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Where,
ΔE = energy absorbed or emitted
h= Plank’s constant
v= frequency of electromagnetic radiation emitted or absorbed
Distribution of electrical charges within atoms
Neutrons are neutrally charged
Protons: Positive charged particles
Electrons: electrons are negative charged particles.
1) Ionic bond
Ionic boning involves a transfer of an electron, so one atom gains an electron while one atom
loses an electron.
2) Covalent bond
The most common bond in organic molecules, a covalent bond involves the sharing of electrons
between two atoms.
3) Metallic bonding
In this type of bonding, each atom in a metal donates one or more electrons to a "sea" of
electrons that reside between many metal atoms.
Metallic bonding
Insulators, Conductors and Semiconductors (with Band Diagram)
(i) Insulators
(ii) Conductors: conducting materials are those in which plenty of free electrons are available
for electric conduction.
(iii) Semiconductors
1. Have almost an empty conduction band and almost filled valence band with a very
narrow energy gap (of the order of 1 eV) separating the two.
2. Conductivity of semiconductors increases with temperature.
3. Examples are: germanium and silicon.
Sample Multiple Choice Questions:-
1. A neutron has.
a) The opposite charge to an Electron but half the weight of a proton.
b) The same charge as an Electron but half the mass.
c) No electrical charge but will add weight to the nucleus.
2. Atoms are not easily freed, thus stable, preventing flow of electricity
a)insulator b)conductor d) semiconductor
3. Complete transfer of one or more electrons between atoms constitutes in forming
a) ionic bond b)covalent bond c)co-ordinate covalent bond
4. As per Bohr’s atomic model in ___atom, in an outer orbit ___electron revolves around nucleus.
a)Carbon & 4 b) Helium & 2 c) Hydrogen & 1
5. According to Bohr's atomic model, angular momentum of electron in n th orbit is equal to an
integral multiple of
a)2h/π b)h/2π c)h/π d)nh/2π
6. Smallest particle of an element which can take part in any chemical change.
a) Atom b) proton c) electrons
7. Elements whose atoms have fewer than 4 electrons in their valiancy shell are.
a)semiconductors. b) Good insulators. c) Good conductors.
8. A good electrical insulator is a material which.
a) contains a large number of positive ions
b) has its electrons tightly bound to their parent atoms.
c) has more protons than electrons
9. A neutral atom gains electrons.
a) It gains a positive charge. b) It gains a negative charge. c) It remains neutral.
10. Germanium and silicon have how many electrons in their outer shell?
a) 6. b) 4. c). 2.
NOTES
Description
Static electricity
Accumulation of electric charges that occurs when two non-metallic objects rub against
each other
Conduction of Electricity
Movement of the charged particles in an organized manner.
Electrostatic induction
Phenomenon of an uncharged body getting charged merely by the nearness of a charged
body is known as induction.
In Fig.1, a positively-charged body A is brought close to a insulated uncharged body B.
The end of B nearer to A gets negatively charged whereas further end becomes positively
charged.
In Fig.2, the body B has been earthed by a wire. The positive charge flows to earth
leaving negative charge behind. If next A is removed, then this negative charge will
also go to earth, leaving B uncharged.
It is found that:
Liquids
The particles of a substance have more kinetic energy than those in a solid.
very close to each other
Have a definite volume.
Gases
particles of a gas spread out indefinitely,
No definite volume and no definite shape.
Solids
Metals are good conductors because they have unfilled space in the valence energy
band. When an electric field is applied, a slight imbalance develops and mobile electrons
flow.
In semiconductors, Electrons can be thermally excited from the valence band to the next
highest, the conduction band which can also conduct electricity.
Liquid:
Electric currents in liquids are flows of electrically charged atoms (ions)
Gases
Electric currents in gases are because of ionization
Very poor conduction.
Most of the times considered as insulators.
Vacuum
vacuum contains no charged particles,
Vacuums normally behave as very good insulators.
Vacuum to can become conductive by injecting free electrons or ions through either field
emission or thermionic emission.
Description
Similarly, potential difference (p.d.) of one volt exists between two points if one joule of work is
done in shifting a charge of one coulomb from one point to the other.
Current
Current is a measurement of a rate at which a charge flows through some region of space or a
conductor. Unit - Amperes
OR
Conventional Flow- the flow of current is from the positive (+) to the negative (−).
Electron Flow- electrons flow out of the negative (−) source to the positive (+) source.
Resistance
It may be defined as the property of a substance due to which it opposes (or restricts) the flow
of electricity (i.e., electrons) through it. The unit of resistance is ohm.
Laws of Resistance
The resistance R offered by a conductor depends on the following factors
(i) It varies directly as its length, l.
Capacitor
The purpose of a capacitor is to store electrical energy by electrostatic stress in the dielectric.
