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TABLE OF CONTENTS
1. Scope ................................................................................................................................. 4
3. Definitions ......................................................................................................................... 5
Appendix 5 Typical list of exceptional operations with expected corrosion impact ... 30
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1. Scope
This document is related to Corrosion Control on Production Facilities. It is applicable to field
operation activities, from production start-up to field abandonment.
This document specifies the main activities of Corrosion entities in charge of field operations in
operating subsidiaries, based on a defined Corrosion Management strategy. It also specifies
practical methodologies and requirements for:
Performing internal corrosion assessments on operated facilities,
Defining corrosion mitigation and corrosion monitoring programs,
Applying these programs during normal field operations,
Running exceptional operations with no adverse corrosion impact.
Preliminary remarks: Due to the wide variety of parameters and solutions applicable to corrosion
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control, this document not only includes general specifications but also some indicative or
applicative tables to be used within defined application limits. Some comments and explanations
are also given in italics, with no prescriptive value.
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2. Reference documents
The reference documents listed below form an integral part of this General Specification.
EXTERNAL DOCUMENTS
Unless otherwise stipulated, the applicable version of these documents, including relevant
appendices and addendums, is the latest revision published at the effective date of this document.
Reference Title
Not applicable
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3. Definitions
Corrosion management: The overall Corrosion Management process for any production facility is
summarized in the following loop, which is applicable both during design and construction and during
field operations:
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Corrosion mitigation, i.e. all preventive actions undertaken during operation to control the corrosion
of susceptible materials and equipment including but not limited to:
Metallic and non-metallic material selection,
Chemical treatments dedicated to corrosion mitigation: Corrosion inhibition, biocide
treatments, oxygen scavenging, chlorination, pH stabilization,
Physical treatments applicable to corrosion mitigation: Dehydration, de-oxygenation,
operational pigging, etc.
Cathodic protection,
Painting and coating.
Corrosion Monitoring activities, i.e. all actions regularly undertaken to verify the implementation
and efficiency of preventive actions including but not limited to:
Follow-up of chemicals injection rates,
Follow-up of cathodic protection equipment,
Potential and current measurements for cathodic protection,
Corrosion coupons,
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Corrosion probes (if applicable: electrical resistance probe, linear polarization resistance
probe),
Chemical analyses (inhibitor, iron, oxygen, pH),
Bacterial counts (kits, bioprobes, etc.).
The Corrosion Register is generally a part of a wider "Plant Asset Register" managed by the
Inspection entity. It contains the necessary information and documentation on all equipment
involved in corrosion management activities during field operations:
Construction materials,
Other mitigation solutions applied during the design and construction, with all necessary
characteristics,
All equipment available for chemicals' injection,
All equipment available for corrosion monitoring.
The corrosion assessment aims at evaluating whether corrosion is well controlled or not and at
which rate it is likely to proceed, in case of insufficient control.
It is used for revising corrosion mitigation, corrosion monitoring, and inspection programs, and is a
key input for the definition of planned maintenance & repairs.
The deliverables of this Corrosion Assessment are in two parts:
1. The Natural Corrosion Likelihood, i.e. without any applied mitigation.
Note: This Natural Corrosion Likelihood is particularly used to define whether additional
mitigation solutions are needed or not and to evaluate how quick problems might be
experienced if such mitigation was not applied or inefficient.
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Any significant change in operating conditions, such as but not limited to:
- Start-up of a new field using existing facilities or equipment,
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- Implementation of a new process unit which modifies the service conditions of existing
facilities or equipment,
- A change in production rates by more than 50%.
Unexpected corrosion events likely to re-occur at other locations and not covered by
existing corrosion assessment results.
Corrosion monitoring results regularly in contradiction with the corrosion assessment.
The changes in operation and its impact to corrosion need to be documented and follow the
management of change.
7. Corrosion mitigation
A Corrosion Mitigation Program shall be established and regularly updated. This program
specifies all necessary actions to be undertaken during operational life to prevent
corrosion failures of any important equipment before its expected end of service.
