LAMPIRAN A

PERHITUNGAN NERACA MASSA

Kapasitas Produksi = 12000 ton/tahun

Basis Perhitungan
Waktu Kerja per Tahun
Satu Hari Operasi
Satuan Perhitungan
Konversi Bahan Baku
= 1 jam operasi
= 330 hari
= 24 jam operasi
= kg/jam dan kmol/jam
= 0.8

Kapasitas produksi dalam satu jam operasi

= 12000 ton x 1000 kg x 1 tahun x 1 hari
thn 1 ton 330 hari 24 jam
= 1515.151515 kg/jam

Tabel A.1 Berat Molekul

komponen rumus molekul Molecular Weight Boiling point (◦C)
Benzaldehyde C6H5CHO 106 178.1
Acetaldehyde CH3CHO 44 34.45
Polyethylene glycol PEG 400 414 294
Cinnamic Aldehyde C6H5CHCHCHO 132 245
Water H2O 18 100
Deionised Water H2O 18 100
Ion Exchange Resin ‒ ‒ ‒

konversi = mol umpan bereaksi

= 0.8
mol umpan mula-mula

basis
Benzaldehyde = 99.5% 0.995 = 1507.57575757576 kg = 14.2224128073185
1515.151515
Acetaldehyde = 99.0% 0.999 = 1513.63636363636 kg = 34.400826446281
Deionised Water = = 204.802744425386 kg
Rohm & Hass Resin = 10-15% massa benzaldehide 12.5 % 0.125 = 188.44696969697
Cinnamic Aldehyde =

REAKTOR
 Ion Exch Resin
C6H5CHO + CH3CHO ---------------->> C 6H5CHCHCHO + H2O
PEG 400

awal 14.22241281 34.40083 0 0

reaksi 11.37793025 11.37793 11.37793025 11.3779302458548
sisa 2.844482561 23.0229 11.37793025 11.3779302458548

Input Acetaldehyde arus 1 100%

konsentrasi Acetaldehyde 99.9%
konsentrasi H2O 0.1%
massa Acetaldehyde 1513.63636364
mol acetaldehyde 34.4008264463 kmol
massa H2O 1.51515151515

Input Benzaldehyde arus 2 100%

konsentrasi Benzaldehyde 99.5%
konsentrasi H2O 0.5%
massa Benzaldehyde 1507.57575758
mol Benzaldehyde 14.2224128073 kmol
massa H2O 7.57575757576 kg

Input Polyethylene glicol 100% 0.5% dari benzaldehyde

massa PEG 400 7.53787878788
mol PEG 400 15.1060606061

Input Resin Ion Exhange

Konsentrasi Resin 100%
Massa resin 100% wt 10-15% wt dari berat benzaldehyde 12.5%
188.446969697 kg

Input Deonized water 100% 1 kg

mol 0.05555555556 kmol
massa 1.2 kali massa acetal +benzal bereaksi 54.3

Neraca Massa
reaktor
tujuan mereaksikan bahan baku
 Reaktor

tekanan operasi = 1 atm = 760 mmHg

suhu operasi = 30 ◦C = 303.15 K

S1 S2 S3 S4 S5 Out
komponen
kg/jam kg/jam kg/jam kg/jam kg/jam kg/jam
Acetaldehyde 1513.63636364 0 0 0 0 1013.00743281875
Benzaldehyde 0 1507.57575758 0 0 0 301.515151515151
Cinnamic Aldehyde 0 0 0 0 0 1501.88679245283
water 1.51515151515 7.57575757576 0 0 0 213.893653516295
Deonized Water 0 0 54.3 0 0 54.3
Rhom & Hass Resin 0 0 0 188.4469697 0 188.44696969697
PEG 400 0 0 0 0 7.53787878788 7.53787878787879
total 3280.58787878788 3280.58787878788

SCREENING
memisahkan resin dari campuran produk
efisiensi 100%
tekanan operasi 1 atm
suhu operasi 30 ◦C

Screening
 keluar
komponen masuk
atas bawah
Acetaldehyde 1013.00743282 1013.00743282 0
Benzaldehyde 301.515151515 301.515151515 0
Cinnamic Aldehyde 1501.88679245 1501.88679245 0
water 213.893653516 213.893653516 0
Deonized Water 54.3 54.3 0
Rhom & Hass Resin 188.446969697 0 188.44697
PEG 400 7.53787878788 7.53787878788 0
3092.14090909 188.44697
total 3280.58787879
3280.58787878788

SEPARATOR
fungsi memisahkan campuran PEG 400-air dengan produk
efisiensi 100%
tekanan operasi 1 atm
suhu operasi 30 ◦C

Separator
 keluar
komponen masuk
atas bawah
Acetaldehyde 1013.00743282 1013.00743282 0
Benzaldehyde 301.515151515 301.515151515 0
Cinnamic Aldehyde 1501.88679245 1501.88679245 0
water 213.893653516 0 213.893654
Deonized Water 54.3 0 54.3
PEG 400 7.53787878788 0 7.53787879
2816.40937679 275.731532
total 3092.14090909
3092.14090909091

MEMBRAN SEPARATOR
fungsi memisahkan air dan deonized water dari PEG 400
efisiensi 100%
tekanan operasi 1 atm
suhu operasi 30 ◦C

Membrane
Separator
 keluar
komponen masuk
atas bawah
water 213.893653516 213.893653516 0
Deonized Water 54.3 54.3 0
PEG 400 7.53787878788 0 7.53787879
total 275.731532304 268.193653516 7.53787879

DESTILASI 1

Fungsi memisahkan Acetaldehyde dari campuran

kapasitas produksi 1515.15151515 kg/ thn

konversi 0.8

Destilasi 1

Antoine constant data of compount

 Komponen A B C Tmin (oC) Tmax (oC) oK
Acetaldehyde 5.1883 1637.083 22.317 -0.25 34.45 307.6
Benzaldehyde 3.876 1380.72 -94.98 26 178.85 452
Cinnamic Aldehyde 5.45 2767 -27.816 349 245.85 519

feed
p 1 atm 1.013125 bar
T trial 32 C
T 305.15 K

Komponen BM Massa input Kmol XF

Acetaldehyde 44 1013.00743282 23.0228962 0.618142172
Benzaldehyde 106 301.515151515 2.84448256 0.076371566
Cinnamic Aldehyde 132 1501.88679245 11.3779302 0.305486263
37.245309

