NATIONAL LEVEL SCIENCE TALENT SEARCH EXAMINATION- UN472

Solutions for Class : 11 fPCMJ

Math e m atics ::::> ｮＨａｵｂＩｾＶ＠

1. (C) We have, sec e + tanS e cosec e ::::> Minimum number of elements in Au B
is 6.
=sec e ( 1 + tans e cosece) 4. (C) We have, 7 103 = 7(49)5 1= 7(50 - 1)5 1
sece
= 7(5()51 _ 51C1 5000 + 51C2 5()49 - ... -1)
= 7(5051- 51C1 5000 + 51C2 5049- ...) - 25 + 18
= SeC 8 SeC2 8 = seeS 8
= k + 18 (say), since k is divisible by 25,
= (sec2e )312 = (1 + tan2e )312 :. Remainder is 18.
Let ftx) = x and g(x) = xs. Then f(x) g(x)
= x 4, even; option (A) is false.
2. (C) Since a, b, c are in H.P.,
Let f(x) and g(x) are two even functions and
1 1 1 F(x) = f(x) + g(x)
:. a' b' c are in A.P. F(-x) = f(-x) + g(-x) = f(x) + g(x) = F(x)
1 1 2 ::::> F(x) is even, option (B) is true.
::::> -+-=-
a c b Let f(x) be an even function and g(x) be an
odd function and F(x) = f(x) g(x)
.
The given 1.me IS
. -X - + -1 = 0
+ y
a b c F(-x) = ft-x) g(-x) = f(x) (- g(x))
::::> - F(x) is odd, option (C) is true

f ( - x) + f (x) f (x) + f ( - x)
(D) g ( - x ) = =
2 2
1 1 = g(x) is even, option (D) is ture.
::::> - (x -1) +-(y +2) = 0
a b 6. (C) T 20 = (20th term of 2, 4, 6, 8, ... ) x (20th
::::> The given line passes through the point term of 4, 6, 8, ... )
of intersection of x - 1 = 0 and y + 2 = 0 = [2 + (19)(2)] [4 + (19)2] = (40)(42) = 1680
i.e., (1, - 2) which is a fixed point.
7. (B) Given statement is not true for n = 1 as
3. (D) We know that
n(A u B)= n(A) + n(B) - n(A n B) 1 < (1
- + -1
2
J. .
1.e., 1 < l is not true.
Alson(AnB)::; min {n(A),n(B)}
= min {3, 6} = 3 For n = 2, the statement becomes

::::> n(AnB)::;3 ::::> Ｍ ｮＨａｂＩｾ

::::> n(A u B)= n(A) + n(B) - n(An B)

Ｍ Ｓ＠
2 1
1 x 2< ( ; J i.e., 2 < ｾ Ｌｷｨｩ｣＠ is true.

ｾｮＨａＩ＠ + n(B) - 3 8. (C) Since each question can be deal with in 3

ways

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 a) by selecting it
sin ( γ + δ ) + sin ( γ − δ)
⇒
b) by selecting its alternative, or sin ( γ + δ ) − sin ( γ + δ )
c) by rejecting it.
cos (α − β ) + cos ( α + β )
Thus, the total number of ways of dealing
with 10 given questions is 310 including a ( ) (
= cos α − β − cos α + β
)
way in which we reject all the questions. (applying components and dividendo)
Hence the number of all possible selections
of one or more questions is 310 – 1. 2sin γ cos δ 2cos α cos β
⇒ =
2cos γ sin δ 2sin α sin β
9. (A) We have tan α + tan β + tan γ = 0
⇒ cot δ = cot α cot β cot γ
⇒ tan γ = –h, and since tan γ satisfies the
given equation. 14. (D) In case of R1, f(x) = 6x + 7

