Paper Class Paper No 26

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wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h" 2021 Tlaf;daïn¾

General Certificate of Education (Adv. Level) Examination, October 2021

ridhk úoHdj II
Chemistry II
id¾j;% jdhq ksh;h" R = 8.314 J K-1 mol-1
wej.dâfrda ksh;h" NA = 6.022 × 1023 mol-1
ma,Ekalfa .a ksh;h" h = 6.626 × 10-34 J s
(ish¨u m%Yakj,g ms<s;=re imhkak' tla tla m%Yakhg ,l=Kq 15 ne.ska ,efí')
B fldgi - rpkd
(05) (a) 2AB2(g) + B2(g) 2AB3(g) hk m%;l
s s%hdj ;dmodhl m%;sls%hdjls'
(i) idkaøK mo weiqfrka fuu m%;sls%hdj i|yd iS>%;d m%ldYkh ,shkak'
by; m%;sls%hdj W;afma% rlhla we;súg my; hdka;%Khg wkqj isÿ fõ'

2AB2(g) A2B4(g) fõ.fhka (1)

A2B4(g) + B2(g) 2AB3(g) fifuka (2)
(ii) by; nyqms hjr m%;sls%hdj i|yd fõ. ks¾K mshjr l=ula o@
(iii) AB2 m%;sls%hlh wkqnoaOfhka fm< fidhkak'
(iv) W;afma%rlh we;súg isÿjk hdka;%Kh i,ld Bg wod< úNj Yla;s me;slv w¢kak'
m%;sls%hlh" M," ixl%dó wjia:d (T S1, T S2
) w;rueÈh (I) tka;e,ams fjki (DH) yd ils%hk Yla;s ^I
mshjfrys bÈß m%;sls%hdj i|yd ils% hk Yla;sh Ea1, miq m%;sls%hdj i|yd Ea2 fojk mshjr i|yd Ea3 o
iuia; m%;sls%h dj i|yd ils%hk Yla;shl Ea o ,l=Kq lrkak'& ^,l= K q 5'0&

(b) ld¾ñlj hQßhd ksIamdokfha § w;rueÈ M,hla f,i ,efnk wefudakshï ldnfïÜ (NH2CO2NH4) my; mßÈ
iu;=,s;;djhg m;afõ'
NH2CO2NH4(s) 2NH3(g) + CO2(g)
mßudj V jk ixjD; odV Ndckhla ;=< 250C § by; iu;=,s;;dj we;s jQ úg moaO;sfha uq¿ mSvkh 1.17x104 Pa
úh' (RT=2500 Jmol-1 f,i .kak')
(i) by; iu;=,s;;djhg KP i|yd m%ldYkhla ,shkak'
(ii) KP ys w.h .Kkh lrkak'
(iii) tkhska KC ys w.h .Kkh lrkak'
(iv) WIaK;ajh 25 0C § mSvkh 1 x 104Pa hgf;a V mßudjl we;s CO2 m%udKhla iïmQ¾Kfhka" 250C mj;sk
by; iu;=,s; moaO;shg we;=¿ lrkq ,efí' ±ka moaO;sh tu WIaK;ajfha §u iu;=,s; ùug bv yeßh úg
CO2 ys wdxYsl mSvkh uq,ska ;snQ w.hg jvd wvq fõ o@ jeäfõo$ .Kkh lsÍ ula uÕska fmkajkak'
(v) by; (iv) ys iu;=,s; wjia:dfõ NH3 ys wdxYsl mSvkh uq,a w.hg jvd jeäfõ o@ wvqfõ o@ Tnf.a ms<s;=rg
fya;= meyeÈ,s lrkak' ^,l= K q 4'5&

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper No 26 Paper Class
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(c) tla;rd c,Sh ødjKhla ;=< I , Cl whkj, idka øK 2 x 10-2 moldm-3 ne.ska fõ' tu ødjKfhka 50cm3 la
f.k thg 0.2moldm-3 AgNO3 ødjK 50cm3 la fhdok ,§'
Ksp(AgI) = 2 x 10-14 mol2dm-6
Ksp(AgCl) = 1 x 10-10 mol2dm-6
(i) .Kkh lsÍulska f;drj" wjlafIam ùfï iïNdú;dj by< ,jKh l=ula ±hs olajkak'
(ii) by; (i) ys Tn i|yka lrk ,o ,jKh wjlafIam jk nj .Kkh lsÍula u`.ska fmkajkak'
(iii) by; (i) ys ,jKh uq¿ukskau ødjKh ;=< wjlafIam lrjQ úg b;sßjk Ag+ whk idkaøKh fldmuKo@
(iv) tla ,jKhla wjlafIam ù wjika jQ miqj o wfkla ,jKh wjlafIam jk nj fmkajkak'
- -
(v) udOHh ;=< Cl iy l whkj, idfmalaI idkaøK w;r wkqmd;h .Kkh lrkak' ^,l= K q 5'5&

(6) (a) A kï >k ixfhda.hla i|yd my; mÍCIK isÿlrk ,§'

iy wjlafIam i|yd mÍCIK

ødjKh i|yd mÍCIK

(i) A is g I f;la ixfla;j,ska olajd we;s ixfhda. y÷kdf.k tajdfha ridhksl iQ;% ,shkak'
(i) I. A + ;kql H2SO4 B+C
II. C + c,Sh D E+F
by; wjia:d i|yd ;=,s; ridhksl iólrK ,shkak' ^,l= K q 4'6&

