R E V I S I O N 2021

C H E M I S T R Y
Amila Dasanayake
Past Papers Essay - Unit 13 (MBBS Undergraduate, University of Colombo)

jHqy.; rpkd
1.
i. my; ±lafjk iïu; TlaisyrK úNj i,lkak'
EO[Br2(l)/ Br − (aq)] = 1.07V
EO[I2(s)/ I − (aq)] = 0.54V

I. 1.0moldm-3 c,Sh KI ødjKhlg øj fn%daóka tla l< úg isÿfj;ehs Tn wfmalaId lrk m%;sl%shdj
l=ula o@

II. by; mÍlaIKfha § Tn wfmalaId lrk j¾K úm¾hdi ,shd olajkak'

ii. my; i`oyka úoHq;a ridhksl iólrKh i,lkak'

Mg(s) + 2H + (aq) Mg 2+ (aq) + H2(g)

I. by; m%;sl%shdjg wkql+, jk .e,ajdkSh fldaIfhys lef;daãh m%;sl%shdj ,shkak'

II. by; fldaIh ksrEmKh lsÍu i`oyd iïuq;sl wxlkh (conventional notation), ,jK fia;=jla wvx.=
lrñka ,shd olajkak'

III. by; fldaI m%;sl%shdj bÈßhg hk úg tkafg%dmsh jeäfõ o, wvqfõ o, ke;fyd;a ksh; j mj;S o@
Tfí ms<s;=r ieflúka meyeÈ,s lrkak'

IV. T WIaK;ajfha § by; m%;sl%shdj iajhxisoaOj isÿùu i`oyd tka;e,ams fjki (ΔH) iy tkafg%dms fjki
(ΔS) w;r ;sìh hq;= iïnkaO;djh l=ula o@

(2012)

Past Papers 1 Chemistry - wñ, oikdhl

 2. M 2+ (aq) f,day whkh M 3+ (aq) njg TlaislrKh lsÍu i`oyd laf,daÍka jdhqj Tlaisldrlhla f,i fhdod
.kS' my; o;a; imhd we;'

25℃ oS iïu; tka;e,ams fjki

m%;sl%shdj
ΔHO(kJ mol-1)
M(s) M + (aq) + e - 32.5
M(s) M 2+
(aq) + 2e - 48.5
M(s) M 3+ (aq) + 3e - 82.5
Cl2(g) +2e 2Cl (aq)
−
- 334.0

EO M 3+ / M 2+ = +0.77V EO Cl2/ Cl− = +1.36V

by; TlaislrKh úoHq;a ridhkslj isÿ lrkq ,efí'

i. TlaislrK yd TlaisyrK l%shdj,s i`oyd w¾O m%;sl%shd ,shd olajd fldaI m%;sl%shd jHq;amkak lrkak'

TlaislrK m%;sl%shdj :

TlaisyrK m%;sl%shdj :

fldaI m%;sl%shdj :

ii. by; m%;sl%shdfjys EOcell w.h uekSu i`oyd wjYH mÍlaIKd;aul wegjqu my; rEmfhys oelafõ'

wod< wjia:d j, § fN!;sl wjia:dj, idkaøKh/mSvkh i`oyka lrñka A isg E y`ÿkd .kak'

A - …………………………………………………… D - ……………………………………………………

B - …………………………………………………… E - ……………………………………………………

C - ……………………………………………………

Past Papers 2 Chemistry - wñ, oikdhl

 iii. by; fldaIh i`oyd EOcell .Kkh lrkak'

iv. (i) fldgfiys § we;s fldaI m%;sl%shdj i`oyd 25℃ ys § iïu; tka;e,ams fjki (ΔH0) .Kkh
lrkak'

v. fldaI m%;sl%shdj i`oyd iïu; .síia Yla;s fjki, ΔGO iy EOcell w;r iïnkaOh ΔGO =-K EOcell u`.ska
fokq ,efí' fuys K = 1.93 × 105 J mol-1V-1 fõ'
by; fldaI m%;sl%shdj i`oyd, 25℃ oS, iïu; .síia Yla;s fjki (ΔG0) .Kkh lrkak'

vi. by; fldaI m%;sl%shdj i`oyd, 25℃ oS, iïu; tkafg%dms fjki (ΔS0) .Kkh lrkak'

(2013)

Past Papers 3 Chemistry - wñ, oikdhl

 rpkd

1. 25℃ oS, ,nd .;a my; i`oyka o;a; Tng imhd § we;'