⇒ a tan3 γ + (2a – x)tan γ + y = 0 Clearly, every element of A has a unique

image.
⇒ a(–h)3 + (2a – x)(–h) + y = 0
Hence, R1 represents a function.
∴ ah3 + (2a – x)h = y
Similarly, R 2 and R 3 also represent
10. (A) Let Nisha secure x marks in the fifth test, functions.
then her average score
In case of R4, f(x) = ± 4x
87 + 92 + 94 + 95 + x 368 + x
= = ∴ Every element of A has two unequal
5 5
images.
According to given condition, we must e.g., f(1) = ± 4, f(2) = ± 8 etc.
have
∴ R4 is not a function.
368 + x
⇒ ≥ 90 15. (D) (1 + 4x)–5/4.(1 + 2x)1/2
5

⇒ 368 + x ≥ 90 × 5  5  1 
=  1 − .4 x  1 + (2 x) 
 4  2 
⇒ x ≥ 450 – 368
= (1 – 5x) (1 + x)
⇒ x ≥ 82
∴ Coefficient of x = 1 – 5 = –4
11. (B) y = ex and y = x
16. (A) Number of triangles formed with 12 points
⇒ ex = x ⇒ no x ∈ R = 12C3 = 220
Hence, A ∩ B = φ . Number of triangles formed with 5 points
= 5C3 = 10
12. (C) Solving the given equations in pairs, we
get the coordinates of the vertices as (Since, 5 points are collinear, so they
cannot form a triangle)
A = (–3, 3), B = (1, 1), C = (1, –1),
Hence, total number of triangles
D = (–2, –2) = 220 – 10 = 210

−1 − 3 4 17. (B) n(A) = n(A – B) + n(A ∩ B)

m1 = slope of AC = = − = −1
1+3 4 = 30 + x + 2x
= 30 + 3x
−2 − 1 −3
m2 = slope of BD = =− =1
−2 − 1 −3 n(B) = n(B – A) + n(A ∩ B) = x + 2x = 3x

m1m2 = (–1)(1) = –1. n(A) = 2n(B)

So, diagonals AC and BD are perpendicular. ⇒ 30 + 3x = 2.3x

π ⇒ 30 = 6x – 3x
∴ Angle between AC and BD is .
2 ⇒ 30 = 3x
13. (A) We have, cos( α + β ) sin ( γ + β ) sin ( γ – δ ) ⇒ x = 10
sin ( γ + δ ) cos (α − β )
⇒ =
sin ( γ − δ) cos ( α + β)
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18. (A) We have,
2cos5θ cos θ + 5.2cos3θ cos θ + 10.2cos 2 θ
n 2 3
(1 + x) = C0 + C1 x + C2x + C3x + C4x + ... 4 =
cos 5θ + 5 cos3θ + 10cos θ
+ Cnxn .... (1)
Differentiating w.r.t. x, we get 2cos θ(cos 5θ + 5 cos3θ + 10 cos θ)
= = 2 cos θ
n(1 + x)n – 1 = C1 + 2C2x + 3C3x2 + 4C4x3 + ... (cos5θ + 5cos 3θ + 10 cos θ)
+ nCnxn – 1 .... (2) 21. (D) Since α is a root of the equation.
Putting x = 1 in (1) and (2), we get a2x2 + bx + c = 0
n
2 = C0 + C1 + C2 + C3 + C4 + ... Cn ..... (3) ∴ a2 α 2 + b α + c = 0 .... (1)
and n 2n – 1 C1 + 2C2 + 3C3 + 4C4 + ...
Since β is a root of the equation
+ nCn .... (4)
Adding (3) and (4), we get a2x2 – bx – c = 0

(n + 2) 2n – 1 = C0 + 2C1 + 3C2 + ... + (n + 1) Cn. ∴ a2 β 2 – b β – c = 0 .....(2)

19. (C) Since, a, b and c are in A.P. Now let f(x) = a2x2 + 2bx + 2c
⇒ 2b = a + c ∴ f( α ) = a2 α 2 + 2(b α + c)
Also, p is A.M. between a and b .... (1) = a2 α 2 + 2(–a2 α 2) [from (1)]
⇒ a, p, b are in A.P. =–a α <0
2 2

⇒ 2p = a + b .... (2) f( β ) = –a2 β 2 + 2(b β + c)

Also, p ' is G.M. between a and b = a2 β 2 + 2(a2 β 2) [from (2)]
⇒ a, p ' , b are in G.P.
= 3a2 β 2 > 0
⇒ p' = ab .... (3)
Since f( α ) and f( β ) are of opposite sign and
Similarly, γ is a root of the equation f(x) = 0,
2q = b + c .... (4)
∴ γ must lie between α and β .
and q ' = bc Thus α < γ < β .

