CAREER POINT

Fresher Course for IIT JEE (Main & Advanced)–2017

DAILY PRACTICE PROBLEM SHEET
Course : Fresher(XL) Batch Subject : Chemistry DPPS-1

Topic : Chemical Kinetics

d[ A ]
Q.1 In the reaction, A + 2B  6C + 2D, if the initial rate  at t = 0 is 2.6 × 10–2 M sec–1, what will be the
dt
d[B]
value of  at t = 0 ?
dt
(A) 8.5 × 10–2 M sec–1 (B) 2.5 × 10–2 M sec–1 (C) 5.2 × 10–2 M sec–1 (D) 7.5 × 10–2 M sec–1

d[ A ] d[B] d[C]
Q.2 For the reaction 2A  B + 3C; if  = k1[A] 2; = k2 [A] 2; = k3 [A]2 the correct reaction
dt dt dt
between k1, k2 and k3 is:
k1 k
(A) k1 = k2 = k3 (B) 2k1 = k2 = 3k2 (C) 4k1 = k2 = 3k2 (D)  k2  3
2 3

1
Q.3 Consider a reaction A(g) k 0
.1M min
  2B(g). If initial concentration of A is 0.5M then select correct
graph.

1.0M
0.5M [B]
(A) (B) 0.5M
[B]
5 10
time (in min) 5 10
time (in min)

2.0M
1.0M
(C) [B] (D) 1.0M

10 [B]
5
time (in min) 5 10
time (in min)

Q.4 Decomposition of NH4NO2(aq) into N2(g) and 2H2O() is first order reaction. Which of the following graph
is correct ?
[NH4NO2]

[NH4NO2]

[NH4NO2]

[NH4NO2]

(A) (B) (C) (D)

time time time time

CAREER POINT, CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744 -5151200 www.careerpoint.ac.in Page # 1
Q.5 If decomposition reaction A(g)  B(g) follows first order kinetics then the graph of rate of formation (R) of
B against time t will be:
R R R R

(A) (B) (C) (D)

t t t t
1
Q.6 For a reaction A k r 0.6 M min
   2B
starting with 1 M of 'A' only, concentration of B (in M) after 100 sec. and 200 sec. is respectively ?
(A) 2 and 4 (B) 1 and 2 (C) 2 and 3 (D) None of these
k
Q.7 For the reaction 3A(g)   B(g) + C(g), k is 10–14L/mol.min.
d[ A ]
if [A] = 0.5M then the value of  (in Ms–1) is:
dt
(A) 7.5 × 10–5 (B) 3 × 10–4 (C) 2.5 × 10–5 (D) None of these

Q.8 For the reactions

kI
(i) A  P
k II
(ii) B  Q, following observation is made.

2M 2M
Concentration

Concentration

1M 1M
0.5 M
[A] [B]
30 60 30
Time(min) Time(min)
kI
Calculate , where kI and kII and rate constant for the respective reaction.
k II
(A) 2.303 (B) 1 (C) 0.36 (D) 0.693

Q.9 The decomposition of N2O5 in chloroform was followed by measuring the volume of O2 gas evolved:
2N2O5(CCl4)  2N2O4(CCl4) + O2(g). The maximum volume of O2 gas obtained was 100 cm3. In 500
minutes, 90 cm3 of O2 were evolved. The first order rate constant (in min–1) for the disappearance of N2O5 is:
2.303 2.303 100 2.303 90 100
(A) (B) log (C) log (D)
500 500 90 500 100 10  500

Q.10 For a homogeneous gaseous reaction A  3B, if pressure after time t was PT and after completion of reaction
pressure was P then select correct relation
1  P  1  2P 
(A) k  n   (B) k  n  

t  3(P  Pt )  t  3(P  PT ) 
1  3P  1  2P 
(C) k  n   (D) k  n  
t  2P  Pt 
 t  3(P  PT ) 

ANSWERS
1. (C) 2. (D) 3. (C) 4. (D) 5. (C) 6. (D) 7. (D)
8. (D) 9. (A) 10. (D)
CAREER POINT, CP Tower, IPIA, Road No.1, Kota (Raj.), Ph: 0744 -5151200 www.careerpoint.ac.in Page # 2