Paper Class Paper No 28

1
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wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h" 2021 Tlaf;daïn¾

General Certificate of Education (Adv. Level) Examination, October 2021

ridhk úoHdj II meh 02

Chemistry II 02 Hours

id¾j;% jdhq ksh;h" R = 8.314 J K-1 mol-1

wej.dâfrda ksh;h" NA = 6.022 × 1023 mol-1

(ish¨u m%Yakj,g ms<s;=re imhkak' tla tla m%Yakhg ,l=Kq 10 ne.ska ,efí')
A fldgi - jHQy.; rpkd

1. (a) my; § we;s uQ,øjH weiqßka wid we;s m%YaK j,g ms<s;=re imhkak'
C, N, Si, S, Cr, Co, Mn

(i) +3 TlaislrK wxlh iys; WNh.=KS Tlaihsvhla idok uQ,øjH$uQ,øjHhka jkqfha"

(ii) uQ,øjH folla tl;=ùfuka by,u øjdxlh iys; ixfhda.h idok uQ,øjHhka jkqfha"

(iii) tla uQ,øjHhl laf,darhsvh c, úÉfþokfhka wï, folla iuÕ wdú,;djhla we;s lrhs'
(I) uQ,øjH y÷kd .kak'

(II) iEfok M, i|yka lrkak'

(III) wod, ;=,s; iólrKh ,shkak'

(iv) tla uQ,øjHhla u`.ska tys by<u Tlaisldrl wjia:dfjka idok Tlais wï,h wdf,dalh yuqfõ wia:dhS fõ'

(I) uQ,øjH y÷kd .kak'

(II) Tlais wï,h i|yka lrkak'

(III) isÿjk m%;sls%hdj i|yd wod, ;=,s; iólrKh ,shkak'

^,l= K q 3'2&

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper No 28 Paper Class
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(b) fmksis,Ska" fgÜrdihsla,Ska jeks fndfyda m%;snelaàßhd kdYl T!IO (antibacterial drugs) j, i,af*dkeuhsâ
(Sulfonamaide) kue;s ixfhda. ldKavh wvx.= fõ' ir, i,af*dakeuhsvhl wKql iQ;%h C4H5SNO3 jk w;r
tys iels<s jHqyh my; ±lafõ' fuys C1, C2, C3, C4, S iy N mrudKq j, TlaislrK wxl ms<sfj,ska -1, 0, +3,
-3, +5 yd -3 fõ' (C yd S ys úoHq;a iDK;djhka iudk nj i,ld TZlrK wxl § we;s nj i,lkak'&
O O
C1 – C2 – S – N – C3 – C4
O
(i) by; i|yka i,af*dkeuhsâ wKqj i|yd jvd;au ms<s.; yels ¨úia jHqyh w¢kak'

(ii) fuu wKqj i|yd iïm%hqla; jHqy w¢kak' ^by; (i) fldgfiys w¢k ,o jHqyh yer&

(iii) by; (i) fldgfia w¢k ,o ¨úia jHqyh mokï lrf.k my; j.=fõ olajd we;s C2, S, N, C3, C4 hk
mrudKqj,"
(i) mrudKq jgd VSEPR hq.,a (ii) mrudKq jgd bf,lafg%dak hq., cHdñ;sh
(iii) mrudKq jgd yevh (iv) mrudKq j, uqyqïlrKh
(v) nkaOk fldaKh i|yka lrkak'

C2 S N C3 C4

I VSEPR hq.,a

II bf,lafg%dak hq.,a cHdñ;sh

III yevh

IV uqyqïlrKh

V nkaOk fldaKh

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper Class Paper No 28
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(iv) by; (i) fldgfia w¢k ,o ¨úia jHqyfha my; olajd we;s  nkaOk iE§u i|yd iyNd.S jk
mrudKq $ uqyqï ldCIsl y÷kd.kak'
I. C1 - C 2 , C1 ....................................... yd C2 .......................................
II. C2 - S , C2 ....................................... yd S .......................................
III. S - N , S ........................................ yd N ......................................
IV. N - C3 , N ........................................ yd C3 ......................................
V. C3 - C 4 , C3 ....................................... yd C4.......................................