Komponen Ln Pi Pi Ki αi
Acetaldehyde 0.18906954319 1.20812496643 1.19247375 111.7438302
Benzaldehyde -2.6935389447 0.06764113706 0.06676485 6.256372432
Cinnamic Aldehyde -4.527139478 0.01081155858 0.0106715 1

Komponen log αi αi.XF yi

Acetaldehyde 2.04822355342 69.0735738874 0.98878714 Grafik Distribusi Di
Benzaldehyde 0.79632259366 0.47780895779 0.00683983 3
Cinnamic Aldehyde 0 0.30548626254 0.00437303
2
69.8568691077 1 f(x) = 2.92702457835597 x − 3.999565
1
asumsi distribusi produk distilat dan bottom asumsi 0

Log D/B
top bottom 0 0.5 1
Acetaldehyde LK 99% 1% -1
Cinnamic Aldehyde HK 0.01% 99.9% -2
Benzaldehyde 27.10% 73%
-3
Komponen n distilat n bottom mol D/B log D/B log α feed distilat feed bottom -4
Acetaldehyde (LK) 0.61196075011 0.00618142172 99 1.995635195 2.04822355342 1002.87735849057 10.1300743281875
-5
 -2
-3
-4
-5
Benzaldehyde 0.02069669429 0.05567487135 0.37174211 -0.42975824 0.79632259366 81.710606060606 219.804545454545
Cinnamic Aldehyde (HK) 3.054863E-05 0.3051807763 0.0001001 -3.9995655 0 0.15018867924528 1500.38490566

Komponen log α log D/B a= 2.927

Acetaldehyde (LK) 2.04822355342 1.9956351946 c= -3.9996
Cinnamic Aldehyde (HK) 0 -3.9995654882

destilat
tentukan T bubble point destilat
P 1 atm 1.013125 bar
T trial 21.3 C
T 294.45 K

Komponen `Log D/B D/B kmol XD

Acetaldehyde 1.99555034086 98.9806589764 22.7926227 0.997337564
Benzaldehyde -1.6687637684 0.02144056529 0.05970716 0.002612608
Cinnamic Aldehyde -3.9996 0.00010009215 0.00113873 4.9827E-05
22.853469 1

Komponen Ln Pi Pi Ki αi yi
Acetaldehyde 0.02020168168 1.02040711669 1.00718778 140.8538641 1.00450620462
Benzaldehyde -3.0459431493 0.04755144272 0.04693542 6.563855093 0.00012262385
Cinnamic Aldehyde -4.9275212464 0.00724443822 0.00715059 1 3.562947E-07
1.00462918476
tentukan T dew point distilat
P 1 atm 1.013125 bar
T trial 23.8912 C
T 297.0412 K

Komponen yi ln Pi Pi Ki Xi
Acetaldehyde 0.99733756449 0.06213445924 1.06410541 1.050319964 0.94955594325
Benzaldehyde 0.00261260817 -2.957177275 0.05196539 0.051292184 0.05093579467
Cinnamic Aldehyde 4.9827337E-05 -4.8276411718 0.00800538 0.007901673 0.0063059225
1.00679766041
Bottom

tentukan T buble bottom destilasi

P 1 atm 1.013125 bar
T trial 233.62 C
T 506.77 K

Komponen Log D/B D/B Kmol XB

Acetaldehyde 1.99555034086 98.9806589764 0.2302735 0.016000282
Benzaldehyde -1.6687637684 0.02144056529 2.7847754 0.193496823
Cinnamic Aldehyde -3.9996 0.00010009215 11.3767915 0.790502895
14.3918404 1

Komponen Ln Pi Pi Ki αi yi
Acetaldehyde 2.09413401218 8.11840748316 8.01323379 11.26056465 0.12821399704
Benzaldehyde 0.52302882537 1.68712994079 1.66527323 2.340118528 0.32222507985
Cinnamic Aldehyde -0.3271727556 0.72095918251 0.71161918 1 0.56253702262
1.01297609951

Tentukan Dew Point Destilasi

P 1 atm 1.013125 bar
T trial 246 C
T 519.15 K

Komponen yi ln Pi Pi Ki Xi
Acetaldehyde 0.01600028159 2.16487844338 8.71354266 8.600659014 0.0018603553
Benzaldehyde 0.19349682329 0.62089002051 1.86058326 1.836479469 0.10536291122
Cinnamic Aldehyde 0.79050289512 -0.1816070127 0.833929 0.823125478 0.96036742469
1.06759069121

menghitung stage minimum

Xlk Destilat 0.997337564 αL,av 39.8257961942

Xhk Destilat 4.98273E-05 NM 3.74658384479
Xlk Bottom 0.016000282 2.74658384479
Xhk Bottom 0.790502895

Menghitung reflux minimum

P 1 atm 1.013125 bar
t dew point destilat 297.0412
t buble point bottom 506.77

T feed rata-rata 401.9056 K 128.7556 C

 Komponen BM A B C
Acetaldehyde 44 5.1883 1637.083 22.317
Benzaldehyde 106 3.876 1380.72 -94.98 0.02239130434783
Cinnamic Aldehyde 132 5.45 2767 -27.816

Komponen ln pi pi ki xf
Acetaldehyde 1.32928117356 3.77832645024 3.72937836 0.618142172
Benzaldehyde -0.6225494856 0.53657470279 0.5296234 0.076371566
Cinnamic Aldehyde -1.9466236966 0.14275524386 0.14090585 0.305486263
1
Komponen αi αi.xf/αi-Ɵ αi.xd/αi-Ɵ Ɵ 2.5
Acetaldehyde 26.4671639945 0.68262019809 1.10136923
Benzaldehyde 3.75870397679 0.22805847344 0.00780169
Cinnamic Aldehyde 1 -0.2036575084 -3.3218E-05
0.70702116318 1.1091377 1.3
mendekati 0
RM+1 1.109138
RM 0.109138
R 0.141879
Ѱ 0.028673
(N-Nm)/N+1) 0.640309
N 9.416118

