You are on page 1of 3

Stamicarbon’s CO2 stripping process, with

Pool Condenser and Pool Reactor design,


that simplifies the plant’s overall design.

It greatly improves operability and reliability,


plus guarantees maximum production output
over the full lifetime of the plant.

Stamicarbon B.V.
Mercator 3 - 6135 KW Sittard,
The Netherlands.
P.O. Box 53 - 6160 AB Geleen,
The Netherlands.

Tel. +31 46 4237000


Fax. +31 46 4237001

communication@stamicarbon.com
www.stamicarbon.com

05-12-16 13:45

STAMI_Launch_Melt_leaflet_WEB - DEC 2016 PAGE 1/3


The LAUNCH MELT™ The LAUNCH MELT™ TheLAUNCH
LAUNCHMELT MELT™™
The TheLA
The LA
Pool Condenser at work Pool Reactor at work PoolCondenser
Condenserat atwork
work
Pool PoolRe
Pool R
Ammonia and carbon dioxide are introduced to After the pool condenser, the remaining gases and Unlike the Pool Condenser concept, the Pool Reactor concept combines the
The LAUNCH
Ammoniaand
Ammonia MELT
and carbon
carbon ™ dioxide areintroduced
dioxide are introducedtoto Afterthe
After thepoolpoolcondenser,
condenser,the theremaining
remaininggases gasesand and The LAUNCH
Unlikethth
Unlike
he high-pressure synthesis using a high-pressure a liquid containing urea and carbamate enter the condenser and reactor in a single pool reactor. This is achieved by enlarging
Pool the
Condenser
the atsynthesis
high-pressure
high-pressure work using aahigh-pressure
synthesis using high-pressure a liquid containing urea and
a liquid containing urea and carbamate enter the carbamate enter the Pool condense
Reacto
condens
ammonia pump and a carbon dioxide compressor. vertical reactor. Here, the final part of the urea the horizontal condenser so as to incorporate additional reactor volume.
The challenge
The challenge This means:
This means: Ammonia ammonia
and
ammonia carbonpump
pump and
dioxide
and a a carbon
are
carbon dioxide
introduced
dioxide compressor.
to
compressor. After the vertical
vertical reactor.Here,
pool condenser,
reactor. Here,
thethe thefinal
finalpart
remaining part ofofthe
gases the
and urea
urea thehorizo
Unlike the horizC
Pool
The ammonia then drives an ejector, which conveys conversion takes place. The urea solution then
ToToreduce
reduceinvestment,
investment,increase
increaseplantplantefficiency,
efficiency, ••Easy
Easyandandstable
stableplant
plantoperation
operationdue duetotopool
pool the The ammonia
high-pressure
The ammonia then
synthesis
then drives
using
drives an
a
an ejector,
high-pressure
ejector, which
which conveys
conveys a liquid conversion
containing
conversion takes
urea
takes place.
and
place. The
carbamate
The urea
urea solution
enter
solution the then
then condenser and re
he carbamate solution from the high-pressure leaves the top of the reactor (via an overflow funnel) As a result, it becomes possible to achieve sufficiently high residence times,
reduceoperating
The challenge
reduce operatingand andmaintenance
maintenancecosts costsand
and This means:condensationprinciple
condensation principlepool
poolreactor
reactor ammonia the
the carbamate
pump
carbamate solutiondioxide
and asolution
carbon fromthe
from the high-pressure verticalleaves
compressor.
high-pressure leavesthe
reactor. the
Here,topof
top ofthe
the the
final reactor
reactorpart (via
of(via
thean
an overflowfunnel)
urea
overflow funnel) Asaaresul
the horizontal
As resu
co
scrubber to the pool condenser. In the high- before flowing back into the high-pressure stripper. eliminating the need for a separate vertical reactor, while creating the
To reduce minimize
investment,
minimize plantincrease
plant emissions.
emissions. plant efficiency, •Well
• Easy •andWell established
stable technology
plant operation
established technology with
duewith
to pool
ananextensive
extensive The scrubber
ammonia
scrubber then
toto the
drives
the pool
pool an condenser.
ejector,
condenser. In
which
In the
the high-
conveys
high- conversion before
before takesflowing
place.
flowing back
The
back into
urea
into the high-pressure
solution
the then
high-pressure stripper.
stripper. eliminat
eliminatin
pressure stripper, the carbon dioxide, entering the Ammonia and carbon dioxide conversions in the conditions that will allow the reaction to reach its optimum condition with
reduce operating and maintenance costs and provenprinciple
condensation
proven trackrecord
track record
