AL/2022/02/S-IA -1-

úfYaI úNd. fmryqre mÍlaIK

I
I
Two hours
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Total Marks
ku - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
úNd. wxlh - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
mdi, - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
m%Yak m;% mx;shg muKla iyNd.S fõ kï yßhla () fhdod olajkak' -

Wmfoia :
* m%Yak m;%fha kshñ; ia:dkfha Tfí wkkH;djh yÿkd .ekSug wjYH o;a; ,shkak'
* fuu m%Yak m;%h msgq 08 lska hqla; fõ'
* ish¨ u m%Yak j,g ms<s;=re imhkak'
* ms<s;=re W;a;r m;%fha muKla l;srhla () fhdod olajkak'

id¾j;% jdhq ksh;h R = 8.314 J K-1 mol-1 wej.dâfrda ksh;h NA = 6.022 x 1023 mol-1
ma,dkalaf.a ksh;h h = 6.626 x 10-34 Js wdf,dalfha m%fõ.h C = 3 x 108 ms-1

1. mef,aähï - Pd mrudKqfõ ( Z = 46) l = 0 iy l = 2 lafjdkagï wxl we;s bf,lafg%dak ixLHd ms<sfj<ska"

^1& 6 iy 18 fõ' ^2& 8 iy 18 fõ' ^3& 8 iy 20 fõ'
^4& 10 yd 18 fõ' ^5& 10 iy 20 fõ'

2. ;rx. wdhduh jeäjk ksjerÈ wkqms<sfj< jkafka

^1& .eud lsrK" X lsrK" mdrcïnq, lsrK" wfOdarla; lsrK
^2& X lsrK" .eud lsrK" mdrcïnq, lsrK" wfOdarla; lsrK
^3& .eud lsrK" mdrcïnq, lsrK" X lsrK" wfOdarla; lsrK
^4& mdrcïnq, lsrK" X lsrK" .eud lsrK" wfOdarla; lsrK
^5& .eud lsrK" mdrcïnq, lsrK" wfOdarla; lsrK" X lsrK"

3. mrudKqjl wvx.= iudk Yla;sfhka hq;a bf,lafg%dak 2 l lafjdkagïwxl l=,l 2 jkafka"

(a) n = 3 , l = 2, ml = -1 , ms = +1/2
(c) n = 4 , l = 1, ml = -1 , ms = +1/2
(b) n = 4 , l = 2, ml = -1 , ms = +1/2
(d) n = 3 , l = 2, ml = 0 , ms = -1/2
(e) n = 3 , l = 1, ml = -1 , ms = +1/2
^1& a yd b ^2& a yd e ^3& d yd e ^4& b yd c ^5& a yd b

4. my; i|yka m%ldYj,ska wi;H m%ldYh l=ulao@

^1& ClO2- yd ClO-3 ys Cl jgd bf,lafg%dak cHdñ;sh iudk fõ'
^2& IF4- ys I jgd bf,lafg%dak cHdñ;sh wIaG;,Sh fõ'
^3& PCl3 ;%swdk;s msróvdldr wKqjls'
^4& ICl3 , T wlaIr yev;s O%eùh wKqjls'
^5& SOCl3 yd POCl3 iudk yev;s wKq fõ'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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5. my; ±lafjk ixfhda.fha IUPAC kduh l=ula o@

Br O
CH3 - CH = C - CH - C - NH2
CH2 - CH3
^1& 4-bromo-3-ethylpent-2-eneamie ^2& 1-oxo-2-bromopent-2-enamide
^3& 3-bromo-2-ethylpent-2nenamide ^4& 2-bromo-3-ethylpent-3-enamide
^5& 4-bromo-3-ethylpent-2-enamide

6. my; ±lafjk ixfhda. kshqla,sfhda*s,sl wdl,k m%;sl%shdj,g iyNd.s ùfï keUqrej wjfrdayKh jk
ms<sfj<g ilikak'
CH 3CHO CH2O (CH3) 3CCHO Cl3CCHO
(a) (b) (c) (d)
^1& a > b > c > d ^2& d > c > b > a ^3& b > d > c > a
^4& b > d > a > c ^5& b > c > d > a

