wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.

h - 2022
ridhk úoHdj I

me;=ï lrkakdf.dv Time 1 h 47

01.(a) jryka ;=< olajd we;s .=Kh jeäjk ms<sfj<g my; i|yka oE ilikak'

C , O , Mg , CI (uQ,øjHj, mrudKql wrh&

................................... < ..................................... < ........................................ < .....................................

SO2 , SO3 , SO2-3 , SO2-4 (S mrudkqfõ úoaHq;a iDK;djh)

................................... < ..................................... < ........................................ < .....................................

NH2OH, NO2⁺, NO2̄, NO3̄ (N – O nkaOk os.)

................................... < ..................................... < ........................................ < .....................................

CH4 , NH3 , H2O , HF (fïjdfha yhsv%hsv j, ;dmdxlh)

................................... < ..................................... < ........................................ < .....................................

K⁺, Be2+, Mg2+, Ca2+ (whkj, O%eùlrK n,h)

................................... < ..................................... < ........................................ < .....................................

(b) i. CNO3 - whkh i|yd jvd;au ms<s.; yels ¨úia ;s;a-bß jhqyh woskak. tys iels,a, my; olajd we;.
𝐎
ǀ
O-N-C-O

ii. fuu whkh i|yd ;j;a ¨úia ;s;a-bß jhqyh ^iïm%hqla; jhqy& ;=kla woskak. by; (i) ys wosk ,o jvd;au
ms<s.; yels jyqhh iu. ixikaokh lsÍfïos Tn úiska wosk ,o jhqyj, ifmalaI ia:dhs;djhka i|yka lsßug
tu jhqy háka wvq ia:dhs fyda wia:dhs jYfhka ,shd olajkak.
(c).
1 1 2 2 3
i N2 - C - C - N - N - O hk ixfhda.h u; wIaGl kshuhg .e<fmk f,i tlir

Cl hq.,a yd 𝜋 nkaOk fhdod .ksñka " ia:dhs ¨úia jhqyh weo fmkajkak'

ii by; ia:dhs ¨úia jhqyh i,lñka " my; j.=fõ widwe;s f;dr;=re iïmQ¾K lrkak'

C1 C2 N2 N3

1) VSEPR hq.,a .Kk

2) bf,lafg%dk
a hq.,a
cHdñ;sh
3) yevh

4) uqyï
q lrKh

 fldgia (iii) isg (vi), by; ¨úia ;s;a-bß jhqyh u; mokï fõ. mrudKq f,an,a lsÍu (i) fldgfiys wdlrhgu
fõ.
iii my; oelafjk mrudKq fol w;r 𝛔 nkaOk iEosug iydNd.s jk mrudKql/uqyqï ldlaIsl yÿkd.kak.
i Cl—N 1 Cl …………………….. N ……………………….
ii N 3—O N 3 …………………….. O ……………………….
iii N 2—N 3 N 2 …………………….. N 3 ……………………….
iv N 2 —Cl N 2 ……………………… Cl ……………………….
v O —C 2 O ……………………… C 2 ……………………….
vi C 1 —C2 C 1 ……………………... C2 ………………………..

iv my; oelafjk mrudKq fol w;r 𝝅 nkaOk iEoSug iyNd.s jk mrudKql ldlaIsl yÿkd.kak.
i C 1—N 1 C 1 …………………….. N 1 ………………………..
ii O —N 3 O ……………………. N 3 ………………………...
v N 3, N 2, C 1 iy C 2 mrudKq jgd wdikak nkaOk fldaK i|yka lrkak.

N 3 ............... , N 2 ……………. , C 1…………….., C 2…………………

vi N1, N2, N3 mrudKq úoahq;a >DK;dj jeäfjk ms<sfj,g idokak.

…………….. < …………… < …………….

d) my; oelafjk m%Yakj,g ;s;a bß u; ms<s;=re imhkak.

i. Na+, Mg2+ iy F- hk whk ;=k w;=ßka, l=vdu whksl wrh we;af;a l=ulgo ? …………………..
ii. C,N iy O hk uq,øjH ;=k w;=ßka, jeäu fojk whkSlrK Yla;sh we;af;a
l=ulgo ? ………………….
iii. H2O, HOCl iy OF2 hk ixfhda. ;=k w;=ßka, jvd;au õoahq;a >DK Tlaiscka
mrudKqj we;af;a l=ulo ? ………………….
iv. Be, C iy N hk uq,øjH ;=k w;=ßka, jdhquh wjia:dfõoS mrudKqjlg
bf,lafg%dakhla tl;= l< úg [Y(g) + e → Y-(g); Y = Be,C,N] Yla;sh
msglrkqfha l=ulao ? ………………….
v. NaF, KF iy KBr hk whksl hk ixfhda. ;=k w;=ßka, c,fha jeäu ødjH;dj
we;af;a l=ulgo ? ………………….
 02 (a) my; ioyka ridhksl m%fNqo i,lkak'

Li2CO3 , Ba(NO3)2 , Na2CO3 , MgCl2 , NaOH , Ag2CO3 , Ca3N2 , HgO , Cl2O7 , NO2

i. oe,af,a mrSlaIdjg r;= j¾Kh ,nd fokafka

………………………………………………………………………………………………………………………………

ii. ;dm úfhdackhg ,la fkdjkafka (CO32- , -OH)