REBOILER 1

D B
Komponen BM
kmol/jam Kg/jam kmol/jam Kg/jam
Acetaldehyde 44 22.7926227012 1002.8754 0.230273499 10.1320339673
Benzaldehyde 106 0.05970715885 6.32895884 2.784775403 295.186192677
Cinnamic Aldehyde 132 0.00113872748 0.15031203 11.37679152 1501.73648043
total 22.8534685875 1009.35467 14.39184042 1807.05470707
37.2453090077 2816.40937679

Menentukan komposisi uap reboiler

V=(Rop +1)D
v 26.0958961

Komponen BM yi Vi=Yi.Vo Vi (kg/jam)

 Acetaldehyde 44 0.12821399704 3.34585914576775 147.217802414
Benzaldehyde 106 0.32222507985 8.40875220536405 891.327733769
Cinnamic Aldehyde 132 0.56253702262 14.6799076961249 1937.74781589
2976.29335207

Li = Vi + Bi
Komponen BM
kmol/jam kg/jam Fraksi Mol
Acetaldehyde 44 3.576132645 157.34984 0.08759372 1807.0547070703
Benzaldehyde 106 11.193527608 1186.5139 0.274174033
Cinnamic Aldehyde 132 26.056699215 3439.4843 0.638232249
40.8263594675 4783.34806 1

KONDENSOR 1

Komponen BM yi Vi=Yi.Vo Vi (kg/jam)

Acetaldehyde 44 0.9973375645 26.0264174621061 1145.1623683
Benzaldehyde 106 0.0026126082 0.068178351482036 7.2269052571
Cinnamic Aldehyde 132 4.982734E-05 0.001300289003516 0.1716381485
1152.56091174
Komposisi Cair
Li= Vi -Di

Li = Vi + Bi
Komponen BM
kmol/jam kg/jam Fraksi Mol
Acetaldehyde 44 3.2337947609 142.28697 0.99733756
Benzaldehyde 106 0.0084711926 0.8979464 0.00261261
Cinnamic Aldehyde 132 0.0001615615 0.0213261 4.98273E-05 1009.35466972
3.2424275151 143.206242 1

DESTILASI 2

Fungsi memisahkan Cinnamaldehyde dari campuran

 Destilasi 2

kapasitas produksi 1515.15151515 kg/ thn

konversi 0.8

Antoine constant data of compount

Komponen A B C Tmin (oC) Tmax (oC) oK

Acetaldehyde 5.1883 1637.083 22.317 -0.25 34.45 307.6
Benzaldehyde 3.876 1380.72 -94.98 26 178.85 452
Cinnamic Aldehyde 5.45 2767 -27.816 349 245.85 519

feed
p 1 atm 1.013125 bar
T trial 170 c
T 443.15 k
Komponen BM Massa input Kmol XF
Acetaldehyde 44 10.1320339673 0.2302735 0.016000282
Benzaldehyde 106 295.186192677 2.7847754 0.193496823
Cinnamic Aldehyde 132 1501.73648043 11.3767915 0.790502895
1807.05470707 14.3918404 1

Komponen Ln Pi Pi Ki αi
Acetaldehyde 1.67122360146 5.31867175176 5.24976854 17.87372376
Benzaldehyde -0.0896489646 0.9142520638 0.90240796 3.072400328
 Cinnamic Aldehyde -1.2121080865 0.2975693159 0.29371432 1

Komponen log αi αi.XF yi

Acetaldehyde 1.25221504158 0.28598461313 0.1711471
Benzaldehyde 0.48747780281 0.59449970335 0.35577753
Cinnamic Aldehyde 0 0.79050289512 0.47307537
1.67098721161 1

asumsi distribusi produk distilat dan bottom asumsi

Chart Title
top bottom
Acetaldehyde 99.00% 1.00% 72.9 27.1 2
Cinnamic Aldehyde HK 0.10% 99.9%
Benzaldehyde LK 95.0% 5.00% 1 f(x) = 8.77643877220689 x − 2.99956548822598

Komponen n distilat n bottom mol D/B log D/B log α feed distilat feed bottom
0
Acetaldehyde 0.01584027877 0.00016000282 99 1.995635195 1.25221504158 10.0307136275935 0.10132033967266 0 0.1 0.2 0.3
Cinnamic Aldehyde 0.0007905029 0.78971239223 0.001001 -2.99956549 0 1.50173648042603 1500.2347439456
Benzaldehyde 0.18382198213 0.00967484116 19 1.278753601 0.48747780281 292.234330750235 2.95186192677005 -1

-2
Komponen log α log D/B a 8.7764
Acetaldehyde 1.25221504158 1.9956351946 c -2.9996
-3
Cinnamic Aldehyde 0 -2.9995654882
Benzaldehyde 0.48747780281 1.27875360095
-4
destilat
tentukan T bubble point destilat
P 1 atm 1.013125 bar
T trial 150.2 C
T 423.35 K

Komponen `Log D/B D/B kmol XD

Acetaldehyde 7.99034009091 97800278.3667 0.2302735 0.079757519
Benzaldehyde 1.27870018859 18.9976633999 2.64552036 0.916302328
Cinnamic Aldehyde -2.9996 0.00100092146 0.01137589 0.003940152
2.88716975 1

Komponen Ln Pi Pi Ki αi yi
Acetaldehyde 1.51496766891 4.54927404148 4.49033835 21.33979436 0.35813824759
 Benzaldehyde -0.3287690106 0.71980926588 0.71048416 3.376490747 0.6510182913
Cinnamic Aldehyde -1.5456059403 0.21318265611 0.21042088 1 0.00082909031
1.00998562921

tentukan T dew point distilat

P 1 atm 1.013125 bar
T trial 170 C
T 443.15 K

Komponen yi ln Pi Pi Ki Xi
Acetaldehyde 0.07975751928 1.67122360146 5.31867175 5.24976854 0.01519257824
Benzaldehyde 0.91630232846 -0.0896489646 0.91425206 0.902407959 1.01539699311
Cinnamic Aldehyde 0.00394015225 -1.2121080865 0.29756932 0.293714316 0.01341491389
1.04400448524