(b) A, B, C hkq ixlS¾ K ixfhda. 3 ls' fuu ixfhda.j, jHqy wIag;,Sh cHdñ;shla olajhs' fïjdfha ixlS¾K
whkj, mrudKql ixhq;sh FeN6C3H9, FeN6C4H6 iy FeN6C5H3 fõ' fuu ixlS¾K whkj, uOH whkfha
TlaislrK wxlh tlu w.hls' tla tla ixlS¾Kj, ,s.k j¾. folla we;' fuu ixfhda.j, whkslj ne£ we;s
whk mj;S kï tajd tlu j¾.fha fõ'

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper Class Paper No 26
3
A, B iy C ixfhda. ;=ku mj;sk ñY%Khl idkaøKh 0.1moldm-3 jk w;r tys A : B : C ujq, w;r wkqmd;h
1 : 1 : 1 fõ' fuu ødjKfhka 100cm3 g jeämqr ;kql HCl fh¥úg iqÿ wjlafIamhla ,efí' fuu wjlafIamh
fjkalr fidaod úh<s ialkaOh ñkqï l<úg 4.305 fõ'
^iqÿ wjlafIamh NH3 ;kql j, uq¿ukskau ødjH fõ' tys ujq,sl ialkaOh 143.5gmol-1 fõ'&
(i) A, B iy C ixlS¾K ixfhda.j, ne£ we;s ,s.k j¾. y÷kd.kak'
(ii) A, B, C ixfhda.j, uOH whkfha bf,lafg%dak úkHdih ,sh kak'
(iii) iqÿ wjlafIamfha ridhksl iQ;%h ,sh kak'
(iv) A, B iy C ixlS¾Kj, jHqy iQ;% fya;= olajñka y÷kd.kak'
(v) tal Ok ixlS¾K whkhl uOH whkh M3+ fõ' fuys ,s.k j¾. folls'
-
tajd iy Cl fõ' ixlS¾K whkh wIag;,Sh jHqyhla mj;S'
ixlS¾Kfha jHqyh w¢kak'
^ ,s .k ldKavh "en" f,i ,súh yel'& ^,l= K q 4'0&

(c) K2SO4, KNO3 iy KNO2 ñY%Khla c,fha Èhlr ødjK 250cm3 la ms<s fh, lrk ,§' tu ødjKfha 25cm3 la
jeämqr KOH iy Al l=vq u.ska TlaisyrKh l<úg msgjk jdhqj 0.1moldm-3 H2SO4 50cm3 la ;=<g hjk ,§'
b;sß H2SO4 WodiSk lsÍug 0.2moldm-3 NaOH 30cm3 la jeh úh'
;j;a mÍCIKhl§" idkaøKh 4.74gdm-3 jk wdï,sl KMnO4 25cm3 la uq¿ukskau wj¾K lsÍug uq,a ødjKfhka
30cm3 la jeh úh' (K = 39, Mn = 55, N = 14, O = 16)
(i) by; mÍCIKfha § isÿjk ish¿u m%;sls%hd i|yd ;=,s; ridhksl iólrK ,sh kak'
(ii) uq,a idïm,fha jQ KNO3 iy KNO2 ia lkaO fidhkak' ^,l= K q 6'4&

(7) (a) 1-Propanol yd Ethanol muKla wdrïNl ldnksl øjHh f,i Ndú;d lr pent-2-ene ixYaf,aIK l%u 2 lg
l< yelsh'
ie' hq' my; wjia:dj,§ iEfok m%Odk M, muKla i,lkak'
(i) tla tla ud¾.h i|yd by; ixfhda. 2 Ndú;fhka idod.; hq;= m%;sldrl ,shkak'
(ii) by; wdrïNl ixfhda. 2 uÕska ixYaf,aIKh l< yels l%u ,shkak'
(iii) by; tla ud¾.hl§ pent-2-ene g wu;rj fjk;a ixfhda.hla iEfoa' tu M,fha jHqyh ,shkak'
(iv) pent-2-ene muKla M,h f,i ,ndfok l%ufhka isÿjk kshqla,sfhda*s,sl wdl,k m%;l
s s%hdfõ hdka;%Kh
,shkak' ^,l= K q 5'8&

(b) tlu ldnksl ixfhda. f,i methylpropanoate Ndú;d lr"

ixiaf,aIKh lrkafka flfia ±hs meyeÈ,s lrkak' ^,l= K q 3'2&

(c) my; ±lafjk mßj¾;kh mshjr yhlg fkdjeä f,i isÿlrk wdldrh olaj kak'

^,l= K q 2'7&

pß; Èidkdhl B.Sc. Engineering (Hon's)

Paper No 26 Paper Class
4

(d) (i) weks,Ska NaNO2 yd HCl iu`. m%;sls% hd lr ieÿk o" NaNO2 yd HCl iuÕ m%;sls%hd

lr fkdidohs' meyeÈ,s lrka k'

(ii) my; § we;s ixfhda. fjkalr y÷kd .kafka flfia±hs meyeÈ,s lrka k'

(a) yd

(b) yd

(c) yd ^,l= K q 3'3&

pß; Èidkdhl B.Sc. Engineering (Hon's)