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SPECTRUM QUALITY STANDARDS

17360 GROSCHKE RD.


HOUSTON, TX 77084
PHONE: 281-578-7575 ● FAX: 281-578-7576

Part Number: MSX-41 (various part numbers)


SAFETY DATA SHEET
Revision Date: 5/3/2016

SECTION 1: IDENTIFICATION

Chemical Product Identity: BASE FUEL MIX - D5623 MULTI-COMPONENT (41) STANDARD
{Multi-component standard (as component only) with the following volumes of either a 10x2 or 1x2 ml ampoule(s) containing
custom concentration (per customer’s specs) of 41 components in a base fuel matrix which consists of 20% Toluene, 40%
Hexane, & 40% Isooctane.}
Part Number: MSX-41-1-10, MSX-41-1-100, MSX-41-1-50, MSX-41-1-900; MSX-41-10-10, MSX-41-10-100, MSX-41-10-50
Emergency Telephone Number: 1-800-535-5053 or 001-352-323-3500 (Outside the U.S.)
SECTION 2: HAZARD(S) IDENTIFICATION
Identification:
ISOOCTANE
FLAMMABLE LIQUID AND VAPOR. Can accumulate static charge. Vapor is heavier than air and may spread long distances. Distant
ignition and flashback are possible. Liquid can float on water and may travel to distant locations and/or spread fire. Central nervous
system depressant. High vapor concentrations may cause headache, nausea, dizziness, drowsiness, confusion, unconsciousness and
death. Aspiration hazard. Swallowing or vomiting of the liquid may result in aspiration into the lungs.
TOLUENE
FLAMMABLE LIQUID AND VAPOR. Liquid can accumulate static charge by flow or agitation. Vapor is heavier than air and may spread
long distances. Distant ignition and flashback are possible. Liquid can float on water and may travel to distant locations and/or spread fire.
Can decompose at high temperatures forming toxic gases. Closed containers may rupture and explode in heat of fire. Mild central nervous
system depressant. Vapor may cause headache, nausea, dizziness, drowsiness, confusion and incoordination.
SKIN IRRITANT. Causes moderate skin irritation. Aspiration hazard. Swallowing or vomiting of the liquid may result in aspiration into the
lungs. POSSIBLE TERATOGEN/EMBRYOTOXIN - may harm the unborn child, based on animal information. Confined space hazard.
Can accumulate in confined spaces, producing a fire and toxicity hazard.
HEXANE
EXTREMELY FLAMMABLE LIQUID AND VAPOR. Can accumulate static charge. Vapor is heavier than air and may spread long
distances. Distant ignition and flash back are possible. Liquid can float on water and may travel to distant locations and spread fire. Can
decompose at high temperature forming carbon monoxide, carbon dioxide and other irritating and toxic vapors, fumes and smoke. Mild
central nervous system depressant. High vapor concentrations may cause headache, nausea, dizziness, drowsiness, incoordination, and
unconsciousness. High vapor concentrations can displace oxygen in the air and life-threatening asphyxiation (suffocation) may result.
Confined space hazard. Can accumulate in confined spaces, producing a fire/toxicity hazard. SKIN IRRITANT. Causes moderate skin
irritation. VERY TOXIC. Long-term exposure may cause damage to the nervous system of the extremities (the hands, arms, legs and
feet). Aspiration hazard. Swallowing or vomiting of the liquid may result in aspiration (breathing) into the lungs.
GHS LABELING SYMBOLS:

SIGNAL WORD: DANGER


HAZARD STATEMENTS:
Highly flammable liquid and vapor.
May be fatal if swallowed and enters airways.
Causes skin irritation.
May cause drowsiness or dizziness.
Suspected of damaging fertility or the unborn child.
May cause damage to organs (Nervous system) through prolonged or repeated exposure if swallowed.
Very toxic to aquatic life with long lasting effects.
May cause damage to organs (Central nervous system) through prolonged or repeated exposure.
Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment.
PRECAUTIONARY STATEMENTS:
Do not handle until all safety precautions have been read and understood.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Keep container tightly closed.
Use explosion-proof electrical/ ventilating/ lighting/ equipment.
Use only non-sparking tools.
Ground/bond container and receiving equipment.
Take precautionary measures against static discharge.
Do not breathe dust/ fume/ gas/ mist/ vapors/ spray.
Wash skin thoroughly after handling.
Use only outdoors or in a well-ventilated area.

