ASAP 2420 V2.06 (V2.

06 J) Unit 1 Port 4 Serial #: 192 Page 1

Sample: 2
Operator:
Submitter:
File: C:\2420\DATA\VERIFI~1\000-568.SMP

Started: 14/07/2018 8:01:46 Analysis Adsorptive: N2

Completed: 14/07/2018 12:30:48 Analysis Bath Temp.: 77.350 K
Report Time: 14/07/2018 22:00:05 Thermal Correction: No
Sample Mass: 2.3869 g Warm Free Space: 15.5996 cm³ Measured
Cold Free Space: 46.2543 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 51.3991 p1(d), p(a)

Summary Report

Surface Area
Single point surface area at P/Po = 0.249767013: 1.9966 m²/g

BET Surface Area: 2.0558 m²/g

Langmuir Surface Area: 2.8953 m²/g t-

Plot Micropore Area: 0.1661 m²/g

t-Plot External Surface Area: 1.8898 m²/g

BJH Adsorption cumulative surface area of pores

between 1.7000 nm and 300.0000 nm diameter: 1.625 m²/g

BJH Desorption cumulative surface area of pores

between 1.7000 nm and 300.0000 nm diameter: 1.8218 m²/g

Pore Volume
Single point desorption total pore volume of pores
less than 101.1561 nm diameter at P/Po = 0.980646407: 0.006257 cm³/g

t-Plot micropore volume: 0.000062 cm³/g

BJH Adsorption cumulative volume of pores

between 1.7000 nm and 300.0000 nm diameter: 0.007389 cm³/g

BJH Desorption cumulative volume of pores

between 1.7000 nm and 300.0000 nm diameter: 0.007454 cm³/g

Pore Size
Desorption average pore width (4V/A by BET): 12.17373 nm BJH

Adsorption average pore diameter (4V/A): 18.1903 nm BJH

Desorption average pore diameter (4V/A): 16.3657 nm

 Started: 14/07/2018 8:01:46 Analysis Adsorptive: N2
Completed: 14/07/2018 12:30:48 Analysis Bath Temp.: 77.350 K
Report Time: 14/07/2018 22:00:05 Thermal Correction: No
Sample Mass: 2.3869 g Warm Free Space: 15.5996 cm³ Measured
Cold Free Space: 46.2543 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 51.3991 p1(d), p(a)

Isotherm Tabular Report

Relative Absolute Quantity Elapsed Time Saturation
Pressure (P/Po) Pressure Adsorbed (h:min) Pressure
(mmHg) (cm³/g STP) (mmHg)

00:39 764.371887
0.009874152 7.551168 0.3350 00:57 764.740967
0.033155933 25.354097 0.4019 00:59 764.692627
0.068210037 52.163780 0.4548 01:01 764.752258
0.080051052 61.224983 0.4683 01:03 764.824219
0.100325126 76.740265 0.4899 01:05 764.915710
0.120334531 92.029564 0.5088 01:07 764.781006
0.140316338 107.313728 0.5268 01:09 764.798523
0.160326234 122.609184 0.5434 01:11 764.748108
0.180277467 137.884094 0.5592 01:13 764.843750
0.200268360 153.175446 0.5746 01:15 764.850952
0.249767013 191.058670 0.6114 01:17 764.947571
0.300312498 229.714371 0.6480 01:19 764.917786
0.350234656 267.899628 0.6841 01:21 764.914673
0.399826519 305.829071 0.7212 01:23 764.904419
0.449817329 344.049225 0.7602 01:25 764.864319
0.499800614 382.262177 0.8017 01:27 764.829346
0.549723701 420.434082 0.8450 01:29 764.809814
0.599626968 458.558685 0.8948 01:32 764.739929
0.649605685 496.772705 0.9529 01:34 764.729614
0.699460728 534.912720 1.0220 01:36 764.750183
0.749201619 572.955139 1.1109 01:38 764.754272
0.799027360 610.983215 1.2304 01:41 764.658691
0.819822053 626.871399 1.2950 01:43 764.643250
0.849219369 649.370850 1.4014 01:46 764.667969
0.873882963 668.255432 1.5144 01:49 764.696716
0.898549627 687.113342 1.6577 01:52 764.691589
0.922783680 705.624023 1.8477 01:56 764.668945
0.946073792 723.472168 2.1269 02:01 764.710083
0.971491924 742.882690 2.8148 02:11 764.682312
0.978198588 748.084595 3.2004 02:18 764.757385
0.985782797 753.907959 3.9608 02:27 764.781006
0.990983257 757.862793 4.9222 02:39 764.758423
0.984735479 753.059448 4.5529 02:45 764.732727
0.980646407 749.868896 4.0450 02:53 764.667969
0.974977747 745.544250 3.5480 03:01 764.678223
0.951236741 727.411560 2.5014 03:13 764.700867
0.916050814 700.487854 1.9984 03:20 764.682312
0.887377919 678.624268 1.7888 03:24 764.752258
0.860505152 658.033447 1.6439 03:28 764.705994
0.851113275 650.818176 1.5984 03:42 764.666931
0.825735014 631.365540 1.4997 03:45 764.610352
0.801046779 612.507629 1.4139 03:47 764.634033
0.751093168 574.302917 1.2710 03:50 764.622742
 Started: 14/07/2018 8:01:46 Analysis Adsorptive: N2
Completed: 14/07/2018 12:30:48 Analysis Bath Temp.: 77.350 K
Report Time: 14/07/2018 22:00:05 Thermal Correction: No
Sample Mass: 2.3869 g Warm Free Space: 15.5996 cm³ Measured
Cold Free Space: 46.2543 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 51.3991 p1(d), p(a)

