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lk

ish¨u ysñlï weúßKs' ie(hq(- W;a;r m ;% fuu m;%hg weñKsh hq;=h' A D V A N C E D L E V E L 2 0 21

jeäu ‘A’ idud¾: ìys lrk id¾:lu Chemistry mx;sfha bosßm;a lsÍuls' jeäu ‘A’ idud¾: ìys lrk id¾:lu Chemistry mx;sfha bosßm;a
lsÍuls' jeäu ‘A’ idud¾: ìys lrk id¾:lu Chemistry mx;sfha bosßm;a lsÍuls' jeäu ‘A’ idud¾: ìys lrk id¾:lu Chemistry mx;sfha
bosßm;a lsÍuls' jeäu ‘A’ idud¾: ìys lrk id¾:lu Chemistry mx;sfha bosßm;a lsÍuls' jeäu ‘A’ idud¾: ìys lrk id¾:lu Chemistry
mx;sfha bosßm;a lsÍuls' jeäu ‘A’ idud¾: ìys lrk id¾:lu Chemistry mx;sfha bosßm;a lsÍuls' jeäu ‘A’ idud¾: ìys lrk id¾:lu
Chemistry mx;sfha bosßm;a lsÍuls' jeäu ‘A’ idud¾: ìys lrk id¾:lu Chemistry mx;sfha bosßm;a lsÍuls' jeäu ‘A’ idud¾: ìys lrk N U G E G O D A
id¾:lu Chemistry mx;sfha bosßm;a lsÍuls'
wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h 2021
General Certificate of Education (Adv.Level) Examination 2021 2021.02.01
ridhk úoHdj I meh folhs
Chemistry I m%ikak noafoú;dk(B.Sc.) Two hours

Wmfoia(


wdj¾;s;d j.=jla imhd we;'
fuu m%Yak m;%h msgq 08 lska hqla; fõ'
PAPER CLASS-09
 ish¨u m%Yakj,g ms<s;=re imhkak'
 .Kl hka;% Ndú;hg bv fokq fkd,efí'
 W;a;r m;%fha kshñ; ia:dkfha Tfí úNd. wxlh ,shkak'
 W;a;r m;%fha msgmq i oS we;s wfkla Wmfoia ie,ls,su;aj lshjkak'
 1 isg 50 f;la tla tla m%Yakhg ^1&"^2&"^3&"^4&"^5& hk ms<s;=rej,ska ksjeros fyda b;du;a .e,fmk
ms<s;=r f;dard f.k" th W;a;r m;%fha msgmq i oelafjk Wmfoia mßos l;srhla (x) fhdod olajkak'

id¾j;% jdhq ksh;h" R = 8.314JK1mol1

wej.dâfrda ksh;h" NA = 6.022x1023mol1
ma,Ekala ksh;h h = 6.626x1034Js
wdf,dalfha m%fõ.h c = 3x108ms1

^01& mrudKqfõ jHqyh ms<sn|j my; lreKq i,lkak'

(A) bf,lafg%dakhg jvd fm%dafgdakfha e/m úYd, fõ'
(B) mrudKqj .kakd úYajfha jeäu fldgila ysiafõ'
(C) ro¾*â úiska mrudKqfõ bf,lafg%dak mj;sk l%uh id¾:lj meyeos,s lrk ,oS'
(D) iEu mrudKqjlu kshqfg%dak mj;S'
(E) bf,lafg%dakj,g wxY=uh .=K we;'
by; j.ka;s j,ska ksjeros jkafka"
(1) A yd B (2) B yd C (3) B yd E (4) A,B yd C (5) A,B,C,D yd E ish,a,

^02& As fN!ñl wjia:djg wod, jdhquh mrudKq ms<sn|j i<lkak'

tu mrudKqjg wod, l=1 yd ml=0 jk bf,lafg%dak wka;¾.; ldËsl ixLHdj yd tajdfha we;s
bf,lafg%dakh ixLHdj ms<sfj,ska oelafjkafka"

^1& 2 yd 3 ^2& 2 yd 4 ^3& 3 yd 5 ^4& 3 yd 6 ^5& 4 yd 8

^03& my; j.ka;s j,ska fkd.e,fmkafka"

(1) HN3 wKqjg uq¿ iïm%hqla; jHqy 3ls'