(a + b)2 1 22. (B) The given digits are 0, 1, 2, 3, 4 which are

p2 = = (a2 + b2 + 2ab); p ' 2 = ab five in number.
4 4
Since we are to form the numbers that are
(b + c)2 1 greater than 20000 and as no digits is to
q2 = = (b2 + c2 + 2bc); q ' 2 = bc be repeated, every such numbers contains
4 4
five digits and it must have 2, 3 or 4 at
1 2 2 1 2 2 extreme left.
p2 – q2 = (a – c – 2b(a – c)) = (a – c +
4 4 Thus, the extreme left place can be filled
(a + c) (a – c)) up in 3 ways.
[Q a, b, c are in A.P, 2b = a + c] Now the remaining four places can be filled
up with the remaining four digits in 4P4
1 ways. By using the principle of association,
= (a2 – c2) the required number of numbers formed
2

p ' 2 – q ' 2 = ab – bc = b(a – c) = 3 × 4P4 = 3 × 4 = 3 × 4 × 3 × 2 × 1 = 72

23. (C) Statement P, ‘Cardinality of a singleton set
(a + c) 1 is 1’, is true.
⇒ (a – c ) = (a2 – c2)
2 2
Statement Q, ‘Cardinality of a null set is 0’
is true.
∴ p2 – q2 = p ' – q '
2 2

Hence (C) is the answer.

20. (D) The given expression
24. (C) Let h be the height of the triangle.
cos 6θ + cos 4θ + 5 cos 4 θ + 5cos 2θ + 10 cos 2θ + 10
= Since, the area of the triangle is a2
cos 5θ + 5 cos 3θ + 10 cos θ

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 .. !.x ax h =a 2 ::::>h =2a
2 28. (C)
Since the base lies along th e line x = a, th e
vertex lies on the line parallel to th e base
at a distance 2a from it. So, the required
lines are
x = a ± 2a i.e., x = -a or x = 3a
25. (A) The equation reduces to
E = (-1)(-2)(-2)2.... (-2)15

29. (C) Let th e last three numbers in A.P. be b,

===> E = 2 1+2+3+...15
b + 6, b + 12 and th e first number be a .
Hence the four numbers are a, b, b + 6,
b+ 12

:. Coefficient of x 15 in E is Given, a = b + 12 .... (i)

and a, b, b + 6 are in G.P. i.e., b2 = a(b + 6)
2 1+2+3... 15 . (-1-!. __!.__··· __!_)
2 22 215 ::::> b2 = (b + 12Xb + 6) [Since a = b + 12]
or 18b = - 72

ｬ Ｈ ＭＱ Ｉ ｾ ＱＭ ＠ Ｑ
:. b = - 4
12 From (i), a = -4 + 12 = 8
=2
Ｈ ｾ Ｉ＠
0
Hence the four numbers are 8, -4, 2 and 8.
30. (A) Since, (a + ib)5= a+ i P (given)

= - 2105(216 - 1) = 2105- 2121

26. (C) We h ave, (1 + i)2n = (1 - i)2n

ｾ＠ Ｈ ＱＫｾ Ｉ Ｒｮ＠ ｾ＠ t= (b - ta t = a+ tP
1-1

Taking conjugate through out, we h ave

::::> n = 2 is th e required smallest positive :. (b + ta t = P+ta

integer . 31. (C) Let n be th e number of newspapers which
27. (C) We h ave, f( e ) = sin e (sin e + sin 3 e ) are read.
= sin e (2sin2 e cos e ) ===> 60n = (300X5)
= sin 22 e ｾ＠ 0, for all real e :. n = 25