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Page 1 of 6
v.2016SQS
SPECTRUM QUALITY STANDARDS
17360 GROSCHKE RD.
HOUSTON, TX 77084
PHONE: 281-578-7575 ● FAX: 281-578-7576

Part Number: MSX-41 (various part numbers)


SAFETY DATA SHEET
Revision Date: 5/3/2016

Avoid release to the environment.


Wear protective gloves/ protective clothing/ eye protection/ face protection. Response:
IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician.
IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower.
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Do NOT induce vomiting.
Store in a well-ventilated place. Keep cool.
Use explosion-proof electrical/ ventilating/ lighting/ equipment.
Use only non-sparking tools.
Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
Wash skin thoroughly after handling.
Use only outdoors or in a well-ventilated area.
Avoid release to the environment.
Wear protective gloves/ protective clothing/ eye protection/ face protection.
Call a POISON CENTER or doctor/ physician if you feel unwell.
Specific treatment (see supplemental first aid instructions on this label).
Do NOT induce vomiting.
If skin irritation occurs: Get medical advice/ attention.
Take off contaminated clothing and wash before reuse.
In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction.
Collect spillage.
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Dispose of contents/ container to an approved waste disposal plant.

For IATA Proper Shipping Name and identification, refer to Section 15 of this text. Please refer to Section 11 & 15 for Health Hazard
information.
SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS

Chemical Name CAS Num OSHA PEL/TWA ACGIH TLV/TWA % WT Chemical Formula
Benzothiophene 95-15-8 No data No data 0.0 – 0.09 C8H6S
1-Nonanethiol 25360-10-5 No data No data 0.0 – 0.09 C9H20S
Methyl Ethyl Sulfide 624-89-5 No data No data 0.0 – 0.09 C3H8S
Dimethyl Sulfide 75-18-3 Not established 10 ppm 0.0 – 0.09 C2-H6-S
2-Methyl-1-Propanethiol 513-44-0 Not established Not established 0.0 – 0.09 C4H10S
2-Methylthiophene 554-14-3 No data No data 0.0 – 0.09 C5H6S
3-Methylthiophene 616-44-4 No data No data 0.0 – 0.09 C5H6S
1,2 Ethanedithiol 540-63-6 Not established Not established 0.0 – 0.09 C2-H6-S2
1-Pentanethiol 110-66-7 Not established Not established 0.0 – 0.09 C5-H12-S
2-Ethylthiophene 872-55-9 No data No data 0.0 – 0.09 C6H8S
Dipropyl Sulfide 111-47-7 No data No data 0.0 – 0.09 C6H14S
1,5-Pentanedithiol 928-98-3 No data No data 0.0 – 0.09 C5H12S2
1-Decanethiol 143-10-2 Not established Not established 0.0 – 0.09 C10-H22-S
1-Propanethiol 107-03-9 Not established Not established 0.0 – 0.09 C3-H8-S
T-Butyl Sulfide 107-47-1 No data No data 0.0 – 0.09 C8H18S
1-Heptanethiol 1639-09-4 No data No data 0.0 – 0.09 C7-H16-S
1,4-Butanedithiol 1191-08-8 No data No data 0.0 – 0.09 C4H10S2
Propyl Disulfide 629-19-6 No data No data 0.0 – 0.09 C6H14S
1-Octanethiol 111-88-6 Not established Not established 0.0 – 0.09 C8-H18-S
Tert-Butyl Disulfide 110-06-5 No data No data 0.0 – 0.09 C8H18S2
1-Hexanethiol 111-31-9 Not established Not established 0.0 – 0.09 C6-H14-S
Diethyl Sulfide 352-93-2 Not established Not established 0.0 – 0.09 C4-H10-S
Thiophene 110-02-1 No data No data 0.0 – 0.09 C4H4S
1-Butanethiol 109-79-5 10 ppm (35 mg/m3) 0.5 ppm 0.0 – 0.09 C4-H10-S
Diethyl Disulfide 110-81-6 No data No data 0.0 – 0.09 C4H10S2

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Page 2 of 6
v.2016SQS
SPECTRUM QUALITY STANDARDS
17360 GROSCHKE RD.
HOUSTON, TX 77084
PHONE: 281-578-7575 ● FAX: 281-578-7576

Part Number: MSX-41 (various part numbers)


