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Document Name: ASTM D1415: Standard Practice for Rubber and Rubber
Latices--Nomenclature
CFR Section(s): 21 CFR 177.2600(c)(4)(i)
Official Incorporator:
THE EXECUTIVE DIRECTOR
OFFICE OF THE FEDERAL REGISTER
WASHINGTON, D.C.
~~l~ Designation: D 1415 - 88 (Reapproved 1994)
Jhi~ ~t~~paf<i is issue<Ulp,der ~11e ,jixe<\ ,d~si~rat~onJ::? 1.415; rtpe )1UmQ~r.immeqiately, fol~o:sving, the 4~si~natio!1 ~n,di~ates ,the year of
~riglllall,l,doptiQ~ 9f" ~n, the sase of revision,~~~ ~~~~;oQ~st~evis~oJ,1. A number in parentheses indicates th~year oflast reapproval. A
superscript epsilon (€) indicates an editorial cnangy ~iy.cet~~ If}st.revisionforreapprQ:val. "
This test 11'let~(Jd,has,bfBn approved by agencies oJ:t~\e.l)(!partmen(.ofl)efenseto,replacf!,method 3061 ofFed,eral,'{'est M.ethpd Standard
No. 601. Consult the DoD Index of Specijicatfons and Standards for the specific year of !$suewhich ha$);een. adopted by .the
Department of Defense.
"I '
1. Scope 'tions and' a table or' graph constructed from the table. In the
1.1 This test method describes a procedure for measuring micro-tester procedure, the difference in penetration must
the hardness of rubber. The hardness iS '6btained ,!by the j first be multipled by scale factor 6. Alternatively" the
difference in penetration depth of,a specified dimension ball penetration-mea~ut:ing instrument may be calibrated directly
iri' IRHD.': ;' :. '. . ' 0 ' .; "" ". : '
under two conditions of contact with the rubber: (1) with a ,!
small initial force and (2),,with a much larger final force. The
differential penetration (is taken at a speQified time and
'j'
converted to a hardness scale value.
1.2 This test method iS,identical in substance with ISO 48. 4.1 The International Hardness test is based on measure-
1.3 This standard does' not purport to address all of the met;1t ,0Lthe penetration of a rigid ball into' the rUbber
safety concerns, if any, . associated with its use. It is the specimen"undttf. specified Gonditions. The measured· penetra-
responsibility of the userbf this standard to establish appro- tioP, is conv~I1ed into InternationaLR»pl1er Hardnes,s ,De-
priate safety and health practices and deterrYzlne the applica- grees, theJ~cale of,d~g~ees being;so cho~en that orepresents a
bility of regulatory limitations prior to use. D?-atet;i~i ,~a;vi1,1g an el~s.ti9; ~?dul»s o(~rr~, a~d '109' repre-
seR-ts ~,w~t~ti~~.pfin~~i~~, ela~ttcm~~~t'!s. Ther~9alF chos.en
2. Referenced Documents also fulfills the follOWIng condItions over most of the, l}pr,nJ.~~
range of hardlless: one International Rubber Hardness De-
2.1 ASTM Standards>, gree tange' represents apprdidrilately' the 'sa:m~' proportionate
D 1349 Practice for Rubber-Standard Temperatures for diffefe~te in young~s!n1odi.ll1;ls, '~llld for fubb'et"v~ICal1iz~tes
in' toe usti~d" range oftesilienc'e;' 'readings' iIi Int~rnati'6nal
2
Testing
',1? UatOd".n,!e"·s~ss.l M.' ~th,04 for".R.,,;u.,.~per, Pr,oP,,ert. ,¥-;:-:-D"l;lrometer Rribber Hardnes's'Degtees are'comparable with,tfiose'giveri
. , by a Type A durometet Cfest Method D2240),wheii testIng
,D 4483; Practice, tdr D~t~rmihiag" "P~cicision for'; Te~t standard specimens. The term "usual range of resilience" is
I,'~ , '~~~".,p,s.;O,t~e.s.~t.'~.ri~~r.;d~, ii\, t~~ .R4pber ·~',Q.d . Ca~1?oh: ,~~a~*."