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32. (A) Let orthocentre be ( α, β ) . = p3 – 2( α + β + γ )p2 + 4 ( α β + β γ + γ α )
p – 8α β γ
2 (6) + 1 ⋅ α 2 (2 ) + 1 ⋅ β
Then, 3 = and 3 = = p3 + 4pq – 8r
2+1 2+1
39. (C) We have, sin(A + B + C) = 1,
⇒ α = –3 and β = 5
1
∴ Orthocentre is (–3, 5). tan(A – B) =
3
and sec (A + C) = 2
33. (B) We have,
⇒ A + B + C = 90o, A – B = 30o and A + C = 60o
cos A cos B cosC
+ + ⇒ B = 30o, A = 60o and C = 0o
sin Bsin C sin A sin C sin A sin B
1 1 1
sin A cos A + sin B cos B + sin C cosC We have n n + 1 = n − n + 1
=
40. (D)
( )
sin A sin B sin C
1 1 1
sin 2A + sin 2B + sin 2C ∴ 1 × 2 + 2 × 3 + 3 × 4 + .......
=
2sin A sin Bsin C
1
4sin A sin Bsin C +
= =2 2007 × 2008
2sin A sin Bsin C
34. (C) A1 = {2}, A2 = {2, 4}, A3 = {2, 4, 6} and so on. 1 1 1 1 1
= 1− + − + − + .....
2 2 3 3 4
Therefore = {2} 1 1
+ −
2007 2008
35. (A) (7C0 + 7C1) + (7C1 + 7C2) + ... + (7C6 + 7C7)
1 2007
= 8C1 + 8C2 + .... + 8C7 = 1− =
2008 2008
= (8C0 + 8C1 + 8C2 + ... + 8C7 + 8C8) – (8C0 + 8C8)
Physics
= 28 – 1 (1 + 1) = 28 – 2
41. (B)
36. (A) Let x18 = y21 = z28 = k. Then, wood
18 log x = 21 log y = 28 log z = log k

21 28 18 u = 100 m s 1
⇒ log y x = , log z y = , log x z =
18 21 28
m = 0.01 kg x 1
7 9 v=0ms
⇒ 3 logyx = , 3 logz y = 4, 7 logx z = t = 0.02 s
2 2
u = 100 m s–1 v = 0 m s–1
⇒ 3, 3 logyz, 3 logz y = 4, 7 logxz are in A.P.
a=? t = 0.02 s
37. (C) We have (x, y) ∈ R iff x + y < 6 v = u + at
Given the value x = 1, we get possible 0 = 100 + a × 0.02
values of y = 1, 2, 3, 4. 0.02 a = – 100
Thus 1R1, 1R2, 1R3, 1R4. Similarly we a = – 100 / 0.02
may find other values. The set of such a = – 5000 m s–2
ordered pairs is R A bullet penetrating a wooden block
= {(1, 1), (1, 2), (1, 3), (1, 4), (2, 1), (2, 2), (2, 3), F=? m = 0.01 kg a = – 5000 m s–2
(3, 1) (3, 2), (4, 1)} F = ma
F = 0.01 × (– 5000)
n(R) = 10
The average retarding force exerted by the
38. (C) α + β + γ = p, αβ + βγ + γα = q , αβγ = r wood is – 50 N.
42. (A) T1 = 27 + 273 = 300 K
∴ (β + γ − α )( γ + α − β)( α + β − γ )

= (p – 2 α )(p – 2 β )(p – 2 γ )

