AL/2022/02-S-IIA/B -1-

úNd. fmryqre mÍlaIK -2022

II
II Three hours
II

Total Marks
ku - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
úNd. wxlh - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
mdi, - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
m%Yak m;% mx;shg muKla iyNd.S fõ kï yßhla () fhdod olajkak' -

Wmfoia :
* m%Yak m;%fha kshñ; ia:dkfha Tfí wkkH;djh yÿkd .ekSug wjYH o;a; ,shkak'
* fuu m%Yak m;%h msgq 16 lska hqla; fõ'
* ish¨ u m%Yak j,g ms<s;=re imhkak'

id¾j;% jdhq ksh;h R = 8.314 J K-1 mol-1 wej.dâfrda ksh;h NA = 6.022 x 1023 mol-1
ma,dkalaf.a ksh;h h = 6.626 x 10-34 J s wdf,dalfha m%fõ.h C = 3 x 108 m s-1
A fldgi - jHqy.; rpkd
m%Yak y;rg u fuu m;%fhau ms<s;=re imhkak' ^tla tla m%Yakh i`oyd kshñ; ,l=Kq m%udKh 10 ls&
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1. (a) jryka ;=< § we;s .=Kh wdfrdayKh jk wkqms<sfj<g tla tla fldgfiys ±lafjk ridhksl m%fNao
ilia lrkak'
(i) NH4+ , H3O+ , H2F+ , NO2+ ( H - X - H nkaOk fldaKh &
'''''''''''''''''''''''''''''' < '''''''''''''''''''''''''''''' < '''''''''''''''''''''''''''''' < ''''''''''''''''''''''''''''''
(ii) H2O2 , O2 , O3 ^ O - O nkaOk È. &
'''''''''''''''''''''''''''''' < '''''''''''''''''''''''''''''' < ''''''''''''''''''''''''''''''
(iii) Ba(OH)2 , Sr(OH)2 , Ca(OH)2 , Mg(OH)2 ^ ødjH;djh &
'''''''''''''''''''''''''''''' < '''''''''''''''''''''''''''''' < '''''''''''''''''''''''''''''' < ''''''''''''''''''''''''''''''
(iv) H2O , OH- , CH3OH , CH3O- ^ Ndiañl;dj &
'''''''''''''''''''''''''''''' < '''''''''''''''''''''''''''''' < '''''''''''''''''''''''''''''' < ''''''''''''''''''''''''''''''
(v) LiCl , BeCl2 , MgCl2 , AlCl3 ^ c,Sh ødjKj, pH w.h &
'''''''''''''''''''''''''''''' < '''''''''''''''''''''''''''''' < '''''''''''''''''''''''''''''' < ''''''''''''''''''''''''''''''
^ ,l=Kq 2'0 hs &
(b) (i) S2O32- iy S4O62- whk j, ¨úia jHqyh w`Èkak'
S 2O 32- S4O62-

CHEMISTRY - TARGET - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]

AL/2022/02-S-IIA/B -2-

(ii) idkaø H2SO4 wï,h idkaø HNO3 wï,h iu. m%;sls%hd lr H2NO3+ kï whkh idohs' tys
iels,s jHqyh my; wdldr fõ'
_ _ _ +
H O N O
H O

tu whkh i|yd ¨úia ;s;a - bß jHqy ^¨úia jHqy& 3 la we| jvd;a wia:dhS ¨úia jHqyh
zz wia:dhS ZZ f,i kï lrkak'

(iii) ;fhdaweisguhsâ (CH3CSNH2) wKqj i|yd jvd;au ia:dhs ¨úia ;s;a bß jHqyh my; ±la fõ'
tys mrudKq my; ±lafjk mßÈ wxlkh lr we;'
H H
_ 1_ 2 _ 3_ 4 _
H _C_CS_N_H
:
:

H C C S N H
H H H H

tu ia:dhS ¨úia ;s;a - bß jHqyh mokï lrf.k j.=fõ olajd we;s C , S yd N mrudKqj,
I' mrudKqj jgd VSEPR hq.,a
II' mrudKqj jgd bf,lafg%dak hq., cHdñ;sh'
III' mrudKqj jgd we;s yevh'
IV' mrudKqfõ TlaislrK wxlh i|yka lrkak'

C1 C2 S3 N4
I VSEPR hq.,a
II bf,lafg%dak hq.,a cHdñ;sh
III yevh
IV TlaislrK wxlh

(iv) by; (iii) fldgfiys fok ,o ¨úia ;s;a bß jHqyfhys my; i|yka  nkaOk iE§ug iyNd.s
jk mrudKql $ uqyqï ldlaIsl y÷kd.kak'
I' H _ C
1 1
H '''''''''''''''''''''''''''''''''''''''''''''''''' C ''''''''''''''''''''''''''''''''''''''''''''''''''
1 _ 2 1 2
II' C C C '''''''''''''''''''''''''''''''''''''''''''''''''' C ''''''''''''''''''''''''''''''''''''''''''''''''''
III' C _ S
2
3 2 3
C '''''''''''''''''''''''''''''''''''''''''''''''''' S ''''''''''''''''''''''''''''''''''''''''''''''''''
IV' S _ N
3 4 3 4
S '''''''''''''''''''''''''''''''''''''''''''''''''' N ''''''''''''''''''''''''''''''''''''''''''''''''''
V' N _ H
4 4
N '''''''''''''''''''''''''''''''''''''''''''''''''' H '''''''''''''''''''''''''''''''''''''''''''''''''''
(v) by; (iii) fldgfiys fok ,o jHqyfhys C1 iy C2 mrudKq fol w;ßka úoHq;aRK;djh jeä
l=ul o hkak myokak'
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CHEMISTRY - TARGET - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]