(v) by; (i) fldgfia w¢k ,o ¨úia jHqyfhys C1, C2, C3 yd C4 hk ldnka mrudKq j, úoHq;a iDK;dj
wdfrdayKh jk ms<sfj,g ilia lrkak' ^fya;= ±laùu wjYH ke;'&

^,l= K q 5'6&

(c) my; oelafjk m%ldY i;H o ke;fyd;a wi;Ho hk nj i|yka lrkak' ^fya;= ±laùu wjYH fkdfõ'&
(i) my; olajd we;s úfYaI j, NdIañl m%n,;dj"

NH2
< NH3 < NH2(CH3) < NH(CH3)2

hk wdldrhg wdfrdayKh fõ' ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

(ii) N - H nkaOkfha O%eùh;djhg jvd N - F nkaOkfha O%eùh;djh by, ksid" NH3 g jvd NF3 j, oaúO%ej
>Q¾Kh by< fõ'

''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

(iii) idfmalaI wKql ialkaO iudk odudldr fkdfkaka (nonane)" C9H20 ys ;dmdxlh" g%hsfu;s,a fylafiaka
(2,3,4 - trimethylhexane), (C9H20) ys ;dmdxlhg jvd by< fõ'

''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

^,l= K q 1'2&
(2) (a) X, Y iy Z hkq wdj¾;s;d j.=fõ tlu wdj¾;hg wh;a wkqhd; uQ,øjH ;=kls' X, Y iy Z ys Wmßu TlaislrK
;;ajfhka jHq;amkak jk Tlafid wekdhk p;=ia;,Sh yevh .kS' X, Y iy Z wdf,day fõ' ldur WIaK;ajh §
X yd Y >k jk w;r Z jdhqjls'

(i) X, Y iy Z y÷kd.kak' ^mrudKql ixfla; fokak'&

X = ............................... Y = ............................... Z = ...............................

(ii) X, Y iy Z iïnkaOfhka my; oE ys idfmaCI úYd,;ajh olajkak'
(I) whksl wrh > >

(II) bf,lafg%dakSlrKh > >

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper No 28 Paper Class
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(III) m<uq whkSlrK Yla;sh > >

(IV) úoHq;a iDK;dj > >

(iii) Y iy Z ys wekdhk c,Sh ødjK fjk fjku Tng imhd we;' fuu wekdhk y÷kd .ekSu i|yd
Ndú;d l< yels ;ks m%;sldrlhla i|yka lrkak'
^ie' hq' tla tla wekdhkh i|yd ksÍCIKh Tn i|yka l< hq;=h'&
m%;sldrlh (-

ksÍCIKh ^wekdhk i|yd& (-

Y :

Z:

(iv) idkaø H2SO4 iuÕ Y ys m%;sls%hdj i|yd ;=,s; ridhksl iólrK ,shkak'

(v) c,Sh NaOH iu. Z m%;sls%hdj i|yd ;=,s; ridhksl iólrK ,shkak'

(vi) Y ys nyqrEmS wdldr mj;S o$ mj;S kï wdldr y;rla ,shkak'

(vii) Y iy Z ys tla m%fhdackhla ne.ska i|yka lrkak'

Y '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

Z '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

^,l= K q 5'9&

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper Class Paper No 28
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(b) A c,Sh ødjKfhys wekdhk folla wvx.= fõ' fuu wekdhk y÷kd .ekSu i|yd my; mÍCId isÿ lrk ,§'
(1) isg (4) olajd tla tla mÍCIdj i|yd ødjKfhka w¨;a fldgila Ndú;d lrk ,§'

mÍCIdj ksÍCIKh

1 I ;kql HCl tl;= lrk ,§' wj¾K jdhqjla msgúh' meyeÈ,s ødjKhla ,enqKs'

II msgjQ jdhqj j¾Kj;a u,a fm;a;la u`.ska u,a fm;af;ys fjkila isÿ fkdfõ'
mÍCId lrk ,§'
2 I Za(NO3)2 ødjKhla tl;= lrk ,§' iqÿ wjlafIamhla iEÿks'

II iqÿ wjlafIamh fmrd fjkalr thg ;kql HCl jdhqjla msglrñka iqÿ wjlafIamh Èhúh'
tl;= lrk ,§'

III msgjqKq jdhqj wdï,sl KMnO4 ødjKhla ;=,g ødjKh oï meyefha isg wj¾K wmeyeÈ,s ødjKhla
nqnq,kh lrk ,§' njg fjkia jqKs'

3 w¨; ieÿ f*ria i,afmaÜ ødjKhla tl;= lr ÿUqre j<hla fkdiEÿKs'

mÍCIK k<fha ì;a;sh Èf.a idkaø H2SO4 tl;=
lrk ,§'

4 I c,Sh AgNO3 ødjKhla tl;= lrk ,§' ly wjlafIamhla iEÿks'

II wjlafIamhg idkaø NH3 ødjKhla tl;= lrk ,§' fjkila ke;'