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 T2 = – 13 + 273 = 260 K x = x1 + x2 = 40 km
Coefficient of performance = x 40 km
v= = = 40 km h −1
T2 260 260 t 1h
= = = 6.5
T1 − T2 300 − 260 40 48. (C) Mass m = 1500 kg, h = 50 m
43. (B) On the surface of the earth t = 2 × 60 = 120 s
GM W mgh 1500 × 9.8 × 50
g= ; Weight mg = 99 N Power = = =
R 2 t t 2 × 60
At a height h above the earth = 6125 W
GM R Power of the engine operating the lift
g' = , where h =
(R + h) 2 2 100 × 6125
= = 8166.67 W
75
g' R2 R2 R2 49. (C) On the surface of the earth, the atmospheric
= = =
g (R + h )2  R
2 9 2 pressure is quite high. The astronauts will
R
R + 2  4 feel great discomfort if they move on the
  earth immediately after coming back from
4g the moon. To avoid it, they need to get used
g' =
9 to normal air pressure gradually. That is
why, they have to live for some days in a
4g 4
Weight = mg ' = m × = mg × caravan with the air pressure lower than
9 9 outside.
4 ∆t
Here mg = 99 N = 99 × = 44 N =
1
9 50. (B) Here
t 1011
1 1
44. (B) Mean diameter = ∆t = 11 × t = 11 × 1011 = 1
10 10
0.39 + 0.38 + 0.39 + 0.41 + 0.38 + 0.37 + 0.40 + 0.39
or ∆ t = 1 s
8
Hence, maximum difference in time
d = 0.38875 mm between two such clocks = 2 s
= 0.39 mm (rounded off to two significant One may be 1 s faster and the other may be
figures) 1 s slower.
Absolute error in the first reading = 4S 4S 4S
0.39 – 0.39 = 0.00 mm 51. (D) − =
r1 r2 r
Similarly finding the absolute error in the
other seven readings and taking the mean; 1 1 1 1 1 1
or r = r − r = 4 − 5 = 20 or r = 20 cm
1 2
Mean absolute error = ∆ d =
52. (B) As no external torque acts on the system,
0.00 + 0.01 + 0.00 + 0.02 + 0.01 + 0.02 + 0.01 + 0.00 the angular momentum L is conserved. As
8 the beads slide down, the moment of inertia
= 0.00875 = 0.01 mm of the system shall change. As L = I ω =
constant and I changes, therefore, ω would
∆ d 0.01 change. As no work is being done, total
Relative error = = = 0.0256
d 0.39 energy cannot change.
45. (B) Energy stored per unit volume
dm
53. (C) a= = −10 kg s −1 , Vr = 5 km s–1 (5000)
1 dt
U = stress × strain
2 M = 1500 kg, t = 50 s
1 strain 10 × 5000
= stress × = 50 m s −2
2 Y 1500 − 10 × 50
54. (A) Here, m = 0.5 kg, v= 1.5 m s–1
1 S 1 S2
= S× = K = 50 N m–1
2 Y 2Y x=?

