AL/2022/02-S-IIA/B -1-

úNd. fmryqre mÍlaIK -2022

II
II Three hours
II

Total Marks
ku - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
úNd. wxlh - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
mdi, - '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
m%Yak m;% mx;shg muKla iyNd.S fõ kï yßhla () fhdod olajkak' -

m%Yak wxlh 1 2 3 4 5 6 7 8 9 10 tl;=j

,enQ ,l=K

I m;%h II m;%h tl;=j W;a;r m;% mÍlaIl

id¾j;% jdhq ksh;h R = 8.314 J K-1 mol-1 wej.dâfrda ksh;h NA = 6.022 x 1023 mol-1
ma,dkalaf.a ksh;h h = 6.626 x 10-34 J s wdf,dalfha m%fõ.h C = 3 x 108 m s-1
A fldgi - jHqy.; rpkd
m%Yak y;rg u fuu m;%fhau ms<s;=re imhkak' ^tla tla m%Yakh i`oyd kshñ; ,l=Kq m%udKh 10 ls&
----------------------------------------------------------------------------------------------------------------------------------------

1. (a) jryk ;=< § we;s .=Kh jeäjk ms<sfj<g my; i|yka oE ilikak'
(i) CH4 , H2O , NH3 , HF ^;dmdxlh&
''''''''''''''''''' < ''''''''''''''''''' < ''''''''''''''''''' < '''''''''''''''''''
(ii) NH3 , H2O , H2S , SiH4 ^nkaOk fldaKh&
''''''''''''''''''' < ''''''''''''''''''' < ''''''''''''''''''' < '''''''''''''''''''
(iii) CuO , MgO , Na2O , Al2O3 ^wdï,s l;dj&
''''''''''''''''''' < ''''''''''''''''''' < ''''''''''''''''''' < '''''''''''''''''''
(iv) F, O , S, Cl ^m<uq bf,lafg%daklrK Yla;sh&
''''''''''''''''''' < ''''''''''''''''''' < ''''''''''''''''''' < '''''''''''''''''''
(v) NaCl, Na2S, KF, KCl ^whksl ,CIK&
''''''''''''''''''' < ''''''''''''''''''' < ''''''''''''''''''' < '''''''''''''''''''
(vi) CO2 , C2H6 , C2H4 , C2H2 ^C mrudKqfõ úoHq;a RK;djh&
''''''''''''''''''' < ''''''''''''''''''' < ''''''''''''''''''' < '''''''''''''''''''
(vii) F , Mg , Al, Cl
- 2+ -
^mrudKq $ whkj, wrhh&
''''''''''''''''''' < ''''''''''''''''''' < ''''''''''''''''''' < '''''''''''''''''''
(viii) N , O , F , Cl ^olajk by<u ixhqc;dj&
''''''''''''''''''' < ''''''''''''''''''' < ''''''''''''''''''' < '''''''''''''''''''
(ix) H, He, Li, Be ^m<uq whkSlrK Yla;sh&
''''''''''''''''''' < ''''''''''''''''''' < ''''''''''''''''''' < '''''''''''''''''''
(x) HCHO, CHCl3, H2O2 , CH3COOH ^wka;¾-wKql n, j, m%n,;djh&
''''''''''''''''''' < ''''''''''''''''''' < ''''''''''''''''''' < '''''''''''''''''''
^ ,l+Kq 2'0 hs &

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -2-

(b) H2Y2O42- wekdhkfha ¨úia jHqyh ks¾udKfha § w;rueÈ wjia:djla my; ±lafõ' fuys Y hkq
p f.dkqfõ uQ,øjHhla fõ'
..
O

..
..
.. .. ..
H _ Y _ .O. _ Y _ .O.

..
H .O.

..
..
(i) fuu mrudKqj, úêu;a wdfrdamK we;akï" tajd § we;s jHqyfhys tla tla mrudKqj u; olajkak'
(ii) mrudKqj, wdfrdamK wjuj we;s jHqyh jvd;au ia:dhs hhs Wml,amkh lr fuu wKqj i|yd
jvd;au ms<s.; yels ¨úia jHqyh w¢kak'

(iii) wdj¾;s;d j.=fjys l=uk ldKavhg Y wh;afõ ±hs i|yka lrkak' '''''''''''''''''''''''''''''''''
(iv) wdj¾;s;d j.=fjys ;=kajk wdj¾;hg Y wh;a fõ kï Y y÷kd.kak' '''''''''''''''''''''''''''''''''
(v) C2H2N2O2 wKqj i|yd jvd;au ia:dhs ¨úia jHqyh my; olajd we;' fuu wKqj i|yd ;j;a ¨úia
jHqy ^iïm%hqla; jHqy& ;=kla w¢kak'
:O:
.. .. ..
H _ N _ C _ N = C = O
..
H

(vi) my; i|yka ¨úia jHqyh mokï lrf.k my; j.=fõ olajd we;s C, N yd S mrudKqj,
I. mrudKqj jgd VSEPR hq.,a II. mrudKqj jgd bf,lafg%dak hq.,a cHdñ;sh
III. mrudKqj jgd yevh IV. mrudKqfõ uqyqïlrKh
V. TlaislrK wxlh i|yka lrkak'
my; ±lafjk mßÈ mrudKq wxlkh lr we;'
H
.. .. .. H
: F.. _ C _ C  S _ N _ H _ C _ C _ S _N _H
1 2 3 4 5
F
H H
H H

C1 C2  S3 N4
I. VSEPR hq.,a
II. bf,lafg%dak hq.,a cHdñ;sh
III. yevh
IV. uqyqïlrKh
V. TlaislrK wxlh