AL/2022/02-S-IIA/B -3-

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^ ,l=Kq 5'0 hs &
(c) (i) 27
13
Al kHIaáhla u; fm%disfg%dakhla ( +1e) új¾IKh l< úg X kï úlsrKYS,S kHIaáhla iEfoa' X
0

u; kshqfg%dakhla .eàfuka yS,shï kHIaáhla iy ;j;a Y kï ia:dhs kHIaáhla iEfoa'

I. wod< kHIaál m%;sl%shd i|yd ;=,s; iólrK ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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II. X yd Y y÷kdf.k my; fldgq ;=< ,shkak'
X Y

(ii) mrudKql ldlaIslhla úia;r lrkqfha n , l iy ml lafjdkagï wxl ;=k u.sks' wod< lafjdkagï wxl
iy mrudKql ldlaIslfha ku my; ±lafjk fldgqj, ,shkak'
n l ml mrudKql ldlaIslh
I. +1 3p
II. 4 2 -1
III. 4s
(iii) mrudKqjlg mej;sh yels ^ n + l & = 5 jk"
I. Wm Yla;s uÜgï fudkjd o@ ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
II. I, ys i`oyka l< Wm Yla;s uÜgï j, Yla;sh wdfrdaykh jk wdldrhg ilikak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
III. Wmßu bf,lafg%dak ixLHdj fldmuK o@
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^ ,l=Kq 3'0 hs &
2. (a) f;jk wdj¾;fha M keue;s f,dayuh uQ,øjHh HCl iuÕ fukau NaOH iu`. o m%;sl%shd lr vhs
yhsv%cka jdhqj msg lrhs'
(i) M y÷kd.kak' ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(ii) M ys bf,lafg%dak úkHdih ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iii) M uQ,øjHh HCl iy NaOH iuÕ m%;sl%shdj i|yd ;=,s; iólrK ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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(iv) M uQ,øjHh il%sh;d fY%aKsfha msysàu wkqj b;d il%sh uQ,øjHhla úh hq;= kuq;a c,h iy jd;h
iuÕ m%;sl%shdYS,s;ajh b;d wjuh' Bg fya;=j ieflúka meyeÈ,s lrkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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(v) M Tlaiscka iu`. m%;sl%shd lr idok ixfhda.fha iQ;%h ,shkak' ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(vi) I. M u.ska idok ir,;u laf,darhsvfha jdhquh wjia:dfõ § iQ;%h ,shkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
II. by; Tn i|yka l< laf,darhsvfha ¨úia jHqyh ,shkak'

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(vii) I. M ys khsfÜ%g ødjKhlg NaOH ødjKhla iaj,amh ne.ska tl;= lrf.k hdfï § olakg
,efnk ksÍCIK fudkjd o@
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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II. NaOH ødjKhlg M ys khsfÜ%g ødjKhlska iaj,amh ne.ska tl;= lrf.k hdfï § olakg
,efnk ksÍCIK fudkjd o@
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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(viii) M u`.ska idok laf,darhsvh" wefudakshd iu`. idok ixfhda.fha ¨úia jHqyh w¢kak'

(ix) M vhs khsg%cka iu. idok"

I. ixfhda.h l=ula o@
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
II. tu ixfhda.h c,h iu`. m%;sls%hdj l=ula o@
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(x) NaNO3 , M , iu`. NaOH we;s úg isÿ jk m%;sls%hdj i`oyd ;=,s; iólrKh l=ula o@
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(xi) I. c,Sh ødjKhl § M u.ska idokq ,nk ir,u whkh l=ula o@
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
II. fuu whkfhys c,Sh ødjKhlg >k Na2CO3 tla l< úg" Tn ksÍlaIKh lsÍug n,dfmdfrd;a;=
jkafka l=ula±hs mqfrdal:kh lrkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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III. by; Tn i`oyka l< ksÍlaIKhg fya;=j ieflúka meyeÈ,s lrkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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^ ,l=Kq 7'0 hs &

(b) f,an, fkdue;s mÍlaIK k< 4 la A, B, C, D f,i kï lr we;' tajdfha Pb(NO3)2, MgCl2, BaCl2,
ZnSO4 hk ,jKj, c,Sh ødjK wvx.= fõ' ^ms<sfj<g fkdfõ'& fuu ødjK hq., jYfhka ñY% lsÍfï §
,enqKq m%;sM, my; ±lafõ' ^ = wjlafIam fõ" - = wjlafIamhla ke;&
A B C D
A -   
B  -  -
C   - -
D  - - -

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AL/2022/02-S-IIA/B -5-

by; ksÍlaIK weiqfrka my; m%Yakj,g ms<s;=re imhkak'

(i) A n÷fkys ;sfnkafka l=uk ,jKh o@ ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(ii) B n÷fkys ;sîug bv we;s ,jK fol fudkjd o@ ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iii) D n÷fkys we;af;a l=uk ,jKh o@ '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iv) A n÷fkys we;s ødjKh" D n÷fkys we;s ødjKh iu`. jQ m%;l s hs% dj i|yd iólrKhla ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(v) C n÷fkfys wvx.= ødjKh;a A n÷fkys wvx.= ødjKh;a tla l< úg iEfok wjlafIamh iaÓr
jYfhka y÷kd.ekSug fjk;a ridhksl øjH Ndú;d fkdlr Tng isÿ l< yels mÍlaIKhla ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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(vi) by; (v) ys ksÍlaIK u`.ska C n÷fka we;s ødjKh y÷kd .kakd whqre olajkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''' ^ ,l=Kq 3'0 hs &

3. (a) A(g) + 2B(g) AB2(g) hk m%;sl%shdj i|yd 25 0C ys§ wod< jk úNj Yla;s me;slv igyk my;
rEmfha olajd we;'
Yla;sh / kJ mol-1

