Professional Documents
Culture Documents
DENTAL WAXES
INTRODUCTION
TERMINOLOGY
COMPOSITION OF WAXES
CLASSIFICATION OF WAXES
PROPERTIES OF WAXES
DENTAL WAXES
I) Pattern Waxes
Inlay Wax
Casting Wax
Resin pattern
Base Plate Wax
II) Processing Wax
Boxing Wax
Carding Wax
Utility Wax
Sticky Wax
White Wax
Black Out Wax
III) Impression Waxes
Corrective impression waxes
Bite registration waxes
Conclusion
References
1
2
DENTAL WAXES
INTRODUCTION
Polymers and metals are the basic foundation stone of prosthodontics. Waxes
are basically organic polymers which show thermo plastic property. The oldest
record about the use of waxes in dentistry reveals that they were used as
impression materials. Later, due to their favorable properties they have
established their existence in dentistry with wide range application. They are
commonly used to prepare patterns (for inlays, onlays, pontics, full and partial
dentures), bite registration, during processing of prosthesis, and making of
impression. Waxes are basically thermoplastic materials, which are normally
solids at room temperature and melt on heating without decomposition, to form
mobile liquids.
2
3
The optimum required properties are attained by bending of waxes, resins and
other ingredients.
Natural Waxes
They are hydrocarbon/ hydrocarbon derived polymer weight of 400 – 4,000. they
may be mineral, plant, insect (or) animal origin.
I. Mineral Wax
They are derived from distillation of petroleum. They contain principally
hydrocarbons with more than 17-34 carbon atoms, commonly used mineral
waxes are:
Paraffin Wax:
It is obtained from high boiling point fraction of petroleum (refined crude
oil). It is a soft wax with low melting range of 40-71 C. it is a mixture of straight
chain saturated hydrocarbon, which tend to crystallize as needles and plates. As
the temperature of the wax is raised there is a solid- solid transition point. Where
change of orthorhombic lattice form to hexagonal form occurs. The melting range
3
4
It cannot be used alone due to the following drawbacks. It tends to flake when
trimmed, do not present smooth and glossy surface, brittle at low temperatures.
Microcrystalline waxes:
It is similar to paraffin wax, except that they are obtained from the heavier
oil fraction in the petroleum industry, due to which they have high melting points (
60 –90 C). is a branched chain hydrocarbon of 41-50 carbon atoms. It
crystallizes as small plates. It is more tough, more flexible than paraffin wax. It
shows affinity for oils, less volumetric change during solidification. When it is
added to paraffin, causes raise in melting point, decrease brittleness of paraffin
wax.
Barsnsdahl wax:
It is a type of micro crystalline wax, which is added to paraffin wax to
increase its melting range and hardness. Its melting range is 70-74 C.
Ozokerite Wax:
It is an earth wax, which is similar to micro crystalline wax. It is composed
of straight and branched- chain hydro carbons. It has great affinity to oils. When
added ( 5 – 15 %) to paraffin wax cause raise of melting range of 54 C.
Cerasin Wax:
It is a term used to describe waxes from wax bearing distillates from
natural mineral petroleum refining/ lignite refining. It poses straight & branched
chain paraffin (High molecular weight), with increased hardness and increased
melting range. It improves toughness and carving characteristics of paraffin wax.
4
5
Montan Wax:
It is obtained from extraction of various lignite's. though it is a mineral wax, it
behaves as a plant wax. It contains a large amount of esters. It is hard brittle,
lustrous and blend with other waxes. It is used as substitute for plant wax and
added to paraffin for improving its hardness and melting range.
II Plant Wax:
These are derived from trees and plants. Plant waxes are basically
hydrocarbons (saturated alkenes) with 19:31 carbon atoms.
Carnauba wax:
It is composed of straight chain, alcohols, acids and hydrocarbons,
carbons wax consists of 85% alkyl casters. It is characterized by high hardness,
brittleness and high melting range ( 84-91 C). It is derived from fine powder on
leaves of certain tropical palms.