pool reactor pressure
the carbamate
pressure stripper,
solution
stripper, fromthecarbon
the carbon
the dioxide,entering
high-pressure
dioxide, enteringthe theleaves the Ammonia
top of the
Ammonia and
and carbon
reactor
carbon (via dioxide
an overflow
dioxide conversions
funnel)
conversions ininthe
the conditio
As a result, it bec
condition
synthesis as a feed, flows countercurrent to the urea synthesis section of a Stamicarbon carbon dioxide the advantage of having a plant height of about 30 meters.
minimize Our
Our solution
solution
plant emissions. •Compact
Compactand
• Well •established andlow
lowelevation
technology elevation
with an plant designresults
extensive
plant design results scrubber synthesis
to the pool
synthesis asasacondenser.
afeed,
feed,flows
flowsIn countercurrent
the high-
countercurrent totothe
theurea
urea synthesis
before flowing
synthesis back section
into of
section ofaahigh-pressure
the Stamicarboncarbon
Stamicarbon carbondioxide
stripper. dioxide theadvan
eliminating
the adva
the n
solution leaving the reactor. stripping plant, are particularly high. As a result
Stamicarbon’sanswer
Stamicarbon’s answerisisits itsLAUNCH
LAUNCHMELT™ MELT™ proven ininlower
tracklower constructioncosts
record
construction costs pressure solution
stripper,
solution leaving
the
leaving the
carbon
the reactor.
dioxide,
reactor. entering the Ammonia stripping
and
stripping carbonplant,
plant, are
dioxide
are particularly
conversions
particularly high.
high.in AsAs
thea a result
result conditions that w
of that, the Stamicarbon CO2 stripping process is The high pressure scrubbing operation can also be simplified in the Pool
series.Depending
Our solution
series. Dependingon onyour
yourcapacity requirements, • Compact
capacityrequirements, ••Easier
Easier
and lowmaintenance
maintenance andlonger
elevation plant
and longer time
designtime between
results
between synthesis as a feed, flows countercurrent to the urea synthesisofofthat,
that,the
section the Stamicarbon
ofStamicarbon
a Stamicarbon COCO2carbon
stripping
2strippingdioxideprocessisis
process Thehigh
the advantage
The high
of
On the shell side, the high-pressure stripper is the only commercial available process that does Reactor concept by placing the scrubber sphere above the pool reactor and
Stamicarbon’s
Stamicarbon’s answerLAUNCH
Stamicarbon’s LAUNCH
is its LAUNCH MELT™
MELT™ MELT™seriesoffers
series offers turn
in lowerturn aroundswith
construction
arounds with
costs significantreduction
significant reductionon on On
solutionOn theshell
leaving
the shell side,the
theside,
reactor. thehigh-pressure
high-pressurestripperstripperisis stripping the
the onlycommercial
plant,
only commercial
are particularly available process
high. process
available As a resultthatdoes
that does Reactorco
Reactor c
heated with steam. The off-gas of the high-pressure not require a medium-pressure recirculation stage adding the ammonia to the synthesis via this scrubber. This ensures that no
twodesigns:
two designs:
series. Depending on your capacity requirements, corrosionissues
• Easier maintenance
corrosion issues withSafurex
andwith
longer Safurex ®®
time between heated
heated with
with steam.
steam. The
The off-gas
off-gas of
of the
the high-pressure
high-pressure of that, not
the
not require
Stamicarbon
require a a medium-pressure
CO
medium-pressure
2 stripping recirculation
process is
recirculation stage
stage The high adding
pressur
adding t
th
stripper, containing the carbon dioxide, together downstream from the high-pressure stripper. separate heat exchanging section in this scrubbing operation is required.
Stamicarbon’s LAUNCH MELT™ series offers turn • •Suitable
Suitable
arounds for
with
for anytype
typeofof
significant
any plantcapacity
reduction
plant capacity (suitable
on (suitable stripper,
On the stripper,
shell side, containing
the high-pressure
containing thecarbon
the carbon dioxide,
stripper
dioxide,is together downstream
together the onlydownstream
commercialfrom fromthe
available thehigh-pressure
high-pressure
process that does stripper.
stripper. separateh
Reactorseparate
concept
with the dissociated carbamate, is then fed into In the Pool Reactor concept, carbamate from the low pressure recirculation
1)1)AAhorizontal
two designs: horizontalhigh-pressure
high-pressurePool PoolCondenser
Condenser corrosion forissues