250
200
150
A(g) + 2B(g)
100
AB2(g)
50
0 m%;sls%hd LKavdxlh

(i) by; m%;sl%shdj wod<j bÈß m%;sl%shdfõ il%shk Yla;sh Ea(f), miq m%;sl%shdfõ il%shk Yla;sh Ea(r),
iy m%;sl%shdfõ tka;e,ams fjki H by; m%ia;drh u; ,l=Kq lrkak'
(ii) m%;sl%shdfõ tka;e,ams fjki .Kkh lrkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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(iii) Y kï W;afm%arKh moaO;shg y÷kajd ÿka úg bÈß m%;sl%shdfõ il%shk Yla;sh 100 kJ la fjkia úh'
Y iys;j m%;sl%shdj isÿjk wjia:dj i|yd jk jl%h o" by; rEmfha u igyka lrkak'
^ ,l+Kq 2'0 hs &
(b) 25 0C WIaK;ajfha § my; m%;sl%shdj i,lkak'
XY(s)  P(s) + 2Q(g)
25 C § H yd S i|yd my; o;a; § we;'
0
f
0 0

Hf0 / kJ mol-1 S0 / J K-1 mol-1

XY(s) -1250 100
P(s) -800 60
Q(g) -600 180
(i) by; m%;sl%shdfõ"
I. iïu; tka;e,amsh fjki H0 .Kkh lrkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

CHEMISTRY - TARGET - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]

AL/2022/02-S-IIA/B -6-

'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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II. iïu; tkafg%dms fjki S0 .Kkh lrkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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III. iïu; .síia fhdacH Yla;s fjki G0 .Kkh lrkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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(ii) tuÕska fuu m%;sl%shdj iajhxisoaOj isÿ fõ o@ fkdfõ o@ hkak meyeÈ,s lrkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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(iii) by; m%;sls%hdj iajhxisoaO isÿ jk WIaK;ajh .Kkh lrkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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(iv) by; (iii) ys .Kkfha § Tn Ndú; l< Wml,amk i|yka lrkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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^ ,l=Kq 5'0 hs &
(c) C, H yd O wvx.= A kue;s ldnksl ixfhda.hl 10 cm3 la O2 100 cm3 iuÕ ñY%lr oykh lrjd
kej; ldur WIaK;aj yd mSvkhg m;aùug yer ,enqKq jdhq mßudj uek.;a úg 90 cm3 la
úh' fuu jdhq mßudj KOH yryd hejQ úg 20 cm3 lska wvq úh'
ie'hq' (- A j, fu!,sl ialkaOh 46 g mol-1 fõ' ^ish¨u mßud ñkqï uek we;af;a ldur
WIaK;aj yd mSvkfha §h &
(i) A j, wKql iQ;%h CxHyOz kï oykh i|yd wod< iólrKh x, y, z weiqßka ;=<s; lr
,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(ii) A kue;s ldnksl ixfhda.fha wKql iQ;%h ks¾Kh lrkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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CHEMISTRY - TARGET - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]

AL/2022/02-S-IIA/B -7-

'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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(iii) A i`oyd mej;sh yels ishÆu ixfhda. j, jHqy w`Èkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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^ ,l=Kq 3'0 hs &
4. (a) wKql iQ;%h C7H14O2 jk tiagrh úh<s B;¾ udOHfha LiAlH4 iu`. m%;sl%shd lrjd c,hg tlal< úg
A yd B ixfhda. ñY%Khla ,nd foa' B m%ldY iudjhúl;djh olajhs' A yd B ks¾c,Sh Al2O3 iu`. r;al<
úg ms<sfj<ska C yd D ixfhda. ,nd foa' C iy D ixfhda. fjk fjku HBr iu`. msßhï l< úg C u`.ska
m%Odk M,h E iy iq¿ M,h F ixfhda. ñY%Kh o D u.ska G ixfhda.h o ,nd foa'
(i) A, B, C, D, E yd G ys jHqy my; § we;s fldgq ;=< w¢kak'

A B

C
D

E G
(ii) D ys iudjhúl j¾.h kï lr tys iudjhúl jHqy my; fldgq ;=< w¢kak'

'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''' ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iii) C ixfhda.h HBr iu`. msßhï l< úg m%Odk M,h E yd iq¿ M,h F f,i ,eîug fya;= meyeÈ,s
lrkak'

CHEMISTRY - TARGET - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]

AL/2022/02-S-IIA/B -8-

'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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(iv) A iy B ixfhda. wdï,sl CrO3 iu`. m%;sl%shdfjka H yd I M, ,nd foa' H yd I jHqy my; § we;s
fldgq ;=< w¢kak'

H I
(v) by; H yd I ixfhda. fjkalr y÷kd .; yels ridhksl mÍlaIdjla i|yka lrkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
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'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^ ,l=Kq 4'5 hs &
(b) my; § we;s m%;sl%shdj, m%Odk M, K, L, M, N, O, P, Q, R, S, T yd U fõ' wod< M, fldgq ;=< i|yka
lrkak'

(1) CH3C  CH + C2H5Br / Mg / úh<s B;¾ K

+L

(2) C6H5CN + CH3Cl / ks¾' AlCl3 M

(3) C2H5COCl + CH 3 NH 2 N

(4) C2H5-C  C-C6H5 + Hg2+ ;' H2SO4 / 60 0C O

CHEMISTRY - TARGET - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]