Corrosion Mitigation Programs shall include all relevant mitigation solutions as described in § 3.
A typical structure of a corrosion mitigation program is shown in Appendix 2.
For any preventive actions in the corrosion mitigation program, the following needs, as a minimum,
be specified:
The method to be used,
The location where it will be used,
The equipment to be used,
The requirements for use (dose rates, potential values, flow rates, etc.),
The quantitative efficiency levels targets,
The relevant application procedures.
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The corrosion mitigation program needs to be formally delivered to all entities in charge of its
implementation, together with all relevant procedures to allow its correct application.
The availability of the necessary material and human resources for the implementation of the
corrosion mitigation program is to be verified.
The Corrosion mitigation program needs to be updated regularly, and as a minimum:
Every year,
For physical and chemical treatments: when production rates are changed by more than ±
25%, or new fields or new process facilities are added,
When corrosion monitoring results are regularly in contradiction with expectations, or quickly
drifting from previous average values,
When inspection results are in contradiction with expectations, based on the supposed
performance of preventive actions.
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A corrosion inhibitor product selected and used on a field/asset shall only be changed due to any
following major reasons:
Documented lack of efficiency,
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8. Corrosion monitoring
Note: Corrosion monitoring is different from inspection. It aims at evaluating the performance of
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preventive actions within short time delays (days to months depending on the technique) without any
direct indication of the physical condition of the equipment. Inspection is focused on the corrosion
status of equipment on a longer term basis (months to years).Among the various preventive actions
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undertaken, corrosion monitoring activities will be focused on cathodic protection and physical and
chemical treatments, whereas monitoring of painting-coating and corrosion resistant materials are
mostly covered by Inspection programs.
The Corrosion Monitoring program is a formal document defining all activities and measurements to
be handled to cover the objectives listed here above.
The monitoring program shall cover all relevant production and injection facilities. A typical list of
monitoring techniques is given in Appendix 4, Table 4.1.For each monitoring activity the following
needs to be included, as a minimum:
The monitoring technique used,
The location where it is used,
The relevant application procedure,
The measurement frequency,
The entity in charge of the activity,
The threshold acceptance values,
The actions to be undertaken when threshold values are exceeded.
All application procedures necessary to the satisfactory application of the corrosion monitoring
program must also be made available to the entities in charge.
The Corrosion monitoring program is regularly up-dated, as a minimum when:
New facilities are installed or existing facilities are closed,
Process modifications are made, which may modify the corrosiveness of the fluids which are
monitored or the efficiency of the applied mitigation,
Changes are made on the applied mitigation programs,
Corrosion monitoring or inspection results are regularly in contradiction with expectations.
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As long as chemical treatments are concerned, the corrosion monitoring program includes:
The verification of injection specifications (flow rates, dose rates, continuity or frequency and
duration), based on typical guidelines indicated in Appendix 4, Table 4.2.
Indicative parameters related to treatments’ efficiency, as per reference documents (coupons,
probes, titrations, bacterial counts, etc.).
A sound corrosion monitoring program requires combining several monitoring techniques in parallel.
The typical guideline for monitoring of microbial induced corrosion in production facilities is given in
Appendix 4, Table 4.3.
Maintain a permanent and close relationship with the Inspection department, with
systematic and mutual exchange of information on significant corrosion events
experienced, inspection results involving corrosion damages, poor corrosion
monitoring results, etc.
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Be involved in the definition of RBI type inspection programs for the Corrosion
Likelihood evaluation of the concerned equipment.
Be involved in the implementation of inspection programs where corrosion is the
essential reason for inspection, particularly when the objective of the
inspection/survey is to establish the painting maintenance program.
For RBI programs, the Corrosion entity is in charge of validating the Corrosion Likelihood evaluation
used in the RBI tool. This evaluation shall be consistent with the Corrosion Assessment defined in §
4.3.
The Corrosion entity checks that the planned inspection programs are adequate with respect to
corrosion assessment and corrosion threats, and consistent with any additional information regarding
corrosion events, corrosion monitoring results, etc.