SAFETY DATA SHEET
Revision Date: 5/3/2016

Thiophenol 108-98-5 0.5 ppm 0.1 ppm – skin 0.0 – 0.09 C6H6S
Methanethiol 74-93-1 10 ppm (20 mg/m3) 0.5 ppm 0.0 – 0.09 CH4S
Ethanethiol 75-08-1 10 ppm (25 mg/m3) 0.5 ppm 0.0 – 0.09 C2-H6-S
2-Propanethiol 75-33-2 Not established Not established 0.0 – 0.09 C3-H8-S
Bromothiophene 1003-09-4 No data No data 0.0 – 0.09 C4H3BrS
Diphenyl Sulfide 139-66-2 No data No data 0.0 – 0.09 C12H10S
t-Butanethiol 75-66-1 Not established Not established 0.0 – 0.09 C4-H10-S
Tetrahydrothiophene 110-01-0 No data No data 0.0 – 0.09 C4H8S
2-Methyl 1-Butanethiol 1878-18-8 No data No data 0.0 – 0.09 C5H12S
3-Methyl 1 Butanethiol 541-31-1 Not established Not established 0.0 – 0.09 C5H12S
2-Propylthiophene 1551-27-5 No data No data 0.0 – 0.09 C7H10S
2-Butylthiophene 1455-20-5 No data No data 0.0 – 0.09 C8H12S
3-Butylthiophene 34722-01-5 No data No data 0.0 – 0.09 C8H12S
Methylbenzothiophene 1195-14-8 No data No data 0.0 – 0.09 C9H8S
T-Butyl Methyl Sulfide 6163-64-0 No data No data 0.0 – 0.09 C5H12S
CS2 (Carbon Di Sulfide) 75-15-0 20 ppm 1 ppm – skin CDA4 0.0 – 0.09 C-S2
Toluene 108-88-3 200 ppm (skin) 20 ppm 20 C6H5CH3
Hexane 110-54-3 500 ppm (1800 mg/m3) 50 ppm - skin 40 C6-H14
Isooctane 540-84-1 500 ppm (23550 mg/m3) 300 ppm (octane, all isomers) 40 C8-H18
* Any component that comprises .1% or less, is not required to be listed individually on a SDS. Please consult the Certificate of Analysis for this information.

SECTION 4: FIRST-AID MEASURES Unusual Fire and Explosion Hazards: Flammable. Vapor may
travel considerable distance to source of ignition and flash back.
Inhalation: If large amounts inhaled, remove victim to fresh air.
Container explosion may occur under fire conditions. Use water spray
If breathing is difficult give oxygen. If breathing has stopped
to cool unopened containers.
administer mouth-to-mouth resuscitation. Keep the affected
person warm and at rest. Contact physician. SECTION 6: ACCIDENTAL RELEASE MEASURES
Eye Contact: Contamination of the eyes should be treated Procedure for Spill Control: Shut off all sources of ignition. Restrict
by immediate and prolonged irrigation with copious amounts access to area until completion of clean-up. Ventilate area. Notify
of lukewarm water by separating the eyelids with fingers. Contact government occupational health and safety and environmental
physician. authorities.
Skin Contact: In case of contact, immediately wash skin Personal Procedure: Wear appropriate respiratory and personal
with soap and copious amounts of lukewarm water. protective equipment when engaged in clean-up outside of hood.
Ingestion: If swallowed, get medical attention immediately. Do Clean-Up Procedure: Absorb with non-combustible absorbent.
NOT induce vomiting. Never give anything by mouth to an Place leaking ampoules in a plastic bag containing absorbent
unconscious person. and dispose of as hazardous waste.
SECTION 5: FIRE-FIGHTING MEASURES SECTION 7: HANDLING AND STORAGE
ISOOCTANE Handling: Adequate ventilation is required to protect personnel from
Flash Point (Method): -12°C (10.4°F) closed cup exposure to chemical vapors exceeding PEL and to minimize fire
Flammable Limits: LEL (1.1%) LEL (1.1%) hazards. Safety glasses are considered minimum protection.
The choice of protective gloves or clothing must be based on
TOLUENE chemical-resistance and other user requirements. Chemical-resistant
Flash Point (Method): 4°C (39.2°F) (closed cup) protective gloves and clothing are recommended. Remove and wash
Flammable Limits: LEL (1.2%) LEL (1.2%) contaminated clothing promptly.
HEXANE Storage: Store in a cool dry place. Keep away from heat, sparks,
Flash Point (Method): -23°C (-9.4°F closed cup) open flame, and oxidizing agents. Proper storage must be determined
Flammable Limits: LEL (1.1%) LEL (1.1%) based on other materials stored and their hazards and potential
chemical incompatibility. Store in an acceptable, protected and
Extinguishing Media: Carbon dioxide, dry chemical secure, ‘Flammable Liquid Storage’ cabinet or room.
powder, Halon, water spray or standard foam.
SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
Special Fire Fighting Procedures: Wear full protective
clothing and self-contained positive pressure breathing Respiratory: Use NIOSH approved respirator equipment.
apparatus certified by NIOSH, when fighting chemically Eyes: Chemical safety goggles or face shield may be
related fires. necessary depending on quantity of material and conditions
of use. Emergency eye wash fountains should be available
in the vicinity of any possible exposure.