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -3-

(vii) by; (vi) fldgfiys fok ,o ¨úia jHqyfhys my; i|yka nkaOk iE§ug iyNd.s jk mrudKql
$ uqyqï ldlaIsl y÷kd.kak' ^mrudKqj, wxlkh (iv) fldgfiys wdldrhg fõ'&
I. F  C1 F '''''''''''''''''''''''''''''''''''''''''''' C1 ''''''''''''''''''''''''''''''''''''''''''''
II. C1 C2 C1 '''''''''''''''''''''''''''''''''''''''''''' C2 ''''''''''''''''''''''''''''''''''''''''''''
III. C2  S3 N 2 '''''''''''''''''''''''''''''''''''''''''''' S3 ''''''''''''''''''''''''''''''''''''''''''''
IV. S3  N4 S3 '''''''''''''''''''''''''''''''''''''''''''' N 4 ''''''''''''''''''''''''''''''''''''''''''''
5 5
V. N4  H P4 '''''''''''''''''''''''''''''''''''''''''''' H ''''''''''''''''''''''''''''''''''''''''''''
(viii) by; (vi) fldgfiys fok ,o ¨úia jHqyfyys my; i|yka nkaok iE§ug iyNd.s jk mrudKql
ldlaIsl y÷kd.kak' ^mrudKqj, wxlkh (iii) fldgfiys wdldrhg fõ'&
C2  S3 C2 '''''''''''''''''''''''''''''''''''''''''''' S3 ''''''''''''''''''''''''''''''''''''''''''''
(ix) fuu wKqj O%eùh o ke;fyd;a ks¾O%eùh o@ ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(x) wdikak nkaOk fldaK olajñka by; (vi) fldgfiys fok ,o ¨úia jHqyfha yevh o< igyka
lrkak'

^ ,l=Kq 4'4 hs &

(c) yhsv%ckays mrudKql úfudapk j¾Kdj,sfha ,hsudka iy ndu¾ fY%AKsj, uq,a f¾Ld lsysmhla my;
igyfka olajd we;'

A B C D EFG H
(i) by; f¾Ld we;sjkafka yhsv%cka mrudKqfõ l=uk Yla;s uÜgï w;r bf,lafg%dakh ixl%uKfhka
o hk nj my; Yla;s uÜgï igykl we| olajkak' (A, B, C, D, E, F, G, H f¾Ld ,l=Kq l< hq;=h'&
n=6
n=5
n=4

n=3

n=2

n=1

(ii) ,hsudka fY%aKsfha H, H, H, H hk f¾Ld iudk úh yelafla by; l=uk f¾Ld j,g o@
H  = ''''''''''''''''''''' H = ''''''''''''''''''''' H  = ''''''''''''''''''''' H = '''''''''''''''''''''
(iii) by; j¾Kdj,sfha oDYH l,dmhg wh;a f¾Ldjka iy Bg wod< j¾Khka my; i|yka lrkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iv) by; m<uq igyfkys olajd we;s úfudapk j¾Kdj,sfha ixLHd;h jeä jk ÈYdj B;,hla u.ska
fmkajkak'
(v) by; j¾Kdj,sfha f¾Ldjka w;ßka ;S¾j;djh jeäu f¾Ldj l=ula o@
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -4-

(vi) ,hsudka fY%aKsfha m<uq f¾Ld foflys ixLHd; w;r fjki iudk jkafka ndu¾ fY%aKsfha l=uk
ixLHd;h we;s f¾Ldjg o@
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(vii) by; f¾Ld fYa%Ks fol wh;a jkafka úoHq;a pqïnl j¾Kdj,sfha l=uk l,dmj,g o@
I. ,hsudka = ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
II. ndu¾ = ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(viii) yhsv%cka mrudKqj whkSlrKhla isÿjqjfyd;a tys whkSlrKh fmkaùu i|yd iólrKh my;
,shkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(ix) yhsv%cka mrudKqfõ m<uq Yla;s uÜgfï Yla;sh -1312 kJ mol-1 kï yhsv%cka j, whkSlrK Yla;sh
fldmuK o@
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(x) by; j¾Kdj,sfha 6 jk Yla;s uÜgfï isg fojk Yla;s uÜgug bf,lafg%dak ixl%uKh ùfï§
we;s jk úlsrKfha ;rx. wdhduh 410 nm jk w;r 3 jk Yla;s uÜgfï isg 2 jk Yla;s uÜgug
bf,lafg%dak ixl%uKh ùfï§ we;sjk úlsrKfha ;rx. wdhduh 660 nm fõ kï 6 jk Yla;s
uÜgfï isg 3 jk Yla;s uÜgug bf,lafg%dak ixl%uKfha§ we;sjk úlsrKhl ;rx. wdhduh
.Kkh lrkak'
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^ ,l+Kq 4'0 hs &
2. (a) A, B, C, D, E f,i kïlrk ,o c,Sh ødjKj, Na2S2O3 , KI, Pb(CH3COO)2 , Na2SO3, Na2S
,jK wvx.=h' ^ms<sfj<ska fkdfõ& tajd úYaf,aIKh lsÍu i|yd isÿ lrk ,o mÍlaIK yd tajdfha
ksÍlaIK my; olajd we;'
mÍlaIK ksÍCIK
1. A ys c,Sh ødjK iaj,amhlg B tla lrk ,§' ly wjlafIamhla ,enqKs'
2. by; 1 ys ,enqK wjlafIamh c,h iaj,amhla wjlafIamh Èhù ly meye ødjKhla
iuÕ r;a lrk ,§' ,enqKs'
3. C ys c,Sh ødjKhg B tla lrk ,§' iqÿ wjlafIamhla ,enqKs'
4. by; 3 § ,enqK wjlafIamh r;a lrk ,§' fjkila isÿfkdùh'
5. E ys c,Sh ødjKhg B tla lrk ,§' iqÿ wjlafIamhla ,enqKs'
6. by;ska ,enqK wjlafIamh r;a lrk ,§' wjlafIamh l¿ meyeúh'
7. D ys c,Sh ødjKhg B iaj,amhla tla lrk ,§' l¿ wjlafIamhla ,enqKs'

(i) A , B , C , D , E f,i kïlrk ,o c,Sh ødjK y÷kd.kak'

A = ''''''''''''''''''''''''''''''''''''''''' B = '''''''''''''''''''''''''''''''''''''''''
C = ''''''''''''''''''''''''''''''''''''''''' D = '''''''''''''''''''''''''''''''''''''''''
E = '''''''''''''''''''''''''''''''''''''''''
(ii) tla tla wjia:djkag wod< ;=,s; ridhksl iólrK ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -5-

'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^ ,l=Kq 2'6 hs &
(b) my; m%;sl%shd ud,dj i,lkak'

(i) NH 4NO 2  A jdhq + B jdhq

(ii) Na + B øj  C jdhq + D ødjKh

(iii) A + C  E jdhq

(iv) E + Cl2  A + F

(v) Cl2 + D  G + H + B
WKq idka ø
(i) A isg H olajd wCIrj,ska i|yka lr we;s ixfhda.j, iQ;% i|yka lrkak'
A = ''''''''''''''''''''''''''''''''''' B = ''''''''''''''''''''''''''''''''''' C = '''''''''''''''''''''''''''''''''''
D = ''''''''''''''''''''''''''''''''''' E = ''''''''''''''''''''''''''''''''''' F = '''''''''''''''''''''''''''''''''''
G = ''''''''''''''''''''''''''''''''''' H = '''''''''''''''''''''''''''''''''''
(ii) by; (v) mshjr i|yd ;=,s; ridhksl iólrKh ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^ ,l+Kq 2'0 hs &
(c) iqÿiq jpk fhdod my; ysia;eka mqrjkak'