AL/2022/02-S-IIA/B -9-

(5) C6H5CHO + CH3CHO/ ;' Ba(OH)2 P

(6) CH3C(C2H5 )HCl + ;' KOH(aq) Q

(7) C2H5COC2H5 + NaBH 4 R

(8) (CH3)2 C = CH2 + HBr S

(9) C6H5OH + ;' HNO3 T

(10) CH3CHOHCO2H + 1) LiAlH4 2) H2O U

^ ,l=Kq 3'0 hs &

(c) my; i`oyka m%;sl%shd fYa%Ksh i,lkak'

HBr KCN H2O/ H+

CH3- CH2 - OH (A) (B) (C)
mshjr ^1& mshjr ^2& mshjr ^3&

(i) A , B , iy C ixfhda. y`ÿkd .kak'

A B C
(ii) mshjr ^2& § isÿ jk m%;sl%shdfõ hdka;%Kh ,shkak'

CHEMISTRY - TARGET - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]

AL/2022/02-S-IIA/B - 10 -

(iii) by; m%;sl%shd mshjr j,g wod, m%;sl%shd j¾.h y`ÿkd .kak'
mshjr ^1& - ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
mshjr ^2& - ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
mshjr ^3& - ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^ ,l=Kq 2'5 hs &
----------------------------------------------------------------------------------------------------------------------------------------
B fldgi - rpkd
m%Yak folgu ms<s;=re imhkak' ^tla tla m%Yakh i`oyd kshñ; ,l=Kq m%udKh 15 ls&
----------------------------------------------------------------------------------------------------------------------------------------
5. (a) mßudj 0.5 m3 la jk Ndckhla ;=< 27 0C § yd 1.2 × 105 Nm-2 hgf;a§ N2 jdhqj ;sfí' mßudj 1.5 m3
jk Ndckhla ;=< 87 0C § iy 9.0 × 105 Nm-2 hgf;a § He jdhqj ;sfí' fuu Ndck fol mßudj
fkd.sksh yels ùÿre k,hla u.ska iïnkaO l< úg" tajd ksoyfia ñY%fjñka moaO;sfha WIaK;ajh
47 0C njg m;a úh' fuu moaO;sh iïnkaOfhka my; tajd .Kkh lrkak'
(i) wjidk moaO;sfha N2 ujq, .Kk
(ii) wjidk moaO;sfha N2 ys wdxYsl mSvkh
(iii) wjidk moaO;sfha iuia; mSvkh
(iv) wjidk moaO;sfha He ys ujq, Nd.h
(v) 47 0C § moaO;sfha iuia: mSvkh ;=ka .=Khla l< úg He ys wdxYsl mSvkh
(vi) wjidk moaO;sfha WIaK;ajh 30 0C olajd wvql< úg N2 ys ujq, Nd.hg l=ula jkafka±hs m%ldY
lrkak'
^ ,l=Kq 5'0 hs &
(b) my; ±lafjk ;dm ridhksl o;a; i,lkak'
Na j, iïu; ;+lrK tka;e,amsh = 107.5 kJ mol-1
Na j, iïu; m<jk whkSlrK tka;e,amsh = 494 kJ mol-1
O2 j, iïu; nkaOk tka;e,amsh = 496 kJ mol-1
O(g) j, iïu; m<jk bf,lafg%daklrk tka;e,amsh = -139 kJ mol-1
O(g) j, iïu; fojk bf,lafg%daklrk tka;e,amsh = +794 kJ mol-1
Na2O(s) j, iïu; ±,si tka;e,amsh = 2522 kJ mol-1
Na(s) j, iïu; tkafg%dmsh = 51.5 J mol-1 K-1
O2(g) j, iïu; tkafg%dmsh = 205.0 J mol-1 K-1
Na2O(s) j, iïu; tkafg%dmsh = 30.05 J mol-1 K-1
(i) by; tka;e,ams úm¾hdi i`oyd ridhksl iólrK ,shkak'
(ii) by; tka;e,ams úm¾hdi Ndú; lr my; § we;s m%;sl%shdfõ iïu; tka;e,ams fjki .Kkh
lrkak'
2Na(s) + 1/2 O2(g) Na2O(s)
^ ,l+Kq 5'0 hs &
(c) iam¾Y l%ufhka H2SO4 wï,h ksIamdokfha§ isÿjk jeo.;au m%;sl%shdj fufiah'
2SO2(g) + O2(g) 2SO3(g) ; H= -197 kJ mol-1
3 × 105 Pa mSvkhla hgf;a§ SO2(g) iy O2(g) , 2 : 1 mßud wkqmd;hg ñY%lr 430 0C r;alrk ,o
W;afm%arlhla u;ska hjhs' iu;=,s;;djfha§ SO2(g) j, wdxYsl mSvkh 1.8 × 105 Pa nj fihd .kS'
(i) iu;=,s;;djfha§ SO3(g) iy O2(g) j, wdxYsl mSvk iy iuia: mSvkh fidhkak'
(ii) SO3(g) njg m;a ù we;s SO2(g) m%;sY;h fidhkak'
(iii) 430 0C § by; iu;=,s;h i|yd iu;=,s;;d ksh;h Kp .Kkh lrkak'
(iv) 430 0C § KC .Kkh lrkak' (RT = 6000 Nm mol-1)
(v) fuu moaO;sh my; úm¾hdij,g ,lal< úg iu;=,s;;d ksh;h KC wvq fõo jeä fõo

CHEMISTRY - TARGET - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]

AL/2022/02-S-IIA/B - 11 -

fjkia fkdfõ o hkak i`oyka lrkak'