Bottom

tentukan T buble bottom destilasi

P 1 atm 1.013125 bar
T trial 265 C
T 538.15 K

Komponen Log D/B D/B Kmol XB

Acetaldehyde 7.99034009091 97800278.3667 2.3545E-09 2.04658E-10
Benzaldehyde 1.27870018859 18.9976633999 0.13925504 0.012104218
Cinnamic Aldehyde -2.9996 0.00100092146 11.3654156 0.987895782
11.5046707 1

Komponen Ln Pi Pi Ki αi yi
Acetaldehyde 2.26737334419 9.65400972115 9.52894235 9.386877484 1.9501786E-09
Benzaldehyde 0.76044614933 2.13923042385 2.11151677 2.080036635 0.02555825879
Cinnamic Aldehyde 0.02806064264 1.02845805094 1.01513441 1 1.00284700358
1.02840526432

Tentukan Dew Point Destilasi

P 1 atm 1.013125 bar
T trial 260 C
T 533.15 K

Komponen yi ln Pi Pi Ki Xi
 Acetaldehyde 2.0465845E-10 2.24108081326 9.40348921 9.281667329 2.204975E-11
Benzaldehyde 0.01210421778 0.72489426478 2.0645128 2.037767103 0.00593994169
Cinnamic Aldehyde 0.98789578202 -0.0255864438 0.97473812 0.962110416 1.02680083861
1.03274078033

menghitung stage minimum

Xlk Destilat 0.916302328 αL,av 14.1532340875

Xhk Destilat 0.003940152 NM 3.71749492722
Xlk Bottom 0.012104218 2.71749492722
Xhk Bottom 0.987895782

Menghitung reflux minimum

P 1 atm 1.013125 bar
t dew point destilat 443.15
t buble point bottom 538.15

T feed rata-rata 490.65 K 217.5 C

Komponen BM A B C
Acetaldehyde 44 5.1883 1637.083 22.317
Benzaldehyde 106 3.876 1380.72 -94.98
Cinnamic Aldehyde 132 5.45 2767 -27.816

Komponen ln pi pi ki xf
Acetaldehyde 1.99689977347 7.36618382415 7.27075516 0.016000282
Benzaldehyde 0.38642535446 1.47171053634 1.45264458 0.193496823
Cinnamic Aldehyde -0.528385339 0.58955613485 0.58191846 0.790502895

Komponen αi αi.xf/αi-Ɵ αi.xd/αi-Ɵ Ɵ 0.1

Acetaldehyde 12.4944570817 0.01612937382 0.08040101
Benzaldehyde 2.49630264081 0.2015716307 0.9545405
Cinnamic Aldehyde 1 0.87833655014 0.00437795
1.03931946 1.3

RM+1 1.03931946
RM 0.03931946
R 0.051115298
Ѱ 0.011222211
(N-Nm)/N+1) 0.704947495
N 11.59943524

REBOILER 2
D B
Komponen BM
kmol/jam Kg/jam kmol/jam Kg/jam
Acetaldehyde 44 0.2302734969 10.1320339 2.35453E-09 1.0359923E-07
Benzaldehyde 106 2.64552036332 280.425159 0.139255039 14.7610341655
Cinnamic Aldehyde 132 0.01137588839 1.50161727 11.36541563 1500.23486316
2.8871697486 292.05881 11.50467067 1514.99589743
14.3918404202 1807.054707

Menentukan komposisi uap reboiler

V=(Rop +1)D
V 3.034748292

Komponen BM yi Vi=Yi.Vo Vi (kg/jam)

Acetaldehyde 44 1.9501786E-09 5.91830103308067E-09 2.6040525E-07
Benzaldehyde 106 0.02555825879 0.077562882187733 8.2216655119
Cinnamic Aldehyde 132 1.00284700358 3.04338823094568 401.727246485
409.948912257

Li = Vi + Bi
Komponen BM
kmol/jam kg/jam Fraksi Mol
Acetaldehyde 44 8.2728291E-09 3.64E-07 5.65639E-10
Benzaldehyde 106 0.21681792149 22.9826997 0.014824527
Cinnamic Aldehyde 132 14.4088038609 1901.96211 0.985175473 1514.99589743
14.6256217907 1924.94481 1

KONDENSOR 2

Komponen BM yi Vi=Yi.Vo Vi (kg/jam)

Acetaldehyde 44 0.07975751928 0.242043995397817 10.6499357975
Benzaldehyde 106 0.91630232846 2.78074692597861 294.759174154
Cinnamic Aldehyde 132 0.00394015225 0.011957370315667 1.57837288167
306.987482833
Komposisi Cair
Li= Vi -Di

Li = Vi + Bi
Komponen BM
kmol/jam kg/jam Fraksi Mol
Acetaldehyde 44 0.0117704985 0.5179019 0.07975752
Benzaldehyde 106 0.1352265627 14.334016 0.91630233
Cinnamic Aldehyde 132 0.0005814819 0.0767556 0.003940152 292.058809642
0.14757854309 14.9286732 1
kmol
kmol

kg
 272.9 307.6
-0.25 34.45

Grafik Distribusi Distilat dan Bottom

) = 2.92702457835597 x − 3.99956548822598

0.5 1 1.5 2 2.5

log α log D/B

Benzaldehyde 0.796322594 -0.42975824

Log α
Log α
1.600164467
0.087062557
 Chart Title

7220689 x − 2.99956548822598

0.2 0.3 0.4 0.5 0.6

 LAMPIRAN B
PERHITUNGAN NERACA MASSA RECYCLE

Kapasitas Produksi = 12000 ton/tahun

Basis Perhitungan = 1 jam operasi
Waktu Kerja per Tahun = 330 hari
Satu Hari Operasi = 24 jam operasi
Satuan Perhitungan = kg/jam dan kmol/jam
Konversi Bahan Baku = 0.8