(2) N2O5 wKqjg uq¿ iïm%hqla; jHqy 9ls'
(3) O3 ys O—O nkaok os. iudk fõ'
(4) NO2─ j,g jvd NO3─ ys N—O nkaok os. jeäh'
(5) SF3N wKqfõ uOH mrudKqjg ixhqc;d ljpfha bf,lafg%dak 8ls'
Prasanna Baddewithana(B.Sc.) 1
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^04& ldnkaj, úfudapk j¾Kdj,sfha tla f¾Ldjl ;rx. wdhduh 538nm fõ'
Bg wod, f*dafgdak ujq,hl Yla;sh jkafka (kJmol─1)

(1) 3.69x10─22 (2) 3.69x10─19 (3) 222 (4) 2.22x104 (5) 2.22x105

^05& oS we;s ixfhda.fha IUPAC kduh jkafka"

OH
HOOC—CH2—CH=CH—CH—CH2NH2

(1) 1-amino-2-hydroxyhex-3-en-6-ol (2) 1-amino-2-hydroxyhex-4-en-5-al

(3) 6-amino-5-hydroxyhex-3-enoic acid (4) 5-hydroxy-6-aminohex-3-enoic acid
(5) 6-amino-5-hydroxyhex-4-enoic acid

^06& (A) CrO5 (B) Na3[Cr(OH)6] (C) Mn2O7 (D) [CuCl2(H2O)4]

by; tajdfha uOH f,day mrudKqfõ TlaislrK wxlh jeäjk ksjeros wkqms<sfj, oelafjkafka"

(1) D<A=B<C (2) D < B < A < C (3) B<D<A<C

(4) D<B<C<A (5) B < D < C < A

^07& ixjD; oDV Ndckhl we;s He m%udKhla iy O3 ujq, 0.4la wvx.= jdhq ñY%Khl tla;rd
WIaK;ajhl§ mSvkh 1105Pa fõ' jdhq ñY%Khl ál fõ,djla ;enQúg my; i|yka iu;=,;
s ;djh
we;súh'
2O3(g) 3O2(g)
iu;=,s; ñY%Khl by; WIaK;ajfha§u uq¨ mSvkh 1.1105Pa fõ' iu;=,s;;djhg t<öfïoS jehjQ
O3 m%udKh 25% ls' wjidk jdhq ñY%Kfha He j, ujq, Nd.h'

(1). 0.09 (2). 0.12 (3). 0.14 (4). 0.18 (5). 0.47

^08& we,alSk" we,alhsk jeämqr O2 ;=< oykh l< úg TlaislrKh ùfuka CO2 yd H2O njg m;afõ' kuq;a
iS;, ;kql ËdÍh KMnO4 u.ska ËdÍh ;;aj hgf;a Nd.slj TlaisyrKh l< úg (partially oxidized)
ÿUqre >khla idoñka KMnO4 TlaisyrKh fõ' ta i|yd ;=,s; fkdlrk ,o iólrKh my; oelafõ'
H H
─
.....CH3CH=CH2 + .....MnO4 (aq) + .....H2O ........CH3—C—C—H + ......MnO2(s) + .....OH─(aq)
O O
H H
i'W'mS' oS propene mßmQ¾K jdhqjla nj i<lñka jdhq 6.72dm3 m%udKhla jeämqr KMnO4(aq) iuÕ l%shd
lf<a kï iEfok MnO2(s) úh,s >kfha ialkaOh (g) úh yelafla" (O=16, Mn=55)

(1) 52.2 (2) 42.6 (3) 14.2 (4) 17.4 (5) 26.1

^09& c,Sh NaOH iuÕ lskï ;;ajhla hgf;a fyda l%shd fkdlrkafka"

(1) CH3CHO (2) CH3COONH4 (3) CH3CONH2 (4) CH3C≡CH (5) (CH3)2CHI

^10& 250C oS BaCrO4 ys Ksp =1.2x10─10mol2dm─6 fõ'

BaCl2 yd K2CrO4 wiudk m%udK j,ska ñY% l< wjia:djl BaCrO4 ly mdg wjfËamh we;sù mj;S' tu
wjfËamh iuÕ iam¾Y fjñka mj;sk c,Sh ødjKfha [CrO42─(aq)]=3.5x10─4moldm─3 fõ kï tu
ødjKfha [Ba2+(aq)] ppm j,ska úh yelafla" (Ba=137)