r. used to exclude those compounds that have unusually high
; t2' ISO Stand'a···~d.;· . . ' . . ; . ' \,'; ,:., .' rates of stress relaxation or deformational hysteresis. For
r such compounds, differences in the dwell time in the two
ISO/4~ ,.Vulcaniie~rkal)bers~petermination:ofHardiiess hardness tests result in differences in hardness values. Read-
:, .CfICI:~9,ri~~~i ~rt~~¥~ 30 a~d:~\5" IRHP)3 ' ings may not be comparable when testing curved or irregu-
" . . ' "\ h 'I', • , ' . I lady shaped test pieces.
i S~mffl:ary,' .Q(Te,~i,M.~t~o,d,~ ! 4.1'.2' Fdr SUbstantially elastic isotropic: materials like well-
3.1 Two procedures are given to accommodate~p'~qi11l;ens Virldfdited ~jnatu'tal : tubbers,' 'the hardness, flt'.'iliit~tn~tJ6nl~1
of different dimensions. The standard test is intertd~d to De Rupber aatrdlJ.~ss .Degree~ bears, a known I~e\ation to Young's
used on specimens greater ;tliah/4 mlli. in: thlc1(iie~s, ptefer- modulus, although, formavkedly Jplastic' or anisotropic: I!llb-
ably 8 to 10 mm. The micro-tester is used on specimens less bers the relationship will be less precisely known.
than 4 mm i1f;thi~kiiess,:6'if specimensJl1i¢~ett~~n'4\:'rttrfi' "~"~.1.;3':rh~;teUl~i91!' he~\Veert t~e,:'differe~ce()f penetration
having lateral dlmensi6'llsless lh~h those'~p~¢diij~4,' (ofth¢, ana·the\'J1~tq,~¢~f~,~pre~sea}lf(,nit~tnJltidl1a~' Rubber Hard-
standard test, or on rubber articles that do not' have flat ness Degrees IS based' on the followmg:
surfaces suitaQle?Sor making . . ,the, standard; :test. "In. both '" \\, ,r\::,4, 1.3.1· T4e "rela~ip,Q4 , bet~~~n" pen~t~ation . and Young's
procedures, the ,hardness:in International Rubber. Hardness'./ ,modulus for a perfectly, elastw ISOtroPIC; m-atenal:
Degrees (lRHR),i~'"dei1y~~l;rtqvr U'1e(diff.~r&nge,in p~i1~t~~~' .:w' ,? ' Fltvi:i:\l)} R2(P/R)L35 ,II,
where:
J This test method is under the jurisdiction of ASTM Committee 0·11 on
F = indenting force,
Rubber and is the direct responsibility of Subcommittee D 11.10 on Physical M = Young's modulus, MPa,
Testing R = radius of ball, mm, and
Current edition approved Sept. 30, 1988. Published February 1989. Originally P = penetration, mm.
published as D 1415 - 56 T. Last previous edition D 1415 - 83.
2 Annual Book ofASTM Standards, Vol 09.01.
3 Available from American National Standards Institute, 11 West 42nd Street,
13th Floor, New York, NY 10036. 4 This relation is approximate and is included as an indication.
234
~I D 1415
Lo9 1o M (M In MPo)
- 0,85 -0,65 -0.45 -0,25 0,05 0.15 0.35 0.55 0.70 0.95 1,15 1.35 1.55 1.75
100.0
97.5
95.5 ~
92:0
86.5 l/
01 79.5 V
V
Cj.I
'C
ui
en
QI 70.5
~
c
'E
0
60.0 /
~
QI
..c
..c
::l
c:: 49.0 V
'0
c
0 37.5 /
V
:;::
c
E
....