7. my; ±lafjk m%fNaoj, oaú;Sl wka;¾ l%shdj, m%N,;djh jeäjk wkqms<sfj< l=ula o@
H2O iy CH3CH2OH K+ iy H2O CH4 iy CH4 HBr iy HBr He iy He
(A) (B) (C) (D) (E)
^1& E < C < D < A < B ^2& E < C < D < B < A ^3& C < E < D < A < B
^4& E < C < A < D < B ^5& B < A < D < C < E

8. my; ldnksl ixfhda.h ms<sn|j wi;H jkafka"

CHO

^1& ish¨u c mrudKqj, uqyqïlrK sp2 fõ'

^2& th ;%sudK iudjhúl;djh olajhs'
^3& th CIdÍh KMnO4 ys j¾Kh fjkia lrkafka tys oaú;aj nkaOkh ksidu muKs'
^4& th fgd,kaia m%;sldrlh TlaisyrKh lrjhs'
^5& th Br2 iu. bf,lafg%da*s,sl wdl,k m%;sl%shdjl ksr; fõ'

9. my; l=uk j.ka;sh wi;H fõo@

^1& ldnkavfhdlaihsâ" wdydr l¾udka;fha§ ysudhk ldrlhla f,i Ndú; lrhs'
^2& i,a*¾ hkq TlaislrK wjia:d -2 isg +6 mrdihl we;s wf,dayhls'
^3& Si iy S j, yhsv%hsv ÿ¾j, wdï,sl .=K fmkakqï lrhs'
^4& wdj¾;s;d j.=fõ ish¨u uQ,øjH w;ßka ma¨fjdÍka jvd;au m%;sl%shdYS,S jk kuq;a th ksIal%Sh jdhq iu.
m%;sl%shd fkdlrhs'
^5& >k we¨ñkshï laf,darhsâ c,fha Èh l< úg idok ødjKh NdIañlh'

10. H2C2O4 iy HCOOH wvx.= ñY%Khla id' H2SO4 iu. r;a lsÍfï§ jdhquh M,hka f,ig H2O , CO iy
CO2 ,enqKs' fuu jdhquh M,hka ldur WIaK;ajfha§ KOH ødjKhla iu. msßï l< úg jdhquh
M,hkaf.kao mßudfjka 1/6 la wvq úh' wï, foflys H2C2O4 : HCOOH ujq, wkqmd;h úh yelafla"
^ie' hq' CO2 ,nd fokqfha H2C2O4 u.ska muKs'&
^1& 4 : 1 ^2& 1 : 4 ^3& 3 : 1 ^4& 2 : 1 ^5& 1 : 2

11. C6H12O2 hk wKql iQ;%hg ;sìh yels Na2CO3 iu. m%;sl%shd lr CO2 jdhqj msglrk m%ldY il%sh
ixfhda. ixLHdj jkqfha"
^1& 3 ^2& 4 ^3& 5 ^4& 6 ^5& 8

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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12. 25 0C § NH3(aq) + H+(aq) NH4+(aq) m%;sl%shdj i|yd iu;=,s;;d ksh;h 1.8 × 109 mol-1 dm3 fõ' tu
WIaK;ajfha§ NH3(aq) + H2O(g) NH4+(aq) + OH-(aq) m%;sl%shdfõ iu;=,s;;d ksh;h jkqfha"
^1& 1.80 × 10-5 mol dm-3 ^2& 5.55 × 10-9 mol dm-3 ^3& 1.80 × 10-9 mol dm-3
^4& 5.55 × 10-10 mol dm-3 ^5& 1.80 × 10-23 mol dm-3