Kapasitas produksi dalam satu jam operasi

= 12000 ton x 1000 kg x 1 tahun
thn 1 ton 330 hari
= 1515.151515 kg/jam

Tabel A.1 Berat Molekul

komponen rumus molekul Molecular Weight Boiling point (
Benzaldehyde C6H5CHO 106 178.1
Acetaldehyde CH3CHO 44 34.45
Polyethylene glycol PEG 400 414 294
Cinnamic Aldehyde C6H5CHCHCHO 132 245
Water H2O 18 100
Deionised Water H2O 18 100
Ion Exchange Resin ‒ ‒ ‒

konversi = mol umpan bereaksi

= 0.8
mol umpan mula-mula

basis
Benzaldehyde = 99.5% 0.995 = 1507.57575757576
1515.151515
Acetaldehyde = 99.0% 0.999 = 1513.63636363636
Deionised Water = = 204.802744425386
Rohm & Hass Resin = 10-15% massa benzaldehide 12.5 %
Cinnamic Aldehyde =

REAKTOR

Ion Exch Resin

C6H5CHO + CH3CHO ---------------->> C 6H5CHCHCHO + H2O
PEG 400

awal 14.22241281 34.40083 0 0

reaksi 11.37793025 11.37793 11.37793025 11.3779302458548
sisa 2.844482561 23.0229 11.37793025 11.3779302458548

Input Acetaldehyde arus 1 100%

konsentrasi Acetaldehyde 99.9%
konsentrasi H2O 0.1%
massa Acetaldehyde 1513.63636364 1503.50433
mol acetaldehyde 34.4008264463 kmol
massa H2O 1.51515151515

Input Benzaldehyde arus 2 100%

 konsentrasi Benzaldehyde 99.5%
konsentrasi H2O 0.5%
massa Benzaldehyde 1507.57575758 1227.150599
mol Benzaldehyde 14.2224128073 kmol
massa H2O 7.57575757576 kg

Input Polyethylene glicol 100% 0.5% dari benzaldehyde

massa PEG 400 7.53787878788
mol PEG 400 15.1060606061

Input Resin Ion Exhange

Konsentrasi Resin 100%
Massa resin 100% wt 10-15% wt dari berat benzaldehyde
188.446969697 kg

Input Deonized water 100% 1 kg

mol 0.05555555556 kmol
massa 1.2 kali massa acetal +benzal bereaksi 54.3
input arus 6 Recycle
massa benzal 6.32895883815
massa acetal 1002.87539885

input acetaldehyde arus 7

massa benzal 280.425158511
massa acetal 10.1320338637

Neraca Massa
reaktor
tujuan mereaksikan bahan baku

5 6

2 7
Reaktor
3

tekanan operasi = 1 atm = 760 mmHg

suhu operasi = 30 ◦C = 303.15 K

S1 S2 S3 S4 S5 S6 R
komponen
kg/jam kg/jam kg/jam kg/jam kg/jam kg/jam
Acetaldehyde 1503.50432977 0 0 0 0 10.132033863667
Benzaldehyde 0 1227.15059906 0 0 0 280.42515851148
Cinnamic Aldehyde 0 0 0 0 0
water 1.51515151515 7.57575757576 0 0 0
Deonized Water 0 0 54.3 0 0
Rhom & Hass Resin 0 0 0 188.4469697 0
PEG 400 0 0 0 0 7.53787878788
total 3280.58787878788
 SCREENING
memisahkan resin dari campuran produk
efisiensi 100%
tekanan operasi 1 atm
suhu operasi 30 ◦C

8
7
Screening

keluar
komponen masuk
atas bawah
Acetaldehyde 1013.00743282 1013.00743282 0
Benzaldehyde 301.515151515 301.515151515 0
Cinnamic Aldehyde 1501.88679245 1501.88679245 0
water 213.893653516 213.893653516 0
Deonized Water 54.3 54.3 0
Rhom & Hass Resin 188.446969697 0 188.44697
PEG 400 7.53787878788 7.53787878788 0
3092.14090909 188.44697
total 3280.58787879
3280.58787878788

SEPARATOR
fungsi memisahkan campuran PEG 400-air dengan produk
efisiensi 100%
tekanan operasi 1 atm
suhu operasi 30 ◦C

8 10

Separator

11

keluar
komponen masuk
atas bawah
Acetaldehyde 1013.00743282 1013.00743282 0
 Benzaldehyde 301.515151515 301.515151515 0
Cinnamic Aldehyde 1501.88679245 1501.88679245 0
water 213.893653516 0 213.893654
Deonized Water 54.3 0 54.3
PEG 400 7.53787878788 0 7.53787879
2816.40937679 275.731532
total 3092.14090909
3092.14090909091

MEMBRAN SEPARATOR
fungsi memisahkan air dan deonized water dari PEG 400
efisiensi 100%
tekanan operasi 1 atm
suhu operasi 30 ◦C

11

Membrane
Separator
12

13

keluar
komponen masuk
atas bawah
water 213.893653516 213.893653516 0
Deonized Water 54.3 54.3 0
PEG 400 7.53787878788 0 7.53787879
total 275.731532304 268.193653516 7.53787879

DESTILASI 1

Fungsi memisahkan Acetaldehyde dari campuran

15
kapasitas produksi 1515.15151515 kg/ thn
konversi 0.8

Destilasi 1
 10

Destilasi 1

14

Antoine constant data of compount

Komponen A B C Tmin (oC) Tmax (oC)

Acetaldehyde 5.1883 1637.083 22.317 -0.25 34.45
Benzaldehyde 3.876 1380.72 -94.98 26 178.85
Cinnamic Aldehyde 5.45 2767 -27.816 349 245.85

feed
p 1 atm 1.013125 bar
T trial 32 C
T 305.15 K

Komponen BM Massa input Kmol XF

Acetaldehyde 44 1013.00743282 23.0228962 0.618142172
Benzaldehyde 106 301.515151515 2.84448256 0.076371566
Cinnamic Aldehyde 132 1501.88679245 11.3779302 0.305486263
37.245309