EO Mg 2+ (aq)/Mg(s) = - 2.37V
EO Pb2+ (aq)/Pb(s) = - 0.126V

i. iïu; ;;a;aj hgf;ys l%shd lrk, Pb2+ (aq)/Pb(s) bf,lafg%davhlska yd Mg 2+ (aq)/Mg(s)

bf,lafg%davhlska iukaú;, úoHq;a ridhksl fldaIhl úoHq;a .dul n,h ^ú'.'n'& 25℃ § .Kkh lrkak'
ii. ms<s.;a wxlkh Ndú;fhka by; i`oyka úoHq;a ridhksl fldaIh ,shd olajkak'
iii. by; i`oyka úoHq;a ridhksl fldaIfhka Odrdjla ,nd.kakd úg lef;davfhys yd wefkdavfhys isÿjk
w¾O fldaI m%;sl%shd i`oyd ;=,s; ridhksl iólrK ,shd olajkak'
(2000)

2. L iy M hkq oaú ixhqc legdhk muKla idok f,day folls' 25℃ WIaK;ajfha §, L ys lene,a,la MSO4 ys
c,Sh ødjKhla ;=< ;nk ,§' ødjKfha L f,dayh ødjKh jk nj;a M f,dayh wjlafIam$ksê.; jk nj;a
ksÍlaIKh lrk ,§'
25℃ § fuu f,day foflka tll iïu; bf,lafg%dav úNjh EO -1.23 V jk w;r, wksla f,dayfha th -2.12 V
fõ'

i. by; ksÍlaIK j,g wkql+, ridhksl m%;sl%shdj i`oyd iólrK ,shd olajkak'
ii. by; i`oyka (i) g wkqrEm ridhksl iólrKhg wod< TlaislrK yd TlaisyrK w¾O m%;sl%shd ,shkak'
iii. tla;rd úoHq;a ridhksl fldaIhla úi¾ckfha § (during discharge), isÿjk Y=oaO fldaI m%;sl%shdj (i) by;
ys ±lafjk m%;sl%shdju fõ' iïu; ;;a;aj hgf;ys mj;S hehs i,lñka iïu; wxlk Ndú;fhka fuu
úoHq;a ridhksl fldaIh ,shd olajkak'
iv. by; (iii) ys i`oyka úoHq;a ridhksl fldaIfhys úoHq;a .dul n,h ^ú'.'n'& 25℃ § .Kkh lrkak'

3. úoHq;a úÉfcaok l%uhla u`.ska ldnka l+rla u; ixY=oaO Cu f,day ia;rhla ksê.; lr .ekSu i`oyd fmkajd
we;s wdldrfha ( P iy Q bf,lafg%dav we;s ) úoHq;a mßm:hla Ndú;d lrk ,§' P fyda Q hk foflka tllaj;a
Cu fkdfõ'

i. bf,lafg%dav foflka (P fyda Q), Cu ksê.; jk bf,lafg%davh y`ÿkd f.k th wefkdavho lef;davho
hk j. i`oyka lrkak'
ii. Z jYfhka Ndú;d l< yels iqÿiq úoHq;a úÉfcaoHhla fhdackd lrkak'
iii. wdrïNfha § lef;davfha § isÿjk whksl w¾O m%;sl%shdj ,shkak'
(2001)

Past Papers 4 Chemistry - wñ, oikdhl

 4. hlv úLdokh yd iïnkaO w¾O m%;sl%shdjka folla Bg wod< iïu; bf,lafg%dav úNjhka iu`. my; §
we;'

Fe(s) Fe2+ (aq) + 2e ; EO = -0.44V

2H2O + O2(g) + 4e 4OH − (aq) EO = +0.40V

i. by; i`oyka w¾O m%;sl%shdjka muKla i,lñka hlv úLdokfha § isÿjk iuia: m%;sl%shdj i`oyd ;=,;
s
ridhksl iólrKh ,shkak'
ii. úoHq;a ridhksl fldaI ms<sn`o Tfí ±kqu Ndú;d lrñka fldaI úi¾ckfha § by; i`oyka iuia;
m%;sl%shdj isÿjk úoHq;a ridhksl fldaIfha iïu; ú'.d'n .Kkh lrkak'
iii. lef;daãh wdrlaIK l%uh u`.ska hlv gexlshl úLdokh je<elaùug wjYHj we;' wod< uQ,O¾uh
fláfhka i`oyka lrñka my; úia;r imhd we;s Q yd R f,day fol w;frka fï i`oyd l=uk f,dayh
iqÿiq ±hs wfmdaykh lrkak'

