AVKI

NTERNATI
ONALRESI
DENTIALSR.SEC.SCHOOL,
(CBSE)
SANKARANKOVIL
WORKSHEET
CHEMISTRY
STD :XI
I
CHAPTER :11.ALDEHYDESKETONES&CARBOXYLI
CACI
DS

1)
Drawt
hest
ruct
uresoft
hef
oll
owi
ngcompounds.

(
i)p-Met hyl benzal dehy de (
ii
)4-Met hyl pent -
3-en-2-one
(
ii
i)Hex-2- en-4-y noicaci d (
iv)3-Chloro-4- pheny lpentanoicaci
d
(
v)4-Bromopent an- 2-
one (
vi)p,p’
-Dihydr oxybenzophenone
(
vii
)p-Nitropr opi ophenone (
vii
i)Prop-2-enal
(
ix)2-Bromocy clopentanecar bal
dehy
de(
x)4-Hy droxy acetophenone
(
xi)α-Ethoxy but yraldehy de (
xii
)But ane-1,2, 3,
4-tetr
acarbaldehyde
(
xii
i)3-Oxobut anal (
xiv)Benzene- 1,2-
dicar bal
dehyde
(
xv)Benzene- 1, 2-di
car boxyli
caci
d (
xv i
)3- Pheny l
propanoicacid
(
xvii
)4-Ni trobenzoi caci d (
xvii
i)3-Met hy lbut-2-enoicacid
(
xix)α-Hy droxy pheny l
aceticaci
d (
xx)Acet ophenone

2)Whatismeantbyt hefol
lowi
ngterms?Giveanexampl
eoft
her eact
ionineachcase.
(i
)Cy nohydr i
n (
ii
)Acetal (
ii
i)Ketal (i
v)Imi
ne
(v)Semi carbazone (
vi)Hemiacet
al (
vii
)Oxime (v
ii
i)Al
dol
(i
x)2,4-DNPHy dr
ozone (
x)Schif
f’
sbase (
xi)Hydrazone
3)Expl
ainthef ol
lowingwi t
hanexampl e.

(i
)Rosenmundr educti
on (i
i)Etar
dr eaction (i
ii
)Gattermannr eaction
(i
v)St ephenr eacti
on (v)Clemmensenr eduction(vi
)Gattermann–Kochr eact
ion
(vi
i)Friedelcraftacety
lati
on (vi
ii
)Halof or
mr eaction ( i
x)Wol f
f-
Kishnerr educti
on
(x)Aldol condensation (xi
)Canni zzaror eaction ( xi
i)Est
erifi
cat
ion
(xi
ii
)HVZr eaction (xi
v)Kolbeel ectrolysis. ( xv)Decarboxyl
ation
(xvi
)Cr ossaldol condensati
on
4)Ar
ranget hef ol
lowingsetofcompoundsinincreasingor deroft hei
rpropert
yasi ndicated:

(i)Acetaldehyde,Acet one, Di
-t
ert-
butylket one,
Met hy ltert
-butylketone(reacti
vit
ytowardsHCN)
(ii
)Benzoi cacid;4-Nit
r obenzoicacid;3,4-Dini
tr
obenzoi caci d;4-Methoxybenzoicacid(aci
d
strengt
h)
(ii
i)Butanal,Butanol,Pent ane,Diethylketone( Boil
ingpoi nt)
(iv)Acetaldehyde,Ethanol ,Dimethy l
ket one,Propane ( Boil
ingpoint
(v)Benzal dehyde,p-Tol ual
dehyde,p-Nitrobenzaldehy de,Acet ophenone
(r
eact i
vitytowar dsnucl
eophi l
i
cadditi
onreact
ion)
(vi)Ethanal,Propanal,Pr opanone,Butanone (react i
vi
tyt owardsnucleophil
i
cadditi
on
reacti
on)
5)Dot
hef
oll
owi
ngconv
ersi
ons.

(
i)Benzenet om- Nit
robenzoicaci d (i
i)Hexan-1-oltoHexanal
(
ii
i)CyclohexenetoHexane- 1,6-dioi
cacid (i
v)Ethanol t
o3- Hydr
oxybutanal
(
v)Ethanal t
oBut -2-
enoicacid (vi
)Benzoicaci dtoBenzaldehyde
(
vii
)Pr opanonetoPr opene (
vii
i
)Bromobenzenet o1-Phenylet
hanol
(
ix)Ethanenit
ri
letoEt hanal (
x)EthanaltoBut-2-enal
(
xi)Benzaldehydet oα-Hydroxypheny l
aceti
caci
d (xi
i)Benzenet op-Nit
robenzoicacid
(
xii
i)Benzaldehydet o3-Phenylpropan-1-
ol (xi
v)Bromobenzenet oBenzoicacid
(
xv)Ethanal t
oBut ane-1,
3-di
ol (
xvi)3-
Nitr
obromobenzenet o3-Nit
robenzoic
aci
d
(
xvii
)Ethylbenzenet oBenzoi cacid (
xviii
)But-
2-enet oEthanal
(
xix)Cyclohexanol toCy clohexanone (
xx)Benzenet oPheny laceti
cacid
(
xxi)Benzoicaci dtom- Nit
robenzylal
cohol ( xxii
)Allylal
coholtoPropenal
(
xxii
)Benzenet om- Nitroacetophenone (
xxii
i)AcetophenonetoBenzoi cacid
(
xxiv)Benzy lalcohol toPheny let
hanoicaci
d ( xxv)p-Fluorot
oluenetop- Fl
uorobenzal
dehy
de
(
xxvi)Butan-1-ol toBut anoicacid (
xxvii
)Benzenet oMet hy l
benzoat
e
(
xxvii
i)Pheny lethenet oBenzoi cacid (
xxix)BenzaldehydetoBenzophenone
(
xxx)4-Met hylacet ophenonet oBenzene-1,
4-di
carboxyl
icacid

6)Namet
hef
oll
owi
ngcompoundsaccor
dingt
oIUPACsy
stem ofnomencl
atur
e:
7)Gi
vesi
mpl
echemi
cal
test
stodi
sti
ngui
shbet
weent
hef
oll
owi
ngpai
rsofcompounds.