Inspection results needs to be reviewed with respect to their possible impact on any other equipment
potentially subjected to similar corrosion damages.
Inspection results needs to be analysed in view of adjusting, if necessary, corrosion mitigation and
monitoring programs, particularly when unpredicted corrosion damages are detected by inspection.
The Corrosion entity is directly involved in Painting Maintenance activities, as detailed in Appendix 3:
1. Definition of the Painting maintenance strategy, as part of the Corrosion Management
strategy,
2. Performance of "Corrosion and Coating Integrity Inventories" as per MHK-COMP-SPE-EP-
COR-0451,
3. Definition of multi-years painting maintenance programs,
4. Technical qualification of contractors performing painting maintenance,
5. Checking, inspection and acceptance of painting works.
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Mitigation and monitoring data shall be archived throughout the whole service life of the
relevant facilities.
A periodic report needs to be issued containing at the minimum:
Inspection/verification results for corrosion mitigation
What has been implemented on corrosion mitigation,
The gap in the corrosion mitigation and its analysis,
The main monitoring results, with a particular emphasis and analysis on results exceeding
threshold levels,
PIs (Important results need to be reported on a graphical basis versus time (can be over a one
year sliding period of time),
A list of anomalies and a follow-up of corrective actions, if any.
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Appendix 1
The minimal content of the Corrosion Management during Field Operations" document of a production
subsidiary and a possible list of associated application documents (programs, procedures, methodologies,
etc.) is given in Table 1.1. This list is not exhaustive; a number of additional documents may be added.
Table 1.1 Minimum structure of Corrosion Management document and the associated application
documents
a) Organization charts,
2. Organization b) Responsibilities matrix.
a) Material selection and other mitigation methods,
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Appendix 2
* Preventive solutions usually implemented at design/construction stages and not requiring any activity
during operation are indicated in italics.
Crude oil and multiphase gas Risers and pipelines, receiving Corrosion inhibition, biocides,
trunklines separators operational pigging, pH
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separation process disposal facilities, crude part is lost due to oil/ water
dehydration and stabilisation partitioning, biocides.
Water injection network Topside piping, flowlines, risers Chlorination, filtration, physical
(Produced & Sea Water) and pipelines, wells and chemical de-aeration of SW,
biocide treatment, corrosion
inhibitors
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Appendix 2
Pipelines
Internal surface FBE
Occasionally internal coatings
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Appendix 3
Table 3.1: Typical corrosion inhibitor treatments for oil and gas production facilities
Table 3.2: Typical biocide treatments for oil and gas production facilities
Table 3.3: Typical pH stabilisation treatments for gas production facilities
Table 3.4: Anticorrosion treatment of seawater lift for firewater
Table 3.5: Typical oxygen removal for corrosion control
Table 3.6: Typical guidelines for operational pipeline pigging for corrosion purpose
Table 3.7: Typical guidelines for definition of paint maintenance programs
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Appendix 3
Table 3.1 - Typical corrosion inhibitor treatments for oil and gas production facilities
Target
Typical service Typical Injection Frequency/
Facility Typical dosage monitoring Comments
conditions chemicals mode duration
values
Gas wells with no "Oil-soluble" Batch Diluted to 5 to 1 to 2 months > 10 ppm in Unusual mode of treatment, limited
downhole injection inhibitors 20% diluted with produced to corroded wells not equipped for
facilities diesel or water any other type of inhibition
condensate
Oil-water lines, T < 50°C "Water- Continuous 20 ppm/Water Continuous ≤ 4 mpy Typical dose rates are given for
50 < T < 80°C soluble" 50 ppm/Water BSW ≥ 50%. Half of the specified
Oil wells equipped film forming dosage vs. Oil + Water to be
with down-hole 90 < T < 110°C inhibitors
100 ppm/Water
specified up to 50% BSW.
injection devices T > 110°C 150-200 ppm/
These dose rates also apply to 3
Water
phase lines with oil and water as
main fluids.
