GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017

SKEMA KIMIA KERTAS 2 SET 2

Question Answer Mark

Number
1 (a)(i) Contact process 1
(a)(ii) Catalyst : Vanadium(V) oxide 1
Temperature : 450 oC 1
(a)(iii) 1. The reaction is too exothermic 1
2. Produce acidic vapor instead of liquid
(b)(i) ammonia 1
(b)(ii) 1:3 2
(c)(i) Ammonium sulphate 1
(c)(ii) firtilizer 1

Total 9

2 (a) Proton, electron and neutron 1

(b) (i) Isotopes are atoms of the same element with the 1
same number of proton but different number of
neutrons

(ii) R and S 1

(iii) Cobalt-60 1

(c) (i) 2.8.1 1

(ii) 1 1

(d) 24
11
S 1

(e) (i)

T 1

(ii) Group 2 , Period 3 1

TOTAL 9
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017

No 3 Mark scheme Mark ∑Mark

3 (a) Able to state the meaning of end point correctly
Answer:
The volume of an acid which exactly neutralizes the fixed volume 1 1
of an alkali
(b) Able to name the indicator correctly
Answer:
Phenolphthalein 1 1
Reject : methyl orange
(c) Able to state colour change of phenolphthalein at end point
Answer:
Pink to colourless 1 1
(d) Able to name reaction correctly
Answer:
Neutralization 1 1
(e) Able to write a balanced equation correctly

Correct formulae of reactants 1

Correct formulae of products 1 2
Answer:
HCOOH + NaOHHCOONa + H2O
(f) Able to state the volume of methanoic acid correctly
Answer:
48.60 cm3 1 1
(g) Able to calculate the concentration of methanoic acid correctly
Answer:
Mol ratio of HCOOH and NaOH =1:1
M ( 48.60 ) =1 1
0.493 X 40.551

/ concentration = 0.411mol dm-3 1 2

(h) Able to give two reasons for using ammonia gas instead of
ammonia solution
Sample answer
1. Ammonia gas does not have water in it // So latex is not 1
diluted // Latex added with ammonia gas is lighter
compared to latex added with ammonia solution .
2. It is easier to transport from estate to factory // Save 1 2
transportation cost.
11
Total
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017
Question Answer Mark
Number
4 (a)(i) CnH 2n+1 OH 1
(a)(ii) Hydroxyl 1

(b)(i) propena 1
(b)(ii) 1
H H H
| | |
H- C = C -C–H
|
H

(c) (i) Potassium manganate(VII) // potassium dichromate(VI) 1

(ii) Purple to colourless // orange to green 1
(d)(i) 2C3H6 + 9O2 6CO2 + 6H2O 1+1
11.2 = 0.2667
(d)(ii) 42 1

2mol C3H6 : 6mol CO2 1

0.2667 mol C3H6 : 0.8 mol CO2
Bil molekul CO2 = 4.824 x 1023

Total 10

Question Answer Mark

Number
5 (a) Acidified Potassium manganate(VII) 1
(b) +7 1
(c) reduction 1
(d)(i) Colourless solution turn brown 1
(ii) 2I- → I2 + 2e 2
(iii) Iodide ion release electron 1
(e) To allow the flow of ion from both electrolytes 1
(f) Functional diagram of simple cell 1
Label 1
Total 10

Numbe Answer / sample answer Marks

r
6 (a) CaCO3 + 2HCl CaCl2 + CO2 + H2O
1. Correct formula reactants and products 1
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017
2. Balanced equation 1 2
(b) (i)  correct label of axes and units for both axes – X and – Y and
correct uniform scale 1
 correct transfer of data 1
 smooth curve 1 3
(ii)  tangent on the curve 1
 answer : 0.14 ± 0.05 cm3s-1 1 2
(c) (i) Volume of gas / cm3

b(i)
c(i)

Time /s

(ii) (Refer to (b) (i)

1. The smaller the size of reactants, the larger the total surface
area // 1
2. frequency of collision between particles increases 1
3. frequency of effective collision increases 1 4
( vice versa for (c) (i) )
11

NO JAWAPAN MARKAH
7 (a) Blue precipitate formed 1
Copper(II)hydroxide salt that insoluble in water form 1
Cu2+ + 2OH-  Cu(OH)2 1
(b) Observation :Blue precipitate formed and dissolve in excess 1
ammonia solution 1
Explanation : Cu(OH)2 dissolve in excess ammonium solution
(c) (i) Solid J – copper(II)oxide 1
Gas K – oxygen 1
Gas L – nitrogen dioxide 1
(ii) 2Cu(NO3)2  2CuO + O2 + NO2 1+1
(d) (i) *anion : probably is nitrate 1
Salt Q is dissolved in water 1
Iron(II)sulphate and concentrated sulphuric acid are added 1
slowly
A brown ring is formed 1
(ii) *cation : probably are aluminium & lead(II) 1
Potassium iodide is added to solution Q 1
Yellow/white precipitate is formed 1
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017
Yellow/white precipitate shows the presence of lead(II) ion 1
No precipitate formed
No precipitate indicates the presence of aluminium ion

