SMJK Chung Ling Pulau Pinang

Peperiksaan Penggal 2 / 2019

CHEMISTRY PAPER 2

Form 4

Name: _______________________________( ) Time: 2 Hours 30 Minutes

School number: ________________________ Class: _________________

This question paper consists of two sections. Answer all questions in Section A in the space provided.
Answer all questions in Section B in the textpad provided.

Section A [60%]

1. Diagram 1 shows the structural formulae of compound X and compound Y.

Compound X Compound Y
Diagram 1
a. Based on the structural formulae of compound X and Y, state one similarity and one difference
among them. [2 marks]

Similarity

Difference
Compound X Compound Y

b. Given the melting point of compound Y is -138ºC while the boiling point of compound Y is
4ºC. What is the physical state of compound Y at room temperature? [1 mark]
_____________________________________________________________________________
c. Other than melting and boiling point, state one physical property of compound Y. [1 mark]
_____________________________________________________________________________
d. What is the meaning of empirical formula? [1 mark]
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 _____________________________________________________________________________
_____________________________________________________________________________
e. Write the empirical formula for compound Y. [1 mark]
_____________________________________________________________________________
f. Compound Y can react with oxygen gas to form carbon dioxide and water.
i. Write a balanced chemical equation for the reaction. [2 marks]
_______________________________________________________________________
ii. If 5.6g of compound Y react with excess oxygen gas, calculate the volume of carbon
dioxide gas formed at room condition. [2 marks]
{R.A.M. : H,1; C,12; O,16, molar volume of gas at room condition=24dm3 mol-1}

2. Diagram 2 shows a part of the Periodic Table of Elements. The symbols are not actual symbols of
elements.

A E
B D F H
C G
Diagram 2
a. What is the basic principle used in arranging the elements in the Periodic Table? [1 mark]
_____________________________________________________________________________
b. What is the position of element B? [1 mark]
_____________________________________________________________________________
c. Among elements B, D ,F and H, which element do not form oxide? Explain. [2 marks]
_____________________________________________________________________________
_____________________________________________________________________________
d. State one special characteristic of element C. [1 mark]
_____________________________________________________________________________
e. Arrange the reactivity of element E,F,and G in ascending order. [1 mark]
_____________________________________________________________________________
f. Element A and element F can form a compound.
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 i. Write the balanced chemical equation for the reaction occur between element A and
element F. [2 marks]
_______________________________________________________________________
ii. Draw the structure to show electron arrangement of compound formed. [2 marks]

3. Diagram 3 shows the apparatus set-up for cell I and cell II.

Diagram 3
a. Name all the anions present in copper (II ) sulphate solution. [1 mark]
_____________________________________________________________________________
b. State the energy change occur in [2 marks]
i. cell I: __________________________________________________________________
ii. cell II: _________________________________________________________________
c. What is the function of porous pot in cell I? [1 mark]
_____________________________________________________________________________
d. After twenty minutes, state the observation at [2 marks]
i. copper electrode at cell I: __________________________________________________
ii. copper anode at cell II: ____________________________________________________
e. Write the overall ionic equation for the reaction in cell I. [1 mark]
_____________________________________________________________________________
f. State the colour change of copper (II) sulphate solution in cell II. Explain. [3 marks]
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 _____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________

4. Sulphuric acid is a strong diprotic acid. Table 1 shows the sulphuric acid with different
concentration and pH value.

Sulphuric acid solution Concentration ,mol dm-3 pH value

M 0.100 1
N 0.001 4
Table 1
a. What is the meaning of diprotic acid? [1 mark]
_____________________________________________________________________________
b. Why the solution M and N have different pH value? [2 marks]
_____________________________________________________________________________
_____________________________________________________________________________
c. 25 cm3 of 0.1 mol dm-3 potassium hydroxide solution is put in a conical flask. Then a few drops
of phenolphthalein are added. This solution is titrated with solution M.
i. What is the colour change of the mixture at the end point? [1 mark]
______________________________________________________________________
ii. Write the balanced chemical equation for the reaction. [2 marks]
______________________________________________________________________
iii. Calculate the volume of sulphuric acid used. [2 marks]

d. Why the sulphuric acid solution is stored in a reagent bottle made up of glass,but not
aluminium? [2 marks]
_____________________________________________________________________________
_____________________________________________________________________________

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5. Diagram 4 shows the arrangment of atoms in two types of copper alloy.

