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Worksheet - 51 (Lecture-03) Topic : Hydrocarbon

1. The intermediate in the Electrophilic addition–reaction is :-
(1) Carbocation (2) Carbanion
(3) Free radical (4) Carbene

CH3
2. +HI — major product is

I
CH3 CH3 CH2–I CH3
(1) I (2) (3) (4)
I

3. 3–Phenyl propene on reaction with HBr gives (as a major product)

(1) C 6H 5CH2 CH(Br)CH3 (2) C 6H 5CH(Br)CH2CH 3
(3) C6 H5 CH2 CH2 CH 2Br (4) C6 H5 CH(Br)CH CH2

HBr
4. Isobutene "product". The product is
H2O2

(1) Isobutyl bromide (2) Tert. butyl bromide

(3) Tert. butyl alcohol (4) isobutyl alcohol

5. Reaction of HBr with propene in the presence of peroxide gives

(1) 3–bromo propane (2) Allyl bromide
(3) n–propyl bromide (4) Isopropyl bromide

CH3
6.
H3C CH CH CH2 + HBr A

A (Predominantly) is :

CH3 Br CH3
(1) CH3 C CH2CH3 (2) CH3 CH CH CH3
Br

CH3 Br CH3
(3) CH3 CH CH CH3 (4) CH3 CH CH2 CH2Br

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Worksheet - 51 (Lecture-03) Topic : Hydrocarbon

CH3
Peroxide
7. Ph CH C CH3 + HBr (X) 'X' is

Br CH3 Br
(1) Ph CH CH CH3 (2) Ph CH2 C CH3
CH3

(3) Ph CH2 CH CH2 Br (4) Ph CH C CH2 Br

CH3 CH3

Br
8. CH3–CH=CH2 HBr
CH3–CH–CH3
(A)
+
CH3–CH2–CH2–Br
(B)

(a) The product A is major

(b) Formation of A follows markovnikov rule
(c) Carbocation formed in A is less stable than that formed in B
(d) Formation of B follows markovnikov rule
The correct statements are :
(1) c, d (2) a, b, c, d (3) a, b (4) a, d

9. CH3–CH=CH OH H Br
A
major
product
A is :–
(1) CH 3 –CH(Br)CH2 OH (2) CH 3CH2CH(Br) OH

(3) CH3 CH2CH(Br) Br (4) CH3 CH(Br)CH2 Br

HBr
10. CH2=CH–CCl3 ?
(1) CH2 =CH–CBr3 (2) CH2–CH 2–CCl3 (3) CH3–CH–CCl3 (4) CH2–CH–CCl3
Br Br Br Br

CH3
11. HBr Major product :-

(1) (2) (3) Br (4)

Br Br
Br

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Worksheet - 51 (Lecture-03) Topic : Hydrocarbon

12. CH=CH HBr

Major product

Br
(1) Ph–CH–CH 2 (2) Ph–CH –CH
2

Br

(3) CH=CH (4) Both (1) and (2)

Br

HBr
13. CH2–CH=CH2 H 2O 2 ? (Major Product)

(1) CH–CH2–CH3 (2) CH2–CH–CH3

| |
Br Br

(3) CH2–CH=CH2 (4) CH2–CH2–CH2Br

Br

(i) B2 H6
14. CH2 (ii) H 2 O2 / OH ?

CH3 CH3
(1) (2) CH2OH (3) (4) CH2BH2
OH OH

15. What is the major product of the following reaction:

CH3
HBr
Peroxide ?

CH3 Br
CH2Br CH3 CH3
(1) (2) Br (3) (4)
Br

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Worksheet - 51 (Lecture-03) Topic : Hydrocarbon

CH3
16. CH3–C–CH=CH2+D–Cl ?
CH3

CH3 Cl CH3
(1) CH3–C – CH–CH2–Cl (2) CH3–C – C–CH 3
CH3 D CH3 D
Cl CH3
(3) CH3–C – CH–CH2–D (4) CH3–C – CH–CH2
CH3 CH3 CH3 Cl Cl

HI
17. P (Major product) :-

I
(1) I (2) (3) (4)
I I

(1) BH3/THF
18. CH3
(2) D2O2/OH
?

OH OH H OD
(1) CH3–C–D (2) CH3–C–CH2–D (3) CH3–CH–CH 2–OD (4) CH 3–C–CH3
CH3 H H

CH 3
19. C 7 H12 HBr
Br
(A )

Which of the following can not be A?

CH2 CH2 – CH 3
CH = CH2 CH 3
(1) (2) (3) (4)

CH3
(i) BH 3 / THF
20. (ii ) H 2 O2 / OH Product.

The main product will be :

CH3 CH3
CH3 CH 3
H H
(1) (2) (3) OH (4)
H OH OH
OH H

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Worksheet - 51 (Lecture-03) Topic : Hydrocarbon

21. In the given reaction :–
COOH
HBr [X]

[X] will be :
COBr COOH COOH COOH
Br Br
(1) (2) (3) (4)

BD 3 /THF
22. H 2O 2 /OH Product A, A is :-

CH3 CH3
D OH OH
(1) OH (2) (3) (4)
OH D D

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