(1) 3.43x10─7 (2) 4.69x10─5 (3) 0.046 (4) 1.72x10─7 (5) 0.024

2
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^11& my; oelafjk ixfhda. i,lkak'

(A) HCHO (B) CO2 (C) CH3OH (D) HCOOH
by; ixfhda.j, ;dmdxl jeäjk ms<sfj, ksjerosj oelafjkafka"
(1) A< C < B < D (2) B < A < C < D (3) B < A < D < C
(4) B < C < A <D (5) D < C < A <B

^12& NaF, KF, MgO yd CaO hk ixfhda.j, øjdxl jeäjk ksjeros ms<sfj, jkafka"

(1) MgO < CaO < NaF < KF (2) CaO < MgO < NaF < KF (3) KF < NaF < MgO < CaO
(4) NaF < KF < CaO < MgO (5) KF < NaF < CaO < MgO

^13& my; iïu; tka;e,ams o;a; ms<sn|j i,lkak'

iïu; W;amdok tka;e,ams ∆H0f(250C oS) kJmol─1
NaHCO3(s) = -950.8 Na2CO3(s) = -1130.8
CO2(g) = -393.5 H2O(g) = -241.8
by; o;a;o Wmfhda.s lrf.k NaHCO3 úfhdackfha ;=,s; iólrKhg wod, tka;e,ams fjki jkafka"

(1) -407.65 (2) -815.3 (3) 67.75 (4) 135.5 (5) 271

^14& hlv ksiaidrKh lsÍu i|yd Odrd WIaulh i|yd ySughsÜ (Fe2O3) yqkq.,a" fldala Wmfhda.s lr.kS' tajd
ksIaÑ; ixhq;sh wkqj ñY% lr l=vq lr fhoSfuka Fe2O3, CO Tlaisydrlh u.ska TlaisyrKh lrkq ,efí'
ySughsÜj, SiO2, Al2O3 we;=¿ ;j;a ix>Gl mj;sk kuq;a tajd CO iuÕ m%;sl%shd fkdlrk nj
i,lkak' ySughsÜ idïm,fha 50% Fe2O3 mj;sk nj Wml,amk lrkak' ySughsÜ 10kg m%udKhlg
wod,j m%dfhda.slj ,enqKq ixY=oaO hlv ialkaOh 2.0kg fõ' fuu TlaisyrK l%shdj,sfhaoS iEÿk Fe j,
m%;sY; M,odj yd ffiOHdka;slj ySughsÜ TlaisyrKhg jehjQ CO ialkaOh ms<sfj,ska oelafjkafka"
(O=16, Fe=56)
(1) 70% - 1.5kg (2) 57.1% - 2.625kg (3) 40% - 5kg
(4) 28.57% - 2.625kg (5) 20% - 0.2625kg

^15& mßudj 0.718dm3 jk f¾Ñ; ùÿre n,anhla ;=<g PCl3(g) 0.272mol, PCl5 8.56x10─4mol tl;= lr my;
iu;=,s;;djg t<öug i,iajk ,oS'
PCl5(g) PCl3(g) + Cl2(g)
iu;=,s;hg t<UqKq úg 2.51x10─4mol m%udKhla PCl3(g) jeäùu isÿù ;snqKs' i,lk ,o WIAK;ajfhaoS
m%;sl%shdfõ Kc w.h moldm─3 j,ska oelafjkafka"

