Then, cot1 x  2 and cot1 x  3
 0 9 2x  2  2y 
9 
x  4  2y 2x  2  2y x 2  4  y 2 
  x  cot 2 and x  cot 3 a
  ( a  x )2 dx .
Hence, x  ( , cot 3)  (cot2,  ) . a

1 2
63. Sol. Let f1 (x )  cos (x  x ) 68. Sol. ( x 2 y 2  xy  1)y dx  ( x 2 y 2  xy  1)x dy  0
2
f1 ( x) is defined when 1  x  x  1  y dx  x dy  xy( y dx  x dy)  x 2 y 2 ( y dx  x dy)  0

1  (1  x 2 y 2 )d(xy)  xy(y dx  x dy )  0
1 5 1 5
 x and let f2 ( x)  1  x
2 2  1  dx dy
  2 2  1 d(xy)   0
x y  x y
 1 
f2 (x ) is defined when  1    0  x  1 and
 x  1
  xy  ln x  ln y  c  0
xy
1
x  1 and let f3 (x ) 
[x 2  1] x 1
 xy  ln  c.
y xy
f3 (x ) is defined when x 2  1 , x 2  2
69. Sol. The equation of the plane through the line
 x  ( ,  2]  ( 1, 1)  [ 2,  ) intersection of the planes.

  4x  7y  4z  81  0 and 5x  3y  10z  25
Then, Df  Df  Df  Df   2, 1  5  .
1 2 3
 2  If (4x  7y  4z  81)  (5x  3y  10z  25)  0
64. Sol. Required number  (4  5 )x  (7  3 )y  (4  10 )z  (81  25 )  0
10 7
 C3  C3  120  35  85 . Which is parallel to x  4y  6z  k , then
65. Sol. Let A denote the event that a bulb taken at 4  5 7  3 4  10
random is defective.  
1 4 6
10 1 We get,   1
Then, P(A)   .
100 10 Then from equation (i),
9 x  4y  6z  106  0
 P(A ') 
10
 x  4y  6z  106
5
 9  Hence, k  106 .
 Required probability    .
 10  70. Sol. Draw the figure. Clearly, centre  (0, 3 )
4
x 1 and radius  2 .
66. Sol.  x(x2
dx
 1)2 NUMERICAL VALUE QUESTIONS:
(x 2  1)2  2x 2 1 2x  ax
 2 2
dx     2 2 
dx 71. Sol. y 
x(x  1)  x (x  1)  bx
Since, (1, 1) lies on eq. (1)
1
 ln x  2 C  b 1  a
(x  1)
dy ab
 a 1 , b 1. From eq. (1), 
dx (b  x)2
a

67. Sol. Area   y dx dy ab

0 At (1, 1),  2
dx (b  1)2

Y b(b  1)
a From eqns. (2) and (3), 2
(b  1)2

 b  2b  2  b  2 .

a X
O
72. Sol. Solving given equations, we get
5
x
3  4m
x is an integer, if 3  4m  1,  5

2 4 2 8
 m , , ,
4 4 4 4
So, ‘m’ has two integral values.
y

y  ln x

3
73. Sol. x'
2 1 O 2
x
1 3

It is clear from the figure the total number of

solutions  6 .
74. Sol. 1  99n  1  (100  1)n

 1  {n C0 100n  nC1 100n1  ...  nCn }

because n is odd
 100{n C0  100n1  nC1  100n 2

...  nCn2  100  nCn1 }

 100  integer whose units place is different
from 0 (n having odd digit in units place)
75. Sol. Here, y 2  2y  1  4(x  1)

or (y  1)2  4(x  1)
So, the axis is y  1  0 . Also (–2, 1) lies on the
axis, and it is exterior to the parabola because
12  4( 2)  2(1)  3  0 . Hence, only one
normal is possible.

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