Komponen Ln Pi Pi Ki αi
Acetaldehyde 0.18906954319 1.20812496643 1.19247375 111.7438302
Benzaldehyde -2.6935389447 0.06764113706 0.06676485 6.256372432
Cinnamic Aldehyde -4.527139478 0.01081155858 0.0106715 1

Komponen log αi αi.XF yi

Acetaldehyde 2.04822355342 69.0735738874 0.98878714
Benzaldehyde 0.79632259366 0.47780895779 0.00683983
Cinnamic Aldehyde 0 0.30548626254 0.00437303
69.8568691077 1

asumsi distribusi produk distilat dan bottom asumsi

top bottom
Acetaldehyde LK 99% 1%
Cinnamic Aldehyde HK 0.01% 99.9%
Benzaldehyde 27.10% 73%
 Komponen n distilat n bottom mol D/B log D/B log α feed distilat
Acetaldehyde (LK) 0.61196075011 0.00618142172 99 1.995635195 2.04822355342 1002.87735849057
Benzaldehyde 0.02069669429 0.05567487135 0.37174211 -0.42975824 0.79632259366 81.710606060606
Cinnamic Aldehyde (HK) 3.054863E-05 0.3051807763 0.0001001 -3.9995655 0 0.15018867924528

Komponen log α log D/B

Acetaldehyde (LK) 2.04822355342 1.9956351946
Cinnamic Aldehyde (HK) 0 -3.9995654882

destilat
tentukan T bubble point destilat
P 1 atm 1.013125 bar
T trial 21.3 C
T 294.45 K

Komponen `Log D/B D/B kmol XD

Acetaldehyde 1.99555034086 98.9806589764 22.7926227 0.997337564
Benzaldehyde -1.6687637684 0.02144056529 0.05970716 0.002612608
Cinnamic Aldehyde -3.9996 0.00010009215 0.00113873 4.9827E-05
22.853469 1

Komponen Ln Pi Pi Ki αi yi
Acetaldehyde 0.02020168168 1.02040711669 1.00718778 140.8538641 1.00450620462
Benzaldehyde -3.0459431493 0.04755144272 0.04693542 6.563855093 0.00012262385
Cinnamic Aldehyde -4.9275212464 0.00724443822 0.00715059 1 3.562947E-07
1.00462918476
tentukan T dew point distilat
P 1 atm 1.013125 bar
T trial 23.8912 C
T 297.0412 K

Komponen yi ln Pi Pi Ki Xi
Acetaldehyde 0.99733756449 0.06213445924 1.06410541 1.050319964 0.94955594325
Benzaldehyde 0.00261260817 -2.957177275 0.05196539 0.051292184 0.05093579467
Cinnamic Aldehyde 4.9827337E-05 -4.8276411718 0.00800538 0.007901673 0.0063059225
1.00679766041
Bottom

tentukan T buble bottom destilasi

P 1 atm 1.013125 bar
T trial 233.62 C
T 506.77 K

Komponen Log D/B D/B Kmol XB

Acetaldehyde 1.99555034086 98.9806589764 0.2302735 0.016000282
Benzaldehyde -1.6687637684 0.02144056529 2.7847754 0.193496823
Cinnamic Aldehyde -3.9996 0.00010009215 11.3767915 0.790502895
14.3918404 1

Komponen Ln Pi Pi Ki αi yi
Acetaldehyde 2.09413401218 8.11840748316 8.01323379 11.26056465 0.12821399704
Benzaldehyde 0.52302882537 1.68712994079 1.66527323 2.340118528 0.32222507985
Cinnamic Aldehyde -0.3271727556 0.72095918251 0.71161918 1 0.56253702262
1.01297609951
Tentukan Dew Point Destilasi
P 1 atm 1.013125 bar
T trial 246 C
T 519.15 K

Komponen yi ln Pi Pi Ki Xi
Acetaldehyde 0.01600028159 2.16487844338 8.71354266 8.600659014 0.0018603553
Benzaldehyde 0.19349682329 0.62089002051 1.86058326 1.836479469 0.10536291122
Cinnamic Aldehyde 0.79050289512 -0.1816070127 0.833929 0.823125478 0.96036742469
1.06759069121

menghitung stage minimum

Xlk Destilat 0.997337564 αL,av 39.8257961942

Xhk Destilat 4.98273E-05 NM 3.74658384479
Xlk Bottom 0.016000282 2.74658384479
Xhk Bottom 0.790502895

Menghitung reflux minimum

P 1 atm 1.013125 bar
t dew point destilat 297.0412
t buble point bottom 506.77

T feed rata-rata 401.9056 K 128.7556 C

Komponen BM A B C
Acetaldehyde 44 5.1883 1637.083 22.317
Benzaldehyde 106 3.876 1380.72 -94.98
Cinnamic Aldehyde 132 5.45 2767 -27.816

Komponen ln pi pi ki xf
Acetaldehyde 1.32928117356 3.77832645024 3.72937836 0.618142172
Benzaldehyde -0.6225494856 0.53657470279 0.5296234 0.076371566
Cinnamic Aldehyde -1.9466236966 0.14275524386 0.14090585 0.305486263
1
Komponen αi αi.xf/αi-Ɵ αi.xd/αi-Ɵ Ɵ 2.5
Acetaldehyde 26.4671639945 0.68262019809 1.10136923
Benzaldehyde 3.75870397679 0.22805847344 0.00780169
Cinnamic Aldehyde 1 -0.2036575084 -3.3218E-05
0.70702116318 1.1091377 1.3
mendekati 0
RM+1 1.109138
RM 0.109138
R 0.141879
Ѱ 0.028673
(N-Nm)/N+1) 0.640309
N 9.416118

REBOILER 1

D B
Komponen BM
kmol/jam Kg/jam kmol/jam Kg/jam
Acetaldehyde 44 22.7926227012 1002.8754 0.230273499 10.1320339673
Benzaldehyde 106 0.05970715885 6.32895884 2.784775403 295.186192677
 Cinnamic Aldehyde 132 0.00113872748 0.15031203 11.37679152 1501.73648043
total 22.8534685875 1009.35467 14.39184042 1807.05470707
37.2453090077 2816.40937679

