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  • Aluminium Aquo Speciation

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    Quốc Nguyễn
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    aluminium aquo speciation

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    11 views1 page

    Aluminium Aquo Speciation

    Uploaded by

    Quốc Nguyễn

    Copyright:

    © All Rights Reserved
    Download as XLS, PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 1

    pH [H+] alpha Al3+ alpha AlOH2+ alpha Al(OH)2+ alpha Al(OH)3 alpha Al(OH)4-

    0.0 1.00E+00 1.0000 0.0000 0.0000 0.0000 0.0000


    0.5 3.16E-01 1.0000 0.0000 0.0000 0.0000 0.0000 Ka1 Ka2 Ka3 Ka4
    1.0 1.00E-01 0.9999 0.0001 0.0000 0.0000 0.0000 1.00E-05 7.94E-06 1.58E-07 1.58E-06
    1.5 3.16E-02 0.9997 0.0003 0.0000 0.0000 0.0000 5.00 5.10 6.80 5.80
    2.0 1.00E-02 0.9990 0.0010 0.0000 0.0000 0.0000
    2.5 3.16E-03 0.9968 0.0032 0.0000 0.0000 0.0000
    3.0 1.00E-03 0.9900 0.0099 0.0001 0.0000 0.0000 pH Speciation for Al aquo species
    3.5 3.16E-04 0.9686 0.0306 0.0008 0.0000 0.0000
    4.0 1.00E-04 0.9026 0.0903 0.0072 0.0000 0.0000 1.00
    4.5 3.16E-05 0.7163 0.2265 0.0569 0.0003 0.0000
    5.0 1.00E-05 0.3560 0.3560 0.2828 0.0045 0.0007 0.90 Al3+
    Al(OH)4-
    5.5 3.16E-06 0.0787 0.2489 0.6253 0.0313 0.0157 0.80

    fraction of species
    6.0 1.00E-06 0.0081 0.0813 0.6459 0.1024 0.1622 Al(OH)2+
    6.5 3.16E-07 0.0003 0.0098 0.2467 0.1236 0.6196 0.70
    Column C
    7.0 1.00E-07 0.0000 0.0005 0.0361 0.0572 0.9063 0.60
    7.5 3.16E-08 0.0000 0.0000 0.0039 0.0195 0.9766 Column D
    8.0 1.00E-08 0.0000 0.0000 0.0004 0.0063 0.9933 0.50 Column E
    8.5 3.16E-09 0.0000 0.0000 0.0000 0.0020 0.9980 0.40 Column F
    9.0 1.00E-09 0.0000 0.0000 0.0000 0.0006 0.9994 AlOH 2+ Column G
    9.5 3.16E-10 0.0000 0.0000 0.0000 0.0002 0.9998 0.30
    10.0 1.00E-10 0.0000 0.0000 0.0000 0.0001 0.9999 0.20 Al(OH)3
    10.5 3.16E-11 0.0000 0.0000 0.0000 0.0000 1.0000
    11.0 1.00E-11 0.0000 0.0000 0.0000 0.0000 1.0000 0.10
    11.5 3.16E-12 0.0000 0.0000 0.0000 0.0000 1.0000 0.00
    12.0 1.00E-12 0.0000 0.0000 0.0000 0.0000 1.0000 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0
    12.5 3.16E-13 0.0000 0.0000 0.0000 0.0000 1.0000
    13.0 1.00E-13 0.0000 0.0000 0.0000 0.0000 1.0000
    13.5 3.16E-14 0.0000 0.0000 0.0000 0.0000 1.0000
    pH
    14.0 1.00E-14 0.0000 0.0000 0.0000 0.0000 1.0000

    Fraction at pH 5 Formulas:
    35.6% alpha Al3+ ([H+]^4)/(([H+]^4)+(Ka1*[H+]^3)+(Ka1Ka2*[H+]^2)+(Ka1Ka2Ka3*[H+])+(Ka1Ka2Ka3Ka4))

    35.6% alpha AlOH2+ (Ka1*[H+]^3)/(([H+]^4)+(Ka1*[H+]^3)+(Ka1Ka2*[H+]^2)+(Ka1Ka2Ka3*[H+])+(Ka1Ka2Ka3Ka4))

    28.3% alpha Al(OH)2+ (Ka1Ka2*[H+]^2)/(([H+]^4)+(Ka1*[H+]^3)+(Ka1Ka2*[H+]^2)+(Ka1Ka2Ka3*[H+])+(Ka1Ka2Ka3Ka4))

    0.5% alpha Al(OH)3 (Ka1Ka2Ka3*[H+])/(([H+]^4)+(Ka1*[H+]^3)+(Ka1Ka2*[H+]^2)+(Ka1Ka2Ka3*[H+])+(Ka1Ka2Ka3Ka4))

    0.1% alpha Al(OH)4- (Ka1Ka2Ka3Ka4)/(([H+]^4)+(Ka1*[H+]^3)+(Ka1Ka2*[H+]^2)+(Ka1Ka2Ka3*[H+])+(Ka1Ka2Ka3Ka4))

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