(1) 8.51x10─2 (2) 0.157 (3) 0.114 (4) 2.40x104 (5) 8.88x104

^16& fnkafidhsla wï,h Br2 yd FeBr3 u.ska isÿjk fn%dañkSlrK m%;sl%shdfõoS $ hka;%KfhaoS my; oelafjk
tajdhska wfmaËd l< fkdyelafla" O
COOH COOH
C—Br
+ ─ + +
^1& Br—Br—FeBr3 ^2& H ^3& FeBr─4 ^4& ^5& H
Br Br
^17& 298K oS my; oelafjk m%;sl%shdj i,lkak'
N2(g) + 3H2(g) 2NH3(g)
fuu m%;sl%shdfõ iïu; tka;e,ams fjki ∆H0 = ─92.2kJmol─1
iïu; tkafg%dms fjki ∆S0 = ─199Jmol─1K─1
wefudakshd ksIamdokh iïnkaOj by; m%;sl%shdj iïnkaOfhka idjoH jkafka"
(1) 298K oS fuu m%;sl%shdj ;dm.;slj iajhxisoaOj isÿúh yel'
(2) 1000K oS fuu m%;sl%shdj jvd myiqfjka ;dm .;slj iajhxisoaO úh yel'
(3) f,apeg,sh¾ uQ,O¾uh wkqj WIAK;ajh jeäjk úg NH3 M,odj wvqfõ'
(4) 298K oS ∆H0, ∆S0 yd ∆G0 ish,a, iDK fõ'
(5) 4500C oS fuh isÿ lsÍug W;afm%arl yd m%Yia: mSvk wjYH fõ'
Prasanna Baddewithana(B.Sc.) 3
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^18& mod¾: yd úlsrK iïnkaOj my; j.ka;s j,ska wi;H jkafka"

(1) bf,lafg%dakfha ;rx. wdhduh γ lsrK j,g jvd by< fõ'
(2) β úlsrK j,g jvd α úlsrKj,g by< e/m wkqmd;h mj;S'
(3) ;rx.dldrj p,kh jk kshqfg%dakhl pd,l Yla;sh y;r .=Khlska jeä l< úg kshqfg%dakfha
;rx. wdhduh wvlska wvqfõ'
(4) pqïnl lafIa;%hla yuqfõoS β lsrKj,g jvd α wxY=j, wm.ukh wvqh'
(5) úksúo hdfï n,h α wxY=j,g jvd β lsrKj, by<h'

^19& my; oelafjkafka iïu; bf,lafg%dav lSmhl TlaisyrK úNjh (V)

Al3+(aq) + 3e Al(s) E0= ─1.66V
Fe2+(aq) + 2e Fe(s) E0= ─0.41V
*erfâ ksh;h F=96500Cmol─1
by; m%;sl%shdj iïnkaOj i;H fkdjkafka"
(1) m%;sl%shdfõ iïu; úNjh +1.25V fõ'
(2) hlv bf,lafg%davfha ødjKfha j¾Kh fjkia úh yel'
(3) m%;sl%shdfõ ∆G0w.h (─) 7.23x102kJmol─1 muK fõ'
(4) fuu fldaIfha ,jK fia;=j i|yd KOH fhdod.; yelsh'
(5) fuu fldaIfha lef;davh Fe bf,lafg%davhhs'

^20& ethanoyl chloride m%;sl%shdj iïnkaOj my; m%ldY j,ska fkd.e,fmkafka"

(1) OH─ iuÕ kshqla,sfhda*s,sl wdl,k l%shdjla isÿfjñka m<uqj p;=Ia;,Sh w;rueoshla f.kfohs'
(2) NaOH(aq) fh¥ úg ;dmh ksoyia ùula isÿfõ'
(3) ;kql HNO3/AgNO3 fh¥ úg iqÿ wjfËamhla f.kfohs'
(4) c,Sh ødjKfhaoS úoHq;a ikakdhl;dj idudkH c,hg jvd fnfyúka by< fõ'
(5) jeämqr CH3MgBr iuÕ m%;sl%shd lr c,úÉfÊokfhka oaú;sl we,afldfyd,h f.kfohs'

^21& iïu; W;amdok tka;e,ams my; oelafõ' (kJmol─1)

S(rhombic) =0
SO2(g) = -297
SO3(g) = -396
2SO2(g) + O2(g) 2SO3(g) hk m%;sl%shdfõ iïu; tka;e,ams úm¾hdih jkafka" (kJmol─1)
(1) ─693 (2) +198 (3) ─198 (4) +99 (5) -99

^22& my; oelafjk m%ldY j,ska jeros j.ka;sh jkafka"

(1) N(g) j,g bf,lafg%dakhla ,nd .ekSfï Yla;sh Ok fõ'
(2) P(g) j,g bf,lafgdakhla ,nd .ekSfï Yla;sh iDK fõ'
(3) Li, Na, Mg yd Al hk f,day iuÕ N2 m%;sl%shd lr khsgh
% sv idohs'
(4) SO2 jdhqjg Tlaisldrlhla f,io" Tlaisydrlhla f,io l%shd l< yel'
(5) H2 jdhqjg Tlaisldrlhla f,i" Tlaisydrlhla f,io l%shd l< yel'