KMnO4 c,Sh ødjKfha j¾Kh ''''''''''''''''''''''''''''''''''''''''' fõ' fuhg idkaø KOH ødjKhla tl;= l< úg uq,a
j¾Kh ''''''''''''''''''''''''''''''''''''''''' yef¾' tu meyehg wod< whkh ''''''''''''''''''''''''''''''''''''''''' fõ' fuu whkfha
Mn ys TlaislrK wxlh ''''''''''''''''''''''''''''''''''''''''' fõ' tu ødjKhg ''''''''''''''''''''''''''''''''''''''''' ^Tlaisldrl $
Tlaisydrl& jk ''''''''''''''''''''''''''''''''''''''''' tl;= l< úg ødjKh ÿUqre meye;s wjlafIamhla ,nd foa'
wjlafIamh ''''''''''''''''''''''''''''''''''''''''' fõ' tys§ Mn j, TlaislrK wxlh ''''''''''''''''''''''''''''''''''''''''' h' fuu
wjlafIamh id' HCl iu. ''''''''''''''''''''''''''''''''''''''''' ødjKhla iy jdhq nqnq ¿ msg lrhs ' tu jdhqj
''''''''''''''''''''''''''''''''''''''''' fõ' fuys§ Mn j, TlaislrK wxlh ''''''''''''''''''''''''''''''''''''''''' isg '''''''''''''''''''''''''''''''''''''''''
olajd fjkia fõ'
^ ,l+Kq 2'4 hs &
(d) A hk ixfhda.h (A = XYn, X hkq d f.dkqjg wh;a uQ,øjHhls' Y hkq p f.dkqjg wh;a uQ,øjHhls'&
idkaø HCl tl;= l< úg Èh ù B kï j¾Kj;a oaúmrudKql jdhqjla msg ù C kï j¾Kj;a ødjKhla
idohs'
fuu C ødjKhg NaOH tlal< úg D kï wjmeye wjlafIamhla ,enqKq w;r th jeämqr NaOH ys Èh
fkdùh' fuu D wjlafIamh jd;hg ksrdjrKh l< úg kej; A iefoa' fuu D wjlafIamhg NH4Cl
tlal< úg wjlafIamh Èh ù C ødjKh iy E kï r;= ,sÜuia ks,a meyehg yrjk jdhqjla msg fõ'
(i) A, B, C, D, E iy F y÷kd.kak'
A = ''''''''''''''''''''''''''''''''''' B = ''''''''''''''''''''''''''''''''''' C = '''''''''''''''''''''''''''''''''''
D = ''''''''''''''''''''''''''''''''''' E = ''''''''''''''''''''''''''''''''''' F = '''''''''''''''''''''''''''''''''''
(ii) my; m%;sl%shd i|yd ;=,s; ridhksl iólrK ,shkak'
I. A, id' HCl iu`. '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
II. D, jd;h iu`. '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
III. D, NH4Cl iu`. '''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
IV. C, (NH4)2S iu`. ''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''' ^ ,l+Kq 3'0 hs &

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -6-

3. (a) my; § we;s úoHq;a ridhksl fldaIh i,lkak'

Cl2 (g , 1 atm)
pt(s)

Ag(s)
Cl- (aq , 1 mol dm-3)

AgCl(s)

EAg / AgCl = 0.22 V | ECl- / Cl2 = 1.36 V

(i) by; fldaIfha wefkdavh y÷kd.kak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(ii) wefkdav m%;sl%shdj ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iii) lef;dav m%;sl%shdj ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iv) iuia: fldaI m%;sl%shdj ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(v) úoHq;a .dul n,h .Kkh lrkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(vi) fldaI wxlkh ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(vii) my; idOl wkqj fldaIfha úohq;a .dul n,h wvqfõo@ jeä fõ o@ fjkia fkdfõ o@ hk j.
fya;= olajñka myokak'
I. ødjkfha Cl-(aq) idkaøKh jeä lsÍu
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
II. ødjKfha WIaK;ajh jeä lsÍu
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(viii) fldaIh ;=<ska 0.25 A Odrdjla úkdä 9.65 ld,hla ;=< § .uka lf<a kï" AgCl(s) >kfha iso
jQ ialkaO fjki .Kkh lrkak' (IF = 96500 C, Cl - 35.5 , Ag - 108)
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^ ,l=Kq 5'0 hs &

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -7-

(b) úYaj úoHd, YsIHh lKavdhula j¾Kldrlhla fhdok ,o meKs îu j¾.hl" j¾Kldrlfha idkaøKh
fiùu i|yd my; l%ufõoh fhdod.kakd ,§'

* idkaøKh 80 ppm jQ j¾Kldrl iys; meKs îu c,Sh ødjK 500 mL la C6H6 100 mL la iu.
fyd¢ka fid,jd .;sl iu;=,s; ùug bv yßhs' C6H6 j,ska j¾Kldrlh 30 mg la
fjkalr.; yels úh'
* c,Sh ødjK 500 mL fjkqjg meKsîu j¾.fha ,Sgrhla yd C6H6 100 mL la fyd¢ka fid,jd
.;sl iu;=,s;;djhg m;aùug bv yßhs' fuúg C6H6 ia;rfhka j¾Kldrlh 50 mg la
,nd.; yels úh'
* by; meKs îu j¾.h il%Sh l< wÕ=re iys; k,hla ;=<ska jEiafikakg bv i,iajd h<s;a
by; wdldrhg mÍCIKh l< úg" c,Sh C6H6 j,ska j¾K ldrlh 4 mg la ,nd.; yels úh'

(i) meKs îu j¾.fha we;s j¾Kldrl idkaøKh g dm-3 j,ska fidhkak'

'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(ii) C6H6 yd meKs îu c,Sh ødjK w;r j¾Kldrlfha jHdma;s ix.=Klh fidhkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iii) il%Sh wÕ=re iu. msßhï l< miq meKsîu j¾Kldrlfha idkaøKh fidhkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iv) il%sh wÕ=re 500 g la by; mÍlaIdjg fhdod.kq ,enQfõ kï" il%sh wÕ=rej, wêfYdaIK n,h ppm
j,ska fidhkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^ ,l=Kq 5'0 hs &