I. moaO;sfha mSvkh jeä lsÍu
II. moaO;shg ndysßka SO2(g) tl;= lsßu
III. moaO;sfha WIaK;ajh jeä lsÍu
^ ,l+Kq 5'0 hs &
6. (a) my; wegjqu Ndú;fhka Y f,dayfha idfmaCI mrudKql ialkaOh fiùu i|yd ksh; Odrdjla Ndú;fhka
ñks;a;= 20 l ld,hla ;=< úoHq;a úÉfþokh isÿ lrk ,§' fuu l%shdj,sh w;r;=r § ^1& fldaIfha
lef;davfha 13.5 mg ialkaOh jeäùula o ^2& fldaIfha lef;davfha 48.75 mg ialkaOh jeäùula o isÿ
úh' ^fldaI 2 ysu c,h úoHq;a úÉfþokh ùula isÿ fkdjk nj Wml,amkh lrkak'&
( Al j, id'm'ia' 27" *erfâ ksh;h 96500 C mol-1 )
(+) (-) ksh; Odrd iemhqu



Al   Y

c,Sh Al2(SO4)3   c,Sh YSO4

A B C D
^1& fldaIh ^2& fldaIh
(i) ^1& iy ^2& fldaIj, wefkdavh iy lef;davh y÷kd.kak' (A, B, C, D weiqfrka&
(ii) tla tla fldaIfha tla tla bf,lafg%davfhys isÿjk warO m%;sl%shd ,shd olajkak'
(iii) fuu úoHq;a úÉfþok l%shdj,sh i|yd Ndú; lrk ,o ksh; Odrdj .Kkh lrkak'
(iv) Y f,dayfha idfmaCI mrudKql ialkaOh .Kkh lrkak'
^ ,l+Kq 5'0 hs &
(b) (i) fu;fkdhsla wï,h (HCOOH), Ka = 1.77 × 10 mol dm jk ÿn, wï,hls'
-4 -3

I. HCOOH j, Ka i|yd m%ldYkhla ,shkak'

II. tu m%ldYkh Ndú;fhka 0.05 mol dm-3 HCOOH ødjKhl [H+(aq)] .Kkh lrkak'
III. ødjKh ;=< whkSlrKh ù we;s HCOOH wKqj, m%;sY;h .Kkh lrkak'
IV. ødjKfha pH w.h .Kkh lrkak'

(ii) HCOOH fuka u HCl wï,h o Mg f,day l=vq iu. m%;sl%shd lrhs'
I. HCOOH yd Mg w;r m%;sl%shdj i|yd ridhksl iólrKh ,shkak'
II. fuu wï, foflkau 0.05 mol dm-3 ys 20 cm3 l mßud folla f.k fjk fjku jeämqr Mg
l=vq iu. m%;sl%shd lrjQ úg iudk H2(g) mßudjla msgúh' tfy;a HCl wï,hg idfmaCIj
HCOOH j, m%;sl%shd YS>%;djh b;d wvqhs' msgjk H2(g) mßudj .Kkh lrkak' ^iïu;
WIaK;aj mSvkfha§ Vm = 22.4 dm3 mol-1)
III. HCl wï,hg idfmaCIj HCOOH ys m%;sl%shd YS>%;dj b;d wvqùug fya;=j meyeÈ,s lrkak'
IV. wjidkfha§ HCOOH u`.ska fuka u HCl u.ska o iudk jdhq mßudjka msg lsÍug fya;=j
meyeÈ,s lrkak'
^ ,l+Kq 5'0 hs &
(c) HA kï ÿn, tal NdIañl wï,h c,h iy CHCl3 hk ødjl foflysu ødjH fõ' HA ys idkaøKh
0.057 mol dm-3 jk CHCl3 ys HA ødjK 500.0 cm3 la c,h 500.0 cm3 la iu. fyd¢ka fid,jd 25 0C §
iu;=,s;;djhg t<öug bv yßk ,§' fuúg c,Sh iy CHCl3 ia:r fjkajk w;r fuu ;;a;aj hgf;a
c,Sh ia:rfha pH w.h 3.21 nj fidhd .kakd ,§' 25 0C § c,fha § HA ys ú>gk ksh;h
1 × 105 mol dm-3 fõ'
(i) c,h iy CHCl3 w;r HA ys jHdma;sh i|yd 25 0C § jHdma;s ix.=Klh .Kkh lrkak'

CHEMISTRY - TARGET - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]

AL/2022/02-S-IIA/B - 12 -

(ii) fjk;a mÍCIKhl§ idkaøKh 0.057 mol dm-3 jk CHCl3 ys HA ødjK 500.0 cm3 la ;j;a fldgila
idkaøKh 0.027 mol dm-3 jk c,Sh NaOH ødjKhl 500.0 cm3 l iu`. fyd¢ka fid,jd 25 0C §
iu;=,s;;djhg t<öug bv yßk ,§' fuu ;;a;aj hgf;a§ c,Sh ia:rfhys pH w.h .Kkh
lrkak'
(iii) by; .Kkh lsÍïj,§ Tn isÿ lrk Wml,amk i|yka lrkak'
^ ,l+Kq 5'0 hs &

7. (a) my; m%;sl%shdj i,lkak'

H2O2(aq) + 3I-(aq) + 2H+ (aq)  I3-(aq) + 2H2O(l)
30 0C § by; m%;sl%shdfõ fm< fiùu i|yd isÿ lrk ,o mÍCIKhl ksÍCIK yd iïnkaO f;dr;=re
my; j.=fõ ±lafõ'

wdrïNl idkaøKh (mol dm-3) wdrïNl YS>%;djh

mÍCIKh H2O2(aq) I-(aq) H+(aq) mol dm-3 s-1
1 0.01 0.01 0.0005 1.15 × 10-6
2 0.02 0.01 0.0005 2.30 × 10-6
3 0.01 0.02 0.0005 2.30 × 10-6
4 0.01 0.01 0.0010 1.15 × 10-6

(i) by; § we;s m%;sl%shdj i|yd YS>%;d iólrKh ,shd mo y÷kajkak'