^23& yqkq.,a yd H2C2O4 (Oxalic acid) w;r my; wdldr fõ'

CaCO3(s) + H2C2O4(aq) CaC2O4(s) + H2O(l) + CO2(g)
yqkq.,a idïm,fha 438mg m%udKhlg jeämqr H2C2O4 fhdod msßhï lr ,enqKq wjfËamh úh,d
ialkaOh ñkqï l< úg 469mg ,enqKs' yqkq.,a idïm,fha CaCO3 ialkaO m%;sY;h jkafka"
(C=12, O=16, Ca=40)
(1) 41.82% (2) 83.7% (3) 20.91% (4) 62.73% (5) 73.19%
4
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^24& 250C oS pH w.h 9.55 jk ødjKhl OH─(aq) whk idkaøKh jkafka" (moldm─3)

(1) 2.8x10─10 (2) 3.5x10─5 (3) 3.1x10─10 (4) 3.2x10─5 (5) 3.8x10─5

^25& c,Sh ødjKhl Na2SO4 iy Ba(NO3)2 wka;¾.;h' tys SO42─ fuka y;r .=Khl idkaøKh iys;j
NO3─ whk mj;S' ødjKfha uq¨ whk idkaøKh 0.18moldm─3 kï" tys we;s Na+ whk idkaøKh
moldm─3 j,ska"

^1& 0'02 ^2& 0'04 ^3& 0'06 ^4& 0'01 ^5& by; lsisjla fkdfõ'

^26& my; oelafjkafka tla;rd iïu; bf,lafg%dav 2la Ndú;d lrñka wgjd we;s .e,ajdks fldaIhl
wdlD;shls'
●
(A)
(A)
Cd

[Fe3+(aq)]=1.0M
[Cd2+(aq)]=1.0M
[Fe2+(aq)]=1.0M

E0Cd2+
(aq)/Cd(s) = ─0.40V E0Fe 3+
(aq)/Fe(g) = +0.77V
by; fldaIh iïnkaOj wi;H ms<s;=r jkafka"

(1) iaúph l%shd;aul lr ke;s úg (off) il%sh;dj jeä bf,lafg%davfhaoS Cd2+(aq) + 2e Cd(s)
hk iu;=,s;h mj;S'
(2) fldaIfha iïu; úNjh 1.17V f,i wfmaËd l< yelsh'
(3) iaúph l%shd;aul lr we;s úg (on) ál fõ,djloS lef;dav ødjKfha + yd – wdfrdamK ;=,s; fkdù
mj;S'
(4) A hkq Fe(s) fkdj Pt(s) úh hq;=h'
(5) wefkdav ødjKfha Cd2+(aq) idkaøKh by< hhs'

^27& tla;rd ksh; WIAK;ajhloS isÿjk my; m%;sl%shdj i,lkak'

2N2O5(g) 4NO2(g) + O2(g)
úfhdack m%;sl%shdj isÿjk úg tla;rd ld, 2loS ,nd.;a f;dr;=re my; oelafõ'
ld,h (s) N2O5 idkaøKh (moldm─3)
600 1.24x10─2
1200 0.93x10─2
fuu oS we;s ;;aj j,g wod,j my; j.ka;s w;ßka fkd.e,fmk j.ka;s jkafka"
∆[O2(g)] 1 ∆[N2O5(g)]
(1) iS>%;d w;r iïnkaOh =─ 2 ∆t fõ'
∆t
1 ∆[NO2(g)] ∆[O2(g)]
(2) iS>%;d w;r iïnkaOh = fõ'
4 ∆t ∆t
(0.93-1.24)x10─2moldm─3
(3) N2O5 úfhdackh ùfï uOHkH iS>%;dj = (1200-600)s fõ'
(4) m%;sl%shdj i|yd iS>%;d kshuh R=k[N2O5(g)]m f,i oelaúh yelsh'
(5) tla m%;sl%shl j¾.hlska wdrïN lrk m%;sl%shdj, muKla iuia: fm< 1 fõ'

^28& my; j.ka;s j,ska wi;H jkafka"