46. (B) A raw egg behaves like a spherical shell and 1 1

Kx2 = mv2
a half boiled egg behaves like a solid sphere. 2 2
m 0.5
I r 2 / 3 MR 2 5 x= v = 1.5 = 0.15 m
∴ = = >1 K 50
Is 2 / 5 MR 2 3
55. (A) Relative velocity of overtaking =
1 1
47. (B) x1 = 30 × km, x2 = 50 × km
2 2
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 40 m s–1 – 30 m s–1 = 10 m s–1 . a=+g,s=h
Total distance covered with this relative
velocity during overtaking will be = v 22 = u 2 + 2gh
100 m + 200 m = 300 m.
v12 u 2 + 2gh
Time taken t = 300 m/10 m s–1 = 30 s = =1
v22 u 2 + 2gh
56. (D) Specific heat (in cal/g/oC) : Copper (0.09)
Aluminium (0.21), Iron (0.11), Lead (0.03). v1 : v2 = 1 : 1
57. (B) Error in time period is 63. (C) Time taken in reaching bottom of incline is
∆ T= (0.1/20)s = 0.005 s.
Also T = (20 s / 20) = 1s t=
(
2l 1 + K 2 / R2 )
g sin θ
∆T 0.005
Hence = = 0.005 × 100% = 0.5% For solid cylinder (SC), K2 = R2 / 2
T 1
For hollow cylinder (HC), K2 = R2
3 5
58. (B) Cm = R, Cdi = R . 2 2
2 2 For solid sphere (S), K2 = R
5
If change in temperature is ∆T , then
∴ tS < tSC < tHC
3 5
1 × R ∆ T + 1 × R ∆ T = 2 × Cv × ∆ T K1 2
2 2 64. (B) Here dx1 = dx2 , A1 = A2, K = 3
2
This gives Cv = 2 R
Let θ be the temp. of the junction.
GM G 4 4
59. (A) g= = 2 × π R3 ρ = π GR ρ,
R 2
R 3 3 dQ1 dQ2
As =
i.e. g ∝ ρ dt dt
dT1 dT
g ' 2ρ ∴ K1 A1 = K 2 A2 2
∴ = =2 dx1 dx 2
g ρ
K1 = (100 – θ ) = K2 ( θ – 0 )
or g ' = 2 g = 2 × 9.8 = 19.6 m s–2
K1 θ 2
m1u1 + m 2u 2 40 × 4 + 60 × 2 or = =
60. (C) υ= = K 2 100 − θ 3
m1 + m 2 40 + 60
3 θ = 200 – 2 θ ; 5 θ = 200 ; θ = 40 oC
= 2.8 m s–1
65. (C) m = 3 kg, u = 10 m s–1 , v = 0
Loss in K.E. =
Impulse = F × t = ?
1 1 1
m1 u12 + m 2 u 22 − ( m1 + m 2 ) υ2 Impulse = Change in momentum
2 2 2
F × t = m(v – u)
1
40 × 16 + 60 × 4 − 100 × 2.8 2  = 48 J = 3 [0 – 10 ] = – 30 N s
2 
Chemistry
61. (A) Temperature of source = 66. (C) The set of elements given in options (A), (B)
T1 = 100 + 273 = 373 K and (D) have decreasing atomic radius.
o
Temperature of sink = Atomic radius in ( A )
T2 = 30 + 273 = 303 K
Oxygen 0.73
T1 − T2 Sulphur 1.09
Efficiency = ç =
T1 Selenium 1.16
373 − 303 Tellurium 1.35
= = 0.188 = 18.8% As the atomic number increases within a
373
group, the atomic size increases
62. (A) The vertical displacement of the two stones
accordingly.
and their initial velocities are the same. So,
the final velocity acquired by them should 67. (D) All the alkali metals and their salts impart
also be equal. colour to bunsen flame. The colours
imparted by different alkali metals are as
For the stone thrown vertically upwards
follows.
a = – g, s = – h
Element Li Na K Rb Cs
v12 = u2 + 2 as Colour Crimson Golden Pale Red Bluish
red yellow violet violet
v12 = u 2 + 2 (− g )( − h ) = u 2 + 2gh
For the stone thrown vertically downwards,
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 When heat energy is supplied to alkali metal 73. (B) HN0 3 is added to decompose Na 2S and
atom or ion in salt, the electronic excitation NaCN otherwise ｎｾｓ＠ will give black ppt.
occurs in which electron jumps to higher
energy level. When this excited electron de- of Ag2S and NaCN will give white ppt. of
excites to ground state, the energy is AgCN which would interfere with the test
emitted in the form of electromagnetic of halogens.
radiation which lies in visible region thereby
imparting colour to the flame. The colour 74. (A) 2-Ethylanthraquinol -7
of flame depends upon the wavelength of 2-Ethylanthraquinone + 2Hp2
radiation emitted e.g., yellow D-line of Na-
spectra arises from 3s 1 -7 3p 1 transition.
75. (C) K-
[Nof
2
(1.2x10- molL-
ＭＮＺ｟ｾ＠
1
t
w c- [N204]- 4.8x1o-2 mol L-1
68. (A) CO= N 2 = w g :. n 1 (CO)=
28
= 3 x 10-3 mol L-1

76. (A) C : H = 12 x 100 = 1 x100 = 1 : 1

*69. (C) 13x12 13x1
70. (D) Only coloured salts will form coloured metal :. E.F. = CH
metaborates. Since, P decolourises ｂｲ Ｒ ＭｾＰＬ＠ but Q does
71. (B) BF3 is triangular planar and B2H is a dimer not, therefore, P = C 2H 2 (acetylene) and
of triangular planar molecu)e (BH 3),
therefore, both of these have zero dipole Q = C6H 6 (benzene).
moment. NH 3 and NF3 , on the other hand 77. (B) According to Fajan's rule, the covalent
have pyramidal structures and thus have bonding is maximum when W+ is small and
dipole moments. X-is large.
78. (A) TiHL
73
is a non-stoichiometric metallic or

\It 79. (A)

interstitial hydride.
Except lime (50 - 60%), the major
constituent of cement is silica (20 - 25%).