13. IO3-(aq) + HC2O2H3(aq) HIO3(aq) + C2H3O2- (aq) hk iu;=,s;fha iu;=,;

s ;d ksh;h 1 g jvd wvq fõ'
my; i|yka ix>gl j, wdï,sl NdIañl m%n,;djh ksjerÈ ms<sfj< iys; j.ka;sh jkafka"
wï, NIau
^1& HIO 3 < HC 2 O 2 H 3 HIO 3 < C 2 H 3O 2 -
^2& HIO 3 < HC 2 O 2 H 3 IO 3 - > C 2 H 3O 2 -
^3& HIO 3 > HC 2 O 2 H 3 IO 3 - > C 2 H 3O 2 -
^4& HIO 3 > HC 2 O 2 H 3 IO 3 - < C 2 H 3O 2 -
^5& HIO 3 = HC 2 O 2 H 3 IO 3 - = C 2 H 3O 2 -

14. khsg%ckaj, Tlaihsvhl iQ;%h fidhd .ekSu i|yd l< mÍCIKhl § ixY=oaO Tlaihsvh" yhsv%cka iuÕ
ñY%lr iqÿiq WIaK;ajhlg r;alr W;afma%rlhla u;ska hjhs' túg Tlaihsvh uq¿ukskau NH3 iy H2O
njg m;a úh'
NxOy + H2  x NH3 + y H2O
ldur WIaK;ajfha § yd mSvkfha § uksk ,o tu Tlaihsvfha 2400 cm3 la úiska c,h 7.20 g la ,nd ÿks'
ksoyia jk NH iuÕ uq¿ukskau m%;sls%hd ùug 1.0 mol dm-3 HCl ødjKhlska 200 cm3 la jeh úh' ldur
3
WIaK;ajfha § yd mSvkfha § jdhqjl ujq,sl mßudj 2.4 dm3 mol-1 ls' khsg%ckaj, Tlaihsvh ;=< §
khsg%ckaj, TlaislrK wxlh"
^1& +1 ^2& +2 ^3& +3 ^4& +4 ^5& +5

15. C2H5MgBr iïnkaOfhka my; § we;s l=uk m%ldh wi;H fõo@

^1& C2H5MgBr iy CH3CCH w;r m%;sl%shdfjka CH3CCMgBr ,nd foa'
^2& C2H5MgBr iy CH3NH2 w;r m%;sl%shdfjka C2H6 ,nd foa'
^3& C2H5MgBr iy CH3COCl w;r m%;sl%shdfjka ,efnk M<h c,úÉfþokh lsÍfuka ;D;shsl we,afldfyd,hla
idohs'
^4& C2H5MgBr iy CH3CO2H w;r m%;sl%shdfjka we,aflakhla ,nd foa'
^5& C2H5MgBr ys we,alhs,a ldKavhg bf,lafg%d*hs,hla f,i fukau NIauhla f,i o l%shd l< yelsh'

16. X(OH)3 hkq c,fha iq¿ jYfhka ødjH whksl ixfhda.hls' T WIaK;ajfha § iy pH w.h 9 § ix;Dma;
X(OH)3 ødjKhl X3+ idkaøKh 1.6 × 10-4 mol dm-3 fõ' tu WIaK;ajfha§u X3+ whk idkaøKh 2 × 10-5
mol dm-3 jk úg ødjKfha pH w.h jkqfha
^1& 4.70 ^2& 8.00 ^3& 8.40 ^4& 9.30 ^5& 12.42

17. HO CH 2CHO H+/ KMnO4

A
CH2OH
fï m%;sl%shdfõ m%Odk M,h A jkafka"
HO CH 2CHO HO CH2COOH HO COOH
^1& ^2& ^3&
CHO COOH COOH
O COOH O CH2COOH
^4& ^5&
COOH COOH

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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18. FeCl3 yd KI w;r m%;sl%shdfõ pd,l ridhkh wOHhkh msksi tajdfha úúO mßud iu`. ksh; Na2S2O3
yd msIagh mßud tl;= lr m%;sl%shd lsÍug i,iajk ,§' fuys§ uq¿ mßudj ksh; jk mßÈ c,h tl;=
lrk ,§' ñY%Kh ks,a meye ùug .; jQ ld,h my; ±lafõ'