Q 2+ (aq) + 2e Q(s) ; EO = -0.60V

R 2+ (aq) + 2e R(s) ; EO = -0.13V

(2002)

5. ksIal%Sh bf,lafg%dav fhdod .ksñka ;kql c,Sh CuCl2 ødjKhla úoHq;a úÉfcaokh lsÍul § ffioaOdka;slj
isÿúh yels ish¨u w¾O m%;sl%shd i`oyd ;=,;
s iólrK ,shkak'
fuu tla tla w¾O m%;sl%shdjka isÿjkafka lef;davfha § o wefkdavfha § o hk j. i`oyka lrkak'

(2003)

6. A hkq AgCl ys ix;Dma; c,Sh ødjKhla jk w;r, B hkq AgCl j,ska ix;Dma; 0.1moldm-3 c,Sh ødjKhls'

25℃ § AgCl ys ødjH;d .=Ks;h = 1×10−10 mol2dm-6 (Ag = 107.0, Cl = 35.5)

i. 25℃ § A iy B hk tla tla ødjKfha Ag + (aq) idkaøKh yd mgdm-3 j,ska AgCl ys ødjH;djh hk fïjd
.Kkh lrkak'
ii. A iy B hk ødjK foflka tlla fhdod .ksñka, l=vd ;T uqoaola Ag j,ska úoHq;a wdf,amkh lsÍu i`oyd
fhdod .; yels, mÍlaIKd;aul wegjqul, kï lrk ,o lgq igykla w`Èkak' bf,lafg%dav j, O%eùh;djh
( + fyda – nj) olajd, wefkdavh yd lef;davh meyeÈ,sj kïlrkak' wefkdavh yd lef;davh i`oyd fhdod
.kakd f,day kï lrkak'
iii. úoHq;a f,daydf,amkfha YS%>%;djh wvqjk ;rug, ,efnk wdf,amkfha ishqï nj fukau È,sfik iq`M nj o
jeäjk nj fidhdf.k we;' Tn i;= ridhksl pd,kh ms<sn`o ±kqu Wmfhda.S lr f.k by; (ii) jk
mÍlaIKhg jvd;au iqÿiq jkafka A iy B w;frka l=uk ødjKh o hkak, fya;= olajñka wfmdaykh
lrkak'
iv. is,aj¾ ,jKhla c,Sh KCN ødjKhl Èh l< úg my; iu;=,;
s ;djh we;s fõ'
[ Ag(CN2)]- (aq) ⇌ Ag + (aq) + 2CN − (aq)
ld¾ñl Ag, úoHq;a f,daydf,amkh i`oyd c,Sh KCN ys is,j
a ¾ ,jKhl ødjKhla, tu ,jK idkaøKfhkau
hq;a is,aj¾ ,jKfha c,Sh ødjKhlg jvd fhda.H jkafka uka±hs meyeÈ,s lrkak'
by; iu,s;;djfha iu;=,;
s ksh;fhys úYd,;ajh .ek woyia olajkak'

Past Papers 5 Chemistry - wñ, oikdhl

 v. ldnksl Tlaisydrl i`oyd jk fgd,ka ߧ levm;a mÍlaIdfõ § Tlaisldrlh f,i c,Sh AgNO3 ødjKhla
fkdj, wefudakSlD; AgNO3 ødjKhla fhdod .kafka wehs ±hs myod fokak'
vi. 0.15A l ksh; úoHq;a Odrdjla fhdod .ksñka, ñks;a;= 40 l ld,hla mqrd ;U uqoao Ag j,ska úoHq;a
wdf,amkh l< úg uqoafoa ialkaOfha jeä ùu .Kkh lrkak' (*erfâ ksh;h, F = 96,540C mol-1)
vii. úoHq;a úÉfcaolfhys Ag + (aq) idkaøKh jeä jk úg, Ag| Ag + bf,lafg%davfhys bf,lafg%dav úNjh jvd
Ok w.hla .kS' A iy B ødjK hq.,h, Ag l+re folla iy ,jK fia;=jla hk fïjd muKla Ndú;d
lrñka idod .; yels úoHq;a ridhksl fldaIhl kï lrk ,o lgq igykla w`Èkak' Tfí lgq igyfkys
wefkdavh yd lef;davh meyeÈ,sj kï fldg, wefkdav ødjKh iy lef;dav ødjKh hk fïjd A fyda B
fyda hkqfjka y`ÿkajd fokak'