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -8-

4. (a) C9H13N wKql iQ;%h we;s A m%ldY il%sh wefrdaueál weókhls' th NaNO2 / HCl iu. m%;sl%shd lr
idok M,h B fõ' B o m%ldY il%Sh jk w;ru H+ / KMnO4 iu. r;al< úg C7H6O2 jk wKql iQ;%h
we;s ixfhda.hla idohs' B , Na f,dayh iu. wj¾K jdhqjla ,ndfoa' B ixfhda.h msßãkshï laf,dafrda
lafrdafïÜ iu. m%;sl%shd lrjQ úg iEfok C ixfhda.h HCN iu. m%;sl%shd ù D iEfoa' D, wdka;ßl
f,day W;afm%arlhla yd X jdhqj u.ska E kï m%d:ñl wefrdaueál weók njg TlaisyrKh fõ'
(i) by; ixfhda. y÷kdf.k tajdfha jHqy my; fldgq ;=< ,shkak'
A B C

D E

(ii) X jdhqj l=ula o@ ''''''''''''''''''''''''''''''''''''''''''''''''''''''''

(iii) E ys wKql iQ;%h l=ula o@ '''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iv) B - ixfhda.h id' H2SO4 iu. r;al< úg iEfok ;%sudk iudjhúl;djh olajk jHqy 2 we| tu
wdldr y÷kajkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(v) E ys wKql iQ;%h we;s m%ldY jk m%d:ñl wefrdaueál weókj, ;sìh yels ;%sudk iudjhúlj,
jHqy we| tu wdldr y÷kajkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(vi) A yd C ridhkslj tlsfklska fjkalr y÷kd.ekSug tla ridhksl m%;sl%shdjla ,shkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^,l+Kq 4'0 hs'&
(b) my; i|yka m%;sl%shd i|yd fhdod.; hq;= m%;sl%shl j, jHqy w¢kak'

ks¾c,Sh Al2O3
(i) A  CH3C  CH

H2 / BaSO4 / Pd
(ii) B CH3CH = CH2
laúfkd,ska

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B -9-

OH
laIdÍh KMnO4
(iii) C CH3  CH  CH2  OH

NaNH 2 C  C-Na+
(iv) D

O
 C  Cl O NO 2
(v) E C
ks¾c,Sh AlCl3

CH3
c,Sh uOHidÍh
(vi) F CH3  C  CN
KCN
CH 3

Zn / Hg / idkaø DCl
(vii) G CH3  CD2  CH3

O
wdï,sl CrO3
(viii) H CH3  C  CH3 ^ ,l=Kq 3'0 hs

(c) my; m%;sl%shdj i,lkak'

C2H5Br + CH3NH2 C2H5NHCH3   HBr
(i) fuu m%;sl%shdfõ j¾.h i|yka lrkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(ii) m%;sl%shdfõ hka;%Kh olajkak'
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
(iii) t;s,a fn%dauhsv" fm%dmshkuhsâ iu. my; olajd we;s wdlrhg m%;sl%shd fkdlrkafka uka±Zhs
myokak'
C2H5Br + CH3CH2CONH2 CH3CH2CONHC2H5    HBr
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
'''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''''
^ ,l=Kq 3'0 hs &

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B - 10 -

B fldgi - rpkd
m%Yak follg ms<s;=re imhkak' ^tla tla m%Yakh i`oyd kshñ; ,l=Kq m%udKh 15 ls&
----------------------------------------------------------------------------------------------------------------------------------------
5. (a) 0 0C isg 100 0C w;r WIaK;ajj, § NH4HS >kh ú>gkh ù my; iólrKfhka ±lafjk
iu;=,s;;djhg t<fò'
NH4HS(s) NH3(g) + H2S(g)
27 C § mßudj 4.157 dm jk Ndckhlg NH4HS >kh 10 g la oud by; olajd we;s iu;=,s;;djhg
0 3

t<öug bvyßk ,§' iu;=,s;;djfha § moaO;sfha uq¿ mSvkh 6 × 104 Pa úh' NH4HS(s) mßudj
fkd.skh s yels hhs o iEfok jdhquh M, mßmQ¾K yeisÍula olajk nj o i,lkak' ( N = 14, H = 1, S = 32 )
(i) by; iu;=,s;h i|yd 27 0C § Kp w.h .Kkh lrkak'
(ii) ú>gkh jQ NH4HS j, ialkaOh .Kkh lrkak'
(iii) I. NH4HS(s) ;j;a iaj,amhla tl;= l< úg"
II. mßudj yß wvlska wvq l< úg"
moaO;sfha uq¿ mSvkhg isÿjk fjki ^jeä fõ $ wvq fõ $ fjkila fkdfõ& fya;= olajñka
,shd olajkak'
(iv) by;ska ±lajQ iu;=,s;;d moaO;shg H2S(g) tl;= lsÍfuka miq H2S(g) ys wdxYsl mSvkh NH3(g) ys
wdxYsl mSvkh fuka y;r.=Khla jk mßÈ iu;=,s;hg t<öug bvyßkq ,efí' kj iu;=,s;h
i|yd my; olajd we;s oE .Kkh lrkak'
I. NH3(g) j, ujq, Nd.h
II. H2S(g) j, wdxYsl mSvkh
^ ,l+Kq 6'0 hs &
(b) ksh; mSvkfha § yd T WIaK;ajfha § yrialv j¾.M,h A yd È. l jQ oDV Ndckhla ;=< He yd Ne hk
jdhQka fol wvx.= j we;'
(i) tu wjia:dfõ § moaO;sfha uq¿ mSvkh P1 fõ' uq¿ ujq, ixLHdj nT i|yd m%ldYkhla jHq;amkak
lrkak'
(ii) oDV n÷fka WIaK;ajh fo.=Khla l< úg kj mSvkh P2 fõ' mßudfõ fjkila isÿ fkdfõ kï P2
i|yd m%ldYkhla P1 weiqfrka ,nd.kak'
(iii) by; tla tla WIaK;ajfha § tla tla jdhq i|yd (He fyda Ne) fnda,aÜiaudka jHdma;s jl% my;
m%ia;drfha w¢kak' (Ne i|yd bro He i|yd ---- br o Ndú; lrkak'&
(iv) T WIaK;ajfha § He yd Ne hk jdhQka foflys uOHhkH fõ.h w;r iïnkaoh CHe = 5 CNe nj
jHq;amkak lrkak' (He = 4, Ne = 20)
(v) T WIaK;ajfha § He yd Ne hk jdhQka foflys uOHhkH pd,l Yla;sh EHe = ENe nj idOkh
lrkak'
^ ,l+Kq 4'0 hs &
(c) NO iy O2 w;r jdhq l,dmfha isÿjk m%;sl%shdj i,lkak'
2NO(g) + O2(g)  2NO2(g)
by; m%;sl%shdfõ pd,l ridhkh wOHhkh l< úg my; o;a; ,efí'

mÍCIKh [NO] mol dm-3 [O2] mol dm-3 NO2(g) iE§fï wdrïNl
YS>%;djh mol dm-3 s-1
1 0.020 0.020 0.057
2 0.040 0.040 0.455
3 0.040 0.020 0.228