………………………………………………………………………………………………………………………………

iii. H2O iu. fkia,¾ m%;sldrlh oqUqre meye lrjk jdhqjla msg lrkafka
………………………………………………………………………………………………………………………………

iv. ;dm úfhdackh l< úg uQ,o%jH olajdu úfhdackh jkafka

………………………………………………………………………………………………………………………………

v. ñY% l< úg wjlafIamhla idok c,fha o%jH o%jK hq.,^h& jkafka

………………………………………………………………………………………………………………………………

vi. oe,af,a mrSlaIdjg

 wem,a fld< - ………………………………………………………………
 ly - ………………………………………………………………
 wj¾K - ………………………………………………………………

vii. by; ldnfkagj, ;dm úfhdackfha myiq;djh jeäjk fia ilia lrkak

………………………………..<…………………………………….<……………………………………….

viii. c,fha iïmQ¾Kfhkau o%djH ,jK jkafka

………………………………………………………………
ix. wdï,sl m%n,;djh jeâu Tlaihsvh jkafka
………………………………………………………………
x. by; (iii) m%;sl%shdj i|yd ;=,s; iólrKh ,shkak
………………………………………………………………
xi. by; (iv) m%;sl%shdj i|yd ;=,;
s iólrKh ,shkak
………………………………………………………………
b) A hkq S f.dkqjg wh;a uq,øjH ls ' fuys yhsfv%dlaihsvh c,fha oshjk w;r ldnfkagh c,fha osh fkdfõ' A
j, ,jKfha mykais¿ mßlaIdfõos r;= j¾Khla ,nd foa'
i. A yÿkd.kak'
…………………………………………………………………………………………………………

ii. A j,g by<ska iy my,ska we;s uq,øjH j, yhsfv%dlaihsv iy Tlaihsv c,fha ødjH;djh ,shd
olajkak'
………………………………………………………………………………………………………………
……………………………………………………………………………………………………

iii. A wh;a ldKavfha uq,øjH j, ldnfkag j, úfhdackh jk rgdj v%eùh;djh u.ska myokak'
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
……………………………………………………………………………………
iv. Mg wvx.= ,jK j,ska mykais¿ mßlaIdfõos j¾Khla ,nd fkdfokafka ukaoehs myokak'
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
………………………………………………………………………………………………………………
……………………………………………………………………………………

c) i). 3 jk wdj¾;fha uq,øjH j,ska iEfok by<u TlaislrK wjia:dfjka idok yhsv%hsvj, iq;% ,shd tajdfha
wdï,sl" WNh.=Ks fyda NdIañl iajNdjh olajkak'
…………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………
…………………………………………………………………………………………………………………………
………………………………………………………………………………………………
3)a) my; i|yka ;dm ridhksl o;a; i,lkak¡
úm¾hdih tka;e,ams w.h $ kJ mol-1
BaCI(2) ys iïu; W;amdok tka;e,amsh -855
Ba ys iïu; m<uq yd fojk whkSlrK tka;e,ams j, tl;=j +1470
Ba ys iïu; W!¾Ojmd;k tka;e,amsh +176
laf,darSka ys iïu; mrudKqlrK tka;e,amsh +122
laf,darSka ys iïu; m<uq bf,lafg%dak ,nd.ekSfï tka;e,amsh -350

i) ;=,s; ridhksl iólrKh ,shkak

(ii) BaCI2(s) ys iïu; oe,si ú>gk tka;e,amsh fndaka - fyan¾ pl%hla Ndú;fhka .Kkh lrkak¡

b) wmøjH ñY%s; *sfkda,a idïm,hl m%;sY; ixY=oaO;dj fiùu i`oyd isÿ lrk ,o mÍCIKhla my;
oelafõ. ialkaOh 0.2g jk by; *Sfkda, idïm,h c,fha osh lr 250cm3 ødjKhla idokq ,efí. bka
25.00cm3 la ma,dial=jlg uek thg 0.02moldm-3 KBrO3 25.00cm3, KBr 0.5g muK (jeämqr) yd H2SO4
wï, iaj,amhla tla lr ñY% lr úkdä 15 la muK ;nkq ,efí. fuysoS iEfok Br2 *Sfkda,a iu`.
m%;sl%shd lr 2,4,6-tribromophenol idohs.

OH OH
Br Br
+ 3Br2 + 3HBr

*sfkda,a Br
2,4,6-tribromophenol
bkamiq by; ødjKhg KI jeämqr tla lr 0.1 moldm-3 Na2S2O3 øjKhla iu`. wkqudmkh lrkq
,efí. jeh jQ Na2S2O3 mßudj 20.0cm3 ls.
I. fuysoS isÿjk ish¨u m%;l
s %shd i`oyd ;=,s; whksl m%;sl%shd ,shkak .
BrO3- + Br- Br2 +H2O
Br2 + I- I2 + Br-
II. idïm,fhys wvx.= *Sfkda,ays ialkaO m%;sY;h fidhkak.(C-12,H-1,O-16, Br- 79, K-39)