Petrobras - Cenpes - Pdab - TFCC: Summary Report Surface Area

PETROBRAS - CENPES - PDAB - TFCC
TriStar II 3020 V1.03 (V1.03) Unit 1 Port 1 Serial #: 732 Page 1
Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Operator: JULIANE / GREENTEC
Submitter: PABLO / UFRJ
File: C:\WIN3020\DATA\AMS285.SMP
Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

Completed: 10/1/2014 15:08:10 Analysis Bath Temp.: -195.850 °C
Report Time: 13/1/2014 14:33:12 Sample Mass: 0.3568 g
Warm Free Space: 11.4457 cm³ Measured Cold Free Space: 33.9984 cm³ Measured
Equilibration Interval: 15 s Low Pressure Dose: None
Sample Density: 1.000 g/cm³ Automatic Degas: No
Summary Report
Surface Area
Single point surface area at P/Po = 0.205071556: 3.2350 m²/g
BET Surface Area: 3.2771 m²/g
t-Plot Micropore Area: 1.2587 m²/g
t-Plot External Surface Area: 2.0184 m²/g
BJH Adsorption cumulative surface area of pores

between 20.000 Å and 600.000 Å diameter: 0.609 m²/g
BJH Desorption cumulative surface area of pores

between 20.000 Å and 600.000 Å diameter: 1.0613 m²/g
Pore Volume
Single point adsorption total pore volume of pores
less than 544.254 Å diameter at P/Po = 0.963378296: 0.006476 cm³/g
t-Plot micropore volume: 0.000537 cm³/g
BJH Adsorption cumulative volume of pores

between 20.000 Å and 600.000 Å diameter: 0.004970 cm³/g
BJH Desorption cumulative volume of pores

between 20.000 Å and 600.000 Å diameter: 0.008058 cm³/g
Pore Size
Adsorption average pore width (4V/A by BET): 79.0446 Å
BJH Adsorption average pore diameter (4V/A): 326.223 Å
BJH Desorption average pore diameter (4V/A): 303.690 Å



Isotherm Tabular Report

Relative Absolute Quantity Elapsed Time Saturation
Pressure (P/Po) Pressure Adsorbed (h:min) Pressure
(mmHg) (cm³/g STP) (mmHg)
00:39 773.695740
0.059961337 46.375172 0.7630 00:42 773.417908
0.099969318 77.353615 0.8279 00:45 773.773560
0.132950982 102.824585 0.8678 00:48 773.402222
0.160445367 124.116478 0.8930 00:51 773.574707
0.205071556 158.626678 0.9349 00:54 773.518677
0.276511254 213.911850 0.9866 00:56 773.609924
0.348991290 269.911896 1.0267 00:59 773.405823
0.398967370 308.447021 1.0480 01:02 773.113403
0.448589241 346.864868 1.0697 01:05 773.234924
0.460611196 356.041687 1.0618 01:08 772.976624
0.517582567 400.056732 1.0859 01:11 772.933167
0.549054925 424.452667 1.0903 01:14 773.060486
0.616857166 476.795349 1.1283 01:17 772.942871
0.671045141 518.602722 1.1738 01:20 772.828369
0.717902654 554.854797 1.2294 01:23 772.883057
0.795941261 615.175781 1.3756 01:26 772.890930
0.818974048 632.923279 1.4484 01:29 772.824585
0.839642666 648.669006 1.5021 01:31 772.553650
0.858676519 663.493225 1.5779 01:34 772.692871
0.874801930 675.675354 1.6640 01:37 772.375244
0.884971228 683.643677 1.7180 01:40 772.503845
0.903437689 697.700378 1.9092 01:43 772.272827
0.923122863 713.042603 2.2021 01:46 772.424377
0.938116953 724.649597 2.5958 01:49 772.451233
0.947625566 731.942078 2.9872 01:53 772.395874
0.953206532 735.955322 3.3223 01:57 772.083801
0.959038436 740.340210 3.7554 02:01 771.960938
0.963378296 743.797546 4.1866 02:04 772.072144
0.967288825 746.816284 4.7142 02:09 772.071655
0.970625726 749.571167 5.2670 02:13 772.255615
0.973501166 751.663696 5.8390 02:17 772.124084
0.976268432 754.049561 6.5823 02:22 772.379333
0.977660341 754.996826 7.0679 02:26 772.248596
0.979322750 756.317200 7.6425 02:30 772.285950
0.979656736 756.281128 7.7953 02:33 771.985840
0.983629395 759.608521 9.7757 02:40 772.250732
0.988805172 763.415833 11.8678 02:43 772.058899
0.990014992 764.431641 14.3520 02:47 772.141479
0.991356354 765.119141 17.8775 02:50 771.790222
0.992018772 765.708374 21.6345 02:53 771.868835
0.992256110 766.192322 25.3374 02:56 772.171936
0.992927180 766.538086 29.0492 02:58 771.998291
0.993553755 766.929504 32.6769 03:01 771.905396
0.992674400 766.307617 29.3728 03:04 771.962708
0.991990904 765.668518 25.7871 03:07 771.850342
0.987665141 762.282898 16.7094 03:14 771.802979
0.980841856 756.829346 11.3828 03:26 771.612000
0.975997462 752.877258 8.7567 03:35 771.392639
0.967392854 746.114197 6.0099 03:43 771.262878
0.957455976 738.734497 4.2994 03:51 771.559753
0.945458933 729.351685 3.1800 03:56 771.426086