(ii) H2O2(aq) , I-(aq) iy H+(aq) hk m%;sl%shlhkag idfmaCIj fm< .Kkh lrkak' fõ. m%ldYkh
,shkak'
(iii) fõ. ksh;h fidhkak'
(iv) H2O2(aq) iy H+(aq) idkaøKh ksh;j ;nd .ksñka I-(aq) idkaøKh y;r .=Khlska jeäl<fyd;a
YS>%;djh flfia fjkiafõ o@
^ ,l+Kq 5'0 hs &
(b) X kï uQ,øjH d f.dkqjg wh;a uQ,øjHhls' tys X2+ whkh my; m%;sl%shdj,g Ndckh fõ'
;kql NH3(aq) jeämqr idkaø
Y Z
ìxÿ f,i NH3(aq)
^frdai meye;s wjlafIamh& ^ly meye;s ødjKh&

X2+(aq)

idkaø HCl
D
^ks,a meye;s ødjKh&

ix.; wxlh 6 la jk X3+ whkh" NH3 yd Cl- iu`. A, B yd C kï ixfhda. 3 la idohs' tajdhska
1 mol la fjk fjku AgNO3 iu`. m%;sl%shd l< úg A, B yd C ms<sfj<ska wjlafIam 1 mol, 2 mol yd 3 mol
ne.ska ,nd .kS'
(i) X f,dayh y÷kd.kak'
(ii) by; ix.; ixlS¾Kh AgNO3 iu. idok wjlafIamh l=ula o@
(iii) B, C, D, Y, Z ixfhda.j, iQ;% ,shd olajkak'
(iv) A, B, C ixlS¾Kj, yevh l=ula o@
(v) C ys jHqyh we| olajkak'
(vi) X2+ whkfha j¾Kh l=ula o@

CHEMISTRY - TARGET - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]

AL/2022/02-S-IIA/B - 13 -

(vii) X2+ whkfha iïmQ¾K bf,lafg%dak úkHdih ,shkak'

(viii) my; I yd II Tn n,dfmdfrd;a;= jk ksÍlaIK fudkjd o@
I. ldur WIaK;ajfha§ X2+ wvx.= NdIaul ødjKhlg H2S jdhqj hejQ úg
II. I la ,efnk ñY%Khg WKq idkaø HNO3 tl;= l< úg
^ ,l+Kq 5'0 hs &
(c) A kï uQ,øjH ;kql NaOH iu`. m%;sls%hd lrjQ úg c,h iy A1 , A2 hk ixfhda. fol ,enqKs'
A1 yd A2 ixfhda.j,g fjk fjku ;kql i,a*shqßla wï,h tl;= l, úg A1 j,ska A3 jdhqj o
A2 j,ska A4 jdhqj iy A5 kï ,d ly meye;s wjlafIamhla ^wdú,;djhla& ,enqKs' A3 jdhqj " A4 jdhqfõ
c,Sh ødjKh iu`. m%;sls%hd l< úg kej; A5 ,efí' A2 ixfhda.h AgNO3 ødjKh iu`. iqÿ meye;s
A6 ,ndfok w;r th r;a l< úg l¿ meye;s A7 njg m;a fõ' A4 jdhqj CuSO4 c,Sh ødjKh iu`.
m%;sls%hd lrjQ úg tys ks,a meyeh wj¾K jk w;r A8 iEfoa'
(i) A1 , A2 , A3 , A4 , A5 , A6 , A7 iy A8 hk m%fNao y÷kd.kak'
(ii) my; i|yka tla tla m%;sls%hdj,g wod< ;=,s; iólrK ,shkak'
I' A + NaOH
II' A2 + H2SO4
III' A4 + CuSO4
(iii) by; .eg¨fõ i|yka fkdjk" A4 jdhqj y÷kd.ekSu i|yd isÿl< yels mÍCIKhla ,shkak'
^ ,l=Kq 5'0 hs &

----------------------------------------------------------------------------------------------------------------------------------------
C fldgi - rpkd
m%Yak folgu ms<s;=re imhkak' ^tla tla m%Yakh i`oyd kshñ; ,l=Kq m%udKh 15 ls&
----------------------------------------------------------------------------------------------------------------------------------------

8. (a) A, B iy C hkq wKql iQ;%h C7H14 jk tlsfkflys m%ldY iudjhúl fkdjk" tkï m%;srEm wjhj
fkdjk" m%ldY il%sh iudjhúl yhsfv%dldnk 3 ls' A iy C cHdñ;sl iudjhúl;djh fkdfmkajqj o
B cHdñ;sl iudjhúl;dj fmkajhs' A, B, C W;afm%aß; yhsv%ckSlrKfhka tlu ixfhda.h jk D ,nd
fohs' D o m%ldY il%sh fõ'
(i) A, B, C, D j, jHqyhka w¢kak' ^;%sudK iudjhúl wdldr we| ±laùu wjYH ke;&
(ii) A iy D j, IUPAC kdu ,shkak'
(iii) A iy B tlsfklska fjkalr y÷kd.ekSug ridhksl mÍlaIdjla fhdackd lrkak'
(iv) C ixfhda.h" B ixfhda.h njg mßj¾;k lrkafka flfia o@
(v) D ys m%ldY il%sh iudjhúl wdldrj, jHqy w¢kak'
^ ,l=Kq 4'0 hs &

(b) tlu ldnksl wdrïNl øjH jYfhka § we;s ixfhda.h fhdod .ksñka y;lg ^7& fkdjeä mshjr
ixLHdjla Ndú; lr my; tla tla mßj¾;kh isÿ lrkak'
OH
(i) CH3 CH  CH2 CH3 C  C  C  CH3
CH 3 ^ ,l+Kq 5'0 hs &
O O
(ii) C6H5 C  H C6H5 C  O  CH2  C6H5

