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52.1 - Assemblies of two identical cyclic hydrocarbon systems are named in either of two
ways: (a) by placing the prefix "bi-" before the name of the corresponding radical, or (b)
for systems joined by a single bond by placing the prefix "bi-" before the name of the
corresponding hydrocarbon. In each case, the numbering of the assembly is that of the
corresponding radical or hydrocarbon, one system being assigned unprimed numbers and
the other primed numbers. The points of attachment are indicated by placing the
appropriate locants before the name.
52.2 - If there is a choice in numbering, unprimed numbers are assigned to the system
which has the lower-numbered point of attachment.
52.3 - If two identical hydrocarbon systems have the same point of attachment and
contain substituents at different positions, the locants of these substituents are assigned
according to Rule A-2.2; for this purpose an unprimed number is considered lower than
the same number when primed. Assemblies of primed and unprimed numbers are
arranged in ascending numerical order.
52.4 - The name "biphenyl" is used for the assembly consisting of two benzene rings.
Next:
Non-identical Ring Systems
Three or More Identical Ring Systems
Radicals for Identical Ring Systems
Radicals for Non-benzenoid Ring Systems
This HTML reproduction of Sections A, B and C of IUPAC "Blue Book" is as close as possible to the published version [see
Nomenclature of Organic Chemistry, Sections A, B, C, D, E, F, and H, Pergamon Press, Oxford, 1979. Copyright 1979
IUPAC.] If you need to cite these rules please quote this reference as their source.
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