www.spectrumstandards.com
Page 3 of 6
v.2016SQS
SPECTRUM QUALITY STANDARDS
17360 GROSCHKE RD.
HOUSTON, TX 77084
PHONE: 281-578-7575 ● FAX: 281-578-7576

Part Number: MSX-41 (various part numbers)


SAFETY DATA SHEET
Revision Date: 5/3/2016

Skin: Generally, BUNA-N offers acceptable chemical resistance. *Note: Since other Agencies regulate this information, OSHA will
Individuals who are acutely and specifically sensitive to this not be enforcing Sections 12 through 15 (29 CFR 1910.1200(g)(2)).
chemical may require additional protective clothing.
SECTION 12: ECOLOGICAL INFORMATION
For OSHA’s PEL/TLV information, please refer to Section 3.
ISOOCTANE
SECTION 9: PHYSICAL & CHEMICAL PROPERTIES Toxicity to fish: LC50: 0.11 mg/l. Exposure time: 96 h.
ISOOCTANE Species: Oncorhynchus mykiss (rainbow trout) semi-static test.
Specific Gravity (H20 = 1): 0.72 Method: OECD Test Guideline 203.
Evaporation Rate (n-butyl acetate = 1): > 1 Information given is based on data obtained from similar
Boiling Point (°C): 211°F (99°C) substances.
Vapor Pressure: 1.7 p.s.i.a. @ 100°F (37.8°C) Toxicity to daphnia and other aquatic invertebrates: EC50: 0.4
Vapor Density (Air = 1): <1 mg/l.
Solubility (Miscible) in Water: Insoluble (X) Soluble () Exposure time: 48 h.
Appearance & Odor: Colorless liquid, gasoline-like odor. Species: Daphnia magna (Water flea) static test.
Information given is based on data obtained from similar
TOLUENE substances.
Specific Gravity (H20 = 1): 0.867 @ 20°C
Evaporation Rate (n-butyl acetate = 1): 2.0
Toxicity to algae: EL50: 2.943 mg/l.
110.6°C (231.1°F)
Exposure time: 72 h.
Boiling Point (°C):
Method: QSAR modeled data.
Vapor Pressure: 2.93 kPa (22 mm Hg) at 20°C
Vapor Density (Air = 1): 3.18 Biodegradability: No data available.
Solubility (Miscible) in Water: Insoluble () Soluble (X)
Bioaccumulation: No data available.
Clear, colorless liquid with a benzene-like
Appearance & Odor:
odor. Mobility in soil: No data available.
HEXANE Results of PBT and vPvB assessment: PBT/vPvB assessment
Specific Gravity (H20 = 1): 0.66 @ 20°C not available as chemical safety assessment not required/not
Evaporation Rate (n-butyl acetate = 1): 8.4 conducted.
Boiling Point (°C): 68.7°C Other adverse effects: An environmental hazard cannot be
Vapor Pressure:
16-16.53 kPa (120-124 mm excluded in the event of unprofessional handling or disposal. Very
Hg) @ 20°C toxic to aquatic life with long lasting effects.
Vapor Density (Air = 1): 2.97
TOLUENE
Solubility (Miscible) in Water: Insoluble (X) Soluble ()
Toxicity to fish: LC50 - Oncorhynchus mykiss (rainbow trout) -
Clear, colorless, highly volatile liquid with a
Appearance & Odor:
faint gasoline-like odor.
7.63 mg/l - 96 h. NOEC - Pimephales promelas (fathead minnow) -
5.44 mg/l - 7 d.
SECTION 10: STABILITY & REACTIVITY
Toxicity to daphnia and other aquatic invertebrates: EC50 -
Stability: Stable (X) Unstable () Daphnia magna (Water flea) - 8.00 mg/l - 24 h. Immobilization
Conditions to Avoid: Heat, sparks, open flame, and poor EC50 - Daphnia magna (Water flea) - 6 mg/l - 48 h.
ventilation. Do not leave this material, or any other, in an open Toxicity to algae: EC50 - Chlorella vulgaris (Fresh water algae) -
container. User must follow all proper handling, storage and 245.00 mg/l - 24 h EC50 - Pseudokirchneriella subcapitata (green
safety measures. algae) - 10.00 mg/l - 24 h.
Incompatibility (Materials to Avoid): STRONG OXIDIZING Biodegradability: Readily biodegradable.
AGENTS (e.g. peroxides, nitrates and perchlorates) – can
increase risk of fire and explosion. Bioaccumulation: Leuciscus idus (Golden orfe) - 3 d - 0.05 mg/l.
Bioconcentration factor (BCF): 90.
Hazardous Decomposition or By-products: During a fire,
carbon monoxide, carbon dioxide, irritating aldehydes and Mobility in soil: No data available.
ketones and other irritating/toxic gases may be generated. Results of PBT and vPvB assessment: PBT/vPvB assessment
SECTION 11: TOXICOLOGOCIAL INFORMATION not available as chemical safety assessment not required/not
conducted.
Inhalation? YES Skin? YES Ingestion? YES
Other adverse effects: An environmental hazard cannot be
Inhalation: Symptoms of exposure may include light- excluded in the event of unprofessional handling or disposal.
headedness; headache; nausea; numbness in the extremities; Harmful to aquatic life with long lasting effects.
muscle weakness and irritation to mucous membranes. HEXANE
Eye Contact: Vapor or mist is irritating to the eyes. Toxicity to fish: LC50 - Pimephales promelas (fathead minnow) -
2.5 mg/l - 96.0 h.
Skin Contact: Contact with skin may cause dermatitis.
Toxicity to daphnia and other aquatic invertebrates: EC50 -
Ingestion: Harmful if swallowed. Daphnia magna (Water flea) - 3,878.00 mg/l - 48 h.
For more information on acute and chronic effects, and the Toxicity to algae: EC50 - Chlorella vulgaris (Fresh water algae) -
numerical measures of toxicity, please refer to Section 15. 12,840.00 mg/l - 3 h. EC50 - SKELETOMA - 0.30 mg/l - 8 h.