Isotherm Tabular Report

Relative Absolute Quantity Elapsed Time Saturation
Pressure (P/Po) Pressure Adsorbed (h:min) Pressure
(mmHg) (cm³/g STP) (mmHg)
0.912375864 704.199524 1.6970 04:03 771.830505

0.890247240 687.096069 1.2688 04:08 771.803650
0.860323888 663.427917 0.9510 04:11 771.137390
0.824462692 635.583191 0.7086 04:14 770.905945
0.783493814 604.181519 0.5390 04:17 771.137573
0.723777824 558.328857 0.4175 04:20 771.409180
0.634019739 489.320251 0.3660 04:22 771.774475
0.582268531 449.257629 0.3801 04:25 771.564331
0.532011302 410.392395 0.3975 04:28 771.397888
0.481755802 371.653107 0.4132 04:31 771.455383
0.431488269 332.918060 0.4348 04:34 771.557617
0.381411129 294.186310 0.4712 04:37 771.310242
0.330936578 255.405212 0.5083 04:40 771.764832
0.231438053 178.553116 0.5900 04:43 771.494202
0.127525089 98.287666 0.6439 04:47 770.731995


Isotherm Log Plot

AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014 - Adsorption
AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014 - Desorption
30
25
Quantity Adsorbed (cm³/g STP)
20
15
10
0
0.05 0.1 0.5 1
Relative Pressure (P/Po)


BET Surface Area Report

BET Surface Area: 3.2771 ± 0.0726 m²/g
Slope: 1.325473 ± 0.029112 g/cm³ STP
Y-Intercept: 0.002909 ± 0.004230 g/cm³ STP
C: 456.676447
Qm: 0.7528 cm³/g STP
Correlation Coefficient: 0.9997589
Molecular Cross-Sectional Area: 0.1620 nm²
Relative Quantity 1/[Q(Po/P - 1)]
Pressure Adsorbed
(P/Po) (cm³/g STP)
0.059961337 0.7630 0.083598

0.132950982 0.8678 0.176693
0.205071556 0.9349 0.275952


t-Plot Report
Micropore Volume: 0.000537 cm³/g
Micropore Area: 1.2587 m²/g
External Surface Area: 2.0184 m²/g
Slope: 0.130487 ± 0.008575 cm³/g·Å STP
Y-Intercept: 0.347419 ± 0.036723 cm³/g STP
Correlation Coefficient: 0.989376
Surface Area Correction Factor: 1.000
Density Conversion Factor: 0.0015468
Total Surface Area (BET): 3.2771 m²/g
Thickness Range: 3.2000 Å to 5.5000 Å
Thickness Equation: Harkins and Jura
t = [ 13.99 / ( 0.034 - log(P/Po) ) ] ^ 0.5
Relative Statistical Quantity Fitted