(2005)

7.
i. Na2SO4 l=vd m%udKhla wvx.= 0.1moldm-3 c,Sh CuSO4 ødjK 100cm-3 la, tll ialkaOh 10.0g jQ
fldm¾(Cu) bf,lafg%dav folla Ndú;d lrñka úoHq;a úÉfcaokh lrk ,§' mÍlaIKfha § 300mA Odrdjla
ñks;a;= 9.65 l ld,hla ;=< hjk ,§' fuu úoHq;a úÉfcaokh mÍlaIKh wjidkfha §,
A. lef;davfha ialkaOh
B. wefkdavfha ialkaOh iy
C. ødjKfha Cu2+ whk idkaøKh hk fïjd .Kkh lrkak'

igyk : bf,lafg%dak ujq, tll wdfrdamKh = 96500C, Cu = 63.5

ii. by; (i) ys úia;r lrk ,o mÍlaIKh wjidkfha § úoHq;a úÉfcaoH ødjKhg c,h 100cm3 tl;= lr,
ødjKh ñY%lr, 300mA Odrdjla ;j;a ñks;a;= 9.65 ;=< heùfuka kej;;a úoHq;a úÉfcaokh lrk ,§'
fuu mÍlaIKh wjidkfha §,
A. lef;davfha ialkaOh
B. wefkdavfha ialkaOh iy
C. ødjKfha Cu2+ whk idkaøKh hk fïjd wfmdaykh lrkak'
iii. Pb2+ iy Cu2+ hk whk foj¾.hu wvx.= ødjKhlska Pb2+ whk muKla úi¾ckh lsÍu i`oyd úoHq;a
úÉfcaokh iqÿiq l%uhla fõ o@ Tfí ms<s;=r i`oyd fya;= olajkak'

EO Cu2+ (aq)/Cu(s) = +0.34V EO Pb2+ (aq)/Pb(s) = -0.13V

(2006)

Past Papers 6 Chemistry - wñ, oikdhl

 8. iïu; bf,lafg%dav ;=kla Ndú;d lr ms<sfh, l< A iy B hk úoHq;a ridhksl fldaI foll úia;r my;
olajd we;' fuys P iy Q hkq f,day fõ' (e.m.f = úoHq;a .dul n,h)

m<uq bf,lafg%davh Ok fojk bf,lafg%davh e.m.f/v

H + (aq)/H2(g) P 2+ (aq)/P(s) 1.25

P 2+ (aq)/P(s) Q2+ (aq)/Q(s) 0.95

i. Q f,dayfha iïu; bf,lafg%dav úNjh, EO .Kkh lrkak'

ii. B úoHq;a ridhksl fldaIfha fldaI m%;sl%shdj ,shkak'
iii. B fldaIfha P 2+ (aq) idkaøKh 2.0moldm-3 olajd jeä l< úg fldaIfhys e.m.f ys Tn n,dfmdfrd;a;=
jk fjki .=Kd;aulj mqfrdal:kh lrkak'

(2007)

9. w¨; iE¥ 0.1moldm-3 c,Sh KI ødjKhlg *sfkdma;e,Ska ìxÿ lsym

s hla tl;= lrk ,§' fuu ødjKh fyd`Èka
fid,jd bkamiq ldnka bf,lafg%dav fhdod ksYÑ
a ; ld,hla ;=< úoHq;a úÉfcaokh lrk ,§' ødjKh ;=<ska hejQ
Odrdj ksh;hla f,i ;nd .kakd ,§'
i. úoHq;a úÉfcaokhg fmr ødjKfha j¾Kh l=ula o@
ii.
I. wefkdav m%;sl%shdj
II. lef;dav m%;sl%shdj iy
III. fldaI m%;sl%shdj hk fïjd i`oyd ;=,;
s ridhksl m%;sl%shd ,shd olajkak'