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Page 4 of 6
v.2016SQS
SPECTRUM QUALITY STANDARDS
17360 GROSCHKE RD.
HOUSTON, TX 77084
PHONE: 281-578-7575 ● FAX: 281-578-7576

Part Number: MSX-41 (various part numbers)


SAFETY DATA SHEET
Revision Date: 5/3/2016

Biodegradability: No data available. Spectrum Quality Standards Part Number: MSX-41-1-10, MSX-
41-1-100, MSX-41-1-50, MSX-41-1-900; MSX-41-10-10, MSX-41-
Bioaccumulation: No data available.
10-100, MSX-41-10-50
Mobility in soil: No data available.
DOT (US)
Results of PBT and vPvB assessment: PBT/vPvB assessment UN number: 1993 Class: 3 Packing group: II
not available as chemical safety assessment not required/not Proper shipping name: Flammable Liquid, n.o.s. (Toluene,
conducted. Isooctane,…)
Other adverse effects: An environmental hazard cannot be IMDG
excluded in the event of unprofessional handling or disposal. UN number: 1993 Class: 3 Packing group: II
Harmful to aquatic life with long lasting effects. Proper shipping name: Flammable Liquid, n.o.s. (Toluene,
Isooctane,…)
SECTION 13: DISPOSAL CONSIDERATIONS
IATA
Waste Disposal: Burn in a chemical incinerator equipped with
UN number: 1993 Class: 3 Packing group: II
an afterburner and scrubber. If contaminated with other
Proper shipping name: Flammable Liquid, n.o.s. (Toluene,
chemicals, fully comply with all Federal, State, and Local
Isooctane,…)
regulations prior to disposal.
This item is considered “Dangerous Goods” in “Excepted
SECTION 14: TRANSPORT INFORMATION
Quantities” by IATA regulation. Quantities exceeding 500 ml may
All of Spectrum Quality Standards products are shipped following be shipped as “Dangerous Goods”. Please contact us for more
proper IATA regulations. information if needed.