Isotherm Tabular Report

Relative Absolute Quantity Elapsed Time Saturation
Pressure (P/Po) Pressure Adsorbed (h:min) Pressure
(mmHg) (cm³/g STP) (mmHg)

0.700996359 535.986206 1.1545 03:53 764.606262

0.650824659 497.638672 1.0554 03:55 764.627869
0.600454044 459.122650 0.9753 03:58 764.625793
0.550474799 420.928162 0.9099 04:00 764.663818
0.500522132 382.708008 0.8529 04:02 764.617554
0.450919035 344.780609 0.7792 04:04 764.617554
0.399986477 305.825989 0.7362 04:06 764.590820
0.350956498 268.326935 0.6987 04:08 764.558960
0.300288940 229.606506 0.6611 04:10 764.618591
0.250230883 191.305206 0.6242 04:12 764.514771
0.200107576 152.987457 0.5868 04:14 764.526062
0.140153872 107.152443 0.5353 04:16 764.534302
 Started: 14/07/2018 8:01:46
Completed: 14/07/2018 12:30:48
Report Time: 14/07/2018 22:00:05
Sample Mass: 2.3869 g
Cold Free Space: 46.2543 cm³
Ambient Temperature: 22.00 °C
Automatic Degas: Yes
Analysis Adsorptive: N2
Analysis Bath Temp.: 77.350 K
Thermal Correction: No
Warm Free Space: 15.5996 cm³ Measured
Equilibration Interval: 10 s
Low Pressure Dose: None

Comments: tubo + muestra sin desg = 51.3991 p1(d), p(a)

Isotherm Linear Plot

2 - Adsorption
2 - Desorption
5.0

4.5

4.0

3.5
Quantity Adsorbed (cm³/g STP)

3.0

2.5

2.0

1.5

1.0

0.5

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Relative Pressure (P/Po)
 ASAP 2420 V2.06 (V2.06 J) Unit 1 Port 4 Serial #: 192 Page 5

Sample: 2
Operator:
Submitter:
File: C:\2420\DATA\VERIFI~1\000-568.SMP

Started: 14/07/2018 8:01:46 Analysis Adsorptive: N2

Completed: 14/07/2018 12:30:48 Analysis Bath Temp.: 77.350 K
Report Time: 14/07/2018 22:00:05 Thermal Correction: No
Sample Mass: 2.3869 g Warm Free Space: 15.5996 cm³ Measured
Cold Free Space: 46.2543 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 51.3991 p1(d), p(a)

Isotherm Log Plot

2 - Adsorption
2 - Desorption
5.0

4.5

4.0

3.5
Quantity Adsorbed (cm³/g STP)

3.0

2.5

2.0

1.5

1.0

0.5

0.0
0.01 0.05 0.1 0.5 1
Relative Pressure (P/Po)
 Started: 14/07/2018 8:01:46 Analysis Adsorptive: N2
Completed: 14/07/2018 12:30:48 Analysis Bath Temp.: 77.350 K
Report Time: 14/07/2018 22:00:05 Thermal Correction: No
Sample Mass: 2.3869 g Warm Free Space: 15.5996 cm³ Measured
Cold Free Space: 46.2543 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 51.3991 p1(d), p(a)

BET Surface Area Report

BET Surface Area: 2.0558 ± 0.0112 m²/g
Slope: 2.101178 ± 0.011436 g/cm³ STP
Y-Intercept: 0.016313 ± 0.001772 g/cm³ STP
C: 129.804616
Qm: 0.4723 cm³/g STP
Correlation Coefficient: 0.9998963
Molecular Cross-Sectional Area: 0.1620 nm²
Relative Quantity 1/[Q(Po/P - 1)]
Pressure Adsorbed
(P/Po) (cm³/g STP)

0.068210037 0.4548 0.160957

0.080051052 0.4683 0.185822
0.100325126 0.4899 0.227630
0.120334531 0.5088 0.268856
0.140316338 0.5268 0.309826
0.160326234 0.5434 0.351354
0.180277467 0.5592 0.393268
0.200268360 0.5746 0.435811
0.249767013 0.6114 0.544563
 ASAP 2420 V2.06 (V2.06 J) Unit 1 Port 4 Serial #: 192 Page 7

Sample: 2
Operator:
Submitter:
File: C:\2420\DATA\VERIFI~1\000-568.SMP

Started: 14/07/2018 8:01:46 Analysis Adsorptive: N2

Completed: 14/07/2018 12:30:48 Analysis Bath Temp.: 77.350 K
Report Time: 14/07/2018 22:00:05 Thermal Correction: No
Sample Mass: 2.3869 g Warm Free Space: 15.5996 cm³ Measured
Cold Free Space: 46.2543 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 51.3991 p1(d), p(a)

BET Surface Area Plot

2
0.55

0.50

0.45

0.40

0.35
1/[Q(Po/P - 1)]

0.30

0.25

0.20

0.15

0.10

0.05

0.00
0.00 0.05 0.10 0.15 0.20 0.25
Relative Pressure (P/Po)