Its unit is Farads.
Factors Affecting Capacitance
1. The capacitance of parallel plates is directly proportional to their area.
2. The capacitance of parallel plates is inversely proportional to their spacing.
3. The dielectric material affects the capacitance of parallel plates.
Inductor
It stores electrical energy in a magnetic field when electric current flows through it. The unit of
an inductor is Henry.
Factors that affect inductance are:
1. The number of turns
2. The cross-sectional area of the coil.
3. The length of a coil
4. The core material around which the coil is formed
1. Primary Cell
stored energy is inherently present in the chemical substances
Non-rechargeable
Non reversible reactions.
E.g. zinc-chlorine cell, alkaline-manganese cell
CONSTRUCTION
Zinc container whose base acts as the negative electrode.
The carbon rod cap acts as the positive electrode.
Secondary reactions
The hydroxyl ions generated during the cell reaction liberate ammonia from ammonium
chloride, which in turn combines with the Zn2+ ions to precipitate [Zn[NH3]2Cl2]
complex.
2NH4Cl + 2OH– → 2NH3 + 2H2O + 2Cl–
Zn2+ + 2NH3 + 2Cl– → [Zn [NH3] 2 Cl2]
2. Secondary Cell
Energy is induced in the chemical substances by applying an external source
Rechargeable
Reversible reactions.
Nickel cadmium (NiCd), nickel metal hydride (NiMH), lithium ion (Li-ion), and Lithium ion
polymer (Li-ion polymer).
2. Vehicle Traction Batteries or Motive Power Batteries or Industrial Batteries: These are used
as a motive power source for a wide variety of vehicles.
3. Stationary Batteries
(a) Standby power system which is used intermittently and
(b) Load leveling system which stores energy when demand is low and, later on, uses it to meet
peak demand.
Lead-acid battery
Active materials:
Chemical changes
A. Discharging
When the cell is fully charge, its positive plate or anode is PbO2 (dark chocolate brown) and the
negative plate or cathode is Pb (slate grey).
i. At anode (PbO2), H2 combines with the oxygen of PbO2 and H2SO4 attacks lead to form
PbSO4.
PbO2 + H2 + H2SO4 = PbSO4 + 2H2O
ii. At the cathode (Pb), SO4 combines with it to form PbSO4
Pb + SO4 = PbSO4
B. Charging
When the cell is recharged, the H2 ions move to cathode and SO4 ions go to anode and the
following changes take place:
i. At Cathode PbSO4 + H2 = Pb + H2SO4
ii. At Anode PbSO4 + 2H2O = PbO2 + 2H2SO4
Hence, the anode and cathode again become PbO2 and Pb respectively.
Nickel-Cadmium Batteries
Active materials:
1) Ni(OH)4 for the positive plate
2) Sponge cadmium (Cd) for negative plate (Cathode).
3) The electrolyte is a potassium hydroxide (KOH) solution
Chemical Changes
During discharge
1) Positive plate : Ni(OH)4 + 2K = Ni(OH)2 + 2 KOH
2) Negative plate : Cd + 2 OH = Cd (OH)2
During Charging
1) Positive plate : Ni(OH)2 + 2OH = Ni(OH)4
2) Negative plate : Cd(OH)2 + 2 K = Cd + 2 KOH
Lithium-ion battery
Active materials:
Cathode- Lithium cobalt oxide (LiCoO2)
Anode – Carbon (C6)
Electrolyte -lithium salt in an organic solvent
Chemical Changes
The positive (cathode) electrode half-reaction in the lithium-doped cobalt oxide substrate is,
The internal resistance of a battery is dependent on its size, chemical properties, age,
temperature, and the discharge current, Measured in milliohms (mΩ),
the lower the resistance, the less restriction the pack encounters
. High resistance causes the battery to heat up and the voltage to drop under load,
triggering an early shutdown.
Figure 1 illustrates a battery with low internal resistance in the form of a free-flowing tap against a
battery with elevated resistance in which the tap is restricted.
Thermocouples:
I. Thermocouples will cause an electric current to flow in the attached circuit
when subjected to changes in temperature.
II. The amount of current that will be produced is dependent on;
The temperature difference between the hot and cold junction;
The characteristics of the two metals used;
And the characteristics of the attached circuit.
Photocell:
Based on photoelectric effect- converts light into electricity.
These are the Sensors that allow you to detect light.
Photocells are basically a resistor that changes its resistive value (in ohms Ω) depending
on how much light is shining onto the squiggly face.
They are small, inexpensive, low-power, easy to use and don't wear out
Material: - semiconductors
1. Two types of semiconductor are joined together forming the p-n junction.
2. When the light hits the photocell, electrons on the p-side gain energy that allows them to
move across the junction into the n-type semiconductor.
