Exercise 01

Component n-Butane
Temp 393.3 K
Pressure 16.6 atm
Tr 0.925194071983063
R 8.20573 m3.atm/mol.k
w 0.2
Ideal gas law PV = nRT

V 194.41648246988 m3/mol
V 0.19441648246988 m3/kmol

Van dar waals EOS P = RT/V-b -a/V2

Tc 425.1 K
Pc 37.47 atm

a 137000.420452154
b= 11.6368288730985

V 0.27 m3/kmol

RK-EOS P = RT/V-b -a/V(V+b)

alpha 1.03964143322939
a 144321.934870036
b 8.06571882852202
V 0.1601 m3/kmol

SRK-EOS P = RT/V-b -a/V(V+b)

m 0.78776
alpha 1.06
a 147148.089786148
b 8.06571882852202
V 0.1632 m3/kmol

PENG-ROBINSON EOS P = RT/V-b -a/(V(V+b)+b(V-b)

m 0.6722832
alpha 1.051
a 156055.79295574
b 7.24276229061649

V 0.14657 m3/kmol
Exercise 02

Component Ammonia Gas

Temp 450 K
Pressure 56 atm
Tr 1.10919398570372
R 8.20573 m3.atm/mol.k
w 0.253
Ideal gas law PV = nRT

V 65.9389017857143 m3/mol
0.065938901785714 m3/kmol

Van dar waals EOS P = RT/V-b -a/V2

Tc 405.7 K
Pc 111.35 atm

a 41989.739197505
b= 3.73716284351145

V 0.056 m3/kmol

RK-EOS P = RT/V-b -a/V(V+b)

alpha 0.949502793864007
a 40398.5974421936
b 2.59030231009466
V 0.05696 m3/kmol

SRK-EOS P = RT/V-b -a/V(V+b)

m 0.866956416
alpha 0.9099
a 38713.6131143566
b 2.59030231009466
V 0.05755 m3/kmol

PENG-ROBINSON EOS P = RT/V-b -a/(V(V+b)+b(V-b)

m 0.74753929072
alpha 0.922
a 41959.4103994386
b 2.32601015380153

V 0.056489 m3/kmol
Exercise 03
Compressibility Factor at P= 50
Component Ammonia Gas
Temp 400 K
Pressure 50 atm
Tr 0.98595020951442
R 8.20573 m3.atm/mol.k
w 0.253

Van dar waals EOS P = RT/V-b -a/V2

Tc 405.7 K
Pc 111.35 atm

a 41989.739197505
b= 3.73716284351145

V 0.055 m3/kmol
Z 0.000837829175466
RK-EOS P = RT/V-b -a/V(V+b)
alpha 1.00709979644522
a 42849.1833027009
b 2.59030231009466
V 0.0555 m3/kmol
Z 0.000845445804334
SRK-EOS P = RT/V-b -a/V(V+b)
m 0.866956416
alpha 0.9099
a 38713.6131143566
b 2.59030231009466
V 0.05553 m3/kmol
Z 0.000845902802066
PENG-ROBINSON EOS P = RT/V-b -a/(V(V+b)+b(V-b)
m 0.74753929072
alpha 0.922
a 41959.4103994386
b 2.32601015380153

V 0.055 m3/kmol
Z 0.000837829175466
Compressibility Factor at P= 250s
Component Ammonia Gas
Temp 400 K
Pressure 250 atm
Tr 0.98595020951442
R 8.20573 m3.atm/mol.k
w 0.253

Van dar waals EOS P = RT/V-b -a/V2

Tc 405.7 K
Pc 111.35 atm

a 41989.739197505
b= 3.73716284351145

V 0.006162 m3/kmol
Z= 0.000469336670839
RK-EOS P = RT/V-b -a/V(V+b)
alpha 1.00709979644522
a 42849.1833027009
b 2.59030231009466
V 0.00056 m3/kmol
Z 4.26531216601082E-05
SRK-EOS P = RT/V-b -a/V(V+b)
m 0.866956416
alpha 0.9099
a 38713.6131143566
b 2.59030231009466
V 0.00556 m3/kmol
Z 0.000423484565054
PENG-ROBINSON EOS P = RT/V-b -a/(V(V+b)+b(V-b)
m 0.74753929072
alpha 0.922
a 41959.4103994386
b 2.32601015380153

V 0.0056489 m3/kmol
Z 0.000430255748117
Exercise 04
Components Molar Flowrate Units Mole fraction Pc (atm)
CO2 189 kmol/h 0.09393638171 72.88
CO 630 kmol/h 0.313121272366 34.5409
H2 63 kmol/h 0.031312127237 12.96
H2O 1130 kmol/h 0.561630218688 217.71
Total 2012 kmol/h 1
R 8.20573 m3.atm/mol.k
Temperature 500 K
Pressure 1 atm