(1) iEu úgu trans wdldrhg jvd tys cis wdldrfhaoS ;dmdxlh jeäh'
(2) CH3CH2CHO j,g jvd CH3COCH3 ys ;dmdxlh jeäh'
(3) C6H5COOH j,g jvd C6H5COCl ys c,h iuÕ l%shdldß;ajh by< fõ'
(4) CH3CH2CHO hk ixfhda.h CH3MgBr iuÕ kshqla,sfhda*s,sl wdl,k m%;sl%shdjlg ,lafõ'
─ +
(5) (CH3)2CHBr iuÕ CH3C≡CNa kshqla,sfhda*s,sl wdfoaYhla isÿfõ'
Prasanna Baddewithana(B.Sc.) 5
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^29& my; olajd we;s øjH ms<sn|j i,lkak'

(A) úh<s whsia (B) whäka (C) kema;,Ska (D) mer*Ska
W!¾Ojmd;khg ,laúh yels øjHhla jkafka"

(1) A (2) B (3) A yd B (4) A,B yd C (5) A,B,C yd D

^30& my; oelafjk m%;sl%shd wkql%uh i,lkak'
COCH3
Br2 (1) LiAlH4 Al2O3
X Y Z
ks¾'FeBr3 (2) H+/H2O ∆

X,Yyd Z ksjerosj olajd we;af;a"

OH O OH
COCH3 CHCH3 C—CH3 COCH3 CH—CH3 CH=CH2
Br Br Br
^1& ^2&

Br Br Br OH
COCH3 HO—CH—CH3 CH=CH2 COCH3 CH—CH3 CH2CH3

^3& ^4&
Br Br Br Br Br Br
OH
COCH3 CH—CH3 COOH

^5&
Br Br Br

 wxl 31 isg 40 f;la m%Yak j,g Wmfoia(

wxl 31 isg 40 f;la tla tla m%Yakh i|yd oS we;s (a),(b),(c) iy (d) hk m%;spdr y;r w;=frka tlla fyda
jeä ixLHdjla ksjerosh' ksjeros m%;spdrh$m%;spdr ljf¾oehs f;darkak'
(a) iy (b) muKla ksjeros kï (1) u;o
(b) iy (c) muKla ksjeros kï (2) u;o
(c) iy (d) muKla ksjeros kï (3) u;o
(d) iy (a) muKla ksjeros kï (4) u;o
fjk;a m%;spdr ixLHdjla fyda ixfhdackhla fyda ksjeros kï ^5& u;o W;a;r m;%fhys oelafjk Wmfoia mßos
,l=Kq lrkak'

^31& my; j.ka;s j,ska i;H jkafka"

(a) Cu2+, Co2+, Ni2+ j,g idkaø HCl fh¥úg j¾K úm¾hdihla we;sfõ'
(b) AgNO3 >kh r;al< úg f,dayuh fYaIh b;sßfõ'
(c) 0.001M ødjKj, [H+(aq)], HCl < HBr < HI wdldrhg jeäfõ'
(d) [Co(NH3)6]3+ jd;fhaoS TlaislrKhg ,lafõ'

^32& hk wKqj ms<sn|j i,lkak'

my; j.ka;s j,ska i;H jkafka"

(a) ish¿u ldnka mrudKq tlu ;,fha mej;sh hq;=h' (b) ixfhda.fha wKql iQ;%h C6H12 fõ'
3 2
(c) ixfhda.h ;=< sp , sp uqyqï ldnka mj;S' (d) ixfhda.h cis/trans iudjhúl olajhs'
6
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^33& .;sl iu;=,s;fha we;s moaO;shla iïnkaOj i;H jkafka"

(a) WIAK;ajh ksh;j ;ndf.k M, iaj,amhla bj;al< úg Kc fjkiafõ'
(b) WIAK;ajh ksh;j ;ndf.k m%;sl%shl iaj,amhla tlal< úg Kp fjkia fkdfõ'
(c) we;eï moaO;s le,öu$uka:kh lsÍu u.ska iu;=,s;;djhg t<öu blauka flf¾'
(d) úúO idkaøK i|yd M, yd m%;sl%shlj, idkaøK w;r wkqmd;h ksh; WIaK;ajfhaoS ksh; fõ'

