Copia de BET MUESTRA 7

Started: 02/08/2018 20:54:07 Analysis Adsorptive: N2 Completed: 03/08/2018 1:12:16 Analysis Bat
Temp.: 77.350 K
Report Time: 03/08/2018 16:19:37 Thermal Correction: No
Sample Mass: 3.0574 g Warm Free Space: 15.6881 cm³ Measured Cold Free Space: 47.0184 cm³
Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None Automatic Degas: Yes
Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

Summary Report
Surface Area
Single point surface area at P/Po = 0.249661682: 1.6605 m²/g
BET Surface Area: 1.7081 m²/g Langmuir Surface Area: 2.4064 m²/g t-Plot Micropore Area: 0.1588 m²/g
t-Plot External Surface Area: 1.5493 m²/g
BJH Adsorption cumulative surface area of pores
between 1.7000 nm and 300.0000 nm diameter: 1.309 m²/g
BJH Desorption cumulative surface area of pores
between 1.7000 nm and 300.0000 nm diameter: 1.5749 m²/g
Pore Volume
Single point desorption total pore volume of pores
less than 100.4395 nm diameter at P/Po = 0.980505084: 0.005660 cm³/g
t-Plot micropore volume: 0.000063 cm³/g BJH Adsorption cumulative volume of pores
between 1.7000 nm and 300.0000 nm diameter: 0.006108 cm³/g
BJH Desorption cumulative volume of pores
between 1.7000 nm and 300.0000 nm diameter: 0.006293 cm³/g
Pore Size
Desorption average pore width (4V/A by BET): 13.25365 nm
BJH Adsorption average pore diameter (4V/A): 18.6667 nm BJH Desorption average pore diameter (4V/A): 15.98
Temp.: 77.350 K

Isotherm Tabular Report
Relative Absolute Quantity Adsorbed Elapsed Time
Pressure Pressure (cm³/g STP) (h:min)
(P/Po) (mmHg)
00:41 758.832397
0.009756712 7.406727 0.2763 00:57 759.141663
0.032919422 24.992134 0.3332 01:00 759.191162
0.068011114 51.636658 0.3795 01:02 759.238525
0.079947142 60.696808 0.3907 01:04 759.211731
0.100143522 76.032722 0.4087 01:06 759.237549
0.120165396 91.232841 0.4248 01:08 759.227234
0.140140388 106.401863 0.4402 01:10 759.251953
0.160154226 121.603020 0.4539 01:12 759.286987
0.180132996 136.776169 0.4659 01:14 759.306580
0.200178741 151.999100 0.4781 01:16 759.316895
0.249661682 189.576965 0.5083 01:18 759.335449
0.300155415 227.922989 0.5399 01:20 759.349915
0.350205847 265.925873 0.5706 01:22 759.341614
0.399706176 303.523438 0.6015 01:24 759.366394
0.449715189 341.492096 0.6332 01:26 759.351929
0.499625976 379.406891 0.6665 01:29 759.381836
0.549638945 417.368286 0.7016 01:31 759.349915
0.599556205 455.277893 0.7405 01:33 759.358154
0.649530016 493.258026 0.7839 01:35 759.407593
0.699410162 531.156128 0.8353 01:37 759.434387
0.749295110 569.063660 0.8973 01:39 759.465332
0.799029551 606.846802 0.9748 01:41 759.479797
0.819694795 622.583862 1.0158 01:43 759.531311
0.849381554 645.178284 1.0827 01:46 759.585938
0.873985831 663.892578 1.1539 01:48 759.614807
0.898685900 682.685669 1.2487 01:51 759.648804
0.922837368 701.036133 1.3852 01:55 759.652954
0.945978896 718.671265 1.6004 02:00 759.711731
0.969659513 736.736633 2.1839 02:11 759.789001
0.976623535 742.106384 2.5976 02:20 759.869446
0.983699072 747.506165 3.2834 02:30 759.893127
0.988504291 751.122986 4.0826 02:42 759.858093
0.980505084 745.105347 3.6590 02:51 759.919922
0.975747961 741.481262 3.2425 02:59 759.910645
0.955679735 726.227295 2.1597 03:13 759.906555
0.926179485 703.867126 1.5583 03:23 759.968384
0.891250386 677.386414 1.2921 03:28 760.040527
0.860572048 654.089172 1.1642 03:31 760.063232
0.833651992 633.673767 1.0840 03:34 760.117859
0.807977782 614.159180 1.0241 03:36 760.118896
0.800720896 608.650513 1.0035 03:38 760.128174
0.750476757 570.481750 0.9163 03:40 760.159119
0.701482641 533.244934 0.8464 03:43 760.168396
03/08/2018 1:12:16 Analysis Bath
m³ Measured Cold Free Space: 47.0184 cm³
one Automatic Degas: Yes
: 0.1588 m²/g
Desorption average pore diameter (4V/A): 15.9841 nm
03/08/2018 1:12:16 Analysis Bath
Saturation Pressure (mmHg)