SECTION 15: REGULATORY INFORMATION (per chemical)


The IATA Packing Instruction and Authorization is dependent upon the quantity, which may vary. This information may be subject to change per size variations
obtained, please verify information.

CHEMICAL NAME National Fire Protection Association (NFPA) Hazard Identification


Hexane NFPA – Health: Not assigned.
DSL/NDSL NFPA – Flammability: 3 - Liquids and solids that can be ignited under almost all ambient temperature conditions.
3123 NFPA – Instability: 0 - Normally stable, even under fire conditions, and not reactive with water.
EU EINECS/ELINCS Number HMIS Classification TSCA SARA Title 3
203-777-6 Health Hazards: 2 Status: FOUND Status: List Status: FOUND
Former CAS Number: 8031-34-3 CERCLA RQ: 5,000
DOT TRANSPORT Chronic Health Hazard: * Molecular Formula: C6H14 S313: 313
Identification Number: UN1208 Flammability: 3
Hazard Class/Division: 3 Physical Hazards: 0
Packing Group: II OSHA Hazard Evaluation: Meets criteria for hazardous material, as defined by 29 CFR 1910.1200
Label(s): 3 - Flammable Liquid NTP/ROC: No Data
WHMIS Classification
B2 - Flammable and combustible material - Flammable liquid
D2A - Poisonous and infectious material - Other effects - Very toxic
D2B - Poisonous and infectious material - Other effects - Toxic
Human Toxicity Information Animal Toxicity Values
Inhalation of 5000 ppm for 10 minutes produces marked vertigo; 2500-1000 LC50 (male rat): 38500 ppm (4-hour exposure); cited as 77000 ppm (1-hour
ppm for 12 hours produces drowsiness, fatigue, loss of appetite, paresthesia in exposure)
distal extremities; 2500-500 ppm produces muscle weakness, cold pulsation in LC50 (rat): 73680 ppm (4-hour exposure) (n-hexane and isomers)
extremities, blurred vision, headache, anorexia, and onset of polyneuropathy. LC50 (rat): 48000 ppm (4-hour exposure) (16, unconfirmed)
Slightly toxic by ingestion and inhalation; Human systemic effects include: LD50 (oral, 14-day-old male rat): 15820 mg/kg (cited as 24 mL/kg; hexane,
hallucinations, structural change in nerve or sheath... may be irritating to analytical grade, composition not specified; 7-day observation period)
respiratory tract and narcotic in high concentrations. Nerve conduction blocks, LD50 (oral, young adult male rat): 32290 mg/kg (cited as 49 mL/kg; hexane,
defined by a significant reduction in amplitude or area of the compound muscle analytical grade, composition not specified; 7-day observation period)
action potential at proximal compared with distal sites of stimulation, have LD50 (oral, older adult male rat): 28670 mg/kg (cited as 43.5 mL/kg; hexane,
been described in glue-sniffers and in workers with industrial exposure at an analytical grade, composition not specified; 7-day observation period)
early stage of n-hexane neuropathy. n-Hexane is not known to cause cancer. LD50 (dermal, rabbit): greater than 3295 mg/kg (cited as greater than 5 mL/kg)

CHEMICAL NAME National Fire Protection Association (NFPA) Hazard Identification


NFPA – Health: 2 – Intense or continued (but not chronic) exposure could cause temporary incapacitation or possible
Toluene
residual injury.
DSL/NDSL NFPA – Flammability: 3 – Liquids and solids that can be ignited under almost all ambient temperature conditions.
3022 NFPA – Instability: 0 – Normally stable, even under fire conditions, and not reactive with water.
EU EINECS/ELINCS Number HMIS Classification TSCA SARA Title 3
203-625-9 Health Hazards: 2 Status: Found Status: FOUND
Molecular Formula: C7H8 CERCLA RQ: 1,000
DOT TRANSPORT Chronic Health Hazard: *

www.spectrumstandards.com
Page 5 of 6
v.2016SQS
SPECTRUM QUALITY STANDARDS
17360 GROSCHKE RD.
HOUSTON, TX 77084
PHONE: 281-578-7575 ● FAX: 281-578-7576

Part Number: MSX-41 (various part numbers)