(i) NO j,g idfmaCI fm< .Kkh lrkak'

(ii) O2 j,g idfmaCI fm< .Kkh lrkak'
(iii) YS>%;d iólrKh ,shkak'
(iv) YS>%;d ksh;h .Kkh lrkak'
(v) mÍCIK 2 iy 3 ys § O2 bj;aùfï wdrïNl YS>%;dj .Kkh lrkak'
(vi) by; m%;sl%shd mshjr 2 lska isÿ fõ hehs i,lkak'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B - 11 -

m<uq mshjr 2NO N2O2 kï"

m%;sl%shdfõ hka;%Kh i|yd fojk mshjr ,shkak'
(vii) by; hka;%Kfha fõ. ks¾K mshjr olajd thg fya;= idOl bÈßm;a lrkak'
^ ,l+Kq 5'0 hs &
6. (a) A isg G olajd ødjK i,lkak'
(A) wdi%e; c,h ms<sfh, lr jik ,o fnda;,a
(B) 0.20 mol dm-3 NaOH ødjKhla
(C) 0.1 mol dm-3 NH4OH(aq)
(D) 0.01 mol dm-3 NH4OH(aq)
(E) 0.1 mol dm-3 NH4OH iy 0.1 mol dm-3 NH4Cl ødjKhla
(F) 0.1 mol dm-3 NH4OH iy 0.5 mol dm-3 NH4Cl ødjKhla
(G) C1 mol dm-3 NH3(aq) iy C2 mol dm-3 RNH2 ødjKhla
A isg G olajd ødjK weiqßka m%Yakj,g ms<s;=re imhkak'
(i) A isg E olajd ødjKj, pH w.h jeäjk ms<sfj<g ilikak'
(ii) E ødjKh 10 .=Khla ;kql l< úg pH w.h fjkiaúh yels o@ Tfí ms<s;=r meyeÈ,s lrkak'
(iii) NaOH l=vd m%udKhla tlal< úg E yd F ødjK j,ska pH w.h fjkiaùug jeä m%;sfrdaOhl olajk
ødjKh l=ula meyeÈ,s lrkak'
(iv) jd;hg ksrdjrKh l< úg A ødjKfha pH w.h Tn n,dfmdfrd;a;= jk fjki myokak'
(v) B ødjKfhka 50 cm3 la iy C ødjKfhka 50 cm3 la ñY% lr idok ,o ødjKhl pH w.h .Kkh
lrkak' (Kw = 1 × 10-14)
(vi) E ødjKfha pH w.h .Kkh lrkak' (Kb = 1.8 ×105)
(vii) NH3 j, ú>gk ksh;h Kb1 o CH3CH2 j, ú>gk ksh;h Kb2 o kï G ødjKh [OH-(aq)]
idkaøKh i|yd m%ldYkhla jHq;amkak lrkak'
^ ,l+Kq 5'0 hs &
(b) my; i`oyka o;a; i,lkak'

Hf/ kJ mol-1 Gf/ kJ mol-1 S/ J mol-1 K-1

PCl3(g) -320 -272 217
PCl5(g) -375 -305 365

(i) PCl3(g) + Cl2(g)  PCl5(g) hk m%;sl%shdfõ S0 ys ,l=K .Kkh lsÍulska f;drj wkdjelshla
f,i m%ldY lrkak' Tfí ms<s;=rg fya;= myokak'
(ii) § we;s o;a; Ndú; lr 298 K § by; m%;sl%shdj i|yd
I. iïu; tka;e,ams fjki H .Kkh lrkak'
II. iïu; .síia Yla;s fjki G .Kkh lrkak'
(iii) 298 K ys § m%;sl%shdfõ iajhxisoaONdjh ms<sn|j woyia olajkak'
(iv) (ii) ys § ,nd.;a ms<s;=re Ndú;fhka by; m%;sl%shdj i|yd
I. 298 K § tkafg%dms fjki S.Kkh lrkak'
II. 298 K § Cl2(g) iïu; tkafg%dmsh S0 .Kkh lrkak'
^ ,l=Kq 5'0 hs &
(c) rjq,a kshuh ,shd olajkak'
(ii) X iy Y øj folla ñY% ù mßmQ¾K ødjKhla idohs' fuu ødjKfha øj l,dmfha X iy Y ys ujq,
Nd. ms<sfj<ska a yd b o jdIam l,dmfha ujq, Nd. a' yd b' o ix;Dma; jdIam mSvk P0X iy P0Y o
by; ødjKh iu. iu;=,s;j mj;sk jdIamh ;=< X iy Y ys jdIam mSvk ms<sfj<ska PX iy PY o
kï a' yd b' i|yd .Ks;uh iïnkaO;djka ±lafjk iólrKh wfkl=;a mo weiqßka f.dvk.kak'
(iii) 25 0C § X iy Y øj foflys ix;Dma; jdIam mSvk 4.5 × 104 Pa iy 6.0 × 104 Pa fõ' X ys ujq,
2 la o Y ys ujq, 3 la o tlaj idok ødjKhla rjq,a kshuh ms<smÈkafka hehs i,ld jdIam l,dmh
;=< X yd Y ys ujq, Nd. fidhkak'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B - 12 -