for lowand
low andwithhighest
Safurex
highest singleline
single
® linecapacities)
capacities) heated with
with the
steam.
the dissociated
The
dissociated off-gascarbamate,
of
carbamate,the isis then
high-pressure
then fed
fed into
into not require a medium-pressure recirculation stage adding In Inthe
the the
amm Po
Poo
he pool condenser, where ammonia and carbon Gases leaving the reactor are fed into the high- section flows together with the absorbed gases and the ammonia into the
combinedwith
combined withaavertical
verticalreactor
reactor • Suitable for any type of plant capacity (suitable stripper,the pool
containing
the condenser,
pool condenser,the carbon where
where ammonia
dioxide,
ammonia and
together carbon
and carbon downstream Gases
Gases from leaving
leaving thethethe reactor
high-pressure
reactor are fed are fed into
stripper.
into thethehigh-
high- separate section
heat exc
section fl
flo
dioxide are condensed to form carbamate. The heat pressure scrubber. Here, the gases are washed with Gaspool reactor. As the static liquid height ensures gravity flow, no high-
2)2)AAhorizontal
1) A horizontal horizontal high-pressure
high-pressure PoolReactor
Pool Condenser
high-pressure Pool Reactor for low and highest single line capacities) with the dioxide
dissociated
dioxide arecondensed
are condensed
carbamate, totoisform carbamate.
thencarbamate.
form fed into The Theheat
heat pressure
pressure scrubber.Here,
Gas scrubber. Here,the thegases
gasesarearewashed
washedwith with In theGas
Gas poolReact
Pool
pool reac
react
released by condensation and subsequent formation the carbamate solution from the low-pressure Liquid
pressure ejector is needed.
the pool released
condenser,
released byby condensation
where
condensation ammonia and
and subsequent
and carbon
subsequent formation
formation Gases the
the Liquid
leaving carbamate
the
carbamate reactor solution
are
solution fed from
frominto the
the low-pressure
high-
low-pressure Liquid
Liquid
pressure
combined Design
with
Design (for smaller
a vertical
(for smaller plantcapacities)
reactor
plant capacities) Urea solution/melt/slurry section flows
pressure toge
of carbamate is used to produce re-usable low- recirculation stage. The enriched carbamate Urea solution/melt/slurry Ureasolution
Urea solutio
2) A horizontal high-pressure Pool Reactor Steam/water ofcarbamate
dioxideofare carbamate
condensed isisused
toused
formtotoproduce
producere-usable
carbamate. re-usable
The heat low- pressure
low- recirculation
scrubber.
recirculation Here,stage.
stage. The
theThegases enriched
are washed
enriched carbamate
with
carbamate Gaspool reactor. As t
pressure steam. solution is then fed to the high-pressure ejector and, Steam/water Steam/wate
Steam/water
released pressure
by steam.
condensation
pressure steam. and subsequent formation the solution
carbamate
solution isis
solutionthen
then fed
from
fed totothe
thethe high-pressure
low-pressure
high-pressure ejectorand,
ejector and, Liquid
pressure ejector i
Design Capital investment
(forinvestment
Capital smaller plant is reduced
capacities)
is reduced due to its compact
due to its compact
subsequently, to the pool condenser. Inert gases, Urea solution/melt/sl
designwhich
design whichrequires
requireslesslessequipment.
equipment.ThisThismakes
makes of carbamate is used to produce re-usable low- subsequently,
recirculation stage.
subsequently, Thetoto the
enriched
the pool
pool condenser.
carbamate
condenser. Inert
Inert gases,
gases,
containing some ammonia and carbon dioxide, are Steam/water
Capitalthetheprocess
processsimpler
investment simpler
is reduced and
and due more
more stable
to its andyour
compact
stable and yourplant
plant pressure steam. containing
solutioncontaining
is then fedsome some
to the ammonia
high-pressure
ammonia andcarbon
and carbon dioxide,
ejectordioxide,
and, are are
then released into the 4-bar absorber. Gas
muchless
design much
which lessmaintenance
maintenance
requires intensive.
less equipment.
intensive.This makes then
subsequently,
then released
to the
released into
pool
into the
the 4-bar
condenser.
4-bar absorber.
Inert
absorber. gases,
Liquid
the process simpler and more stable and your plant Urea solution/melt/slurry
containing some ammonia and carbon dioxide, are
much less maintenance intensive. Steam/water then released into the 4-bar absorber.