Pressure (P/Po) Thickness (Å) Adsorbed
(cm³/g STP)
0.059961337 3.3373 0.7630 *

0.099969318 3.6781 0.8279 *
0.132950982 3.9203 0.8678 *
0.160445367 4.1088 0.8930 *
0.205071556 4.4016 0.9349 *
0.276511254 4.8601 0.9866 *
0.348991290 5.3369 1.0267 *
0.398967370 5.6837 1.0480
0.448589241 6.0505 1.0697
0.460611196 6.1435 1.0618
0.517582567 6.6118 1.0859
0.549054925 6.8937 1.0903
0.616857166 7.5749 1.1283
0.671045141 8.2161 1.1738
0.717902654 8.8670 1.2294
0.795941261 10.2515 1.3756


t-Plot
Harkins and Jura
AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014 Not Fitted Points
1.4
1.2
1.0
Quantity Adsorbed (cm³/g STP)
0.8
0.6
0.4
0.2
0.0
0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0 7.5 8.0 8.5 9.0 9.5 10.0
Thickness (Å)


BJH Adsorption Pore Distribution Report

Faas Correction
Harkins and Jura
t = [ 13.99 / ( 0.034 - log(P/Po) ) ] ^ 0.5
Diameter Range: 20.000 Å to 600.000 Å
Adsorbate Property Factor: 9.53000 Å
Fraction of Pores Open at Both Ends: 0.00
Pore Diameter Average Incremental dV/dDiameter dV/dlog(Diameter) Cumulative
Range (Å) Diameter (Å) Pore Volume Pore Volume Pore Volume Pore Area
(cm³/g) (Å) (Å) (m²/g)
-5 -2
603.8 - 540.9 568.8 0.000875 1.3931 x 10 1.8341 x 10 0.062
-5 -2
540.9 - 485.2 509.9 0.000712 1.2772 x 10 1.5073 x 10 0.117
-5 -2
485.2 - 426.4 451.8 0.000711 1.2096 x 10 1.2677 x 10 0.180
-5 -2
426.4 - 382.2 401.8 0.000549 1.2433 x 10 1.1563 x 10 0.235
-5 -3
382.2 - 325.2 348.9 0.000627 1.0992 x 10 8.9326 x 10 0.307
-6 -3
325.2 - 263.5 287.6 0.000606 9.8344 x 10 6.6403 x 10 0.391
-6 -3
263.5 - 211.1 231.2 0.000408 7.7906 x 10 4.2398 x 10 0.462
-6 -3
211.1 - 178.0 191.6 0.000245 7.3811 x 10 3.2989 x 10 0.513
-6 -3
178.0 - 163.8 170.3 0.000040 2.8007 x 10 1.1016 x 10 0.522
-6 -3
163.8 - 145.4 153.4 0.000074 4.0164 x 10 1.4283 x 10 0.542
-6 -4
145.4 - 128.3 135.7 0.000047 2.7266 x 10 8.5809 x 10 0.555
-7 -5
128.3 - 113.7 120.0 0.000003 2.0609 x 10 5.7338 x 10 0.556
-6 -4
113.7 - 100.7 106.3 0.000046 3.5569 x 10 8.7672 x 10 0.574
-7 -5
100.7 - 71.9 81.3 0.000010 3.4273 x 10 6.7480 x 10 0.578
-7 -5
71.9 - 20.8 22.3 0.000017 3.3805 x 10 3.2096 x 10 0.609


BJH Adsorption dV/dD Pore Volume

Harkins and Jura : Faas Correction
-5 AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014
1.4 x 10
-5
1.2 x 10
-5
1.0 x 10
Pore Volume (cm³/g·Å)
-6
8 x 10
-6
6 x 10
-6
4 x 10
-6
2 x 10
-6
0 x 10
50 100 500
Pore Diameter (Å)