(iv) by; iii moaO;sfha jdIam >kSNjkh lr kej; iu;=,s; úug ;enqúg jdIam l,dmh ;=< X yd
Y ys ujq, Nd. fidhkak'
(v) by; moaO;sh i|yd uq`M jdIam mSvk - ixhq;s úp,k m%ia:drh we| olajkak'
(vi) by; moaO;sh i|yd iqÿiq WIaK;aj - ixhq;s l,dm igykla we| olajkak'
^ ,l=Kq 5'0 hs &
7. (a) 25 C § c,Sh ødjKhl Br yd I whk wvx.= fõ' Br (aq) idkaøKh 1 × 10 mol dm jk w;r I-(aq)
0 - - - -6 -3

idkaøKh 1 × 10-6 mol dm-3 fõ' fuu ødjKfha 1 dm3 lg 0.001 mol dm-3 AgNO3 ødjKhlska jrlg ìxÿj
ne.ska tl;= lrk ,§'
25 0C § AgBr ys Ksp = 5.0 × 10-13 mol2 dm-6
25 0C § AgI ys Ksp = 8.0 × 10-17 mol2 dm-6
(i) AgBr wjlafIam ùu wdrïN jk úg øjKfha Ag+ idkaøKh .Kkh lrkak'
(ii) AgI wjlafIam ùu wdrïN jk úg ødjKfha Ag+ idkaøKh .Kkh lrkak'
(iii) m<uqj wjlafIam jkafka l=uk ixfhda.ho@
(iv) m<uq wjlafIamh iE§u wdrïN jk úg tl;= lr we;s AgNO3 ødjK ìxÿ .Kk fidhkak'
^øj ìxÿjl mßudj 0.05 cm3 fõ'&
(v) fojk wjlafIamh iE§u wdrïN jk fudfydf;a m<uq wjlafIamhg wkqrEmj ødjKh ;=< b;sßj
we;s wekdhkfha idkaøKh fidhkak'
(vi) by; .Kkh lsÍfï§ Tn úiska isÿ lrk ,o Wml,amk fudkjd o@
^ ,l+Kq 7'0 hs &
(b) (i) uOH f,day legdhkh" fldfnda,aÜ f,i we;s ixlS¾K ixfhda.hl ,s.k j¾. folla muKla we;'
fldfnda,aÜ ujq, 1 lg" wefudakshd ujq, 4 la yereKq úg ixfhda.fha wvx.= wfkla tlu uQ,øjHh
wdj¾;s;d j.=fõ 17 ldKavhg wh;a fõ'
fuu ixfhda.fhka ujq, 0.15 la c,fha ødjKh lr thg jeämqr AgNO3 tl;= l< úg ly meye;s
wjlafIamhla ,enqKs' fuu wjlafIamfha úh<s ialkaOh 28.2 g jk w;r th idkaø NH3 ys ødjKh
fõ' ixlS¾K ixfhda. wIag;,Sh fõ' ^ly meye;s ixfhda.fha idfmaCI wKql ialkaOh 188 ls'&
I. wefudakshd yereKq úg ixlS¾K ixfhda.fha wvx.= wfkla ,s.k j¾.h l=ula o@
II. ixfhda.fha iQ;%h wfmdaykh lrkak'
III. fldfnda,aÜ mj;sk TlaislrK wjia:dj i|yka lrkak'
(ii) my; ±lafjk m%fNaoj, IUPAC kï ,shkak'
I. [Ni(H2O)6]Cl2
II. [CuCl4]2-
(iii) my; wid we;s m%Yakj,g ms<s;=re imhkak'
I. Co2+(aq) c,Sh ødjKhl j¾Kh i|yka lrkak'
II. fuu c,Sh ødjKhg ;kql wefudakshd tl;= lrk úg ,efnk ksÍCIKh l=ula o@
III. thg jeämqr NH3 tl;= lrk úg ,fnk ksÍCIKh l=ula o@
IV. III. ka ,efnk ødjKhg H2O2 tl;= lrk úg olakg ,efnk ksÍCIKh iy Bg wod<
ixlS¾Kfha iQ;%h ,shkak'
^ ,l+Kq 5'0 hs &
(c) X kï uQ,øjH nyqrEmS wdldr olajk w;r th wdj¾;s;d j.=fõ ;=kajk wdj¾;fha uQ,øjHhla fõ' tys
Tlaihsâ wdï,sl jk w;r iajNdjfha >k jYfhka mj;S' tys laf,darhsv c, úÉfþokh l< úg Tlais
wï, ,nd foa'
(i) X y÷kd.kak'
(iii) X ys Tlaihsvj, ridhksl iQ;% ,shd c,fha øjKh ùug wod< ;=,s; ridhksl iólrK ,shkak'
(iii) X ys laf,darhsv c, úÉfþokhg wod< ;=,s; ridhksl iólrK ,shkak'
(iv) X uQ,øjHh by<u TlaislrK wxlfhka idok Tlaiswekdhkfha c,Sh ødjKhla y÷kd.ekSug
ridhksl mÍCIdjla fokak'
(v) fuu uQ,øjH wh;a ldKavfha uQ,øjHj, yhsv%hsvhkaf.a ;dmdxl úp,kh my; wlaI ;=< we|
olajkak' ^ ,l+Kq 3'0 hs &
------------------------------------------
DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B - 13 -

8. (a) X kï we,als,a fudfkd fn%dauhsvfha ialkaOh wkqj fn%daóka 53] la we;'

(i) tys wKql iQ;%h wfmdaykh lrkak' (Br = 80 , C = 12 , H = 1)
(ii) X ys -CH3 ldKav 3 la ;sfí kï X i|yd ;sìh yels jHqy 3 la w¢kak'
(iii) X j,ska HBr wKqjla bj;a lsÍu l< fkdyels kï X y÷kd.kak'
(vi) X ys IUPAC kï ,shkak'
^ ,l+Kq 3'0 hs &
(b) my; § we;s A yd B hk ldnksl ixfhda. i,ld n,kak'
O OH
_ _
C O CHCH2CH3 CH3 C _ CH2 _ CH3
_

CH 3 CH 2

[A] [B] ^ ,l+Kq 4'0 hs &

A ixfhda.h B ixfhda.h njg mßj¾;kh l< yelafla flfia±hs olajkak' Tnf.a mßj¾;kh mshjr
wglg jeä fkdúh hq;= w;r fjk;a lsisu ldnksl ixfhda.hla m%;sldrlhla f,ig Ndú; fkdl<
hq;=h s'

(c) my; ±lafjk mßj¾;kh mshjr yhlg fkdjeä f,i isÿ lrk wdldrh olajkak'
OH O
CH _ C  C _ H  CH _ CH _ CH _ CH _ C _ H
3 3 2