QI
27,5
.5
19.0 V
12.0
/'
./
7.0
4.0 ~
..--
0
1.3 1.5 1.7 1.9 2.1 2.3 2.5 2.7 2.9 3.1 3,3 3.5 3.7' 3.9
Log 10 M ( M in psi)
FIG. 1 Point Curve to Relate Log 1o M and the Hardness in International Rubber Hardness Degrees
4.1.3.2 Use of a probit (integrated normal error) curve to shall be included in determining the minor and major forces.
relate 10glO M and hardness in International Rubber Hard- This is in order that the forces actually applied to the ball
ness Degrees, as shown in Fig. 1. This curve is defined as shall be as specified.
follows: 5.1.3 Measuring Device-A mechanical, optical, or elec-
4.1 ;3.3 The value of 10glO M corresponding to the mid- trical device graduated either in· standard units of length or in
point of the curve is equal to 0.364, that is, M = 2.31 MPa or International Rubber Hardness Degrees for measuring the
335 psi. increase in depth of penetration. of the plungercaus~d by the
4.1.3.4 The maximum slope is equal to 57 International major l o a d . ,
Rubber Hardness Degrees per unit increase in 10glO M. 5.1.4 Foot-A flat annular-shaped fo.ot that is rigidly
fastened to· the penetration-t;l1easuring device and.nornlal to
the axis of the plunger, and which during the test is forced
5. Apparatus against th~specimen in order to determine accurately the.
5.1 The essential parts of the apparatus are as follows, the position of the upper surface.· ,
appropriate dimensions and loads being given Table 1: in 5.1.5 Vibrating Device-For example, an electrically 'op-
5.1.1 Vertical Plunger, terminating in a rigid ball. erated buzzer, for gently vibrating the apparatus to overcome
5.1.2 Force Applicator'-forapplying a minor force and a any slight friction; this should not exceed 5 % of the minor
major force to the ball the mass of the plunger and of any load. This device may be omitted on apparatus without any'
fittings attached to it and the force of any spring actit1g on it friction.
235
6. Test Specimen "'It: .'.' i (J~imtenting ball, verti~ally onto the s~ecimen.for 5 s. .
6 1 T t . t dd' tO'b comparable' :must;ibe.·niade'bn ".,'; \;\&.2 ofL the. Jgage "'~s.:~.igra~ll~~e~~lfectly In InternatIOnal
. . es s men e ' ...,e, I ' . ;....., .. ". _' K\ibbeJ.\HardnessDegrees, .tUfJ,l ~t4~ bezel of the gage so that
.n···.·· '..'. d·' .'...... "1"0"'0 (... . ........ ,. . t
p -" ,.".. • .....
C0hditiOlled'inart atin.0~bh:(we 'controlled",to'\50 ·±··5% 10. Pt~cisi:()A~hd'Bi~s5·';,.i i . . j" L' J' :.H
relatiVe';, humidity,~fdr; at :least:~z4' h. '·When testS! 'ate 11i~de at 10.1 This precision and bias section has been prepared in
higher or lower: temper~ltcites,c lhe f speciriH-;i1S sballbe lTIaiti.;. accordance with Practice D 4483. Refer to this practice' for
taihed ;at'thecorrditiohs·bf<tesFfbrapierioti oftbne s:ufficient i. t~f}-~WO.~Qg~ l~nd.. otqer l~tati~tic~l ,~a~cula,t~~p., p.~!~il~.;:' ;.