BJH Adsorption dV/dlog(D) Pore Volume

AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014
0.018
0.016
0.014
dV/dlog(D) Pore Volume (cm³/g·Å)
0.012
0.010
0.008
0.006
0.004
0.002
0.000
50 100 500
Pore Diameter (Å)


BJH Desorption Pore Distribution Report

Faas Correction
Harkins and Jura
t = [ 13.99 / ( 0.034 - log(P/Po) ) ] ^ 0.5
Diameter Range: 20.000 Å to 600.000 Å
Adsorbate Property Factor: 9.53000 Å
Fraction of Pores Open at Both Ends: 0.00
Pore Diameter Average Incremental dV/dDiameter dV/dlog(Diameter) Cumulative
Range (Å) Diameter (Å) Pore Volume Pore Volume Pore Volume Pore Area
(cm³/g) (Å) (Å) (m²/g)
-5 -2
596.6 - 458.6 509.4 0.002777 2.0122 x 10 2.4304 x 10 0.218
-5 -2
458.6 - 358.4 396.1 0.001790 1.7875 x 10 1.6728 x 10 0.399
-5 -2
358.4 - 223.0 260.1 0.002291 1.6914 x 10 1.1114 x 10 0.751
-5 -3
223.0 - 177.3 194.9 0.000570 1.2484 x 10 5.7284 x 10 0.868
-6 -3
177.3 - 138.0 152.8 0.000342 8.7178 x 10 3.1485 x 10 0.958
-6 -3
138.0 - 108.2 119.5 0.000205 6.8461 x 10 1.9309 x 10 1.026
-6 -4
108.2 - 85.7 94.4 0.000083 3.6807 x 10 8.1789 x 10 1.061


BJH Desorption dV/dD Pore Volume

-5
2.0 x 10
-5
1.5 x 10
Pore Volume (cm³/g·Å)
-5
1.0 x 10
-6
5 x 10
-6
0 x 10
50 100 500
Pore Diameter (Å)


BJH Desorption dV/dlog(D) Pore Volume

0.025
0.020
dV/dlog(D) Pore Volume (cm³/g·Å)
0.015
0.010
0.005
0.000
50 100 500
Pore Diameter (Å)

Petrobras - Cenpes - Pdab - TFCC: Summary Report Surface Area

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PETROBRAS - CENPES - PDAB - TFCC

TriStar II 3020 V1.03 (V1.03) Unit 1 Port 1 Serial #: 732 Page 1

Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

BET Surface Area: 3.2771 m²/g

t-Plot Micropore Area: 1.2587 m²/g

t-Plot External Surface Area: 2.0184 m²/g

BJH Adsorption cumulative surface area of pores

BJH Desorption cumulative surface area of pores

t-Plot micropore volume: 0.000537 cm³/g

BJH Adsorption cumulative volume of pores

BJH Desorption cumulative volume of pores

BJH Adsorption average pore diameter (4V/A): 326.223 Å

BJH Desorption average pore diameter (4V/A): 303.690 Å

Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

Isotherm Tabular Report

Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

Isotherm Tabular Report

0.912375864 704.199524 1.6970 04:03 771.830505

Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

Isotherm Log Plot

Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

BET Surface Area Report

0.059961337 0.7630 0.083598

Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

Relative Statistical Quantity Fitted

0.059961337 3.3373 0.7630 *

Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

BJH Adsorption Pore Distribution Report

Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

BJH Adsorption dV/dD Pore Volume

Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

BJH Adsorption dV/dlog(D) Pore Volume

Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

BJH Desorption Pore Distribution Report

Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

BJH Desorption dV/dD Pore Volume

Sample: AMOSTRA 1 - ANALISE COMPLETA - 10-01-2014

Started: 10/1/2014 10:19:03 Analysis Adsorptive: N2

BJH Desorption dV/dlog(D) Pore Volume

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