^34& *Sfkda,a ms<sn|j l=uk j.ka;s^h& i;H jkafkao@

(a) t;fkda,aj,g jvd *Sfkda,aj, wdï,sl nj wvqh'
(b) *Sfkda,a NaHCO3(aq) j, oshfõ'
O
(c) *Sfkda,a NdIañl udOHfhaoS H—C—H iuÕ m%;sl%shd lrhs'
(d) *Sfkda,a Br2(aq) iuÕ bf,lafg%da*s,sl wdfoaYh isÿfõ'

^35& nyqwjhúl iïnkaOj i;H jkafka"

(a) khsf,daka" fgr,ska ix.Kk nyqwjhúl fõ'
(b) fmd,sjhskhs,a laf,darhsâ (PVC) odufha C=C mj;S'
(c) fíla,hsÜ wdl,k nyqwjhúlhls'
(d) weuhsfkda wï, ix.Kkh ùfuka fm%daàka we;sfõ'

^36& my; j.ka;s w;ßka i;H jkafka"

(a) Fe2+/Fe3+ ñY%Khl ixhq;sh fiùug Fe(s) , H2SO4, KMnO4 fhdod.; yelsh'
(b) KOH jd;fha .efgñka mej;s ñY%Khl ix>Glj, m%udK ;SrKhg *sfkdama;e,Ska iy fu;s,a
Tf¾kaÊ o¾Yl yd idkaøK okakd H2SO4 Wmfhda.s lr.; yel'
(c) KOH iaMál m%d:ñl m%udKsl øjHhls'
(d) KMnO4 fjk;a øjH TlaislrKh lrk ksid úrxckldrlhla f,i l%shd l< yelsh'

^37& >k ñY%Khl MgCO3 yd CaCO3 muKla mj;sk w;r tu ñY%Khg 0.284g m%udKhla ;dm l< úg
,enqKq ksh; ialkaOh 0.152g fõ' C=12, O=16, Mg=24, Ca=40 jk nj oS we;' my; j.ka;s j,ska i;H
jkafka"
(a) MgO : CaO = 1 : 2 ujq, wkqmd;h we;sj ,efí'
(b) CO2 jdhqj 0.132g ,efí'
(c) wdrïNl n÷kg jeämqr HCl fh¥ úg msgjk CO2 ujq, .Kkg iudk HCl ujq, .Kkhla
m%;sl%shd fjhs'
(d) MgCO3 j,g jvd myiqfjka CaCO3 úfhdackh fõ'

^38& my; ixfhda. hq., fjkalr y÷kd .ekSug ridhksl mÍËd jYfhka fhosh fkdyels wjia:d jkafka"
ixfhda. hq.,h m%;sldrlh
(a) CH3CH2CHO yd CH3COCH3 fgd,xia m%;sldrlh
(b) C6H5CH2Cl yd CH3C6H4Cl ;kql AgNO3
(c) C6H5CH2NH2 yd CH3C6H4NH2 NaNO3(s), HCl, H2O
(d) CH3CH2CBr2CH2CH3 yd CH3(CH2)3CHBr2 KOH, wefudakSh Cu2Cl2

^39& tla;rd ixfhda.hlg ;kql H2SO4(aq) fhÿúg" H+/Cr2O72— j, j¾Kh fjkia lrk jdhqjla ,efí'
by;§ ,enqkq ødjKhg jeämqr NH3(aq) fhÿúg" wjlafIamhla f.k§ jeämqr NH3 fhdod álfõ,djla
.;jk úg tys j¾Kh j¾Okhla fõ' wod, ixfhda.^h& úh yelafla"
(a). FeCO3 (b). Fe(NO2)2 (c). CoSO3 (d). ZnS
Prasanna Baddewithana(B.Sc.) 7
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^40& my; j.ka;s j,ska wi;H jkafka"

(a) CH3CH2CH2Br j,g jvd id¾:lj HC≡CCH2Br iuÕ NaNH2 m%;sl%shd lr weókh f.kfohs'

(b) C2H5OC6H4CH2Br j,g jvd id¾:lj HOCCH2C6H4CH2Br u.ska .%skdâ m%;sldrlh iEosh yelsh'

(c) NH3 j,g jvd (CH3)3N ys NdIañl m%N,;dj jeäh'