(i) A ødjKfha we;s wekdhk ;=k y÷kd .kak'

(ii) ksÍlaIK wxl (2)III ys isÿjk m%;sls%hdj i|yd ;=,s; ridhksl iólrKh ,shkak'

(iii) mÍCIK wxl (4) ys iEfok ly wjlafIamfha ridhksl iQ;%h ,shkak'

(iv) mÍCIK wxl (2)II ys § msgjk jdhqj my; i|yka wjia:dj,§ isÿjk m%;sls%hd i|yd ksÍCIK iy ;=,s;
ridhksl iólrK ,shkak'
I. wdï,sl K2Cr2O7 ødjKhla iuÕ

II. f,v weisfÜÜ ødjKhla iuÕ

^,l=Kq 4'1&

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper No 28 Paper Class
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(3) (a) (i) idkaøKh C moldm-3 jk c,Sh NH4Cl ødjKhl pH w.h my; iïnkaO;djfhka ,efnk nj fmkajkak'
fuys§ Ndú;d l< Wml,amkh ,shd olajkak'
2pH = pKw – pKb - log10 c fuys§ Ndú;d l< Wml,amk ,shd olajkak'

(ii) idkaøKh 0.1moldm-3 NH4Cl ødjKhl pH w.h .Kkh lrkak'

250C § NH3 ys Kb = 1.8 x 10-5 moldm-3 ; Kw = 1 x 10-14 mol2dm-6

(iii) tla;rd c,Sh ødjKhl wvx.= NH3 ys idkaøKh C1 moldm-3 fõ' NH4Cl ys idkaøKh C2 moldm-3 fõ'
ødjKfha 250C § pH w.h my; iïnkaO;djfhka ,efí'
C1
pH + pKb = 14 + log10 C2

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper Class Paper No 28
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by; (ii) fldgfiys ødjKfhka 250cm3 la ;=< NaOH n mol m%udKhla Èh lsÍfï§ tys pH w.h 8.3
olajd jeä úh' ^WIaK;ajh 250C & n ys w.h .Kkh lrkak'

^,l= K q 5'4&
–
(b) whvhsâ whk ( I ) iy f*ßla (Fe3+) whk w;r m%;sls%hdj my; mßÈ fõ'
–
2Fe3+(aq) + 2I (aq) I2(aq) + 2Fee2+(aq)
–
q a lKavdhula úiska 0.060 moldm-3 I ødjK mßud 500cm3 la 0.042mol dm-3 Fe3+ ødjK mßud 500cm3 la
isik
iu. ñY% lr 250C § ld,h;a iuÕ I2 idkaøKh ks¾Kh lr my; m%ia;drh ,nd .kakd ,§'

[½]/mol dm-3

0.04

0.03

0.02
0.01

ld,h / S
5 10 15 20 25

(i) wdrïNl ;;amr 15 l ld, mßÉfþoh wjidkfha § I2(aq) iE§fï YS>%;dj fidhkak'

–
(ii) I (aq) jehùfï YS>%;djh fidhkak'

(iii) Fe3+(aq) jehùfï YS>%;djh fldmuKo@

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper No 28 Paper Class
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(iv) 10 jk ;;amrfha § I2 ie§fï YS>%;djh Tn ks¾Kh lrkafka flfia±hs i|yka lrkak'
^.Kkh lsÍu wkjYHhs&

(v) Fe3+(aq) whk idkaøKhg idfmaCIj fm< fiùu i|yd isiqka úiska lrk ,o mÍCIKfha § ñY% lrk ,o
ødjK mßud iy ks,a j¾Kh ,eîug .;jQ ld,h my; j.=fõ ±lafõ'

+ 3+ msIaGh iys; ks,a j¾Kh

mÍCIK H /Fe ødjK KI ødjK H2O
Na2S3O3 ,nd§ug .;jQ
wxlh mßudj /cm
3
mßudj /cm3 mßudj /cm
3

mßudj /cm
3
ld,h /s

1 25.0 10.0 15.0 – 20

2 20.0 10.0 15.0 5.0 25

3 15.0 10.0 15.0 10.0 33

(I) fok ,o Fe3+(aq) idkaøKhg wkqrEmj m%;sls%hd YS>%;dj ukskafka flfia o@

(II) by; mßCIKfha Na2S2O3 ys ld¾h Ndrh l=ula o@

(III) by; o;a; weiqßka Fe3+(aq) whkj,g idfmaCIj fm< .Kkh lrkak'