ｾＧ＠
80. (D) (a) It is exact neutralisation. Hence,
pH=7.

JJ.= 1.46D (b) After neutralisation, ｾ＠ HCZleft

In NH3, the dipole moments of the three = 10 rnl.
N-H bOnds reinforce the dipole moment due
to lone pair of electrons but in NF 3, the Total volume = 100 ml
dipole moments of the three N-F oonds Dilution = 10 times.
oppose the dipole moment due to lone pair :. [H+] = lQ-2
of electrons. As a result, dipole moment of or pH= 2
NH3 ( J.l= 1.46 D) is higher than that ofNF3
( J.l= 0.24 D).
(c) After neutralisition, ｾ＠ NaOH left
72. (B) Rise in temperature,
= 80 ml.
ｾｴ＠
= (300.78 K- 294.05 K) = 6.73 K
Total volume= 100 ml. pH> 7.
Heat capacity of the calorimeter =
8.93kJK-1
(d) After neutralisation, ｾ＠ HCZleft
Then,
Heat transferred to calorimeter = =50 ml.
Heat capacity of calorimeter x Rise in Total volume = 100 ml
temperature Dilution = 2 times
= 8.93 kJ K-1 X 6.73 K
= 60.1 kJ
*69. (C) The sum of mass % is 99.8. Hence, there is no oxygen in the given compound.

Element Mass% Atomic mass Atomic ratio Simplest ratio Simplest whole
number ratio
c 64.4 12 64.4 I 12 = 5.37 5.37 I 0.53 = 10.1 10
H 5.5 1 5.511 = 5.5 5.5 I 0.53 = 10.4 10
Fe 29.9 56 29.9 I 56 = 0.53 0.53 I 0.53 = 1 1
Thus, the empirical formula of the compound is C 10H 10Fe.
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 1 32 0.233
∴ [H+] = = 10–1 M or pH = 1 85. (B) % of S = × × 100 = 10
10 233 0.32
81. (C) BaO2 + H2SO4 → BaSO4 + H2O2 86. (D) I has the tendency to lose as well as gain
In this reaction, none of the elements electrons. Oxidation states of
undergo, a change in oxidation number or Cs = +1
valency. F = –1, 0
82. (A) Structure of B2H6 contains four 2c - 2e bonds Xe = Nil
and two 3c – 2e bonds. I = –1, 0, +1, +3, +5, +7
83. (C) Molar mass of acetylene (C2H2), 87. (A) NH4+ is a conjugate acid of the base NH3.
M = (2 × 12 + 2 × 1 ) g/mol = 26 g/mol 88. (B) Cs with low IE is used in photoelectric cells.
Mass of acetylene, m= 5.0 g 89. (C) For PCl3,
Temperature, T = (50 oC + 273) = 323 K 1
X= = [VE + MA – c + a]
740 2
Pressure, P = 740 mm Hg = atm
760 1
= 0.9737 atm [5 + 3 – 0 + 0] = 4
2
Using the gas equation, ∴ Hybridization of P in PCl3 is sp3 .
m For PCl5.
PV = nRT = RT
M 1
X= [5 + 5 – 0 + 0] = 5
m RT 2
V=
MP ∴ Hybridization of P in PCl5 is sp3d.

5.0g × 0.082 L atm K −1mol −1 × 323K 90. (B) Due to the poor shielding (screening) effect
26 g mol−1 × 0.9737 atm of d-electrons in case of Ga, the valence
electrons are attracted more strongly and
= 5.23 L
hence, the size is not increased.
c 3 × 108 m s−1
84. (A) c = vë or ë = =
v 589 × 10−9 m
= 5.1 × 1014 s–1 (or Hz)

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