Electrons that have gained energy can pass through an electric circuit and thus produce
an electric current.
Electric measuring instruments.
A meter is any device built to accurately detect and display an electrical quantity in a form
readable by a human being.
Classification of instruments:
1. Absolute- No calibration required
2. Secondary - calibration required
Permanent Magnet Moving Coil:
Galvanometer
electromechanical instrument
Used for detecting and indicating electric current.
Works as an actuator, by producing a rotary deflection (of a "pointer"), in response to
electric current flowing through a coil in a constant magnetic field.
Ammeter
Used to measure the current in a circuit.
Always connected in series with the element
Voltmeter
For measuring potential difference (the voltage) between two wires,
Always connected in parallel with the element
Ohmmeters
for measuring electric resistance
When test probes are in contact with each other: zero resistance
When test probes are separated : Infinite resistance
Megger (Megohmmeter)
Used to measure insulation resistance and other high resistance values.
Also used for ground, continuity, and short circuit testing of electrical power systems.
It consists of two primary elements;
(1) A hand-driven DC generator, G, which supplies the necessary current for making the
measurement,
(2) The instrument portion, which indicates the value of the resistance being measured.
AC Measuring Instruments
1. Electrodynamometer Meter Movement:
It operates on the same principles as the permanent magnet moving coil
meter, except that the permanent magnet is replaced by an air core
electromagnet.
Bonding
To provide a low resistance path for current in electric equipment
To reduce radio interference
To decrease probability of lightening damage
To provide buildup of static charges on surface
Bonding testers
Used to measure the mechanical strength of bonds,
evaluate bond strength distributions
types performed on a bond tester are i) the wire pull test
ii) Die shear test
Shielding
Process of applying a metallic covering to wiring and equipment
To eliminate adverse effects of electromagnetic interference.
A. Switches:
A switch is used to start, to stop, or to change the direction of the current flow in the circuit.
Switches are classified by the number of poles, throws, and positions they have.
1) Toggle Switch
I. Single-Pole, Single-Throw (SPST)
II. Single-Pole, Double-Throw (SPDT)
III. Double-Pole, Single-Throw (DPST)
IV. Double-Pole, Double-Throw (DPDT)
2) Pushbutton Switches: Pushbutton switches have one stationary contact and one movable
contact
3) Micro switch: it will open or close a circuit with a very small movement of the tripping
device
Electromagnet
An electromagnet is a type of magnet in which the magnetic field is produced by an electric
current
Consist of insulated wire wound into a coil.
It requires a continuous supply of current to maintain the magnetic field.
Advantage- magnetic field can be quickly changed by controlling the amount of electric
current.
Relays:
A relay is an electrically operated switch.
It’s an electromagnet with a fixed core
A relay is simply an electromechanical switch where a small amount of current can control a
large amount of current.
Basic parts and functions of electromechanical relays include:
1. Frame
2. Coil
3. Armature
4. Contacts
Solenoid:
It’s an electromagnet with a movable core
Basic parts and functions of solenoid include:
1. coil of wire and
2. the plunger – made from soft iron
Applying a current to the solenoid applies a force to the plunger and may make it move.
2) Circuit breaker
It is safety device which work magneto thermic release principle.
It is connected in the phase, between the supply and load.
When the current drawn by load exceeds the rated value, it trips the circuit.
No fuse to replace or rewire. It needs no repairs.
Supply is restored by resetting it again.
3) Earthing OR grounding
Connecting the metal body of an electrical circuit through a low resistance wire, is called
earthing or Grounding.
1. In _____ cell, there is reversible reaction due to which chemical energy converted into
electrical energy.
a) Primaryb) Secondary c) both (a) and (b) d) either (a) or (b)
2. When lead acid cell gets discharged both anode and cathode becomes
a)H2SO4 b) Pb2SO4 c) PbSO4 d) PbO2
3. The Ni-Cd battery the anode is
a) Hydrated form of nickel oxide b) Cadmium c) Potassium hydroxide
5. If _____ charging system is used then it increases the capacity by 20% but reduces efficiency
by 10%.
a) Constant Current b) Constant Voltage c) either (a) or (b)
6. The control device which uses the magnetic effect of electric current is called –___
NOTES
Kirchhoff’s laws
Electrical Energy
The rate at which electrical power consumed is generally referred as electrical energy. The
energy is measured in watt-seconds.
Electrical energy = power × time
2. A DC generator produces an output of 28 V at 20A. The power supplied by the generator will
be
A) 14Wb) 560W c) 1.4kW
3. Unit of power is
a) Fuel b) Newton c) Watt d) None
5. Algebraic sum of applied voltage and voltage drop around any closed circuit is zero is,
a) KVL b) KCL c) Ohm law
6. A 3, 5 and 2 ohms resistance is connected in series with a 10 V battery. The voltage across
the 2 ohms resistor is____
a) 2 V. b) 10V. c) 4 V.