Temp.: 77.350 K

Isotherm Tabular Report
Relative Absolute Quantity Adsorbed Elapsed Time
Pressure Pressure (cm³/g STP) (h:min)
(P/Po) (mmHg)
0.650465546 494.455292 0.7877 03:45 760.156006
0.600462210 456.449280 0.7374 03:47 760.163208
0.550426847 418.444305
7 - Desorption 0.6912 03:49 760.217834
0.500623565 380.594849 0.6491 03:51 760.241577
0.451060750 342.930939 0.6007 03:53 760.276611
0.381961738 290.396576 0.5535 03:55 760.276611
0.331637489 252.132462 0.5203 03:57 760.265259
0.281460661 213.979248 0.4869 03:59 760.245667
0.231327677 175.870636 0.4530 04:01 760.266296
0.181297683 137.839752 0.4173 04:03 760.295166
0.121570232 92.426003 0.3704 04:05 760.268372
Temp.: 77.350 K

Isotherm Linear Plot
7 - Adsorption
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Relative Pressure (P/Po)
Temp.: 77.350 K

Isotherm Log Plot
7 - Adsorption
7 - Desorption
4.0
3.5
3.0
2.5
2.0
1.5
1.0
0.5
0.0
0.01 0.05 0.1 0.5 1
Temp.: 77.350 K
03/08/2018 1:12:16 Analysis Bath
Saturation Pressure (mmHg)
03/08/2018 1:12:16 Analysis Bath
0.7 0.8 0.9 1.0
03/08/2018 1:12:16 Analysis Bath

0.5 1
03/08/2018 1:12:16 Analysis Bath

BET Surface Area Report
BET Surface Area: 1.7081 ± 0.0113 m²/g
Slope: 2.530466 ± 0.016621 g/cm³ STP
Y-Intercept: 0.018058 ± 0.002573 g/cm³ STP
C: 141.130579
Qm: 0.3924 cm³/g STP Correlation Coefficient: 0.9998490
Molecular Cross-Sectional Area: 0.1620 nm²
Relative Pressure (P/Po) Quantity

Adsorbed (cm³/g
STP)
0.068011114 0.3795 0.192284
0.079947142 0.3907 0.222398
0.100143522 0.4087 0.272281
0.120165396 0.4248 0.321474
0.140140388 0.4402 0.370220
7
0.160154226 0.4539 0.420130
0.180132996 0.4659 0.471600
0.200178741 0.4781 0.523498
0.249661682 0.5083 0.654536
Temp.: 77.350 K

BET Surface Area Plot
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0.00 0.05 0.10 0.15 0.20 0.25
Temp.: 77.350 K
1/[Q(Po/P - 1)]
rptive: N2 Completed: 03/08/2018 1:12:16 Analysis Bath
Correction: No
Free Space: 15.6881 cm³ Measured Cold Free Space: 47.0184 cm³
Low Pressure Dose: None Automatic Degas: Yes
Surface Area Plot
0.0
0.15 0.20 0.25
ve Pressure (P/Po)
rptive: N2 Completed: 03/08/2018 1:12:16 Analysis Bath
Correction: No
Free Space: 15.6881 cm³ Measured Cold Free Space: 47.0184 cm³
Low Pressure Dose: None Automatic Degas: Yes

t-Plot Report
Micropore Volume: 0.000063 cm³/g Micropore Area: 0.1588 m²/g
External Surface Area: 1.5493 m²/g
Slope: 1.001643 ± 0.016299 cm³/g·nm STP
Y-Intercept: 0.040681 ± 0.006627 cm³/g STP
Correlation Coefficient: 0.999207 Surface Area Correction Factor: 1.000
Density Conversion Factor: 0.0015468 Total Surface Area (BET): 1.7081 m²/g
Thickness Range: 0.35000 nm to 0.50000 nm Thickness Equation: Harkins and Jura
t = [ 13.99 / ( 0.034 - log(P/Po) ) ] ^ 0.5
RStatistical Quantity
eThickness (nm) Adsorbed
l (cm³/g STP)
a
t
i
v
0.009756712 0.26157 0.2763 e
0.032919422 0.30373 0.3332
P
0.068011114 0.34124 0.3795 r
0.079947142 0.35167 0.3907 *e
0.100143522 0.36794 0.4087 *s
s
0.120165396 0.38290 0.4248 *
u
0.140140388 0.39705 0.4402 *r
0.160154226 0.41069 0.4539 *e
0.180132996 0.42394 0.4659 *
(
0.200178741 0.43700 0.4781 *P
0.249661682 0.46877 0.5083 */
0.300155415 0.50132 0.5399 P
0.350205847 0.53451 0.5706 o
)
0.399706176 0.56890 0.6015
0.449715189 0.60591 0.6332
0.499625976 0.64589 0.6665
0.549638945 0.68991 0.7016
0.599556205 0.73900 0.7405
0.649530016 0.79491 0.7839
Temp.: 77.350 K

t-Plot
Harkins and Jura
0.8
0.7
0.6
0.5
0.4
0.3
0.2
0.1
0.0
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80
Thickness (nm)
Temp.: 77.350 K
m³/g Micropore Area: 0.1588 m²/g
m²/g
m³/g·nm STP
627 cm³/g STP
07 Surface Area Correction Factor: 1.000
0015468 Total Surface Area (BET): 1.7081 m²/g
to 0.50000 nm Thickness Equation: Harkins and Jura
) ] ^ 0.5
Fitted
pleted: 03/08/2018 1:12:16 Analysis Bath
.6881 cm³ Measured Cold Free Space: 47.0184 cm³
Dose: None Automatic Degas: Yes