3
Crude gas- T < 50°C "Water- Continuous 10 L/MMSm Gas Continuous ≤ 4 mpy Values considered for moderate
condensate lines 50 < T < 80°C soluble" 15 L/MMSm3 Gas liquid flow rates, below 200 - 300
film forming m3/MMSm3
Gas wells equipped 90 < T < 110°C 20 L/MMSm3 Gas
with downhole inhibitors Inhibitor concentration to be also
T > 110°C 30 L/MMSm3 Gas
injection devices consistent with concentrations here
above vs. Water or Oil + Water.
Wet gas line with T < 50°C "Water- Batch 1000 ppm/total 1 week with Treatment designed for making
residual water soluble" condensing water injection time available inhibitor at low points
content (e.g. film forming reached with 2 < 1 hr where condensed water is likely to
downstream inhibitors injections accumulate.
compressors) maximum
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Appendix 3
Table 3.1 - Typical corrosion inhibitor treatments for oil and gas production facilities
Target
Typical
monitoring
service Typical Injection Frequency/
Facility Typical dosage values Comments
conditio chemicals mode duration
ns
Oil production, Corrosion "Water-soluble" Continuou 15-30 < 4 mpy To be adjusted with monitoring
water outlet of 1st control film forming s ppm/Water values, depending on how the
separator inhibitors inhibitor partitions to the water phase
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Appendix 3
Table 3.2 - Typical biocide treatments for oil and gas production facilities
Target
Typical service Typical Injection Periodicity/
Facility Typical dosage * monitoring Comments
conditions chemicals mode duration
values
Biocide treatments
Oil-water lines Mixtures of Batch 400 to 1 week/ 5 hrs < 100 bact/mL Alternate 2 products, with
Gas/ condensate Glutaraldehyde, 500 ppm/Water and < 100 distinct chemistry (change
lines with low flow Quaternary bact/cm2 each month)
velocities (stratified, ammonium, (bioprobe Periodicity and dose rate to
liquid velocity THPS, etc. monitoring) be adjusted depending on
< 2 m/s) monitoring results
Any line Short duration Biocide + O2 100% of the 300 ppm biocide Permanent O2 scavenger optional if fluid
pressure testing scavenger or water + 100 to 200 ppm flushed within 1 week
multi-purpose volume O2 scav., or O2 scavenger as per Supplier's
dedicated 500 ppm documentation + 20%
chemical multipurpose
Refer to COR 0560.
chemical
Any line Long term Biocide + O2 100% of the 500 ppm biocide Permanent O2 scavenger as per Supplier's
cocooning of scavenger or water + 100 to 200 ppm documentation + 20%
already used multi-purpose volume O2 scav., or Slight Nitrogen over-pressure +
lines dedicated 1000 ppm pressure follow-up, to prevent
chemical multipurpose and monitor oxygen entries
chemical
* Biocide dosages given in this table refer to the commercial product itself, considering that it contains 50 ± 5% of active biocide components. Dosages/injection rates have to
be increased/ decreased accordingly if biocides with lower/ higher contents in active components are provided.
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Appendix 3
Table 3.3 - Typical pH stabilisation treatments of glycol used on gas production facilities
Target
Typical service Typical Injection Periodicity/
Facility Typical dosage monitoring Comments
conditions chemicals mode duration
values
pH stabilisation
Gas-condensate Sweet MDEA, KOH, Initial + Calculated to Occasional top- In situ pH of Dose rate dependent on
lines with conditions NaOH, etc. periodic reach an in situ up depending rich DEG > 6.5 pressure and CO2 content
permanent glycol (%H2S < additions in pH of 6.5 on pH decrease at line outlet (Typically 0.02 to 0.2 m/L in rich
injection %CO2/1000) case of pH and glycol top- glycol = 0.3 to 3% vol in lean
decrease up glycol)
Calculated with dedicated tools
Sweet TEG TEG closed MDEA. Initial + Calculated to Occasional top- In situ pH of Same as above for dose rates
dehydration units circuit. Water periodic reach an in situ up depending rich TEG > calculation
(H2S < 100 ppm vol) content from additions in pH of 6.8 on pH decrease 6.5 (Typically 0.02 to 0.2 m/L in rich
0.1 case of pH and glycol top- glycol = 0.2 to 2% vol in lean
to 5% in TEG decrease up glycol)
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Appendix 3
Table 3.4 – Typical corrosion treatment of sea water lift for fire water
Periodicity/ Target
Typical service Typical Injection
Injection point Typical dosage duration monitoring Comments
conditions chemicals mode
values
Chlorination
Upstream seawater Raw seawater Hypochlorite Continuous 1 to 5 ppm Continuous 0.7 ppm Not only important for fouling
lifting pumps chlorine/Water, chlorine at control, but also to prevent
depending on inlet of the bacterial growth in filters
organic content fire water piping
Deaeration
Inlet of pipelines Raw seawater Oxygen scavenger Continuous 100 ppm to 200 ppm Continuous 10 ppb to 30 Refer to COR 0560 Appendix 1
ppb for detail calculation of O2
scavenger dose.