8. A current of 5A flows for 2 minutes. How many coulombs passed a point in the circuit?
a) 2.5. b) 600. c) 100.
NOTES
Laws of Resistance
The resistance R offered by a conductor depends on the following factors :
(i) It varies directly as its length, l.
(ii) It varies inversely as the cross-section A of the conductor.
(iii) It depends on the nature of the material.
(iv)It also depends on the temperature of the conductor.
Neglecting the last factor for the time being, we can say that
The fourth and fifth bands are used to determine the percentage tolerance of the resistor.
Resistor tolerance is a measure of the resistors variation from the specified resistive value.
Resistance in Series
In this situation, to find the total resistance is to basically add up all the resistor values.
1. Same current flows through all parts of the circuit.
2. Different resistors have their individual voltage drops.
3. Applied voltage equals the sum of different voltage
drops.
4. Resistances are additive.
Resistance in Parallel
1. P.d. across all resistances is the same
2. current in each resistor is different and is given by Ohm’s
Law and
3. The total current is the sum of the three separate currents.
To find the total resistance of a parallel circuit ,divide one
by each of the resistors. Next add them up and once
again divide one final answer.
Potentiometer
a 3-terminal variable resistor and is used to adjust the resistance in a circuit
Potentiometers are often used to vary voltage
It has a resistive element as the track and a sliding contact called the wiper.
Uses of a Potentiometer
POTs are used for controlling the signal level of a circuit and not the power of the circuit
Volume control on TV’s and other audio equipments.
Used in joysticks as a position transducer.
TRIAC switching applications.
Voltage divider circuits.
Rheostat
2-terminal variable resistor
Rheostats are used to vary current.
One terminal will be connected to the end of the track and the other to a moveable
wiper.
For a positive or PTC, as temperatures increase the resistor's resistance also increases.
Conversely, for a negative or NTC, as temperatures increase the resistor's resistance
decreases.
Types of thermistors
with the change in temperature:
Negative Temperature Co-efficient (NTC) thermistors
Positive Temperature Co-efficient (PTC) thermistors
Advantages of thermistors
The resistance of thermistors changes rapidly with small change in temperature.
Low cost
Small size
It is easy to carry thermistors from one place to another place.
Disadvantages of thermistors
Thermistors are not suitable over a wide operating range
The resistance versus temperature characteristics is non-linear.
Applications of thermistors
medical equipment
Home appliances Computers.
Temperature sensors.
As inrush current limiter.
3. If two series opposing voltages each have voltage of 9V,the net or total voltage is
a) 0V b) 18V c) 9V
9. Resistors required to carry a comparatively high current and dissipate high power are
usually of. a) Wire wound metal type. b) Carbon compound type. c) Wire wound
ceramic type.
10. What happens to the resistance of a copper conductor when the temperature
increases?.
A) It decreases. B) It increases. C) It remains the same
NOTES
Capacitance
The property of a capacitor to ‘store electricity’ may be called
its capacitance.
The capacitance of a capacitor is defined as “the amount of
chargerequired to create a unit p.d. between its plates.”
Capacitors in Parallel
In this case, p.d. across each is the same but charge on each is different
Q = Q1 + Q2 + Q3 or
CV = C1V + C2V + C3V or
C = C1 + C2 + C3
NOTES
Induced E.M.F.
The ability of one coil (or circuit) to produce an e.m.f. in a nearby coil by induction when
the current in the first coil changes is known as mutual inductance.
Let a I1 = current flowing in the first coil ;
φ1 = flux produced by first coil;
N2 = number of turns in second coil.
b) Self-induced e.m.f.:
This is the e.m.f. induced in a coil due to the change of its own flux linked with it.
Property of the coil due to which it opposes any increase or decrease or current of flux
through it is known as self-inductance.
Inductor
1) An inductor is a passive two-terminal electrical component .
2) It stores electrical energy in a magnetic field when electric current flows through it.
3) The primary aspect of the operation of a coil is its property to oppose any change in
current through it. This property is called inductance.
The current through inductors in series stays the same, but the voltage across each
inductor can be different.
Where, τ = seconds
L = inductance (H)
R = Resistance (Ω)
Inductive Reactance.
The effects of the magnetic fields are a continuously inducted voltage opposition to the
current in the circuit. This opposition is called inductive reactance, symbolized by X L, and
is measured in ohms.
The inductive reactance of a component is directly proportional to the inductance of the
component and the applied frequency to the circuit. This relationship is given as:
XL = 2πfL
3. Eddy current should be eliminated in order to prevent equipment from the damage.
a) True b) False