0.50 0.55 0.60 0.65 0.70 0.75 0.80
pleted: 03/08/2018 1:12:16 Analysis Bath
.6881 cm³ Measured Cold Free Space: 47.0184 cm³
Dose: None Automatic Degas: Yes

BJH Adsorption Pore Distribution Report
Faas Correction Harkins and Jura
t = [ 13.99 / ( 0.034 - log(P/Po) ) ] ^ 0.5
Diameter Range: 1.7000 nm to 300.0000 nm Adsorbate Property Factor: 0.95300 nm
Density Conversion Factor: 0.0015468 Fraction of Pores Open at Both Ends: 0.00
Pore Average Incremental Pore Cumulative Pore Incremental Pore Cumulative Pore Area (m
Diameter Diameter (nm) Volume (cm³/g) Volume (cm³/g) Area (m²/g)
Range
168.6 - (nm) 135.9 0.001306 0.001306 0.038 0.038
119.7
119.7 - 84.1 95.7 0.001142 0.002448 0.048 0.086
84.1 - 72.3 0.000700 0.003148 0.039 0.125
65.3
65.3 - 44.0 0.001021 0.004169 0.093 0.218
37.4
37.4 - 30.1 0.000374 0.004543 0.050 0.267
26.6
26.6 - 22.7 0.000236 0.004779 0.042 0.309
20.5
20.5 - 18.1 0.000162 0.004941 0.036 0.345
16.6
16.6 - 15.1 0.000120 0.005060 0.032 0.376
14.0
14.0 - 12.6 0.000111 0.005172 0.035 0.412
11.7
11.7 - 11.1 0.000069 0.005240 0.025 0.437
10.6- 8.5
10.6 9.3 0.000128 0.005369 0.055 0.492
8.5 - 7.1 7.6 0.000102 0.005470 0.053 0.545
7.1 - 6.0 6.4 0.000084 0.005554 0.052 0.597
6.0 - 5.2 5.5 0.000068 0.005622 0.049 0.647
5.2 - 4.6 4.8 0.000062 0.005684 0.051 0.698
0.000056 0.005740
4.6 - 4.0 4.3 0.052 0.750
4.0 - 3.6 3.8 0.000054 0.005794 0.057 0.807
3.6 - 3.2 3.4 0.000052 0.005845 0.061 0.868
3.2 - 2.9 3.0 0.000052 0.005898 0.069 0.937
2.9 - 2.6 2.7 0.000052 0.005950 0.076 1.013
2.6 - 2.3 2.4 0.000055 0.006004 0.090 1.104
2.3 - 2.1 2.2 0.000048 0.006053 0.089 1.193
2.1 - 2.0 2.0 0.000018 0.006070 0.035 1.228
2.0 - 1.9 1.9 0.000015 0.006086 0.032 1.261
1.9 - 1.8 1.8 0.000022 0.006108 0.048 1.309
Cumulative Pore Area (m²/g)

Copia de BET MUESTRA 7

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Started: 02/08/2018 20:54:07 Analysis Adsorptive: N2 Completed: 03/08/2018 1:12:16 Analysis Bat

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

m³ Measured Cold Free Space: 47.0184 cm³

one Automatic Degas: Yes

Desorption average pore diameter (4V/A): 15.9841 nm

03/08/2018 1:12:16 Analysis Bath

m³ Measured Cold Free Space: 47.0184 cm³

one Automatic Degas: Yes

Saturation Pressure (mmHg)

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

m³ Measured Cold Free Space: 47.0184 cm³

one Automatic Degas: Yes

Saturation Pressure (mmHg)

03/08/2018 1:12:16 Analysis Bath

m³ Measured Cold Free Space: 47.0184 cm³

one Automatic Degas: Yes

0.7 0.8 0.9 1.0

03/08/2018 1:12:16 Analysis Bath

m³ Measured Cold Free Space: 47.0184 cm³

one Automatic Degas: Yes

03/08/2018 1:12:16 Analysis Bath

m³ Measured Cold Free Space: 47.0184 cm³

one Automatic Degas: Yes

Relative Pressure (P/Po) Quantity

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

rptive: N2 Completed: 03/08/2018 1:12:16 Analysis Bath

Low Pressure Dose: None Automatic Degas: Yes

Surface Area Plot

Low Pressure Dose: None Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

pleted: 03/08/2018 1:12:16 Analysis Bath

.6881 cm³ Measured Cold Free Space: 47.0184 cm³

Dose: None Automatic Degas: Yes

pleted: 03/08/2018 1:12:16 Analysis Bath

.6881 cm³ Measured Cold Free Space: 47.0184 cm³

Dose: None Automatic Degas: Yes

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