CH 3
^ ,l+Kq 3'0 hs &
(d) (i) CH2 = CH2 iy Br2 / CCl4 w;r m%;sl%shdfõ§ w;rueÈ Ok whkfha jHqyh w¢kak'
(ii) by; m%;sl%shdj c,Sh udOHfha§ isÿ l< úg M,hla f,i Br_CH2CH2_OH iEfoa' H2O wKqjg
kshqla,sfhda*hs,hla f,i l%shd l< yels nj i,lñka fï i|yd hdka;%Khla fhdackd lrkak'
^ ,l+Kq 2'0 hs &
(e) (i) my; i|yka m%;sl%shdfõ hdka;%Kh fokak'
O CH 3
_ _ _ _ _
CH3C  CMgBr + CH3 C CH3  CH3 C  C C OMgBr
CH 3
(ii) by; i|yka m%;sl%shdj kHIaáldó wdfoaY m%;sl%shdjla o (eletrophilic) ke;fyd;a bf,lafg%dakldó
(nuclephilic) wdfoa Y m%;sl%s hdjla o hkak i|yka lrkak' wod< mßÈ ksha la,sfhda*hs, h fyda
bf,lafg%da*hs,h y÷kd.kak'
OH
(iii) .%Skdâ m%;sldrlhla idod .ekSug CH3 CH _ CH2Br iqÿiq fkdjkafka uka±hs fya;= olajñka
_
meyeÈ,s lrkak'
^ ,l+Kq 3'0 hs &
9. (a) X kï ødjKh legdhk 3 lska iukaú;h' tu legdhk y÷kd.ekSu i|yd my; mÍCIK isÿ lrk ,§'

mÍCIKh ksÍCIK
^1& X ødjKhg ;' HCl tla lsÍu' lsisÿ wjlafIamhla fkd,enqKs'
^2& X ødjKh ;=<ska H2S nqnq,kh lsÍu' l¿ meye;s wjlafIamhla (P) ,enqKs'
^3& P wjlafIamh fjka lrf.k fmrkh" H2S fld< meye;s wjlafIamhla (Q) ,enqKs'
wjika jk;=re r;alr id' HNO3 ìxÿ lsysmhla
tlalr ;jÿrg;a r;alr" tu ødjKh isis,a lr
NH4OH / NH4Cl tla lsÍu'
^4& Q wjlafIamh fjka lrf.kk fmrkh ;=<ska l¿ meye;s wjlafIamhla (R) ,enqKs'
H2S nqnq,kh lsÍu'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B - 14 -

P, Q, R wjlafIamh i|yd mÍCIK

mÍCIKh ksÍCIK
^5& P WKq idkaø HNO3 ;=< Èh fõ' bkamiq jeämqr ;o ks,a ødjKhla ,efí'
NH3 tla lrk ,§'
^6& NaOH tlal< úg Q Èh fõ' fld< meye;s ødjKhla ,efí'
;' HCl tlal< úg o Q Èh fõ' ks,a oï meye;s ødjKhla ,efí'
^7& R wjlafIamh WKq" idkaø H2SO4 ys Èh fõ' fld< meye;s ødjKhla ,efí'
by; ødjKh NH3 iu. m%;sl%shd lrk ,§' ;o ks,a meye;s ødjKhla ,efí'

(i) X ødjKfhys we;s leg whk 3 y÷kd.kak'

(ii) P, Q yd R wjlafIamj, ridhksl ixfla; ,shkak'
^ ,l+Kq 5'0 hs &

(b) wldnksl whksl ,jKhla jk X wvx.= c,Sh ødjKhla iu. my; i|yka mÍCIK isÿ lrk ,§'

mÍCIKh ksÍCIK
1' ixfhda.fha c,Sh ødjKhg HCl tla lrk ,§' Y jdhqj msgjk w;r meyeÈ,s ødjKhla ,enqKs'
2' msgjk Y jdhqj c,h ;=<g hjd tu ødjKhg Z iqÿ mdg wjlafIamhla ,enqKs' tu wjlafIamh
BaCl2 tla lrk ,§' wï,j, Èh fõ'
3' by; ^2& ys c,Sh ødjKhg H2O2 tla lrk ,§' K keue;s iqÿ wjlafIamhla ,enqKs' th wï,j,
wk;=rej tu ødjKhg BaCl2 tla lrk ,§' th wï,j, Èh fkdjqKs'
4' X ys c,Sh ødjKhg NaOH ìxÿ jYfhka tla uq,skau tla lrk ìxÿ u.ska iqÿ mdg wjlafIamhla
lrk ,§' iEÿks' ;jÿrg;a tla lrk úg wjlafIamh Èhúh'
5' X ys c,Sh ødjKhg c,Sh NH3 ìxÿ ne.ska tla uq,skau tla lrk ìxÿ u.ska iqÿ mdg wjlafIamhla
lrk ,§' iEÿks' jeämqr tla lrk úg tu wjlafIamh Èh
úh'

(i) Y jdhqj l=ula o@

(ii) Z iqÿ wjlafIamh l=ula o@
(iii) K iqÿ wjlafIamh l=ula o@
(iv) Y c,Sh ødjKhl iy H2O2 w;r m%;sl%shdj ,shkak'
(v) ^4& ys ,efnk iqÿ wjlafIamh l=ula o@ jeämqr c,Sh NaOH iu. th Èhjkafka l=ula ksid o@
(vi) ^5& ys ,efnk iqÿ wjlafIamh l=ula o@ jeämqr NH3 c,Sh ødjKh tla l< úg th Èhùug fya;=j
l=ula o@ ^ ,l+Kq 5'0 hs &

(c) ødjKhl wvx.= Fe2+ , Fe3+ úYaf,aIKh i|yd my; olajd we;s mshjr wkq.ukh lrhs'

mshjr I
Fe2+ , Fe3+ whk wvx.= X kï ødjKhlska 25 cm3 la f.k thg idkaøKh 0.001 mol dm-3 KMnO4
ødjKhlska 75 cm3 la tla lrk ,§' tys§ ,enqKq oï meye ødjKfhka 25 cm3 la f.k idkaøKh
0.001 mol dm-3 jQ ìhqfrÜgqfõ we;s Tlai,sl wï,h (H2C2O4) iu`. wkqudmkh lrk ,§' tys§
,enqKq ìhqfrÜgq mdGdxlh 10 cm3 la úh'

mshjr II
Fe2+ iy Fe3+ whk wvx.= X kï ødjKhlska 25 cm3 la f.k thg jeämqr SO2 jdhqj nqnq,kh lrk
,§' bk wk;=rej b;sß SO2 bj;a lr thg 0.001 mol dm-3 KMnO4 ødjKfhka 75 cm3 la tl;= lr
tu ødjKfhka 25 cm3 la f.k thg kej; 0.001 mol dm-3 Tlai,sl wï,h iuÕ wkqudmkh l<
úg ìhqfrÜgq mdGdxlh 6.5 cm3 úh'