CHEMISTRY - TARGET - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]

AL/2022/02-S-IIA/B - 14 -

(c) C6H5 COOCH2CH3 tlu ldnksl wdrïNl øjH jYfhka iy m%;sldrl jYfhka ,ehsia;=fõ§
§ we;s m%;sldrl muKla fhdod.ksñka wglg ^8& fkdjeä mshjr ixLHdjla Ndú; lr my; i|yka
ixfhda.h ixiaf,aIKh lrk wdldrh olajkak'

CH2 CH3 ridhk øjH ,ehsia;=j

;kql H2SO4 , Mg / úh<s B;¾ , LiAlH4, HBr , PCC,
C6H5 C  N CH2 CH3
idkaø NH3 , H+ / CrO3
^ ,l+Kq 3'0 hs &

(d) my; § we;s m%;sl%shdj i,lkak'

RCl / AlCl3
R

(i) R - Cl f,i
Cl
I. CH3 - Cl iy II. CH3  C  CH2  CH3 fhdod .;a úg
CH 3
by; m%;sl%shdfõ bf,lafg%d*hs,h fjk fjku i|yka lrkak'
(ii) by; I iy II ys bf,lafg%d*hs, j, jHqyhka ie,l+ úg tla m%;sl%shdjl muKla bf,lafg%d*hs,h
R+ wdldrh o wfkla tfia fkdùug fya;=j meyeÈ,s lrkak'
(iii) II m%;sl%shdjg wod< hdka;%Kh ,shkak'
^ ,l+Kq 3'0 hs &
9. (a) X kï ødjKh legdhk 3 lska iukaú;h' tu legdhk y÷kd.ekSu i|yd my; mÍlaIK isÿ lrk ,§'

mÍlaIKh ksÍlaIKh
^1& X ødjKhg ;' HCl tla lsÍu lsisÿ wjlafIamhla fkd,enqKs'
^2& X ødjKh ;=<ska H2S nqnq,kh lsÍu l¿ meye;s wjlafIamhla (P) ,enqKs'
^3& P wjlafIamh fjka lrf.k fmrkh" H2S wjika
jk;=re r;alr id' HNO3 ìxÿ lsysmhla tlalr fld< meye;s wjlafIamhla (Q) ,enqKs'
;jÿrg;a r;alr" tu ødjKh isis,a lr NH4OH /
NH4Cl tla lsÍu
^4& Q wjlafIamh fjka lrf.k fmrkh ;=<ska H2S l¿ meye;s wjlafIamhla (R) ,enqKs'
nqnq,kh lsÍu

P, Q, R wjlafIam i|yd mÍlaIK

mÍlaIKh ksÍlaIKh
^5& P WKq idkaø HNO3 ;=< Èh fõ' bkamiq jeämqr ;o ks,a ødjKhla ,efí'
NH3 tla lrk ,§'
^6& NaOH tla l< úg Q Èh fõ' fld< meye;s ødjKhla ,efí'
;' HCl tla l< úg o Q Èh fõ' ks,a oï meye;s ødjKhla ,efí'
^7& R wjlafIamh WKq idkaø H2SO4 ys Èh fõ' fld< meye;s ødjKhla ,efí'
by; ødjKh NH3 iu. m%;sl%shd lrk ,§' ;o ks,a meye;s ødjKhla ,efí'

(i) X ødjKfhys we;s legdhk 3 y÷kd.kak'

(ii) P, Q yd R wjlafIamj, ridhksl ixfla; ,shkak'
^ ,l=Kq 5'0 hs &

CHEMISTRY - TARGET - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]

AL/2022/02-S-IIA/B - 15 -

(b) M hkq 3d wdka;ßl uQ,øjHhls'

* M ys by<u TlaislrK wxlh we;s Tlais wekdhkh fmdgeishï iu`. M1 kï oï meye;s

ixfhda.hla idohs'
* M1 ixfhda.h KOH iu`. m%;sl%shd lr M2 kï fld< meye;s ødjKh iy M3 kï wj¾K
jdhqjla idohs'
* M2 ødjKhg wj¾K M4 ødjKh tl;= l< úg ;o ÿUqre meye;s M5 kï wjlafIamh
idoñka M3 jdhqj idohs'
* M5 j,g Tlaisldrlhla fuka u Tlaisydrlhla f,i o l%shd l< yel'

(i) M y÷kd .kak'

(ii) M1 , M2 , M3 , M4 , M5 y÷kd .kak'
(iii) isÿ jk ish¨u m%;sl%shd i|yd ;=,s; iólrK ,shkak'
(iv) M5 idkaø HCl iuÕ m%;sl%shdj i|yd ;=,s; iólrKh ,shkak'
(v) c,Sh ødjKfha § M2+ idok ixlS¾K whkfha iQ;%h" yevh" j¾Kh yd IUPAC kduh ,shkak'
(vi) M2+ c,Sh ødjKhg NaOH tl;= l< úg olakg ,efnk ksÍlaIK meyeÈ,s lrkak'
^ ,l+Kq 5'0 hs'&

