b)

 Proceso a:

∆ U =n ×Cv × ∆ T

∆ U =( 3,14 mol ) ( 32 )(8,314 molJ. K ) ( 1723−273 ) K

∆ U =242,31 KJ

∆ H =n ×Cp ×∆ T

∆ H =( 3,14 mol ) ( 52 )(8,314 molJ. K ) (1723−273) K

∆ H =403,85 KJ

 Proceso b:

∆ U =n ×Cv × ∆ T

∆ U =( 3,14 mol ) ( 32 )(8,314 molJ. K ) ( 27306−172 3) K

∆ U =4275,21 KJ

∆ H =n ×Cp ×∆ T

∆ H =( 3,14 mol ) ( 52 )(8,314 molJ. K ) ( 27306−1723) K

∆ H =7125,35 KJ
 Proceso c:

∆ U =n ×Cv × ∆ T

∆ U =( 3,14 mol ) ( 32 )(8,314 molJ. K ) ( 273−27 3 06 ) K

∆ U =−4517,52 KJ

∆ H =n ×Cp ×∆ T
∆ H =( 3,14 mol ) ( 52 )(8,314 molJ. K ) ( 273−27306 ) K
∆ H =−7529,2 KJ
c)

 Proceso total ∆ U T :

∆UT= ∆Ua + ∆Ub + ∆Uc

∆ U T = 242,31 KJ + 4275,21 KJ −4517,52 KJ

∆ U T = 0 KJ

 Proceso total ∆ H T :

∆ HT= ∆ Ha + ∆ Hb + ∆ Hc
∆ H T = 403,85 KJ + 7125,35 KJ −7529,2 KJ
∆ H T = 0 KJ