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Appendix 3
Table 3.6 - Typical guidelines for pipeline operational pigging for corrosion control
Typical/ max.
Objective Pipelines involved Additional conditions Type of pigs to be used Comments
periodicity
Biofilm/ bacterial Water and oil/ water Suspected or detected Hard plastic plate pigs 1 to 2 weeks No metallic
bjective
cleaning of pipe wall pipelines, bacterial activity abrasive brush
3 phase pipelines with low pigs.
velocity (< 3 m/s total
velocity) Pig to be launched before
the periodic biocide
injection.
Remove water Commercial oil pipelines Flow velocity < 2 m/s Foam or disk pigs 1 to 3 months
accumulating at low Gas pipelines downstream Flow velocity < 10 m/s Id. 2 to 4 weeks
points compression, without
complete dehydration
Gas pipelines downstream Flow velocity < 10 m/s
a undersized dehydration Id. 1 to 3 months
process
Prevent solid particles Oil/ water or 3 phase Identified sand Hard plastic disk pigs Depends on the rate of Each batch of sand
accumulation pipelines with low flow production upstream the solid accumulation, collected should be
velocity pipeline based on assessment weighed and logged.
and quantities of solids Sand size and
recovered during sizes distribution to
operational pigging be measured on
sand
breakthrough.
Top of line corrosion Multiphase wet gas line Subject to top of line Spray pig Monthly Double dosage of
control corrosion corrosion inhibitor 24h
prior to spray pigging.
Note: Indications in this table only refer to pigging made for corrosion purpose, not involving additional operational needs (e.g. wax removal)
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Expected
Level painting
Level Purpose Activity Performer
Description service
life
Washing, houskeeping, Anybody on
Preventive Minimize need
0 eliminating stagnant site, -
maintenance for painting
water, repair leaks continuous
Spot surfaces, light
Small painting
equipment (hand/power
Touch up Delay painting team, regular
1 tool), light surface 1-2 years
painting refurbishment to permanent
preparation (SSPC SP11,
action
St3)
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2 painting
refurbishment abrasive blasting and blaster and years
refurbishment
painting), may require painter team
naval support.
Full scope, large team,
heavy equipment, Dedicated
Long term full
Major painting (dedicated for abrasive and qualified > 10
3 painting
maintenance blasting and painting), blaster and years
refurbishment
may require naval painter team
support.
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The adequate balance between these different levels depends on the existing painting status of the
facilities considered, as well as on climate and hosting conditions. As such this balance must be
defined within each affiliate.
The Corrosion entity is responsible, as a minimum, for the definition of the surfaces to be
maintained, the applicable specifications, the Quality Control and final reception of work.
The Corrosion entity is also involved in the selection and periodic technical evaluation/auditing
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Appendix 4
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Appendix 4
Mixed inspection- monitoring Periodic manual wall thickness 1 to 3 months periodicity. Limited
tools measurement sensitivity for low corrosion rates
Automated wall thickness
sensors at fixed location
Long Range UT tools
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Appendix 4
rectifiers
Efficiency of cathodic protection, Potential surveys, anode Every 2 years for structures,
offshore/swamp structures, consumption Every 3 years for offshore
offshore pipelines
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Appendix 4
Table 4.2 - Typical guidelines for chemicals’ injection monitoring Objectives of injection
monitoring
1. Check that chemicals are injected according to specifications with respect to injection
mode and dose rate.