0.1 mol dm-3 0.2 mol dm-3 ld,h

FeCl3 mßudj / cm3 KI mßudj / cm3 (s)
5 10 20
5 20 10
10 10 10

m%;sl%shdfõ YS>%;d m%ldYkh ksjerÈj bÈßm;a lr we;af;a"

^1& R = K [FeCl3] ^2& R = K [KI] ^3& R = K [FeCl3] [KI]
^4& R = K [KI] [FeCl3]
2
^5& R = K [KI] [FeCl3]2

19. m%;sl%shd YS>%;d m%ldYkh ;=< yuq fkdjk tfy;a ;=,s; ridhksl m%;sl%shdj ;=< yuqjk m%;sl%shlhla
ms<sn| ksjerÈ m%ldYh l=ula o@
^1& th YS>%;d ksh;h ;=< wvx.= fõ'
^2& th m%;sl%shdfõ M, i|yd n,fkdmdhs'
^3& th m%;sl%shdfõ M, iE§ug yd YS>%;djh wvq lsÍug odhl fõ'
^4& th fiñkau isÿjk mshjrg miqj m%;sl%shd lrhs'
^5& th bj;al< o M, iEfok YS>%;dj ksh; fõ'

20. my; o;a; imhd we;'

Ca(s) ys iïu; W!¾Ojmd;k tka;e,amsh = + 177 kJ mol-1
Ca(g) ys iïu; m%:u whkSlrK tka;e,amsh = +590 kJ mol-1
Ca(g) ys iïu; fojeks whkSlrK tka;e,amsh = +1150 kJ mol-1
Ca2+(g) ys iïu; ic,k tka;e,amsh = -1565 kJ mol-1
Ca(s) + H2O Ca2+(aq) hk m%;sl%shdfõ iïu; tka;e,ams úm¾hdih"
^1& -1388 kJ mol-1 ^2& -798 kJ mol-1 ^3& -238 kJ mol-1 ^4& +238 kJ mol-1 ^5& +352 kJ mol-1

21. legdhk folla wvx.= c,Sh ødjKhlg (P) NH4Cl iy NH4OH tl;= lsÍfï§ j¾Kj;a wjlafIamhla (X)
,enqKq w;r" ,enqKq wjlafIamh fmrd fjka lrk §' fmrKhg H2S jdhqj heùfï§ iqÿ wjlafIamhla o
fmr ,enqKq wjlafIamhg (X) jeämqr NaOH tl;= lsÍfï§ j¾KJ;a ødjKhla o ,enqKs' c,Sh ødjKfha
(P) jQ legdhk fol jkafka
^1& Cd2+ , Zn2+ ^2& Co2+ , Al3+ ^3& Cr3+ , Zn2+ ^4& Zn2+ , Cu2+ ^5& Al3+ , Bi3+

22. AX yd AY hk c,fha uo jYfhka ødjH ,jK 2 ys ñY%Khla c,h ;=< Èhlr ixfhda. 2 ka u ix;Dma;
ødjKhla T K § ms<sfh< lr.kakd ,§' T K § AX ys ødjH;d .=Ks;h Ksp jk w;r AY ys th K/sp kï
tu ødjKh ;=< AX ys ødjH;djh jkqfha"
^1& Ksp1/2 ^2& (Ksp + K/sp)1/2 ^3& K1sp / (Ksp + K1sp)1/2
^4& Ksp / (Ksp + K sp)
1 1/2
^5& Ksp + K sp / Ksp
1

23. iïu; ;;a;aj hgf;a§ ir, úoHq;a ridhksl fldaIhl úoHq;a .dul n,h 1.2 v fõ' iïu; bf,lafg%dav
úNj lSmhla § we;' ^uQ,øjHhkaf.a kshu ixfla; fkdfõ'&
E0(P+(aq) / P(s) = -1.8 V E0(Q2+(aq) / Q(s) = -0.30 V
E0(R+(aq) / R(s) = -0.9 V E0(S2+(aq) / S(s) = -0.3 V
fldaIfha bf,lafg%%dav úh yelafla"
^1& P yd Q ^2& P yd S ^3& Q yd R ^4& Q yd S ^5& P yd R