iii. úoHq;a úÉfcaokh wdrïNh;a iu`. bf,lafg%dav wjg isÿ úh yels j¾K úm¾hdi olajkak'
iv. úoHq;a úÉfcaok ld, iSudfjka miq b;sß jQ I − whk j, Nd.h ks¾Kh lsÍu i`oyd iqÿiq l%uhla fhdackd
lrkak' (mÍlaIKd;aul úia;r wkjYH h')
v. 0.1moldm-3 KI fjkqjg 0.5moldm-3 KI Ndú;d lf<a kï b;sß I − whk j, Nd.h (iv) ys w.fhka
fjkia fõ o@ Tfí ms<s;=r fláfhka meyeÈ,s lrkak'
vi. fjk;a mÍlaIKhl § ldnka bf,lafg%dav Ndú;d lr CuSO4 ødjKhla úoHq;a úÉfcaokh lrk ,§'
I. bf,lafg%dav u; II. ødjKh ;=<

Tng ksÍlaIKh l< yels fjkialï fudkjd o@ wod< bf,lafg%dav m%;sl%shd ,shd olajkak'

(2008)

Past Papers 7 Chemistry - wñ, oikdhl

 10. my; § we;s úoHq;a ridhksl fldaIh i,lkak'

i. l=uk bf,lafg%davh (A fyda B) lef;davh o@

ii. l=uk bf,lafg%davh (A fyda B) iDK f,i wdfrdams; o@
iii. A ys isÿjk bf,lafg%dav m%;sl%shdj i`oyd ;=,s; iólrKhla ,shkak'
iv. B ys isÿjk bf,lafg%dav m%;sl%shdj i`oyd ;=,s; iólrKhla ,shkak'
v. iuia; fldaI m%;sl%shdj i`oyd ;=,;
s iólrKhla ,shkak'
vi. by; (iii) iy (iv) fldgia j, § Tn § we; whksl úfYaI iEfok nj fmkakqï lsÍu g tla ridhksl
mÍlaIKh ne.ska fokak'
vii. by; (v) fldgfia § Tn § we;s iuia; fldaI m%;sl%shdj iq,N iajdNdúl l%shdj,shl § isÿ fõ' fuu
l%shdj,sh kï lrkak'
(2009)
11. 25℃ oS, l%shdldÍ jk, my; i`oyka úoHq;a ridhksl fldaI fol i,lkak'

(i) isg (iii) f;la m%Yak, úoHq;a ridhksl fldaIh yd iïnkaO fõ'

i. fldaIfhys úoHq;a .dul n,h( ú'.d'n'e.m.f) .Kkh lrkak'

ii. fldaIfhys 1.0moldm-3 MgCl2 ødjKh fjkqjg, 1.0moldm-3 MgSO4 ødjKhla Ndú;d lf<a kï, fldaI
ú'.d'n' fjkia úh yels o@ Tfí ms<s;=r fláfhka meyeÈ,s lrkak'
iii. ,jK fia;=fjys l%shdldÍ;ajh l=ula o@ ,jK fia;=j iE§u i`oyd Ndú;d l< yels ixfhda.hlg
WodyrKhla fokak'

Past Papers 8 Chemistry - wñ, oikdhl

 (iv) iy (v) m%Yak, A fldaIfhys we;s bf,lafg%dav fol Cu lïìhlska hd l< úg ,efnk wjia:dj yd
iïnkaO fõ'
iv. l=uk bf,lafg%davh lef;davh f,i l%shd lrkafka ±hs i`oyka lrkak'
v. my; i`oyka oE i`oyd ;=,s; iólrK ,shkak'
I. lef;daäl m%;sl%shdj
II. wefkdaäl m%;sl%shdj
III. iuia; fldaI m%;sl%shdj

(vi) isg (viii) f;la m%Yak A fldaIfhys Cu l+r iy Mg l+r ms<sfj,ska B fldaIfhys E bf,lafg%davhg iy F
bf,lafg%davhg Cu lïì u`.ska hd l< úg ,efnk ieliqu yd iïnkaO fõ'

vi. B fldaIfhys l=uk bf,lafg%davh lef;davh f,i l%shd lrhs o@

vii. my; § we;s bf,lafg%dav j, isÿjk m%;sl%shd i`oyd ;=,s; iólrK ,shkak'
I. E bf,lafg%davh
II. F bf,lafg%davh
viii. fldaI ieliqfuys .,d hk Odrdj ksh; kï,
a) E iy F bf,lafg%dav foflys b) B fldaIfhys H2SO4 idkaøKh jeä
j¾.M,h jeä lrk úg lrk úg,
§ we;s ld, m%dka;rhla ;=< F bf,lafg%davfh ys iEfok M, m%udKfhys Tng wfmalaId l< yels
fjki i`oyka lrkak'
(2010)