(d) CH3COOCH3 j,g jvd CH3CH2COOH j, ;dmdxlh by< fõ'

 wxl 41 isg 50 f;la m%Yak j,g Wmfoia(

wxl 41 isg 50 f;la tla tla m%Yakh i|yd m%ldY fol ne.ska bosßm;a lr we;' tu m%ldY hq.,hg fyd|sku a
.e,fmkqfha my; j.=fjys oelafjk mßos ^1&" ^2&" ^3&" ^4& iy ^5& hk m%;spdr j,ska ljr m%;spdrhoehs f;dard
W;a;r m;%fhys WÑ; f,i ,l=Kq lrkak'
m%;spdrh m<uq jeks m%ldYh fojeks m%ldYh
^1& i;H h i;H jk w;r" m<uqjekak ksjerosj myod fohs
^2& i;H h i;H jk kuq;a" m<uqjekak ksjerosj myod fkdfohs
^3& i;H h wi;H h
^4& wi;H h i;H h
^5& wi;H h wi;H h

m<uq jeks m%ldYh fojeks m%ldYh

^41& Hg2Cl2(s) ys ødjH;dj Smoldm─3 jk úg tys Hg2Cl2(s) c,h ;=< ix;Dma; l< úg wod,
ødjH;d .=Ks;h Ksp=16S4mol4dm─12 wdldr fõ' ix;Dma; ødjKfha whksl .=Ks;h Ksp w.hg
iudk fõ'
^42& hlv ksiaidrKh lrk Odrd WIaulfha my< C(s) + O2(g) CO2(g) + ;dmh
WIAK;ajh b;d by< jk w;r" túg CO(g) iEoSu CO2(g) + C(s) 2CO(g) + ;dmh
isÿfõ' hk m%;sl%shd isÿfjñka CO(g) f.k fok úg by<
WIAK;ajfhaoS ∆G0 (─) w.hla fõ'
^43& wdï,sl ;;ajfha we;s I─ yd Br─ tlu ñY%Kfha I─ yd Br─ ødjKhg Cl2/CCl4 fhdod le,;+ úg
we;súg y÷kd .ekSug Cl2 yd CCl4 Wmfhda.s m<uqj ;eô<s mdgo fojkqj oï mdgo f.kfohs'
lr.; yelsh'

^44& TiaÜj,aâ l%ufhka HNO3 ksmoùfïoS NH3 NH3 jd;h iuÕ Pt/Rh W;afm%arl yuqfõ r;al<
TlaislrKh lsÍu ;dmodhl l%shdjls' úg NO(g) f.kfohs'
^45& cis-but-2ene yd trans-but-2-ene j, ;dmdxl trans-but-2-ene j,g jvd cis-but-2ene j, oaúO%ej
tlsfklg fjkia fõ' >Q¾Kh by< fõ'

^46& we,alSkj, ,dËKsl m%;sl%shd kshqla,sfhda*s,sl we,alSkj, ldnka mrudKq 2la w;r oaú;aj
wdl,k fõ' nkaOkhla mj;S'

^47& ;dm odhl m%;sj¾;H m%;sl%shdjl" bosß m%;sl%shdfõ m%;sj¾;H m%;sl%shdjla iu;=,s; úg bosßmi iS>%;dj
il%Shk Yla;sh" miqmi m%;sl%shdfõ il%shk Yla;shg miqmi iS>%;djhg iudk fõ'
iudk fõ'
^48& úoHd.dr myiqlï hgf;aoS Pb2+ yd Ag+ fjkalr PbCl2 fukau AgCl o iqÿ wjfËam fõ'
.ekSug HCl(aq) Wmfhda.s lr.; yelsh'

^49& 2NaHCO3(s) Na2CO3(s) + CO2(g) + H2O(g) iu;=,s; moaO;shg n,mEï l< yelafla tu
hk úIucd;sh iu;=,s; moaO;shg NaOH(s) tla moaO;sfha mj;sk ix>gl fjkia lsÍfuka muKs'
l< úg iu;=,s;;djg n,mEï isÿfõ'

^50& CH3COOH wï,hg jvd HCOOH wï,h c,Sh CH3COOH j,g jvd HCOOH ys O—H nkaokfha
ødjKfhaoS wdï,sl m%N,;djfhka by< fõ' O%eùh ,ËK by< fõ'

***
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