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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24. CH3CHO, CH4 yd CO njg úfhdackh ùu m%:u fm< m%;sl%shdjls' tla;rd WIaK;ajhl§ CH3CHO j,
w¾O Ôj ld,h 29 min ls' CH3CHO ys wdrïNl idkaøKh 1.0 mol dm-3 jk úg 87 min g miq CH3CHO ys
idkaøKh ljf¾ o@
^1& 0.13 mol dm-3 ^2& 0.17 mol dm-3 ^3& 0.25 mol dm-3 ^4& 0.33 mol dm-3 ^5& 0.67 mol dm-3

25. tal NdIañl ÿn, wï, ødjKhl pH w.h 3.2 fõ' tu ødjKh ish .=Khlska ;kql l< úg ødjKfha pH
w.h jkafka"
^1& 2.2 ^2& 3.2 ^3& 4.2 ^4& 5.2 ^5& 6.2

26. khsg%cka Tlaihsâ iïnkaOfhka ksjerÈ fkdjk m%ldYh jkafka

^1& NH4NO3 ;dm úfhdackfhka N2O ,efí'
^2& wefudakshï ,jK NaOH iu. m%;sl%shdfjka NH3 jdhqj msg fõ'
^3& idkaø H2SO4 we;súg FeSO4 iy NO3- w;r m%;sl%shdfjka NO iEfoa'
^4& khsg%cka idok Tlaihsv w;ßka jvd;a wdï,sl Tlaihsvh N2O5 fõ'
^5& (NH4)2Cr2O7 ;dm úfhdackfhka N2O3 ,nd foa'

27. B ixfhda.h jkqfha"

COOH
O NaBH4 / CH3OH
B
CH2-C-CH3
CH 2 OH COOH CH2OH
^1& OH ^2& OH ^3& OH
CH2-C-CH3 CH-CH2CH 3 CH-CH2CH 3
H
COOH COOH
^4& ^5&
OH
CH2-CH-CH3 CH2-CH 2-CH 3

28. T K WIaK;ajfha§ H2(g) + I2(g) 2HI(g) hk iu;=,s; moaO;sh H2(g) yd I2(g) 1 mol ne.ska fhdoñka
wdrïN lrk ,§' iu;=,s; wjia:dfõ§ moaO;sfha uq¿ mSvkh P yd tu WIaK;ajfha§ iu;=,s;;d ksh;h
Kp kï" ú>gk m%udKh fokq ,nkafka"
Kp K p K p
^1& = ^2& = ^3& =
2 + Kp 2 + Kp 2 - Kp

K p K p
^4& = ^5& =
1 + Kp 1 - Kp

29. ikakdhl;dj iïnkaOfhka my; l=uk m%ldY jerÈ fõo@

^1& legdhksl ikakdhl;djh fuf,i jeäfõ' Li + < Na+ < K+ < Rb+
^2& ikakdhl;dj my; mßÈ jeä fõ'
0.1 M F2HCOOH < 0.1 M FH2CCOOH < 0.1 M ClH2CCOOH < 0.1 M CH3COOH
^3& m%n, úoHq;a úÉfþolj, ikakdhl;djh ;kql lsÍu;a iu. wvq fõ'
^4& m%n, úoHq;a úÉfþolj, ikakdhl;djh >k;ajh u; fjkia fõ'
^5& whkj, ikakdhl;djh tu whk p,kh ùfï YS>%;djh u; r|d mj;S'

30. A kï ldnksl ixfhda.hlska 10 g la wvx.= c,Sh ødjKh 50 cm3 lao" tys we;s A ksiaidrKhg B;r 75 cm3
la o imhd we;' A ixfhda.h c,h§g jvd B;r ;=< Èhjk w;r tys úNd. ix.=Klh 8 ls' B;r 25 cm3
ne.ska fhdod.ksñka c,h ;=< we;s A ixfhda.h f;jrla ksiaidrKh l< úg B;r ;=<g ksiaidrKh jk
A ys ialkaOh jkqfha"
^1& 9.23 g ^2& 9.953 g ^3& 9.92 g ^4& 0.08 g ^5& 0.77 g