12.
i. iïu; wjia:dfõ we;s ue.akSishï bf,lafg%davhla lgq igyka lrkak' tys ish¨ fldgia kï lrkak'
ii. bf,lafg%davhl ksrfmalaI úNjh ueksh fkdyelafla uka±hs fláfhka meyeÈ,s lrkak'
iii. ixY=oaO ue.akSishï bf,lafg%davhla iy iújr ldnka bf,lafg%davhla Ndú;fhka ;kk ,o, my;
±lafjk úoHq;a ridhksl fldaIh i,lkak' fuu bf,lafg%dav fol okakd idkaøKhlska hq;a MgCl2 úoHq;a
úÉfcaoH ødjKhl rEmfha olajd we;s mßÈ .s,ajd we;'

Mg bf,lafg%davfhys yd C bf,lafg%davfhys iu;=,s; m%;sl%shd iy tajdfha iïu; bf,lafg%dav úNj my;

olajd we;'
Mg 2+ (aq) + 2e ⇌ Mg(s) Eθ = -2.37V
O2(g) + 2H2O(l) + 4e ⇌ 4OH − Eθ = 0.40V

i. fldaIfhys lef;davh y`ÿkd.kak'

Past Papers 9 Chemistry - wñ, oikdhl

 ii. iïu; wjia:dfõ §, by; fldaIfhys úoHq;a .dul n,h (𝑒. 𝑚. 𝑓) .Kkh lrkak'
iii. bf,lafg%dav, ikakdhl lïìhlska ndysr j iïnkaO l< úg isÿjk wefkdaãh m%;sl%shdj, lef;daãh
m%;sl%shdj iy iuia; fldaI m%;sl%shdj i`oyd ;=,;
s iólrK ,shkak'
iv. fldaIfha úoHq;a úÉfcaoH f,i MgCl2 ødjKh fjkqjg tu idkaøKfhka u hq;a NaCl ødjKhla Ndú;d
l<fyd;a l=ula ksÍlaIKh lsÍug Tn n,dfmdfrd;a;= jkafka o@ Tnf.a ms<s;=r fláfhka meyeÈ,s
lrkak'
v. by; fldaIh mßm:hlg iïnkaO l< úg, ksmofjk Odrdj ld,h;a iu`. l%ufhka wvqfõ' Odrdj
i;=gqodhl uÜgulg kej; by< kexùu i`oyd Ndú;d l< yels l%u folla i`oyka lrkak' Tn
i`oyka l< l%uj, moku fláfhka meyeos,s lrkak'

(2011)

13. ld¾ñl l%shdj,shl § ksmofjk wmc,fhys (pH = 7.0) D j¾Kj;a ixfhda.h wvx.= fõ' j¾Kh bj;a lsÍu
i`oyd fuu ixfhda.h úoHq;a ridhkslj TlaislrKh lsÍu msKsi mú;%d.drhla iE§ug ie,iqï lr we;' D
ixfhda.h c,Sh udOHfha § úoHq;a ridhksl j TlaislrKh ùu my; mßÈ isÿfõ'

D(aq) A2+ (aq) + B(aq) + 2e

2 H2O(l) +2e H2(aq) + 2OH-(aq)

wmc,h ;=< D ixfhda.fhys idkaøKh 0.001moldm-3 nj fidhd .kakd ,§'

i. Pt bf,lafg%dav folla iys; úoHq;a úÉfcaoH fldaIhla u`.ska 100 mA ksh; Odrdjla fhdod .ksñka 1.0 dm3
wmc,h ksheÈhl we;s D ixfhda.h iïmQ¾Kfhkau úoHq;a ridhksl j TlaislrKh lsÍug .; jk ld,h
.Kkh lrkak' (bf,lafg%dak 1.0 mol ys wdfrdamKh = 96500 C)
ii. c,Sh udOHfha § A(OH)2 iïmQ¾Kfhkau whkSlrKh fõ kï úoHq;a ridhksl TlaislrKfhka miqj wmc,h
ksheÈfha pH w.h .Kkh lrkak'
iii. by; l¾udka;h, D ixfhda.h wvx.= wmc,h 10dm3s-1 YS>%;djhlska msg lrkafka kï, D ixfhda.h
iïmQ¾Kfhkau TlaislrKh lsÍug úoHq;a úÉfcaoH fldaIhg iemhsh hq;= wju Odrdj .Kkh lrkak'