(c) S hkq Na2SO4 , Na2SO3 yd Na2CO3 muKla wvx.= c,Sh ødjKhls' S f.ka 50 cm3 lg jeämqr BaCl2
ødjKhla tl;= lsÍfï§ ,enqKq wjlafIamj, úh<s ialkaOh 7.895 g úh' fuhg wjlafIamh jeämqr
;kql HNO3 wï, ødjKhlg tl;= lr fyd¢ka fi,ùfï § b;sß jQ wjlafIamfha úh<s ialkaOh
0.466 g úh' tys § msg jQ jdhQka idkaøKh 0.08 mol dm-3 jQ wdï,slD; KMnO4 50.00 cm3 la ;=<g
hjk ,§' tys§ m%;sl%shd fkdl< MnO4- whk iu. iïmQ¾Kfhkau m%;sl%shd lsÍu i|yd 0.15 mol
dm-3 Fe2+ ødjKhlska 40.00 cm3 jeh úh' (Ba = 137, S = 32, O = 16, C = 12)
(i) by; isÿjk ish¨ m%;sl%shdj,g wod< ;=,s; ridhksl iólrK ,shkak'
(ii) S ødjKfha tla tla ixrplfha idkaøKh fjk fjku .Kkh lrkak'
^ ,l=Kq 5'0 hs &

10. (a) úh<s we,a.S Ndú;fhka ,nd .kakd g%hs.a,sirhsvhla Ndú;fhka ffcj ãi,a iEÈh yel' tu
g%hs.a,sirhsvfha jHqy iQ;%h my; oelafõ'
C 17H 35 CO 2CH 2
C 17H 35CO 2CH tys id'w'ia' M = 890
C 17H 35 CO 2CH 2
ta uÕska ffcj ãi,a iE§ug my; l%uh fhdod .kS'
C 17H 35 CO 2CH 2
1 mshjr C17H35CO2CH  .a,sifrda,a + 3 C17H35COOH
C 17H 35 CO 2CH 2
2 mshjr C17H35COOH  C17H35CO2CH3 (id'w''ia' M = 298)

(i) fuys ffcj ãi,a hkqfjka y÷kajkafka l=ula o@

(ii) by; i|yka mshjr 1 i|yd iqÿiq m%;sldrlh l=ula o@
(iii) mshjr 2 i|yd iqÿiq m%;sldrlh iy m%;sl%shd ;;a;ajh l=ula o@
(iv) by; we,a.Sj, 50 % la ialkaOh wkqj g%hs.a,sirhsâ we;s nj Wml,amkh lr úh<s we,a.S
1000 kg la uÕska ksmoúh yels ffcj ãi,a ialkaOh .Kkh lrkak'

CHEMISTRY - TARGET - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]

AL/2021/02/S-IA/IIA - 16 -

(v) n,Yla;s W;amdokh lsÍu i|yd fmdis, bkaOk nyq,j Ndú;d lrhs' ffcj ãi,a ksmoùu ñ,
wêl l%uhla jqj o th jeä ÈhqKq lsÍu iy th Ndú;hg yqreùu jeo.;a jkq we;' Bg fya;=
folla ,shkak'
^ ,l+Kq 4'0 hs &

(b) (i) i.kaO f;,a hkq fudkjd o@

(ii) Y%S ,xldfõ i.kaO f;,a ksiaidrKh lsÍu i|yd Ydl m;% ,nd.kakd Ydl j¾. 3 la kï lrkak'
(iii) i.kaO f;,a ksiaidrKfhys uQ,O¾h wdijkhhs' fuu ixisoaêfha§ fhfok jdhq kshuh i|yka
lrkak'
(iv) fuu l%uh fhdod .ekSfï we;s jdis 2 la i|yka lrkak'
(v) by; l%uhg wu;rj i.kaO f;,a ksIamdokhg fhdod .kakd fjk;a l%u 2 la olajkak'
^ ,l+Kq 4'0 hs &

(c) wï, jeis hkq j¾;udk f,dalfha mj;sk f.da,Sh mdßißl m%Yakhls'
(i) wï, jeis j,g fya;=jk wdï,sl jdhq fudkjd o@
(ii) by; jdhQka jdhqf.da,hg tlajk iajdNdúl l%shdj,s iy ñksia l%shdldrlï 2 ne.ska olajkak'
(iii) wï, jeis u`.ska Ydlj,g we;sjk wys;lr n,mEï 2 la i|yka lrkak'
(iv) Y%S ,xldfõ úh<s l,dmfha mj;sk c, uQ,dY%j, c,fha lsjq,a rihl=;a iakdkfha§ ysiflia j,g
wef,k iq¿ iajNdjhl=;a r¿ .;shl=;a ksÍCIKh l< yel' fuhg fya;=jk ixisoaêh l=ula o@
(v) by; ixisoaêh Tn w¾: olajkafka flfia o@
(vi) iajNdúlj fuu ixisoaêhg iïmQ¾Kfhka odhl jk whk j¾. i|yka lrkak'
(vii) by; (iv) ys olajQ ixisoaêh iaÓr iy ;djld,sl f,i wdldr follska mj;S' tu wdldr 2 we;sjk
wdldrh;a" tajd bj;a lrk wdldrh;a fjka fjkaj i|yka lrkak' bj;a lrk wdldr i|yd ;=,s;
ridhksl iólrK i|yka lrkak'
^ ,l+Kq 4'0 hs &

(d) (i) ´fidaka ia:rh mej;Sfuka we;sjk tla jdishla i|yka lrkak'
(ii) ´fidaka ia:rh laIh ùu wdY%s;j we;súh yels .eg¨ ;=kla ,shkak'
(iii) ´fidaka ia:rh laIh ùu flfrys CFC yd HCFC j, n,mEu ixikaokd;aulj meyeÈ,s lrkak'
(iv) ´fidaka ia:rh laIh ùug wu;rj CFC odhl jk ;j;a mdßißl .eg¨jla i|yka lrkak'
(v) by; (iv) ys i|yka .eg¨jg CFC odhk jk wdldrh úia;r lrkak'
(vi) CFC j, ridhksl .=Khla ,shkak'
^ ,l+Kq 3'0 hs &

olaIhka w;r w;s olaIhl= ùug