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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 wxl 31 isg 40 olajd jq m%Yak j,g my; Wmfoia mßÈ ms<s;=re imhkak'

(1) (2) (3) (4) (5)

(a) iy (b) (b) iy (c) (c) iy (d) (d) iy (a) m%;spdr tlla muKla fyda fjk;a
muKla muKla muKla muKla m%;spdr ixLHdjla fyda ksjerÈh'
ksjerÈh ksjerÈh ksjerÈh ksjerÈh

31. d f.dkqfõ uQ,øjH ms<sn| my; ±lafjk j.ka;s w;ßka idjoH j.ka;sh $ j.ka;s jkqfha"
(a) wdj¾;h Èf.a jfï isg ol=Kg h;au uQ,øjHhkaf.a mrudKql wrh l%ufhka wvq fõ'
(b) s f.dkqjg idfmaCIj d f.dkqfõ uQ,øjH ±ä f,day fõ'
(c) d f.dkqfõ ish¨u uQ,øjH úp,H TlaislrK wxl olajhs'
(d) 3d wdj¾:fha uQ,øjH w;ßka wvqu øjdxlhla we;af;a Zn j,ghs'

32. ldnksl fya,hsv iïnkaOfhka my; l=uk m%ldY i;H fõo@

(a) (CH3)3CBr, c,Sh NaOH iu. olajk kshqla,sfhda*s,sl wdfoaY m%;sl%shdj mshjr folla Tiafia isÿ fõ'
(b) C6H5Br idudkH ;;aj hgf;a kshqla,sfhda*s,sl wdfoaY m%;sl%shdj,g iyNd.s fkdfõ'
(c) HC  CCH2Br úh<s B;¾ udOHfha§ Mg iu. m%;sl%shdfjka HCCCH2MgBr ,nd.; yelsh'
(d) C6H5Br úh<s B;¾ udOHfha§ Mg iu. m%;sl%shdfjka ,efnk M,h c, úÉfþokfhka C6H5OH ,efí'

33. my; i|yka tajdhska l=ula $ l=uk tajd i;Hh fõ o@

(a) úoHq;a úÉfþokfha § RK w.%fha iEuúgu TlaisyrKhla isÿ fõ'
(b) úoHq;a ridhksl fldaIhl § wefkdavfha TlaislrKhla isÿjk w;r úoHq;a úÉfþokfha wefkdavfha
TlaisyrKhla isÿ fõ'
(c) iEu úoHq;a ridhksl TlaislrKhl §u WodiSk mrudKq Ok whk njg m;aùu isÿ fõ'
(d) úoHq;a úÉfþokfha § bf,lafg%dav u; iu;=,s; bf,lafg%dav m%;sls%hd isÿ fkdfõ'

34. T WIaK;ajfha§ ú>gk ksh;h Ka iy idkaøKh C mol dm-3 jk HA kï tal NdIañl wï, c,Sh
ødjKhl my; iu;=,s;;dj mj;S'
HA(aq) + H2O(l) H3O+(aq) + A-(aq)
by; iu;=,s; moaO;sh iïnkaOfhka ksjerÈ jkafka
(a) wï,fha ú>gk m%udKh C j,g m%;sf,dau jYfhka iudkqmd;sl fõ'
(b) wï,fha ú>gk m%udKh = iu;=,s; moaO;sfha H3O+ ujq, .Kk / iu;=,s; moaO;sfha jk HA ujq,
.Kk" hk iïnkaOh u.ska ,nd.; yelsh'
(c) iu;=,s; moaO;sfha jk HA ujq, .Kk moaO;sfha we;s H3O+ whk ujq iy A- whk ujq,j, tl;=j u.ska
,nd.; yelsh'
(d) fok ,o WIaK;ajhl § [H3O+(aq)] = Ka C u.ska ,nd.; yelsh'