LP carbamate recycle
LPcarbamate
LP carbamaterecycle
recycle

LP absorber LP carbamate recycle


Carbarnate recycle LPabsorber
LP absorber

Absorber
LP absorber Absorber
Absorber
To recirculation
To atmospheric absorber
Scrubber ToToatmospheric
atmosphericabsorber
absorber
Absorber
Poolcondenser NH₃ To atmospheric absorber
Reactor Carbarnate recycle Poolcondenser
Poolcondenser NH₃
NH₃
HP scrubber LP steam Reactor
Reactor Carbarn
Carbarna
HPscrubber
HP scrubber LPsteam
LP steam
BFW
Absorber BFW
BFW
NH3 Poolcondenser Absorber
Absorber NH₃
To recirculation NH3 3
ReactorNH Carbarnate
To LP Pool Reactor HP scrubber LP steam ToTorecyc
rec
recir
Scrubber ToToLP
LP
Ejector MP steam recirculation BFW Scrubber
Scrubber
Ejector
Ejector Absorber
MPsteam
MP recirculation
steam recirculation
NH3
MP steam To recirculation
NH₃ Stripper MPsteam
MP steam
ToNH₃
LP Poo
Stripper condensate NH₃ Scrubber
Ejector Stripper MP steam
Stripper condensate
recirculation
condensate
CO2 CO₂ MP steam
CO2 2
CO NH₃ CO₂
CO₂
Pool Reactor Stripper condensate
PoolReactor
Pool Reactor
CO2 CO₂
Stripper Pool Reactor
Stripper
Stripper

05-12-16 13:45
STAMI_Launch_Melt_leaflet_WEB.indd 6 6
STAMI_Launch_Melt_leaflet_WEB.indd
CO₂
CO₂
CO₂ Stripper

STAMI_Launch_Melt_leaflet_WEB - DEC 2016 PAGE 2/3


STAMI_Launch_Melt_leaflet_WEB.indd 6
CO₂
heated with steam. The off-gas of the high-pressure not require a medium-pressure recirculation stage adding the ammonia to the synthesis via this scrubber. This ensures that no
uitable stripper, containing the carbon dioxide, together downstream from the high-pressure stripper. separate heat exchanging section in this scrubbing operation is required.
) with the dissociated carbamate, is then fed into In the Pool Reactor concept, carbamate from the low pressure recirculation
the pool condenser, where ammonia and carbon Gases leaving the reactor are fed into the high- section flows together with the absorbed gases and the ammonia into the
dioxide are condensed to form carbamate. The heat pressure scrubber. Here, the gases are washed with Gaspool reactor. As the static liquid height ensures gravity flow, no high-
Liquid Gas
released by condensation and subsequent formation the carbamate solution from the low-pressure pressure ejector is needed.
Urea solution/melt/slurry Liquid
of carbamate is used to produce re-usable low- recirculation stage. The enriched carbamate Urea solution/melt/slurry
Steam/water
pressure steam. solution is then fed to the high-pressure ejector and, Steam/water

The LAUNCH MELT ™ subsequently, to the pool condenser. Inert gases,

Pool Reactor at work containing some ammonia and carbon dioxide, are
then released into the 4-bar absorber. Gas
Unlike the Pool Condenser concept, the Pool Reactor concept combines the condenser and reactor
Liquid
in a single pool reactor. This is achieved by enlarging the horizontal condenser so as to incorporate
Urea solution/melt/slurry
additional reactor volume. Steam/water

As a result, it becomes possible to achieve sufficiently high residence times, LP carbamatethe


eliminating recycle
need
for a separate vertical reactor, while creating the conditions that will allow the reaction to reach its
optimum condition with the advantage of having a plant height of about 30 meters.
LP absorber
Carbarnate recycle

The high pressure scrubbing operation can also be simplified in the Pool Reactor concept by placing Absorber
the scrubber sphere above the pool reactor and adding the ammonia to the To recirculation
To synthesis viaabsorber
atmospheric this scrubber.
This ensures that no separate heat exchanging section in this scrubbing operation is required. In the Scrubber

Pool Reactor concept, carbamate from the low pressure recirculation section flows together with the
Poolcondenser NH₃
absorbed
Reactor
gases and the ammonia into the pool reactor. As the static liquid height ensures gravity Carbarnate recycle
HP scrubber LP steam
flow, no high-pressure ejector is needed. BFW
Absorber
NH3
To recirculation
To LP Pool Reactor
Scrubber
Ejector MP steam recirculation

MP steam
NH₃ Stripper
Stripper condensate

CO2 CO₂
Pool Reactor

Stripper

05-12-16 13:45
CO₂

STAMI_Launch_Melt_leaflet_WEB - DEC 2016 PAGE 3/3

You might also like