1. Draw a qualitative graph plot of concentration vs.

time for a zero order reaction and also

draw the same for a non-zero order reaction.

2. 2B k→ B2 Express the rate of this single step reaction in terms of –d[B]/dt.

3. Find the dimension of the rate constant for ½ order reaction.
4.

How much of 10.0 g of radioactive copper will be left after 6 h in the first order radioactive
decay reaction given above?
5. The first-order decomposition of hydrogen peroxide in a suitable medium is characterized by
a rate constant 3×10-2 min-1. Find the time to complete one third of the reaction.
6. A reaction has a rate law of the following form: r = k [A]a [B]b Consider the following set of
data. Find out a and b.

Trial Rate Initial Conc. Initial Conc.

(mole L-1 sec-1) of A (mole L-1) of B (mole L-1)

1 2.73 0.100 0.100

2 6.14 0.150 0.100

3 2.71 0.100 0.200

I. Draw a qualitative graph plot of concentration vs. time for a zero order reaction and also
draw the same for a non-zero order reaction.

II. 2B k→ B2 Express the rate of this single step reaction in terms of –d[B]/dt.
III. Find the dimension of the rate constant for ½ order reaction
IV.

How much of 10.0 g of radioactive copper will be left after 6 h in the first order radioactive
decay reaction given above?
V. The first-order decomposition of hydrogen peroxide in a suitable medium is characterized
by a rate constant 3×10-2 min-1. Find the time to complete one third of the reaction.
VI. A reaction has a rate law of the following form: r = k [A]a [B]b Consider the following set of
data. Find out a and b.

Trial Rate Initial Conc. Initial Conc.

(mole L-1 sec-1) of A (mole L-1) of B (mole L-1)

1 2.73 0.100 0.100

2 6.14 0.150 0.100

3 2.71 0.100 0.200