35. fuu ixfhda. ms<sn|j i;H jkafka"

O O
CH3 C  O  CH3 CH3CH2  C OH
(a) folu LiAlH4 yd m%;sl%shd ù c, úÉfþokh ù we,afldfyd, idohs'
(b) folu CH3MgBr iu`. m%;sl%shd ù tlu M,hla idohs'
(c) fïjd tlsfkfla l%shdldÍ ldKav iudjhúl hq.,ls'
(d) CH3COOCH3 ys ;dmdxlh CH3CH2COOH ys ;dmdxlhg jvd jeä fõ'

36. jdhq iïnkaOfhka my; i|yka m%ldYkj,ska l=ula $ l=uk tajd i;H fõo@
(a) jdhqjla iïmSvkfhka øj l< yelafla tys WIaK;ajh wjê WIaK;ajhg jvd wvq kï muKs'
(b) fndfyda jdhqj,g tajdg wdfõKsl jQ hï ksYÑ
a ; by< mSvkhl§ mßmQ¾K jdhq iólrKhg wkqj yeisßh yelsh'
(c) jdhqjl iïmSvH;d idOlh WIaK;ajh fjkiaùfuka muKla fjkia fõ'
(d) ksh; WIaK;ajfha§ úúO jdhQkaf.a uOHkH fõ. iudk fõ'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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37. 2A(g) + B(g) A2B(g) hk m%;sl%shdj T WIaK;ajfha§ iu;=,s;djfha mj;S' by; iu;=,s; m%;sl%shdj
iïnkaOfhka ksjerÈ jkafka"
(a) iu;=,s; moaO;sfha bÈß m%;sl%shdj i|yd H iy S RK w.hla .kS'
(b) bÈß m%;sl%shdj i|yd G = 0 jk w;r miq m%;sl%shdj i|yd G  0 fõ'
(c) moaO;shg W;afm%arKhla tl;= lsÍfuka iu;=,s;;d ,CIHh jvd;a ol=Kg fhduq l< yelsh'
(d) iu;=,s; moaO;sfha WIaK;ajh H / S u.ska ,nd.; yelsh'

38. my; i`oyka l=uk m%ldYh $ m%ldY i;H fõo@

(a) 2SO2(g) + O2(g) 2SO3(g) iu;=,s;h i|yd WIaK;ajh T K § Kp iy Kc w;r iïnkaOh"
Kc = Kp(RT) fõ'
(b) ksIal%sh jdhqjla tl;= lsÍu m%;sl%shdfõ Q idOlh fjkia fõ'
(c) Kc j, w.h" iu;=,s;;d iólrKh flfia ;=,s; lr weoao hkak u; /§ fkdmj;s'
(d) W;afm%arlhla m%;sl%shdjl § jeh fkdflfrk neúka th iuia; fõ. iólrKh m%ldY lsÍfï §
ie,ls,a,g fkd .efka'

39. A iy B øj folla ´kEu WIaK;ajhl§ iy ´kEu ixhq;shl § mßmQ¾K ødjKhla idok w;r T0B < T0A
fõ' my; i|yka l=ula $ l=uk m%ldYk i;H fõo@ ^T0A < T0B hkq ixY=oaO A iy B øjj, ;dmdxl fõ'&
(a) ksh; WIaK;ajfha§ A iy B ys ´kEu ixhq;shl§ PB > PA fõ'
(b) ;dmdxlfha mj;sk A iy B j, iu ujq, ñY%Khl jdIam l,dmfha A j, ixhq;shg jvd B j, ixhq;sh
jeä fõ'
(c) ;dmdxlfha mj;sk A iy B j, iu ujq, ñY%Khl jdIamh >kSNjkh lsÍfuka ,efnk øjfha B j,
ixhq;sh A j, ixhq;shg jvd by<h'
(d) ´kEu ndysr mSvkhl§ A j, iy B j, ;dmdxl w;r fjki ksh;j mj;S'