Diagram 4
a. What is meaning of alloy? [1 mark]
_____________________________________________________________________________
_____________________________________________________________________________
b. Name alloy X. [1 mark]
_____________________________________________________________________________
c. State the name of atom M. [1 mark]
_____________________________________________________________________________
d. Describe what happens to the atoms when a force is applied to a bronze and a pure copper.
[3 marks]
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
_____________________________________________________________________________
e. Based on the answer in (d), state one reason for making alloys. [1 mark]
_____________________________________________________________________________
f. Magnalium is an alloy used to build aircrafts.
i. State its property that make it suitable to build aircrafts. [1 mark]
______________________________________________________________________
ii. Draw a labelled diagram to show the arrangment of particles in magnalium. [2 marks]

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6. Diagram 5 shows the zinc brush electroplating. It is used to electroplate zinc onto very large iron
supports of buildings. During the process, the zinc brush spreads a layer of concentrated aqueous
zinc sulphate over the iron surface. After electroplating, a layer of zinc forms on the surface of the
iron support.

Diagram 5
a. State all the ions present in the aqueous solution. [2 marks]
_____________________________________________________________________________
b. Write the half ionic equation for [2 marks]
i. anode: _________________________________________________________________
ii. cathode: _______________________________________________________________
c. What will happen to the concentration of zinc ions during electrolysis? [1 mark]
_____________________________________________________________________________
d. Which ion is selectively discharged if dilute aqueous zinc sulphate is used to replace
concentrated aqueous zinc sulphate during the electroplating process? Why? [2 marks]
_____________________________________________________________________________
_____________________________________________________________________________
e. Platinum brush can be used to replace the zinc brush.
i. State one benefit of using platinum brush compare to zinc brush. [1 mark]
_______________________________________________________________________
ii. Explain your answer in e (i). [2 marks]
_______________________________________________________________________
_______________________________________________________________________
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 Section B [40%]

1. When substance K is dissolved in solvent L, it forms solution M which can conduct electricity and
shows pH value 1 when tested with pH metre. When substance K is dissolved in solvent N, it forms
solution O which cannot conduct electricity and shows pH value 7 when tested with pH metre.
a. Suggest substance K, solvent L, solution M and solvent N. [4 marks]
b. Explain the differences in properties between solution M and solution O. [4 marks]
c. When calcium carbonate chips are added into solution M and solution O, compare the
observations. Write the chemical equation for the reaction occurs. [4 marks]
d. 50 cm3 of 0.1 mol dm-3 solution M is pipetted out and put into a 200 cm 3 volumetric flask to
prepare a standard solution. Distilled water is added into the volumetric flask until it reaches the
calibration mark.
i. Name the process involved and predict the pH value of solution in volumetric flask.
Explain your answer. [4 marks]
ii. Calculate the concentration of solution prepared in the volumetric flask.[2 marks]
e. A solution P which has the same concentration with solution M has pH value 4. Explain a factor
that cause the pH of solution P to be different with solution M. [2 marks]

2. Salt is a chemical substance formed when the hydrogen ion of an acid is replaced with metallic ion
or ammonium ion.
a. Eggshell, cockles and limestone contain a chemical substance called calcium carbonate salt.
i. State the type of salt in terms of solubility. [1 mark]
ii. Name the reaction to prepare the salt in laboratory. [1 mark]
iii. Describe an experiment to prepare the salt. Your description should include the
following:
 chemical substances used to prepare the salt
 procedure
 ionic equation for the reaction
[7 marks]

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 b. Ammonia is used to produce ammonium fertiliser. Under normal condition of the soil, the
higher the percentage of nitrogen by mass in a fertiliser is, the better the fertiliser will be.
i. If you are given the following fertilisers, decide which fertiliser you should choose to
improve the fertility of soil. [4 marks]
{RAM: H,1; N,14; O,16; P,31; S,32}

Fertiliser Molecular formula

ammonium nitrate NH4NO3
ammonium phosphate (NH4)3PO4
ammonium sulphate (NH4)2SO4

ii. The ammonium fertiliser you choose in b (i) can be prepared using acid X and ammonia
solution. Name the acid X. Write the chemical equation for the reaction. [3 marks]

iii. If 50 cm3 of 0.2 mol dm-3 acid X solution is added to 50 cm3 of 1.0 mol dm-3 ammonia
solution, calculate the mass of fertiliser produced. State the reactant that is in excess.
[4 marks]

_____________________________________THE END _____________________________________

Prepared by: Mr Lim SL Checked by: Miss Fazrin Verified by: Mdm Sim JN