It is added to paraffin to decrease the flow at mouth temperature. When
10% of caranauba wax is added to paraffin it increase melting temperature to
46C. it has an agreeable odor and contributes to glossiness of wax surface.
Ouricury Wax:
It's composition is similar to carnauba wax. It has high melting range (84-
91% C ) when it is added to paraffin wax the effects observed are similar to those
produced by carnauba wax when added to paraffin. But it is less effective than
carnauba wax.
Candelilla wax:
It contains 40- 60% paraffin hydrocarbons with 29 –33 carbon atoms
accompanied with free alcohols, acids, esters and lactones. It's melting range is
68 – 75 C. it can be used as an alternative to carnauba wax. It mainly increases
the hardness of wax.
5
6
Japan Wax:
It contains glycerides of palmitic and stearic acid and high molecular weight
acids. It is tough malleable and sticky material that melts at 51C. when mixed
with paraffin, it improves the tackiness and emulsifying ability.
Coco butter:
It is basically a fat and contain glycerides of stearic, palmatic, oleic, lauric and
lower fatty acids. It is brittle substance at room temperature. It is mainly used to
prevent, dehydration of soft tissues and glass ionomers.
Synthetic Wax
They are complex organic compounds of varied chemical composition.
They differ chemically from natural waxes but show same physical properties.
They show high degree of refinement / purity in composition.
6
7
Polyethylene wax:
It is a polymer with molecular weight of 2000 – 4000 and a melting range of 100 -
105C. they posses properties similar to high molecular weight paraffin wax.
Polyoxyethylene Wax:
It is a polymer of ethylene glycol, with a melting temperature of 37- 63 C.
they have limited compatibility with other wax, but do function as plasticizer and
tend to toughen the film of wax.
Halogenated hydrocarbon wax:
It is prepared by reacting natural wax with chlorine.
Hydrogenated wax:
It is prepared by reacting natural wax with hydrogen.
Resins
They are complex anomalous mixtures of organic substance that are
characterized by specific physical behavior rather than, by a definite chemical
composition. They are separate group of substances, which resemble to wax in
some aspects like appearance and properties. They may be of natural/synthetic
origin.
1. Natural resins:
They are derived from exudates of many species of trees and other
plants. They are relatively insoluble in water, but show increased solubility,
inorganic solvents. Commonly found natural resins are: dammar resin, rosin,
copal resin, sandrac, mastic, shellac, kauri.
7
8
Copal is a brittle natural resin. Which has melting range well above 149 0
C but when deposited as a film, it serves as a liner on prepared cavities.
11. Synthetic resins:
polyethylene and vinyl resins are added to paraffin wax to improve its
toughness, film forming characteristics, and melting range.
Fats
Fats are composed of esters of various fatty acids with glycerol and are known
as glycerides. They are similar to waxes as both are tasteless, odorless,
colorless and greasy in nature.
Glycerol tristerate:-
Is a chief ingredient of beef tallow, with a melting temperature of 43 0C. it
is has a lustrous appearance firm & slightly greasy. It is added to waxes to
increase the melting range and hardness.
Other examples are: Glycerides of stearic acid, mixed glycerides of oleic, palmitic
and butyric acids found in butter.
Oils
They have a pronounced effect on melting temperature of wax (decreases the
melting temperature). Hydrocarbon oils are used to soften mixtures of waxes,
silicone oils are added in was to improve ease of polishing.
Gum
It is a viscous amorphous liquid exudates from plants which harden or exposure
to air. It is a mixture containing largely of carbohydrates. When dissolved in
water form sticky viscous liquids. Most of the Gums (except gum arabica and
tragacantha) resemble waxes obtained from plant and animals in appearance.
They are added to paraffin was to increase smoothness and resistance to
cracking and flaking.