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2022/02-S-IIA/B - 15 -

(i) fuys§ isÿjk ish¨ TlaislrK TlaisyrK m%;sl%shd i|yd ;=,s; ridhksl iólrK ,shkak'
(ii) X ødjKfha wvx.= Fe2+ iy Fe3+ whk idkaøK fjk fjku fidhkak'
(iii) wjia:d fofla § KMnO4 tlal< miq wj¾K ødjKhla ,enqKs kï fuu úYaf,aIKh id¾:l fõ ±hs
fya;= olajñka meyeÈ,s lrkak'
^ ,l+Kq 5'0 hs &

10. (a) ld¾ñl ksIamdokh l< yels ixfhda. lSmhla w;r iïnkaO;dj ±lafjk my; .e,Sï igyk i,lkak'

R3 R4
R1 R2 yqKq.,a


R1 : R2 1 : 3
wkqmd;hg M4
m%;sl%shdfõ  
M1
^wjYH ;;aj&

NH4Cl c,h P4
P1 P9


c,h

^wjYH ;;aj& P5
jd;h
M2

P6
P2 i,a*¾ HCl
^wjYH ;;aj&
P7
M3
P3 nyq
wjhùlrKh
P8

R u.ska iajNdúl wuqøjHh;a" M u.ska ksIamdok l%shdj,s;a" P u.ska iEfok jeo.;a M,;a ksrEmKh
flf¾'
(i) I. R1 yd R2 wuqøjH ,nd.kafka flfia o@
II. R3 yd R4 wuqøjH y÷kd.kak' ridhksl iQ;% ,shkak'
III. M1 , M2 yd M3 l%shdj,Skag wjYH fN!;sl yd ridhksl ;;aj fjka fjka j olajkak'
IV. M2 , M3 l%shdj,Ska ms<sfj<ska P2 yd P3 M, iE§fï mshjrj,g wod< ;=,s; ridhksl iólrK
,shkak'
V. P1 , P2 yd P3 M, j, tla m%fhdackhla ne.ska olajkak'
VI. M4 l%shdj,sfha § P4 M,h iE§u i|yd R4 odhl jk wdldrh meyeÈ,s lrkak'
(ii) I. P5  P6  P7  P8 mßj¾;kfha § P5  P6 olajd M,j, ridhksl iQ;% ,shkak'
II. P8 M,fhka iEfok Cl wdfoaYs; nyq wjhjlfha" tal wjhjlh yd mqkrdj¾;S tallh ,shkak'
III. by; nyq wjhjlfha [P8] .=K" tys jHqyh iuÕ ne£ we;s wdldrh fláfhka meyeÈ,s lrkak'
IV. by; nyq wjhjlfha [P8] laf,daÍka fjkqjg fnkaiSka wdfoaY jQfha kï" iEfok nyq wjhjlfha
ku yd jHqyh olajkak'
^ ,l+Kq 5'0 hs &

DIAMOND - Chemistry Special Papers - 2022 ohd,a fyar;a [B.Sc. (Hon’s) / P.G.D.E. (Colombo)]
AL/2021/02/S-IA/IIA - 16 -

(b) iam¾Y l%uh u.ska i,a*shqßla wï,h ksmoùfï l%shdj,sh weiqßka my; m%Yakj,g ms<s;=re imhkak'
(i) fuys§ wdrïNl øjH f,i Ndú; lrk øjH i|yka lrkak'
(ii) wdrïNl øjH l%shd lsÍfuka ,efnk M,h W;afm%arl yuqfõ jdhqf.da,Sh O2 iu`. isÿjk m%;sl%shdj
,shkak'
(iii) by; m%;sl%shdfjka iEfok M,h ixY=oaO;djfhka by< w.hlg m;a lsÍug l< hq;= l%shdj,shla
fláfhka úia;r lrkak'
(iv) fuys§ b;d idkaø (98 %) H2SO4 fhdod .ekSu isÿ fõ' thg fya;=j úia;r lrkak'
(v) by; úia;r l< isÿùug wkqj 98 % idkaø H2SO4 ,nd .ekSfï m%;sl%shdj ,shkak'
(vi) fuys§ wjika jYfhka 100 % idkaø H2SO4 ,nd .ekSfï m%;sl%shdj ,shkak'
(vii) H2SO4 ys ld¾ñl m%fhdack ;=kla i|yka lrkak'
(viii) H2SO4 W;afm%Arl f,i fhdod .ksñka fíla,hsÜ nyqwjhúlh iE§h yel'
I. fíla,hsÜ nyqwjhjlh"
(x) iajdNdúl fyda lD;%su nyqwjhjl
(y) wdl,k fyda ix.Kk nyqwjhjl
f,i j¾.SlrKh lrkak'
II. fíla,hsÜ iE§fï§ Ndú; jk tal wjhjl fol kï lrkak'
III. fíla,hsÜ nyqwjhjlfhys jHqyh wÈkak'
IV. nyqwjhjl tajdfha ;dmc .=K wkqj j¾. follg fnÈh yel' tu j¾. fol i|yka lrkak'
fíla,hsÜ ñka l=uk j¾.hkag wh;a±hs ,shkak'
V. fíla,hsÜ nyqwjhjlfha Ndú;hla i|yka lrkak'
^ ,l+Kq 6'0 hs &
(c) (i) mßir ¥IKh jk my; l%shd i|yd odhl jk ixfhda. y÷kd.kak'
I. ´fidaka ia:rh CIh ùu'
II. yß;d.dr wdprKh'
III. m%ldY ridhksl OQñldj'
(ii) iajNdúlj ´fidaka iE§u yd úkdY ùfï l%shdj,shg wod< m%;sl%shd olajkak'
(iii) (Chloro Fluoro Carbon) u.ska isÿjk ´fidaka CIhùug wod< m%;sl%shd olajkak'
(iv) yß;d.dr wdprKhg fhÈh yels ms<shï ;=kla i|yka lrkak'
(v) wï, jeis we;sùu fláfhka meyeÈ,s lrkak'
(vi) wï, jeis we;sùfï isÿjk wys;lr n,mEï folla i|yka lrkak'

^ ,l+Kq 4'0 hs &

*****

olaIhka w;r w;s olaIhl= ùug