(2014)

14. 25℃ § fY%aKs.;j iïnkaO lr we;s úoHq;a ridhksl fldaI folla my; rEmfha fmkajd we;'

Past Papers 10 Chemistry - wñ, oikdhl

 M1, M2 iy M3 f,day ms<sfj,ska tajdfha M12+ (aq), M22+ (aq) iy M32+ (aq) whkj, c,Sh ødjK j, .s,j
a d we;'
ish¨ u ødjKj, idkaøK 1 moldm-3 fõ' M1 iy M3 f,day j, iïu; bf,lafg%dav úNj my; § we;'

EO M12+ (aq)/M1(s) = -2.36V

EO M32+ (aq)/M3(s) = 0.34V

i. tla tla fldaIfha wefkdavh yd lef;davh fya;= olajñka y`ÿkd.kak'

ii. tla tla fldaIfha wefkdavh yd lef;davh u; isÿ jk m%;sl%shd ,shd olajkak'
iii. P ixLHdxl fjda,Ü
a ógrfha mdGdxlh .Kkh lrkak'
iv. fldaIh 1 ys úoHq;a .dul n,h (EOcell(1)) +1.60v nj fidhd f.k we;' M22+ (aq)/M2(s) bf,lafg%davfha
iïu; bf,lafg%dav úNjh EO(M22+ (aq)/M2(s)) .Kkh lrkak'
v. fldaIh 2 ys úoHq;a .dul n,h (EOcell(2)) .Kkh lrkak'
vi. by; moaO;shg wu;rj M4 f,dayhla yd M42+ (aq), 1 moldm-3 ødjKhla muKla Tng imhd we;akï
EO(M42+ (aq)/M4(s)) ys w.h ks¾Kh lsÍu i`oyd mÍlaIKd;aul l%uhla fláfhka fhdackd lrkak'
(2015)
15. my; ±lafjk oE Tng imhd we;'

• Al(NO3)3, Cu(NO3)3 iy Fe(NO3)2 j, 1.0 moldm-3 c,Sh ødjK

• Al, Cu iy Fe f,day l+re
• ,jK fia;= j, Ndú;d lsÍug wjYH ridhksl øjH
• ikakdhl /yeka (Conducting wires) iy îlr

óg wu;rj my; ±lafjk o;a;o imhd we;'

EO( Fe2+ /Fe) = -0.44v, EO( Al3+ /Al) = -1.66v, EO( Cu2+ /Cu) = +0.34v

i. by; i`oyka øjH Wmfhda.S lr .ksñka f.dvke`.sh yels úoHq;a ridhksl fldaI ;=k rEmSh.;
lrkak' tla tla fldaIfhys wefkdavh yd lef;davh tajdfha ,l=Kq iu`. olajkak'
ii. by; (i) fldgfiys w`Èk ,o tla tla úoHq;a ridhksl fldaIfha
I. fldaI wxlkh fokak'
II. EOcell ks¾Kh lrkak'
III. fN!;sl ;;aj olajñka bf,lafg%dav m%;sls%hd i`oyd ;=,;
s ridhksl iólrK fokak'
iii. my; ±lafjk l=uk ixfhda. ^h& ,jK fia;= j, Ndú;hg iqÿiq ±hs fya;= olajñka myod fokak'
NaOH , NaNO3 , weisála wï,h

iv. wdrïNfha § jeäu EOcell fmkakqï lrk úoHq;a ridhksl fldaIh i,lkak' fuu úoHq;a ridhksl
fldaIh ilia lr we;af;a tys tla tla l=àrhg wdod< ødjK j, mßudjka iudk jk f,I nj;a
tajdfha mßudjka mÍlaIKh isÿ lrk ld,h ;=< § fkdfjkia jk nj;a Wml,amkh lrkak'
v. fuu fldaIfhys bf,lafg%dav fol ikakdhl /yeklska iïnkaO lr hï ld,hlg miq wefkdav l=àrh
;=< we;s f,day whk idkaøKh C moldm-3 nj fidhd .kakd ,§' lef;dav l=àrh ;=< we;s f,day
whk idkaøKh C weiqßka m%ldY lrkak'

(2016)

Past Papers 11 Chemistry - wñ, oikdhl

Past Papers 12 Chemistry - wñ, oikdhl