University of Engineering and Tec

Department of Chemical En
Zubair Amjad

Problem 3.32:

Calculate Z and V for ethylene at 25 0C and 12

a: The truncated virial equation with the following experimental values of vir

Symbol Value
Z ?
V ?
T 298.15
P 12
B -140
C 7200
R 83.144598

𝒁=𝑷𝑽/𝑹𝑻=𝟏+𝑩/𝑽+𝑪/𝑽^𝟐

𝑽=𝑹𝑻/𝑷⋅𝟏+𝑩/𝑽+𝑪/𝑽^𝟐

RT/P 2065.796824475

Iteraton X
1 1919.13641559284
100 1919.13641559284

Value
V 1919.13641559284
Z=PV/RT 0.929005405011488
(b) The truncated virial equation (3.38) find value of B from the ge

𝒛=𝑷𝑽/𝑹𝑻=𝟏+𝑩𝑷/𝑹𝑻

𝑩 ̂=𝑩^𝟎+𝝎𝑩^𝟏

𝑩=(𝑩 ̂𝑹𝑻𝒄)/𝑷𝑪

Symbol Value
Tc 282.3
T 298.15
Tr 1.05614594403117
w 0.087
Pc 50.4
B0 -0.303682176219561
B1 0.002262411111445
B^ -0.303485346452866
B -141.335775411078

BY using

𝑽=𝑹𝑻/𝑷+𝑩

V 1924.46104906392
Z 0.931582925418139

(c) The RK Equation

𝒁=𝟏+𝜷−𝒒𝜷((𝒁−𝜷)/((𝒁+∈𝜷)(𝒁+𝝈𝜷)))
 𝒁=𝟏+𝜷−𝒒𝜷((𝒁−𝜷)/((𝒁+∈𝜷)(𝒁+𝝈𝜷)))

𝜷=𝜴_(𝑷_𝒓 )/𝑻_𝒓 𝒒=𝝍𝜶(𝑻_𝒓 )/(𝜴𝑻_

𝜶(𝑻_𝒓 )=𝑻_𝒓^(−𝟏/𝟐) 𝒛=𝑷𝒗/𝑹𝑻

Symbol Value

Ω 0.08664
ψ 0.42748
Pr 0.238095238095238
Tr 1.05614594403117
α(Tr) 0.973056442098974
β 0.019531932632184
q 4.54581182253896
ε 0
σ 1

Iteration X

1 0.927778151909692
100 0.927778151909692

Z 0.927778151909692
V 1916.60116003233

d: Using SRK EOS

Symbols Values

ψ 0.42748
Ω 0.08664
 ε 0
σ 1
Tr 1.05614594403117
α(Tr,w) 1.67276095879037
w 0.087
β 0.019531932632184
q 4.54581182253896

Iteration X

1 0.927778151909692
100 0.927778151909692

Z 0.927778151909692
V 1916.60116003233

e: Using PR EOS

Symbols Values

ε -0.414213562373095
ψ 0.45724
Ω 0.07779
σ 2.41
Tr 1.05614594403117
w 0.087
α(Tr,ώ) 0.972203137835783
q 5.41070090525635
β 0.017536807934645

Iteration x

1 0.921167518982305
100 0.921167518982305
Z 0.921167518982305
V 1902.94493552316
and Technology Lahore
mical Engineering
2017-Ch-44

0
C and 12 bar by the following equation:

lues of virial equation: B = -140 cm 3 mol-1 C = 7200 cm6 mol-2

units
no
cm^3 mol^-1
K
bar
cm^3 mol^-1
cm^6 mol^-2
cm^3 bar k^-1 mol^-1

^𝟐

cm^3 mol^-1

f(v)--RT/P * 1+B/V+C/V^2
1919.13641559284

Units
cm^3 mol^-1
no
om the generalied pitlzer correlation equation (3.63)

Units
K
K
no
no
bar
no
no
no
cm^3 mol^-1

cm^3 mol^-1
No

quation

+𝝈𝜷)))
+𝝈𝜷)))

_𝒓 )/(𝜴𝑻_𝒓 )

𝑷𝒗/𝑹𝑻

Units

no
no
no
no
no
no
no
no
no

Z=1+β-qβ (z-β)/(z+εβ)(z+σβ)

0.927778151909692

no
cm^3 mol^-1

RK EOS

Units

no
no
 no
no
no
no
no
no
no

Z=1+β-qβ (z-β)/(z+εβ)(z+σβ)

0.927778151909692

no
cm^3 mol^-1

R EOS

Units

no
no
no
no
no
no
no
no
no

Z=1+β-qβ (z-β)/(z+εβ)(z+σβ)

0.921167518982305
 no units
cm^3 mol^-1