(
i)BenzaldehydeandAcetophenone (
ii
)Acet al
dehy deandBenzaldehyde
(
ii
i)Phenol andBenzoi
cacid (iv)Met hanalandEthanal
(v)EthanalandPropanal (
vi)Benzoicaci dandEt hy
lbenzoate
(vi
i)PropanalandPropanone (v i
i
i)Acet ophenoneandBenzophenone
(i
x)Pent an-2-
oneandPentan-
3-one (
x)Met hylbenzeneandTer t-
butyl
benzene

8)Whichofthefoll
owingcompoundswouldunder
goal
dolcondensati
on,whi
chwouldundergo
canni
zzaroreact
ionandwhichneit
her?Wr
it
ethestr
uct
uresoftheexpect
edproduct
sofaldol
condensat
ionandcannizzar
oreact
ion.

(
i)But
an-1-ol (
ii
)Cyclohexanone
(
ii
i)2-
Met hyl
pent anal (
iv)2,
2-Dimethyl
but
anal
(
v)Phenylacetaldehyde (
vi)Benzophenone
(
vii
)Benzaldehy de (
vii
i)Methanal
(i
x)1-Phenylpropanone (
x)Ethanal

I
)Onemar
kquest
ions.

1)Gi
veoneuseofFor mali
n.
2)WhatisthechemicalnameofTol l
en’
sreagentandFehling’
ssol
ution.
3)Writ
ethestr
uctureofalkenesthatonozonolysiswil
lgiv
eketoneonly.
4)Whatisthefunct
ionofBaSO4i nrosenmundr eact
ion?
5)Namet hei
somerswi t
hmol ecularfor
mulaC3H6O.Whi chonewill
hav ehi
ghboi
l
ingpoi
nt.
6)Writ
eachemi cal
testtodisti
nguishbetweenaldehydeandketone.
II
)Twomar kquest ions.
1)Et
hanoi
caci dhasmol armassof120i nv apourst ate.Why ?
2)Whyarealdehy desmor ereact
ivethanketonest owar dsnucl eophi
l
icaddit
ion?
3)Whyhavecar boxy l
icaci
dshigherboili
ngpoi ntsthanal coholsofsameno.ofcarbonat
oms?
4)Car
boxyli
caciddonotshowchar acter
isti
cpr opertyofcar bonylgroup.Why?
5)Whydoesf ormaldehy denotundergoaldol condensat i
on?
6)Whyisthefluoroacet i
cacidastrongeracidt hanacet i
caci d?
7)Whyisthecar boxyli
cacidastongeraci dthanphenol ?

II
I)Thr
eemar kquest ions.
1)Tol
uenetobenzal dehy de
2)Methanoltoacet i
caci d
3)Methanoltoethanol
4)Aceti
cacidtopr opionicaci d
5)Ethylal
coholt
oacet one
6)Acetonetoter
t-buty lalcohol

IV)Fivemarkquestions.
1)Acompound‘ A’withformulaC5H10Ogi vesaposi tiv
etest2,4-DNPt estbutnegativetoll
en’stest
.It
canbeoxidizi
ngtocar boxyl
icaci d‘
B’ofmol ecularformulaC3H6O2, whentreatedwithalk.KMnO4under
vigor
ousconditi
ons.Thesal tof‘B’givesahy drocarbon‘C’onkol be’
selectr
olyti
cdecarboxy l
ati
on.
Identi
fyA,
B,C&wr it
echemi cal equat
ions.
2)Acompound‘ A’ wit
hf or
mul aC5H12Oonoxi dati
onformscompound‘ B’wit
hmol ecularformula
C5H10O.Thecompound‘ B’givesiodoformt estbutdoesnotr educeammoni calsil
vernit
rate.The
compound‘ B’
onr educti
onwi thlucasr eagentgi vescompound‘ C’wit
hmol ecularfor
mul aC5H12,under
vigor
ousconditi
ons.Identi
fyA, B,
C&wr it
echemi calequati
ons.

3)Anorgani
ccompound‘ A’
,whichhasacharact
erist
icodour,
ontreatmentwit
hNaOHf or
mstwo
compoundsBandC.CompoundBhasmol ecul
arformulaC7H8O,
whi chonoxi
dati
ongiv
esbackA.
CompoundCi sthesodi
um sal
tofanacid.C,whenheatedwithsodal i
meyiel
dsanaromati
c
hydr
ocarbonD.deducet
hestructur
esofAt oD.

8)TwomolesofcompoundAont r
eatmentwit
hastr
ongbasegivestwocompoundsBandC.The
compoundBondehydr
ogenationwithCugivesAwhi
leaci
dif
icat
ionofCgiv
escarboxy
li
caci
dDhavi
ng
molecul
arf
ormul
aCH2O2.Identi
fyAt oD.
9)Wr
it
ethest
ruct
uresofpr
oduct
soft
hef
oll
owi
ngr
eact
ions.