8
9
CLASSIFICATION
Dental waxes are classified according to their application as:-
1) Pattern waxes.
2) processing waxes.
3) Impression waxes.
1) Pattern waxes, used prepare the pattern of planned prosthesis. They include
- Inlay waxes – Type I, Type II
- Resin
- Casting wax
- Base plate wax - Type I
- Type II
- Type III
2) Processing waxes:
They are used during the intermediate steps of processing a prosthesis. They
include.
- Boxing wax - Block out wax
- Sticky wax - White wax
- Carding wax - Utility wax
3) Impression waxes: They are used for denture impression and are limited to
use in edentulous region of mouth. They include corrective impression waxes
and bite registration waxes.
CHARACTERISTIC PROPERTIES OF WAXES:
9
10
Melting range
Waxes exhibit melting range rather than melting point because, they
contain both crystalline and amorphous components, each having a range of
molecular weight distribution. When two different was are mixed an intermediate
melting range is observed, which depends on the individual percentage
composition of waxes mixed.
Use of waxes with different elastic modulus is advised for different parts of
pattern. So occlusal surface is prepared using soft green wax and proximal
surface using inlay wax.
Carnauba wax show decrease in proportional limit from 11-5.5 mps (in
230-370 C0 range).
Inlay Casting wax show decrease in proportional limit from 48 – 0.2 mpa,
and decrease in compressive strength 83 – 0.5 mpa (in 23 0 C-370 C0 range).
Flow:
The property of flow results from slippage of molecules over each other.
Flow is directly dependent on temperature of wax. Mineral waxes show 50% flow
at 200 C below the melting range due to weak secondary forces. But the plant to
strong secondary bonds.
Yellow bees wax shows extensive flow at 24 0 C below it melting range and
display an 80 C temperature difference between 1% and 70% flow. This is due to
high amount of impurities in bees wax has low amount of impurities so the flow
temperature is near its melting range.
In case of pattern waxes the direct inlay wax should show high flow at a
temperature slightly above the mouth temperature.
The flow is also influenced by presence of solid-solid and melting
transformations that occur in the component wax.
Residual stress;
Regardless of the method used to prepare a wax pattern, residual stress
exists in the completed pattern. This can be demonstrated by comparing
10
11
dimensional change on heating annealed inlay wax patterns and that of waxes
formed under compression and tension.
They are prepared by holding the softened wax under compression during
cooling, followed by determination of thermal expansion. The extent of deviation
from the curve for the annealed wax is a function of magnitude of residual stress.
The deviation can be observed as a shaded area rather than curve (as seen in
annealed specimen).
When wax specimen is subjected to tensile stress, during cooling,
followed by determination of thermal expansion. The shaded are is formed
below the curve for annealed specimen. Which means on heating this specimen
contraction occurs.
Under compression of wax during cooling the atoms and molecules are
forced closer together and set in the strained position. Once the material is set,
the motion of stressed atoms and molecules is restricted. When it is heated
again without any load the strained atom try returning to their original position.
This causes expansion of wax under tensile stress the atoms are pull apart and
set. When they are reheated the wax shows contraction.
Ductility:
Waxes with lower melting temperature have a greater ductility at any given
temperature them those with higher melting temperatures.
Ductility increases as the temperature of wax is increased. In case of
blended wax the ductility depends on range of component. When wide melting
range components are present, the blended wax show high ductility than a wax
with narrow range of components. In wide range components, as the
temperature is raised the component with lowest melting range softens first and
plasticize the entire wax and thereby enhance ductility. This not possible with
narrow range blended waxes. The presence of occluded oils in waxes lead to
increase the ductility.
DENTAL WAXES:
A variety of natural waxes and resins have been used in dentistry for
specific and well defined application. In some instances, the most focusable
11
12
qualities can be obtained from a single was (Ex – bees wax), but more often a
blend of several waxes is necessary to develop the most desirable properties.
Dental waxes are classified as pattern was processing was impression wax.