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper Class Paper No 28
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(vi) ;j;a isiqka lKavdhula úiska my; i|yka fjkialï hgf;a by; mÍCIKh isÿ lrk ,§' tys§ ks,a meye
ùug .;jk ld,h wvqfõ o@ jeäfõ o@ ke;fyd;a fjkia fkdfõ o@ hkak i|yka lrñka § we;s j.=j
mqrjkak'

lrk ,o fjki ks,a meye ùug .; jk ld,h

1' moaO;sfha WIaK;ajh jeä lsÍu'

2' Na2S2O3 idkaøKh jeä lsÍu'

3' I– idkaøKh jeä lsÍu'

– –
(vii) I (aq) idkaøKh fjkia lsÍfuka isÿ lrk ,o mÍCIKfha § I (aq) g idfmaCIj m<uq fm< nj ks¾Kh lrk
,§'
(I) fuu m%;sls%hdj i|yd fõ. ióslrKh ,shkak'

(II) m%;sls%hdfõ iuia; fm< lSho@

^,l= K q 4'6&

(4) (a) (i) CxHyOZ wKq l iQ ; % h iys ; ldnks l ixfhda . hla jdhq u h ;;a ; a j hg m;a lr bka 10.0cm 3 l
mßudjla jdhquh O2, 60.00 iuÕ mQ¾K oykhg ,la lrk ,§' túg jdhquh CO2 40.0 cm3 la o c, jdIam
50.0 cm3la o ,enqKs'
fï i|yd O2 60.0cm3 la o jeh úh' ish¨u ñkqï 1500C § yd jdhqf.da, mSvkfha ñkqï lr we;' by;
ldnksl ixfhda.fha idfmalaI wKql ialkaOh 75 lg wvqh' fuu ldnksl ixfhda.fha wKql iQ;%h .Kkh
lrkak'

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper No 28 Paper Class
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(ii) P, Q, R yd S hkq by; wKql iQ;%hu we;s jHqy iudhúl y;rls' tajd NaOH iuÕ m%;sls%hd fkdl< o Na
iuÕ m%;sls%hdfjka H2 msg lrhs' ta w;ßka P muKla m%;srEm wjhj iudjhúl;djh fmkajhs'
P, Q yd R muKla H+ / K2Cr2O7 iuÕ m%;sls%hd lr ms<sfj,ska T, U yd V hk TlaislD; ldnksl ixfhda.
idohs' T ixfhda.h 2, 4, -DNP iuÕ ly wjlafIamhla ,ndfok kuq;a U yd V tfia fkdlrhs'
Q idkaø H2SO4 yuqfõ r;alr miqj ;kql H2SO4 fh¥ úg S njg m;a fõ'
(I) P, Q, R yd S ixfhda. y÷kd .kak'

p Q R S

(II) T, U yd V ixfhda. y÷kd.kak'

T U V

(III) by; Q yd R ixfhda. fjka lr y÷kd .ekSug ir, mÍCIdjla bÈßm;a lrkak'

^,l= K q 5'6&
(b) my; ±lafjk ir, mßj¾;kh i,lkak'
tys tla tla mshjf¾§ iEfok M, A, B, C, D yd E f,io tla tla mshjf¾o Ndú;d lrk m%;sldrl a, b, c, d,
e yd f f,i olajd we;s w;r tys m%;sldrl f,i ldnksl ixfhda. lsisjla wvx.= fkdfõ' m%;sls%hd igyfkys tla
tla mshjr m%;sls%hdj 1, 2, 3, .......... hkd§ f,i kï lr we;'
(i) by; m%;sls%hd weiqßka A, B, C, D yd E ixfhda. o a, b, c, d, e yd f hk m%;sldrl o m%;sls%hd hdka;%K o
y÷kd .ksñka my; j.=j iïmQ¾K lrkak'

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Paper Class Paper No 28
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C
m%;sl%h
s dj 3
Br Br c m%;sl%h
s dj 4
m%;sls%hdj 1 D
H–C–C–H A
a
H m%;sls%hdj 2 m%;sl%h
s dj 5
b E = H+/H2O
B

Br
m%;sls%hdj 6
–C – C  C – E
f
CH3

m%;sl%h
s dj m%;sldrlh m%;sl%h
s d hdka;%Kh M,h

A=

a=

B=
m%;s 02 b= wï, NIau

C=

m%;s 03 c=

D=

m%;s 04

E=

m%;s 05 e = H+ /H2O

Br
m%;s 06 f= – C – C C –
CH3

(ii) C+B E njg m;aùug wod< hdka;%Kh ,shkak'

^,l=Kq 4'4&

pß; Èidkdhl B.Sc. Engineering (Hon's)