to reach temperature equilibriul11,';,with tJ:ietesti~g' cham1?er~ 10.2:.f~~GisiQ1J"'"7/\iType:1 (mted~Q~ratory);.test program,
a1¥a thetteniperatUreslSnaH' be' cHosen from tho~e specified in to .~eterq}p1,e I l?!eP\~l?p:, ~a,s, ey~lu~ted. lu.,19 8l ~qth repeat-
1
236
~~~ D 1415
TABLE 3 Relation Between International Rubber Hardness Degrees (IRHD) and Penetrations Differences
Movement of Movement of Movement of Movement of
IRHO Plunger IRHO Plunger IRHO Plunger IRHO Plunger
mm mils mm mils mm mils mm mils
28 1.934 76.1 47 1.055 41.5 66 0.589 23.2 85 0.280 11.0
29 1.867 73.5 48 1.024 40.3 67 0.570 22.5 86 0.266 10.5
30 1.803 71.0 49 0.994 39.1 68 0.552 21.7 87 0.251 9.9
31 1.743 68.6 50 0.964 38.0 69 0.534 21.0 88 0.237 9.3
32 1.685 66.4 51 0.936 36.8 70 0.516 20.3 89 0.223 8.8
33 1.630 64.2 52 0.908 35.8 71 0.498 19.6 90 0.209 8.2
34 1.578 62.1 53 0.881 34.7 72 0.481 18.9 91 0.195 7.7
35 1.528 60.1 54 0.855 33.7 73 0.464 18.3 92 0.180 7.1
36 1.479 58.2 55 0.830 32.7 74 0.447 17.6 93 0.166 6.5
37 1.433 56.4 56 0.805 31.7 75 0.431 17.0 94 0.151 5.9
38 1.389 54.7 57 ·0.781 30.8 76 0.415 16.3 95 0.135 5.3
39 1.346 53.0 58 0.758 29.8 77 0.399 15.7 96 0.119 4.7
40 1.305 51.4 59 0.735 28.9 78 0.384 15.1 97 . 0.102 4.0
41 1.265 49.8 60 0.713 28.1 79 0.368 14.5 98 0.083 3.3
42 1.227 48.3 61 0.691 27.2 80 0.353 13.9 99 0.060 2.4
43 1.190 46.9 62 0.670 26.4 81 0.338 13.3 1'00 0.000 0.0
44 1.155 45.5 63 0.649 25.5 82 0.323 12.7
45 1.120 44.1 64 0.629 24.7 83 0.309 12.2
46 1.087 42.8 65 0.609 24.0 84 0.294 11.6
a' mean level in Table 4 closest to the mean level und~r must be cpnsidered to have come from' different or
consideration at any given time for any given material in nonidentical sample populations.
routine testing operations. 10.7 Repeatability and reproducibility expressed as a
10.5 Repeatability-The repeatability, r, of this' test percentage of the mean level, (r) and (R), have equivalent
method has been established as the appropriate value tabu- application statements as above for rand R. For the (r) and
lated in Table 4. Two single test results, obtained under (R) statements,.the difference in the two single test results is
normal test procedures, that differ by more than this expressed as a percent of the arithmetic mean of the two test
tabulated r (for any given level) must be considered as re&ults.
derived from different or nonidentical sample populations. 10.8 Bias-In test method terminology, bias is the differ-
10.6 Reproducibility-The reproducibility, R, of this test ence between an average test value and the reference (or true)
method has been established as the appropriate value tabu- test property value. Reference values do not exist for this test
lated in Table 4. Two single test results obtained in two method since the value (of the test property) is exclusively
different laboratories, under normal test procedures, that defined by the test;, method. Bias, therefore, cannot be
differ. by more than the tabulated R (for any given level) determined.
. The American Society for Testing and Material$ takes no position respecting the valicJity of any patent rights asserted in connection
with any item mentioned in this standard. Users of this standard are expressly advised that determination of the validity of any such
patent rights, and the risk of infringement of such rights, are entirely their own responsibility.
This standard Is subject to revision at any time by the responsible technical committee and must be reviewed every five years and
if not revised, either reapproved or withdrawn. Your comments are Invited either for revision of this standard or for additiona/standards
and should be addressed to ASTM Headquarters. Your comments will receive careful consideration at a meeting of the responsible
technical committee, which you may attend. If you feel that your comments have not received afair hearing you should make your
views known to the ASTM Committee on Standards, .1916 Race St., Philadelphia, PA 19103.
237