SRK calculation at P= 1 atm SRK calculation at P= 200 atm

SRK-EOS P = RT/V-b -a/V(V+b) SRK-EOS P = RT/V-b -a/V(V+b)

a 45347.5150862422 a 45347.51508624
b 5.45647263711731 b 5.4564

V 4.096 m3/kmol V 0.02051

Ideal Gas Equation PV= RT

V 4.102865 m3/kmol V 0.020514325

 Tc (K) Tr w m alpha ai
304.2 1.643655489809 0.224 0.823745024 0.5899 21559.5
132.9 3.762227238525 0.048 0.555146496 0.2414 50291.42
33.19 15.06477854776 -0.216 0.131804544 0.384 213214.4
647.1 0.772678102303 0.345 1.0020816 1.257 41547.72

P= 200 atm

/V-b -a/V(V+b)

m3/kmol

m3/kmol 0.020514
 Exercise 05
bi Components Mole fraction Units Pc (atm)
4.877500324 Ammonia 0.25 111.35
10.29134225 Hydrogen 0.5625 12.96
27.42841231 Nitrogen 0.1875 33.56
1.632778575 Total 1
R 8.20573 m3.atm/mol.k
Temperature 550 K
Pressure 270 atm

SRK Calculation:
SRK-EOS P = RT/V-b -a/V(V+b)

a 4878.15466043747
b 2.17299124067629
V 0.0187 m3/kmol

Ideal Gas Equation PV= RT

V 0.016715375925926 m3/kmol

m3/kmol
Tc (K) Tr w m alpha ai
405.7 1.35568153808 0.253 0.866956416 0.7358 31306.1616986
33.19 16.5712564025 -0.216 0.131804544 0.354 866.089975365
126.2 4.35816164818 0.038 0.539557856 0.17077 2332.69835242
 Exercise 06
bi Components Ammonia Units
2.5903023101 SRK Calculation
1.8206980095 R 8.20573 m3.atm/mol.k
2.6734561751 Temperature 499.8 K
Pressure 10 atm
Tc 405.7 K
Pc 111.352 atm
w 0.25
Tr 1.23194478678827

SRK-EOS P = RT/V-b -a/V(V+b)

m 0.8625
alpha 0.8193
a 34858.2190730216
b 2.59025578551836
V 0.404 m3/kmol

RK-EOS Calculation P = RT/V-b -a/V(V+b)

alpha 0.90095765154415
a 38332.4535494216
b 2.59025578551836
V 0.403 m3/kmol

Ideal Gas Equation PV= RT

V 0.4101223854 m3/kmol

Comparison
we compare the specific volume that are obtained from these three equations. For Ammo
but in bromine case, SRK and RK model are valid
 Components Nitrogen Units Components

R 8.20573 m3.atm/mol.k R
Temperature 183.8 K Temperature
Pressure 19.743 atm Pressure
Tc 126.2 K Tc
Pc 33.56 atm Pc
w 0.039 w
Tr 1.4564183835 Tr

SRK-EOS P = RT/V-b -a/V(V+b) SRK-EOS

m 0.541118304 m
alpha 0.789 alpha
a 10777.648299 a
b 2.6734561751 b
V 0.07208 m3/kmol V

RK-EOS Calculation P = RT/V-b -a/V(V+b) RK-EOS Calculation

alpha 0.8286228858 alpha
a 11318.892314 a
b 2.6734561751 b
V 0.07098 m3/kmol V

Ideal Gas Equation PV= RT Ideal Gas Equation

V 0.0763922998 m3/kmol V

hree equations. For Ammonia and nitrogen gas SRK,RK and ideal gas equation are valid
 Exercise 07
Bromine Units Components
Methanol
8.20573 m3.atm/mol.k CO
500 K H2
20 atm Total
588 K
102.073 atm R
0.108 Temperature
0.8503401361 Pressure

P = RT/V-b -a/V(V+b)
0.647939136
1.1034
107578.87519 SRK calculation at P= 1 atm
4.0954545762
0.007047 m3/kmol SRK-EOS

P = RT/V-b -a/V(V+b) a
1.0844353369 b
105729.86565
4.0954545762 V
0.00721 m3/kmol RK-EOS Calculation

PV= RT a
b
0.20514325 m3/kmol
V

Ideal Gas Equation

V
 Molar Flowrate Units Mole fraction Pc (atm) Tc (K) Tr w m
100 kmol/h 0.25 79.93 512.6 1.117831 0.564 1.311751
100 kmol/h 0.25 34.54 132.9 4.311512 0.048 0.555146
200 kmol/h 0.5 12.96 33.19 17.26424 -0.216 0.131805
400 1

8.20573 m3.atm/mol.k
573 K
100 atm

P= 1 atm

P = RT/V-b -a/V(V+b)

9568.33061385478
2.73406801421642

0.04797 m3/kmol
P = RT/V-b -a/V(V+b)

11657.8656372869
2.73406801421642

0.04756 m3/kmol

PV= RT

0.0470188329 m3/kmol
alpha ai bi alpha for RK ai bi
0.85633 81028.69 4.559366 0.945827615285128 89497.24 4.559366
0.162 2384.476 2.73551 0.48159855977242 7088.642 2.73551
0.3412 834.7737 1.820698 0.240672414641322 588.8248 1.820698