MEHRAN DEGREE COLLEGE RAWAT

B.sc part – I

Examination -2020

Subject : Chemistry-I Time allowed: 3 hrs

Paper: A(physical chemistry) Max Marks: 40

NOTE: Attempt any FOUR questions. All questions carry equal marks.

Section-A

1. What is the co-efficient of viscosity of liquid? How is the viscosity of liquid

is measured by Ostwald’s Viscometer? (06)
B)what is the effect of temperature on surface tension of a liquids? (02)
C)how does surface area affects adsorption? (02)
2. Describe theories of catalysis? (06)
B)what is Langmuir adsorption isotherm? (04)
3. How is the collision number related with average velocity and temperature
of gas molecules? (02)
B)define dipole moment and derive its units? (02)
C)Describe and derive the relation of kinetics of enzyme action? (06)
4. Derive the expression for application of vander waal’s equation to critical
phenomena of gases? (06)
B)calculate the degrees of freedom for tri-atomic linear moecule? (02)
C)what is heterogenous catalysis? Give examples of heterogenous catalysis
with gaseous reactants? (02)
5. Explain and derive Freundlich adsorption isotherm with graphs? (06)
B)differentiate between diamagnetic, ferromagnetic and paramagnetic
substances? (04)
6. How you can measure magnetic susceptibility by usin Gouy’s method?Also
define magnetic susceptibility? (1+5)
B)Define and give expression for law of Equipartition of energy? (02)
C)what is snell’s law? (02)