Menentukan komposisi uap reboiler

V=(Rop +1)D
v 26.0958961

Komponen BM yi Vi=Yi.Vo Vi (kg/jam)

Acetaldehyde 44 0.12821399704 3.34585914576775 147.217802414

Benzaldehyde 106 0.32222507985 8.40875220536405 891.327733769
Cinnamic Aldehyde 132 0.56253702262 14.6799076961249 1937.74781589
2976.29335207

Li = Vi + Bi
Komponen BM
kmol/jam kg/jam Fraksi Mol
Acetaldehyde 44 3.576132645 157.34984 0.08759372 1807.0547070703
Benzaldehyde 106 11.193527608 1186.5139 0.274174033
Cinnamic Aldehyde 132 26.056699215 3439.4843 0.638232249
40.8263594675 4783.34806 1

KONDENSOR 1

Komponen BM yi Vi=Yi.Vo Vi (kg/jam)

Acetaldehyde 44 0.9973375645 26.0264174621061 1145.1623683
Benzaldehyde 106 0.0026126082 0.068178351482036 7.2269052571
Cinnamic Aldehyde 132 4.982734E-05 0.001300289003516 0.1716381485
1152.56091174
Komposisi Cair
Li= Vi -Di

Li = Vi + Bi
Komponen BM
kmol/jam kg/jam Fraksi Mol
Acetaldehyde 44 3.2337947609 142.28697 0.99733756
Benzaldehyde 106 0.0084711926 0.8979464 0.00261261
Cinnamic Aldehyde 132 0.0001615615 0.0213261 4.98273E-05 1009.35466972
3.2424275151 143.206242 1

DESTILASI 2

Fungsi memisahkan Cinnamaldehyde dari campuran

14
Destilasi 2
 14
Destilasi 2

16

kapasitas produksi 1515.15151515 kg/ thn

konversi 0.8

Antoine constant data of compount

Komponen A B C Tmin (oC) Tmax (oC)

Acetaldehyde 5.1883 1637.083 22.317 -0.25 34.45
Benzaldehyde 3.876 1380.72 -94.98 26 178.85
Cinnamic Aldehyde 5.45 2767 -27.816 349 245.85

feed
p 1 atm 1.013125 bar
T trial 170 c
T 443.15 k
Komponen BM Massa input Kmol XF
Acetaldehyde 44 10.1320339673 0.2302735 0.016000282
Benzaldehyde 106 295.186192677 2.7847754 0.193496823
Cinnamic Aldehyde 132 1501.73648043 11.3767915 0.790502895
1807.05470707 14.3918404 1

Komponen Ln Pi Pi Ki αi
Acetaldehyde 1.67122360146 5.31867175176 5.24976854 17.87372376
Benzaldehyde -0.0896489646 0.9142520638 0.90240796 3.072400328
Cinnamic Aldehyde -1.2121080865 0.2975693159 0.29371432 1

Komponen log αi αi.XF yi

Acetaldehyde 1.25221504158 0.28598461313 0.1711471
Benzaldehyde 0.48747780281 0.59449970335 0.35577753
Cinnamic Aldehyde 0 0.79050289512 0.47307537
1.67098721161 1

asumsi distribusi produk distilat dan bottom asumsi

top bottom
Acetaldehyde 99.00% 1.00% 72.9
Cinnamic Aldehyde HK 0.10% 99.9%
Benzaldehyde LK 95.0% 5.00%

Komponen n distilat n bottom mol D/B log D/B log α feed distilat
Acetaldehyde 0.01584027877 0.00016000282 99 1.995635195 1.25221504158 10.0307136275935
Cinnamic Aldehyde 0.0007905029 0.78971239223 0.001001 -2.99956549 0 1.50173648042603
Benzaldehyde 0.18382198213 0.00967484116 19 1.278753601 0.48747780281 292.234330750235

Komponen log α log D/B a

Acetaldehyde 1.25221504158 1.9956351946 c
 Cinnamic Aldehyde 0 -2.9995654882
Benzaldehyde 0.48747780281 1.27875360095

destilat
tentukan T bubble point destilat
P 1 atm 1.013125 bar
T trial 150.2 C
T 423.35 K

Komponen `Log D/B D/B kmol XD

Acetaldehyde 7.99034009091 97800278.3667 0.2302735 0.079757519
Benzaldehyde 1.27870018859 18.9976633999 2.64552036 0.916302328
Cinnamic Aldehyde -2.9996 0.00100092146 0.01137589 0.003940152
2.88716975 1

Komponen Ln Pi Pi Ki αi yi
Acetaldehyde 1.51496766891 4.54927404148 4.49033835 21.33979436 0.35813824759
Benzaldehyde -0.3287690106 0.71980926588 0.71048416 3.376490747 0.6510182913
Cinnamic Aldehyde -1.5456059403 0.21318265611 0.21042088 1 0.00082909031
1.00998562921

tentukan T dew point distilat

P 1 atm 1.013125 bar
T trial 170 C
T 443.15 K

Komponen yi ln Pi Pi Ki Xi
Acetaldehyde 0.07975751928 1.67122360146 5.31867175 5.24976854 0.01519257824
Benzaldehyde 0.91630232846 -0.0896489646 0.91425206 0.902407959 1.01539699311
Cinnamic Aldehyde 0.00394015225 -1.2121080865 0.29756932 0.293714316 0.01341491389
1.04400448524

Bottom

tentukan T buble bottom destilasi

P 1 atm 1.013125 bar
T trial 265 C
T 538.15 K

Komponen Log D/B D/B Kmol XB

Acetaldehyde 7.99034009091 97800278.3667 2.3545E-09 2.04658E-10
Benzaldehyde 1.27870018859 18.9976633999 0.13925504 0.012104218
Cinnamic Aldehyde -2.9996 0.00100092146 11.3654156 0.987895782
11.5046707 1

Komponen Ln Pi Pi Ki αi yi
Acetaldehyde 2.26737334419 9.65400972115 9.52894235 9.386877484 1.9501786E-09
Benzaldehyde 0.76044614933 2.13923042385 2.11151677 2.080036635 0.02555825879
Cinnamic Aldehyde 0.02806064264 1.02845805094 1.01513441 1 1.00284700358
1.02840526432