40. nyq wjhúl ms<sn| my; l=uk m%ldYh $ m%ldY i;H fõo@
(a) CF2 = CF2 u.ska fg*af,daka ,nd foa'
(b) C6H5OH yd HCHO u.ska ;dm ia:dhs nyq wjhjlhla ,nd foa'
(c) H2N(CH2)4COCl nyq wjhùlrKfhka khsf,daka-6"6 ,nd foa'
(d) iajdNdúl rn¾j, Isoprene wvx.= fõ'

 wxl 41 isg 50 olajd m%Yak j,g my; Wmfoia mßÈ ms<s;=re imhkak'

m%;spdrh m<uq m%ldYh fojk m%ldYh

^1& i;Hh i;H jk w;r" bka m<uqjekak ksjerÈj myod fohs'
.
^2& i;Hh i;H jk w;r" bka m<uqjekak ksjerÈj myod fkdfohs'
^3& i;Hh wi;Hh'
^4& wi;Hh i;Hh'
^5& wi;Hh wi;Hh'

m<uq m%ldYh fojk m%ldYh

41. NCl3 iy PCl3 c,úÉfþokfhka HCl ´kEu iyixhqc laf,darhsvhla c,úÉfþokfhka

,ndfoa' tl M,hla f,i HCl ,nd foa'

42. H2(g) + Br2(g) 2 HBr(g) m%;sl%shdfõ mSvkh m%;sl%shdfõ Kp mSvkh iuÕ fjkia fkdfõ'
jeä lrk úg iu;=,s; ,laIh fjkia fkdfõ'

43. W;afm%arlhla fhÿ úg W;afm%arl fkdfhÿ W;afm%arl m%;sl%shdjl hdka;%Kh fjkia lrhs'
m%;sl%shdfõ il%shk Yla;sfhys uq,a w.h tfia u
mj;sk kuq;a W;afm%aß; kj ud¾.hg we;af;a
wvq il%shk Yla;shls'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
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44. C2H5OH yd H2O ñY% ù mßmQ¾K ødjKhla idohs' C2H5OH wKq w;r;a H2O wKq w;r;a C2H5OH yd
H2O wKq w;r;a H nkaOk mj;shs'

45. S yd NaOH w;r m%;sl%shdfjka Na2S2O3 yd Na2S S yd NaOH w;r m%;sl%shdj oaúOdlrK m%;sl%shdjls'
idohs'

46. wdï,sl KMnO4 iuÕ m%ldY il%sh 2-ìhqgfkd,a 2-ìhqgfkd,a TlaislrKfhka iefok ldnksl M,h
m%;sl%shd l< úg ,efnk ldnksl M,h m%ldY il%sh /iñl ñY%Khla fõ'
fkdfõ'

47. WIaK;ajh wvq jk úg wdi%e; c,fha pH w.h WIaK;ajh wvq jk úg c,fha whksl .=Ks;h
jeä fõ' jeä fõ'

48. III ldKavfha wjlafIamkfha§ muKg jeä Ndiañl yhsfv%dlaihsâ whk idkaøKh ie,lsh hq;= ;rï
ødjKhla mj;ajd fkd.ekSug mßiaiï úh hq;=h' by< fõ kï ue.akSishï yhsfv%dlaihsâ wjlafIam
ùu isÿ fõ'

49. Na2CO3 ksIamdokfha § wefudakshd jdhqj n%hska m%;sm%jdy uQ,O¾uh Ndú; lsÍfuka wefudakshd
ødjKfha Èhlr .ekSug m%;sm%jdy uQ,O¾uh jdhqj n%hska ødjKfha Èhlr .ekSu jeälr .; yel'
Ndú;d lrhs'

50. yß;d.dr wdprKhg odhl jk m%Odk khsg%cka wl=Kq .eiSu yd wNHka;r oyk tkaðfï
ixfhda.h N2O h' l%shdldÍ;ajh ksid jdhqf.da,hg jeämqr ,efnk
khsg%cka ixfhda.h N2O h'

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DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]