8 a Aluminium ion : 2.8 1

Oxide ion : 2.8.8 1

b (i)

- 2+
-
Cl Mg Cl

1. Correct number of shells and number of electron

2. Correct charge
[Description]
3. To achieve the stability of electron arrangement
4. Magnesium / Mg atom donates two electron to form
magnesium ion / Mg2+ and Chlorine / Cl atom accepts one
electron to form chloride ion / Cl-
5. [one] magnesium / Mg atom donate two electron to two
chlorine atoms
6. Magnesium ion / Mg2+ and chloride ion / Cl- are attracted
to one another by electrostatic forc

b ii
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017

1. Correct number of shell and electron

2. Correct number of atoms of carbon and chlorine
[Description]
3. To achieve the stability of electron arrangement
4. Carbon atom contribute four electron and chlorine atom
contribute one electron
5. One carbon atom share four electron with four chlorine
atoms.

c i 1. Compound (b)(i) / MgCl2 is an ionic compound 1

2. In molten state, MgCl2 has freely moving ions 1
3. Compound (b)(ii) / CCl4 is a covalent compound. 1
4. CCl4 has no freely moving ions// only consist of molecules. 1

ii 1. Ions in MgCl2 are held together by strong electrostatic force 1

2. A lot of heat energy is needed to overcome / break the 1
strong electrostatic force
3. Molecules in CCl4 are held together by weak intermolecular 1
forces / van der Waals
4. Less heat energy is needed to overcome the forces 1

9 a Water on the wet shirt evaporated 1

Evaporation absorbs heat energy from body 1
b 1. A and B are the reactants 1
2. C and D are the products 1
3. Heat energy is absorbed from surrounding //It is an endothermic reaction 1
4. Total energy content of C and D/ product is higher than total energy
content of A and B/ reactants 1

c 1
1. 1 mole of silver nitrate solution produces 1 mole of Ag + ion 1
2. 1 mole of sodium chloride solution produces 1 mole of Cl - ion 1
3. One e mole of potassium chloride produces 1 mole of Cl - ion 1
4. The heat of precipitation of silver chloride is heat that released when 1 1
mole of AgCl is formed from Ag+ ion and Cl- ion
// Ag+ + Cl- AgCl
5. Number of mole of AgCl produced in bothe reactions are the same, heat
released are the same.

9(d) apparatus and material : 2 marks

- procedures : 5 marks
- Table : 1 mark
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017
- Calculation : 2 marks

Sample answer:
1
Apparatus : Polystyrene cup, thermometer, measuring cylinder. 1
Materials : Copper (II) sulphate, CuSO4 solution, zinc powder.

Procedures :
1
1. Measure 25 cm3 of 0.2 mol dm-3 copper (II) sulphate, CuSO4 solution
and pour it into a polystyrene cup.
1
2. Put the thermometer in the polystyrene cup and record the initial
temperature of the solution.
3. Add half a spatula of zinc powder quickly and carefully into the
1
polystyrene cup. 1
4. Stir the reaction mixture with the thermometer to mix the reactants. 1
5. Record the highest temperature reached.

Tabulation of data:

Initial temperature of CuSO4 solution (oC) 1 1

Highest temperature of the reaction mixture 2
(oC)
Temperature change (oC) 2 - 1

1
Calculation :

Number of mole of CuSO4

= MV/1000 = (0.2)(25)/1000 = 0.005 mol
1
Heat change = mc(2 - 1) = x J

Heat of displacement = x / 0.005 kJ mol-1

= y kJ mol-1

10(a)(i) Electrodes Anode Cathode

Product Oxygen gas Hydrogen gas 1+1
Half- 4OH-→ O2+2H2O+4e 2H+ + 2e → H2
equation 1+1

(ii) 1
1. Concentration of hydrochloric acid increases 1
2. Cl- and OH- ions attracted to the anode
OH- ions selectively discharged – lower position in the
 GERAK GEMPUR KIMIA 2 JPN PERAK SET 2 2017
electrochemical series 1
3. H+ ions attracted to the anode
H+ ions are discharged – one type of ions only 1
4. Therefore only left with H+ and Cl- ions

(iii) 1
Anode: Position of ions the electrochemical series 1
Cathode: Position of ions in the electrochemical series

(b)
Procedure: 1
1. Clean a piece of iron ring with sand paper. 1
2. Pour 100cm3 of copper(II)nitrate solution , 0.1moldm-3 in a
beaker 1
3. Connect iron ring to the negative terminal and a copper plate to
the positive terminal.
1
4. Dip the both terminal into the copper(II)nitrate solution

 Rajah berfungsi 1 markah

 Label bahan kimia 1 markah

Electrode Anode/anod Cathode/katod

Half- Cu → Cu+2 + 2e Cu+2 + 2e → Cu 1+1
equation
Copper becomes Iron ring is coated with
thinner / decrease in shiny brown solid 1+1
Observation
size / mass