Tentukan Dew Point Destilasi

P 1 atm 1.013125 bar
T trial 260 C
T 533.15 K
 Komponen yi ln Pi Pi Ki Xi
Acetaldehyde 2.0465845E-10 2.24108081326 9.40348921 9.281667329 2.204975E-11
Benzaldehyde 0.01210421778 0.72489426478 2.0645128 2.037767103 0.00593994169
Cinnamic Aldehyde 0.98789578202 -0.0255864438 0.97473812 0.962110416 1.02680083861
1.03274078033

menghitung stage minimum

Xlk Destilat 0.916302328 αL,av 14.1532340875

Xhk Destilat 0.003940152 NM 3.71749492722
Xlk Bottom 0.012104218 2.71749492722
Xhk Bottom 0.987895782

Menghitung reflux minimum

P 1 atm 1.013125 bar
t dew point destilat 443.15
t buble point bottom 538.15

T feed rata-rata 490.65 K 217.5 C

Komponen BM A B C
Acetaldehyde 44 5.1883 1637.083 22.317
Benzaldehyde 106 3.876 1380.72 -94.98
Cinnamic Aldehyde 132 5.45 2767 -27.816

Komponen ln pi pi ki xf
Acetaldehyde 1.99689977347 7.36618382415 7.27075516 0.016000282
Benzaldehyde 0.38642535446 1.47171053634 1.45264458 0.193496823
Cinnamic Aldehyde -0.528385339 0.58955613485 0.58191846 0.790502895

Komponen αi αi.xf/αi-Ɵ αi.xd/αi-Ɵ Ɵ 0.1

Acetaldehyde 12.4944570817 0.01612937382 0.08040101
Benzaldehyde 2.49630264081 0.2015716307 0.9545405
Cinnamic Aldehyde 1 0.87833655014 0.00437795
1.03931946 1.3

RM+1 1.03931946
RM 0.03931946
R 0.051115298
Ѱ 0.011222211
(N-Nm)/N+1) 0.704947495
N 11.59943524

REBOILER 2
D B
Komponen BM
kmol/jam Kg/jam kmol/jam Kg/jam
Acetaldehyde 44 0.2302734969 10.1320339 2.35453E-09 1.0359923E-07
Benzaldehyde 106 2.64552036332 280.425159 0.139255039 14.7610341655
Cinnamic Aldehyde 132 0.01137588839 1.50161727 11.36541563 1500.23486316
2.8871697486 292.05881 11.50467067 1514.99589743
14.3918404202 1807.054707

Menentukan komposisi uap reboiler

V=(Rop +1)D
V 3.034748292

Komponen BM yi Vi=Yi.Vo Vi (kg/jam)

Acetaldehyde 44 1.9501786E-09 5.91830103308067E-09 2.6040525E-07

Benzaldehyde 106 0.02555825879 0.077562882187733 8.2216655119
Cinnamic Aldehyde 132 1.00284700358 3.04338823094568 401.727246485
409.948912257

Li = Vi + Bi
Komponen BM
kmol/jam kg/jam Fraksi Mol
Acetaldehyde 44 8.2728291E-09 3.64E-07 5.65639E-10
Benzaldehyde 106 0.21681792149 22.9826997 0.014824527
Cinnamic Aldehyde 132 14.4088038609 1901.96211 0.985175473 1514.99589743
14.6256217907 1924.94481 1

KONDENSOR 2

Komponen BM yi Vi=Yi.Vo Vi (kg/jam)

Acetaldehyde 44 0.07975751928 0.242043995397817 10.6499357975
Benzaldehyde 106 0.91630232846 2.78074692597861 294.759174154
Cinnamic Aldehyde 132 0.00394015225 0.011957370315667 1.57837288167
306.987482833
Komposisi Cair
Li= Vi -Di

Li = Vi + Bi
Komponen BM
kmol/jam kg/jam Fraksi Mol
Acetaldehyde 44 0.0117704985 0.5179019 0.07975752
Benzaldehyde 106 0.1352265627 14.334016 0.91630233
Cinnamic Aldehyde 132 0.0005814819 0.0767556 0.003940152 292.058809642
0.14757854309 14.9286732 1
AMPIRAN B
NERACA MASSA RECYCLE

x 1 hari
24 jam

Boiling point (◦C)

178.1
34.45
294
245
100
100
‒

kg = 14.2224128073185 kmol
kg = 34.400826446281 kmol
kg
0.125 = 188.44696969697 kg
erat benzaldehyde 12.5%

Out
kg/jam
1013.00743281875
301.515151515151
1501.88679245283
213.893653516295
54.3
188.44696969697
7.53787878787879
3280.58787878788
Tmax (oC) oK
34.45 307.6
178.85 452
245.85 519 272.9 307.6
-0.25 34.45

Grafik Distribusi Distilat dan Bottom

3
2
f(x) = 2.92702457835597 x − 3.99956548822598
1
0
Log D/B

0 0.5 1 1.5 2 2.5

-1
-2
-3
-4
-5
Log α
 0

Log D/B
0 0.5 1 1.5 2 2.5
-1
-2
-3
feed bottom -4
10.1300743281875 Benzaldehyde
-5
219.804545454545
1500.38490566 Log α

a= 2.927
c= -3.9996
 1.600164467
0.087062557

0.02239130434783
Tmax (oC) oK
34.45 307.6
178.85 452
245.85 519

27.1
Chart Title
2

1 f(x) = 8.77643877220689 x − 2.99956548822598

feed bottom
0.10132033967266
1500.2347439456 0
0 0.1 0.2 0.3 0.4 0.5 0.6
2.95186192677005
-1

8.7764
-2
-2.9996

-3

-4
-1

-2

-3

-4
log α log D/B
0.796322594 -0.42975824
 LAMPIRAN C
PERHITUNGAN NERACA ENERGI
NERGI
 LAMPIRAN D
PERHITUNGAN NERACA ENERGI
NERGI