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1 Measured Concentration
1.0 (μg/L)
1.00 18.4
0.998 13.6
0.9982 13.6
0.99820 14.2
0.998203 16.0
13.6
➔ Percent error is used to 17.8
estimate the accuracy of a
measurement.
Average = 15.3 μg/L
Standard Deviation = 2.1 μg/L
What is the true concentration of As
in this experiment?
➔ Percent error will ALWAYS be 14.3 μg/L
POSITIVE
Estimate the accuracy of this
What is the percent error if the method.
measured density of titanium (Ti) is
4.45 g/cm3 and the accepted
density of Ti is 4.50 g/cm3? How precise is this method?
2.1 μg/L
Matti Mendoza
Errors
➔ Systematic (or determinate) ➔ For example, the blue line is
errors are reproducible and 2.73 cm long. This
cause a bias in the same measurement has 3 significant
direction for each figures. The first 2 digits (2.7
measurement. cm) are exactly known. The
third digit (0.03 cm) is uncertain
➔ For example, a poorly trained because it was interpolated or
operator that consistently estimated 1 digit beyond the
makes the same mistake will smallest graduation.
cause systematic error.
Matti Mendoza
➔ 16.874 / 2.6?
➔ What is average and standard
deviation for the following 3
measurements of the same
sample?
Significant figures & calculations
that require multiple steps
➔ An average is the best
estimate of the true value of a
parameter.
➔ A standard deviation is a
measure of precision.
• Averages and standard
deviations require several steps
to calculate. You must keep track
of the number of significant
figures during each step. Do NOT