PATTERN WAXES
They are used to prepare pattern of artificial prosthesis/restoration which
is later to subjected casting procedure. A pattern wax has two major qualities,
thermal change in dimension and tendency to warp / distort on standing.
The wax pattern formed defines the shape and size of the resulting appliance
and is eventually replaced by either a polymer / alloy. The wax patterns are
prepared using two techniques:
a. Direct technique: The wax is directly adapted, shaped on the cavity
prepared on tooth in oral cavity. Used to prepare wax pattern for
Inlay.
b. Indirect technique: The wax pattern is prepared on the model which
is obtained using Impression procedure. The whole process is
done outside the oral cavity.
Properties of pattern wax leading to dimensional inaccuracy
1. Pattern waxes contract on cooling
2. Patter waxes have a tendency for flow.
3. regardless of any method used, a prepared wax pattern contains residual /
Internal stress.
12
13
13
14
14
15
Both type I and Type II must have a minimum flow of 70% at 45 0 C and a
maximum flow of 90%. At this temperature sufficient flow is needed to insert wax
into fine details of prepared cavity.
Thermal properties:
They show low thermal conductivity and time is required both to heat them
uniformly and to cool them. They exhibit high co-efficient of thermal expansion.
The wax may show 0.7% expansion with a raise of temperature by200 0 C and
0.35% contraction when cooled from 37 0 C to 250 C. The average linear co-
efficient of thermal expansion is 350 x 10 -6 /C. this property of wax affects the
accuracy of pattern when prepared by direct technique (using type I wax ) due to
change in temperature from oral cavity to room temperature. The glass transition
temperature of inlay wax is 35 0 C, is purely due to paraffin. Above this
temperature wax behaves as plastic material, because this temperature acts as a
transition point of solid crystalline transformation.
This glass transition temperature is not pronounced, when the wax is
cooled under pressure / retention of high qualities of gases and solvents, which
remain under compression. The entrapped gas in wax expands on reheating,
causing a pronounced expansion as the was becomes sufficiently plastic to flow.
Wax distortion:
Dimensional stability of wax pattern is the most ideal requirement
needed. But some amount of distance is seen due to thermal changes and
release of stress (arising from contraction on cooling, occluded, air, change of
shape during molding, carving, removal and time, temperature during storage).
15
16
16
17
17
18
Modeling pastes
- Diurethane dimethacrylate oligomers.
- Fillers polyurethane dimethacrylate (40-50%)
(Or)
Poly (methyl methacrylate)
Liquid
Urethane dimethacrylate
18
19
Properties:
Modeling resins are characterized by lower heat of polymerization
and shrinkage than acrylics, higher strength and resistance to flow than waxes.
Good dimensional stability and burnout without residue. Dimethacrylate pattern
resins do not result in cracked investment from heating during burnout. Which
can occur with acrylic patterns.
When different resin modeling materials were tested to evaluate the
marginal discrepancies for full crown and inlay.
Pattern material Full crown Inlay
Inlay wax (type II) 11 15
Light cure resin A 10 8
Light cure resin B 12 9
Self – cured acrylics 15 7
For full crowns the marginal discrepancy found is similar for Inlay and light
– cure resins. But for Inlays the resins patterns show less discrepancy than
waxes.
Manipulation of pattern resins:
Gypsum and resin dies must be treated with a separator and have
undercuts blocked out. They are brightly pigmented, good dimensional stability
and convenient to use. The powder and liquid are painted on the die/ tooth in
layers and allowing to polymerize. After polymerization, the pattern is modified
using stone and bur they need considerably longer burnout time light – cure
resins.
The modeling resin is applied in layers 3 – 5 mm thick. With each layer
curing chamber for 90 seconds / by using a hand, light curing unit for 20 – 40
seconds / area of irradiation.
The liquid material is used first to obtain close adaptation to the die and
last to provide a smooth surface. Complete lamination of modeling resins occur
between 6700 – 6900 C and requires 45 min.