2. Improve injection reliability in case of inadequate injection.
General methodologies
Chemicals injection must be monitored through a combination of the following methods:
Frequency Activities
Uncontrolled Paper Copy | CMS | 11/21/2018 08:11 AM
Daily (or at each site visit Verification of the injection flow rate either through:
if less than daily)
The measurement of the instantaneous flow rate, on a volumetric cell or on
a dedicated massic flow meter if any,
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The measurement of the average daily flow rate by level change on the
storage tank, if equipped for such measurement,
The follow-up of tank gauging, if equipped with an automated gauging
sensor.
3 months to yearly Overall comparison of consumption versus specifications for each chemical
during the period with the specified injection, over the whole asset (no
detailed analysis per injection device).
Key rules
A few practical rules need to be followed for a successful application of chemical treatments:
Injection facilities must be regularly maintained and verified. In particular, instantaneous
injection rates must be easily measurable.
Operators must be made aware of the objectives and importance of chemical treatments,
and they must be given clear and up-dated injection specifications.
Operators must be fully involved in the application and monitoring of these treatments, and
informed of all monitoring results associated with these treatments.
Periodic site visits of the Corrosion Control representatives must be partly devoted to a review of
treatment application and to the verification of injection devices.
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Appendix 4
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Appendix 4
Frequency
System Sample Point Unknown system Well Characterized system Target values Monitoring objective Note
Routine Troublesh. Routine Troublesh.
Risers / Routine monitoring Combined sample point (Prod. Monthly N/A 3-Monthly N/A Contamination entering the
< 100 cells/ mL
Wellheads (1) point Manifold). system (baseline)
Troubleshooting point All Risers / Wellheads 3-Monthly Monthly Yearly 3-Monthly < 100 cells/ mL Contamination entering the
(6) (6) system (baseline)
Oil Process Routine monitoring First and Last of Oil chain - Monthly N/A 3-Monthly N/A Contamination of (2)
< 100 cells/ mL
vessels point PW Outlet downstream piping/pipelines
Troubleshooting point All Oil process vessels (3) 3-Monthly Monthly Yearly 3-Monthly < 100 cells/ mL Contamination of
(6) (6) downstream piping pipelines
PW Process Routine monitoring First and Last of PW Monthly N/A 3-Monthly N/A Contamination of (5)
< 100 cells/ mL
vessels chain point downstream piping/pipelines
Contamination of
Troubleshooting point All PW process vessels 3-Monthly Monthly Yearly 3-Monthly < 100 cells/ mL
downstream piping/pipelines
(6) (6)
Produced Water Routine monitoring PW Tank Outlet Monthly N/A 3-Monthly N/A < 1000 cells/ mL Contamination of (5)
Tanks point downstream piping/pipelines
Troubleshooting point All PW Tank Outlets (4) 3-Monthly Monthly Yearly 3-Monthly < 1000 cells/ mL Contamination of
(6) (6) downstream piping/pipelines
Drains vessels Routine monitoring Return line towards process – Monthly 3 - Monthly < 1000 cells/ mL Contamination of (5)
point while return pump is running downstream piping/pipelines
Pipelines Routine monitoring Inlet / Outlet Monthly 3 - Monthly < 100 cells/ mL Status of pipeline
point
(1) For multiphase oil isers, monitoring to begin only once BS&W > 5%All oil process vessels with BS&W > 5% at the oil outlet. If no PW outlet available, no sample to be collected
(2) Vessels only - Hydrocyclones / Sandcyclones / Flottation and Wemco units are excluded
(3) Chose one Tank which is online. A different tank can be used every time
(4) Only if recycled to production
(5) Sample to be collected 24h before and after biocide treatment.
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Appendix 5
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