CHEG 211 Chemical Engineering Thermodynamics

Solution to Exam #1
June 20, 2018

Problem 1)

1.1 ∆U = 0 = Q + W
𝑅𝑇 𝑅𝑇 𝑃 𝑃
W = −𝑃 (𝑉 − 𝑉 ) = −𝑃 − = −𝑅𝑇 −
𝑃 𝑃 𝑃 𝑃
𝐽 1 1 𝐽
= −8.314 × 298.15 − = −1983.1
𝑚𝑜𝑙 ∙ 𝐾 1 5 𝑚𝑜𝑙
𝐽
Q = −W = 1983.1
𝑚𝑜𝑙
1.2 Increased because the randomness increased.
1.3 (∆S) = −Rln = −8.314 ∙
𝑙𝑛 = 13.38 ∙
.
1.4 (∆S) = = .
= −6.65 ∙

Problem 2)
2.1

N2 H2 NH3
∆H (25 C), J/mol 0. 0. -46,110
J
∆H (25 C) = (−1)x0. +(−3)x0. +2 x(−46,110) = −92,220
mol
2.2
∆H (T) = ∆H (25 C) + υ C , dT
.
C
= A + BT + CT + DT
RT
A B, 10-3 C, 10-6 D, 105
N2 3.280 0.593 0 0.04
H2 3.249 0.422 0 0.083
NH3 3.579 3.020 0 -0.186
.
υ C , dT
.
J ∆B
= 8.314
[∆A(373.15 − 298.15) + (373.15 − 298.15 )
mol K 2
1 1
− ∆D − ]
373.15 298.15
∆A = (−1)x3.280 + (−3)x3.249 + 2x3.579 = −5.869
∆B = [(−1)x0.593 + (−3)x0.422 + 2x3.02]x10 = 4.181x10
∆D = [[(−1)x0.04 + (−3)x0.083 + 2x(−0.186)]x10 = −0.661x10
.
∫ . υ C , dT = −3155
 J
∆H (100 C) = −92,220 − 3155 = −95,375
mol

Problem 3)
. . .
∙ .
(3.1) ∆S = 1 kg × ∫ .
𝑑𝑇 + 1 𝑘𝑔 × .
= 6.99 ∙
(3.2)
.
𝐽 𝑚𝑜𝑙 𝑘𝐽 𝑘𝐽
∆H = 1 kg × 75.4 𝑑𝑇 + 1 𝑘𝑔 × 2256.9 = 2,571.0 𝑘𝐽
. 𝑚𝑜𝑙 ∙ 𝐾 0.018 𝑘𝑔 1000𝐽 𝑘𝑔
Problem 4)

. × .
4.1 ∆𝑆 = 1 ∫ .
∙
− 8.314 ∙
𝑙𝑛 = 2.286 ∙

4.2∆𝐻 = 1 × × 8.314 ∙
× (323.15 − 473.15)𝐾 = −4364.9
-1 -1
4.3 𝑆 = 0 J K s

4.4
Q
∆S − = S =0
T,
𝐽 𝑄
2.286 − =0
𝐾 ∙ 𝑠 303.15 𝐾
𝐽
Q = 693.0
𝑠
∆H = Q + W
𝐽
W = −4364.0 − 693 = −5067
𝑠
Problem 5)

5.1 S (100.5oC) = 7.3554 + (7.3315-7.3554)/(102-100) x(100.5-100)=7.349 kJ kg-1 K-1

5.2 H (100oC and q=0.8) = 419.1 x 0.2 +2676.0 x 0.8 = 2224.6 kJ kg-1