19
20
20
21
Uses:-
21
22
PROCESSING WAXES
Boxing wax:
Boxing is a procedure employed for pouring of impression. This
procedure involves usage of a long narrow stick/strip of wax (beading) around
the impression 3-4m below its peripheral height, followed by adapting a wide strip
of boxing wax on to the beading wax, providing a form around the entire
impression. Later the boxed impression is poured using plaster / stone.
22
23
Utility wax
This wax is used for many tasks which need individual modification
of armamentarium.
Utility Wax supplied as dark red orange sheet, strips. Their flow at 37.5 0 C(55 % -
80 %). They should be pliable at 21 0 - 240, tacky at 210 - 240 and show sufficient
adhesion to build up.
They probably contain beeswax, petroleum and other soft waxes in
varying properties.
Sticky wax
Properties :
1) Flow - 300 max 5%
430 – min 90%
2) Should be sticky when melted and adhere closely to the surfaces to the
surfaces on which it is applied. But a room temperature wax is firm, free
from tackiness and brittle.
3) Not more than 0.2% residue on burnout.
23
24
4) Not more than 0.5 % shrinkage from 43 0 – 270. This is important to prevent
displacement of structure stabilized using this wax.
5) Federal specification no U- W 001490 – sticky wax should have a dark /
vivid color so that it is readily distinguished from light colored gypsum
materials.
Use:
1) It is used to fixed temporary positioning of metallic parts during investment
soldering.
2) Used to stabilized broken dentistry is taking impression within the mouth.
Because wax formulated for use as an impression material exhibits high
flow and ductility, it distorts readily when with drawn from undercut areas.
Therefore the use of wax has been limited to the non-undercut edentulous
areas of mouth. They are also used for bite registration.
Corrective impression wax :
The basic requirements of any impression wax should have a high degree
of plastic deformation at mouth temperature. One of the commercially available
impression wax it is available as 4 grades.
1) Extra hard no-1(pink) – used as reinforcing material, used only on the
external surface to support wax extension beyond try margin.
2) Hand no-2(yellow)- used to rebasing as a hand foundation for korecta wax
no3 and 4 when extensive alveolar resorption necessitates a bulk of
material. Also used to restore occlusion in a partial denture (or) a
removable bridge which has settled to severe tissue change.
3) Soft no3 (red) – used for minor tray corrections and as an initial lining to
stabilize tray.
4) Extra soft no 4 (orange) - used to secure a completely adapted
impression under natural pressure. It leaves a finished surface and
register time details.
This waxes register the mucosa and underlying tissue in a functional state.
24
25
They are formulated using paraffin, ceresin and beeswax and may contain
some metal particles.
The flow of individual korecta wax at 370
Korecta 1 - 3%
Korecta 2 - 80 %
Korecta 3 - 85 %
Korecta 4 - 90 %
Flow also varies depending on the % composition ratio between paraffin and
bees wax.
At 370
75 % yellow bees wax : 25% paraffin wax – 80% flow
50 % yellow bees wax : 50% paraffin wax – 85 % flow
25 % yellow bees wax : 75 % paraffin wax – 89 % flow
These waxes are subjected to distortion during removal from the mouth.
Bite registration wax :-
It is used to accurately articulate certain models of opposing quadrants.
Bite registration can be done using 28 gauge casting wax sheets / from hard
baseplate wax.
Specially designed bite registration waxes contain, bees wax /
hydrocarbons wax such as paraffin / ceresin. Some may continue aluminum /
copper particle.
Flow of bite wax at 310 C range from 2.5 – 22 % - so they are susceptible to
distortion during removal.
REFERENCES :
1) Craig RG, O' Brein WJ, Powers LM Dental materials, Properties and
manipulation, 11th ed, ST Louis: Cr Mosby, 2002, 424 – 448.
25
26
26