SAFETY DATA SHEET
Revision Date: 5/3/2016

Identification Number: UN1294 Flammability: 3 S313: 313


RCRA CODE: U220
Hazard Class/Division: 3 Physical Hazards: 0
Packing Group: II OSHA Hazard Evaluation: Meets criteria for hazardous material, as defined by 29 CFR 1910.1200
Label(s): 3 - Flammable Liquid NTP/ROC: No Data
WHMIS Classification
B2 – Flammable and combustible material – Flammable liquid
D2A – Poisonous and infectious material – Other effects – Very toxic
D2B – Poisonous and infectious material – Other effects – Toxic
Human Toxicity Information Animal Toxicity Values
Among 61 painters inhaling 100-1100 ppm toluene for 2 wk to 5 yr, depressed LD50 Rat oral 2.6 to 7.5 g/kg
erythrocyte counts with elevated hemoglobin, mean corpuscular volumes, and LD50 Rabbit dermal 14.1 ml/kg
elevated mean corpuscular hemoglobin were found in 5% to 30% compared LD50 Rat (female) ip 1.64 g/kg
with groups of 73-395 workers not known to be exposed to toluene; differential LD50 MOUSE IP 1.15 G/KG
leukocyte counts were not significantly different between the toluene-exposed LD50 Rat oral 5000 mg/kg
and the reference workers. LD50 Rat ip 1332 mg/kg
LD50 Rat iv 1960 mg/kg
LC50 Mouse ihl 400 ppm/24 hr
LD50 Mouse ip 59 mg/kg
LD50 Mouse sc 2250 mgkg
LD50 Mouse ip 640 mg/kg
LD50 Rabbit skin 12,124 mg/kg
The LC50 for toluene in mice is 5320 ppm, 8 hr via inhalation. As the duration
of toluene inhalation exposure increased, the LC50 in rats decreased from
26,700 ppm for 1 hr, to 12,200 ppm for 2-2.5 hr, to 8000 ppm for 4 hr.

CHEMICAL NAME National Fire Protection Association (NFPA) Hazard Identification


Isooctane NFPA – Health: 1 – Exposure would cause significant irritation, but only minor residual injury
DSL/NDSL NFPA – Flammability: 3 – Liquids and solids that can be ignited under almost all ambient temperature conditions
4412 NFPA – Instability: 0 – Normally stable, even under fire conditions, and not reactive with water
EU EINECS/ELINCS Number HMIS Classification TSCA SARA Title 3
208-759-1 Health Hazards: 2 Status: Found Status: FOUND
Former CAS Number: 31921-36-5 CERCLA RQ: 1,000
DOT TRANSPORT Chronic Health Hazard: * Molecular Formula: C8H18
Identification Number: UN1262 Flammability: 3
Hazard Class/Division: 3 Physical Hazards: 0
Packing Group: II OSHA Hazard Evaluation: Meets criteria for hazardous material, as defined by 29 CFR 1910.1200
Label(s): 3 - Flammable Liquid NTP/ROC: No Data
WHMIS Classification
B2 – Flammable and combustible material – Flammable liquid
Human Toxicity Information Animal Toxicity Values
Currently the chemical, physical, and toxicological properties of this material Isooctanes appear to cause pulmonary lesions if aspirated into lungs of rats.
have not been thoroughly investigated as to their affects on Humans. The pathological lung finding in rabbits injected in with Cyclohexane, n-
Hexane, or Isooctane test groups include hemorrhage, edema, & tissue with
polmorphonuclear leukocytic reactions, such as angitis, interstitial pneumonitis,
abscess formation, thrombosis & fibrosis. Isooctane was highly irritating to
mice after 1000 ppm for 5 minutes. Respiratory arrest occurred in the
expiratory phase during prolonged expiration.

SECTION 16: OTHER INFORMATION


DISCLAIMER: This Material Safety Data Sheet is offered without charge to the clients of Spectrum Quality Standards. Data is the most
current available to Spectrum at the time of preparation and is issued as a matter of information only, no warranty as to its accuracy or
completeness is expressed or implied.

Unless otherwise noted, the above information pertains only for the solvent and similar types of components in the sample.
Per GHS & OSHA requirements, please note that Spectrum Quality Standards does not manufacture pure components but rather blend
existing components to create ASTM approved standards.

When no toxicity data is provided, it is prudent to handle this chemical as hazardous. Furthermore, since individual chemical
hypersensitivity cannot be predicted, every chemical should be handled with due respect.

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