PH V - Sankalp022 PCM - 23-6-2021-Adv-P1

(PANINI-eSANKALP022AP1A, AP1-AP8, CP1-DP1, PH1)
IIT – JEE, 2022

PAPER I (PHASE –V)
Time: 3 Hours Maximum Marks: 198
INSTRUCTIONS
A. Question Paper Format

The question paper consists of three parts (Physics, Chemistry and Mathematics). Each part consists of two sections.
1. Section 1 contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which only
ONE option is correct.
2. Section 2: contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of which One
Or More Than One are correct.
3. Section 3 contains 6 Numerical answer type questions with answer XXXXX.XX and each question carries +4 marks
for correct answer. There is no negative marking
B. Marking Scheme
4. For each questions in Section 1 you will be awarded 3 marks if you darken the bubble corresponding to the correct
answer only and (–1) mark for wrong answer and 0 marks if no bubbles are darkened.
5. For each question Section 2: marks will be awarded in one of the following categories:
Full Marks : + 4 If only the bubble(s) corresponding to all the correct option(s) is(are) darkened.
Partial Marks : + 1 For darkening a bubble corresponding to each correct option, provided NO
incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : – 2 In all other cases.
For example, if [A], [C] and [D] are all the correct options for a question, darkening all these three will get +4 marks;
darkening only [A] and [D] will get +2 marks; and darkening [A] and [B] will get -2 marks, as a wrong option is also
darkened.
6. For each questions in Section 3: you will be awarded +4 marks for correct answer and no negative marking.
Enrolment No. :
Name : . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 26515949, 26569493, Fax 26513942
website: www.fiitjee.com.
IT-2022- eSANKALP022AP1A, AP1-AP8, CP1-DP1, PH1–PH-V -PCM-P1-2
PART I: PHYSICS
SECTION – 1 : (Only One Option Correct Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D)
out of which ONLY ONE option is correct.
1. In the circuit shown in the figure, I1, I2, I3, I4 denote current in
2E
the branches. Choose the correct option.
R
(A) I1 > I2 > I3 > I4 I1 2R
R
E R E
(B) I1 = I2 > I3 > I4
R I2 4R
(C) I1 < I3 < I2 < I4 I3 4E
(D) I2 < I1 < I3 < I4 3R I4
13E
2. Nine similar resistors of resistance R are connected as shown in the

A
figure. Equivalent resistance between points A and B is
3 4
(A) R (B) R
5 3 B
9
(C) R (D) R
5
3. The variation of electric field between the two charges q1 E

and q2 along the line joining the charges is plotted against
distance from q1 (taking rightward direction of electric field
as positive) as shown in the figure. Then the correct x2 x
q1 x1 q2
statement is
(A) q1 and q2 are positive charges and q1  q2
(B) q1 and q2 are positive charges and q1  q2

(C) q1 and q2 are negative charges and q1  q2
(D) q1 and q2 are negative charges and q1  q2
q
4. All the charge particles each of magnitude q lie on the
circumference of a ring of radius R as shown in the figure. Find
the magnitude of net electrostatic force acting on the charge +q
+q
P
particle P. 60 R
30 30
30 30
(A)
5 
3  4 kq2
(B)
3 
3  2 kq2
q q
2 3 R2 2 3 R2
+q
(C)
3 
3  2 kq2
(D)
5 
3  4 kq2
3 R2 4 3 R2
IT-2022- eSANKALP022AP1A, AP1-AP8, CP1-DP1, PH1-PHV-PCM-P1-3
5. A large metallic plate is facing a charged sheet having charge 

density  placed parallel to plate at a distance l from the plate.
Potential at point P at a distance x from the sheet is P
x
 
(A) l  x (B) l  x 
20 20
l
 
(C) l  x  (D) l  x 
0 0
6. Resistance of each part is ‘R’ and resistance of circumference

is negligible as shown in figure. Find the equivalent resistance
across AB. B
A
(A) 3R
(B) 3R/2
(C) 3R/4
(D) 3R/16
SECTION – 2: (One or More Than One Options Correct Type)

This section contains 6 multiple choice type questions. Each question has four choices (A), (B), (C)
and (D) out of which ONE or MORE THAN ONE are correct.
7. Inside an electrical conductor there is a cavity and a charge q is

suspended fixed inside the cavity space without any electrical
 Cavity
contact with conductor. Let E1 be the electrostatic field due to q

charge q at P. E2 be the electrostatic field at P due to induced P

charge on the inner surface of cavity. E3 be the electrostatic field at
P due the induced charge on the outer surface of conductor then
       
(A) E1  E2  E3  0 (B) E1  E2  0 (C) E1  E3  0 (D) E3  0
8. Two charged particles have same mass m and charge (+q) and (q) are kept at same horizontal
level in gravitational field of earth with large separation between them so that Coulmbian
attraction becomes negligible. There exists a uniform horizontal electric field of strength E = mg/q.
Now the charge particles are projected with equal speed at t = 0 vertically upward direction. Then
at any time t
(A) Magnitude of change in momentum of two charged particles system in time t is 2mgt.
(B) Magnitude of change in momentum of positively charge particle will be equal to 2mgt .
(C) Sum of linear momentum of +q and q is zero in horizontal direction.

(D) None of these
9. A conducting sphere of radius b has a spherical cavity with its Q

centre displaced by “a” from centre of sphere. A point charge q
is placed at the centre of cavity, Q charge is given to
conducting sphere and charge q0 is placed at a distance c from a P
q c
centre (O1) of sphere such that O1, O2 and P are collinear.
O2 O1 q0
(A) Charge distribution on inner surface of cavity is uniform
b
 q0 Qq 
(B) Potential of conductor is   
 4 0 c 4 0 b 
(C) Charge distribution of outer surface of conducting sphere is non uniform
(D) Charge distribution of outer surface of conducting sphere is uniform
10. A positively charged ring having uniform charge density is

shown in the figure. Two elements of ring of length l1 and l2
subtend same angle (very small) at point A. Point A is in the
plane of ring but not at the centre. The elements l1 and l2 are at
distance r1 and r2 respectively from the point A.
r1
(A) The ratio of charges of elements 1 and 2 is
r2
(B) Net electric field at point A is zero
(C) The elements 1 and 2 produce same potential at A
(D) The direction of net electric field at A is towards 2
11. A positively charged particle of charge q and mass m is suspended from a O

point O by a string of length . In the space a uniform horizontal electric field
E
E exists. The particle is drawn aside so that the string becomes vertical and
then it is projected horizontally with velocity v such that the particle starts to g
move along a circle with same constant speed v.
2 2
(A) tension in string is  mg   qE 
v
  qE 2 
(B) tension in string is mg 1    
mg  
  
q2E2  5 q2E2
(C) kinetic energy of mass is (D) kinetic energy of mass is m  g2  2
2mg 2 m
12. Current through the battery in the circuit shown in the figure S

C R C
(A) immediately after the switch S is closed is /R
R
(B) immediately after the switch S is closed is /2R R C
R C C
(C) after long time is /2R
(D) after long time is 3/4R
SECTION – 3: (Numerical Value Type)

This section contains 6 questions. The answer of each question is a numerical value in a decimal
notation, truncated/rounding off to the second decimal place e.g.
1. What is the potential difference between the points M and N for E1

r1  3
the circuits shown in the figures. A 12 V
B
r2  2
C D
E2 = 6 V
M N
Case I
2. Calculate the electric field (in mV/m) in a copper wire of cross-sectional area 2.0 mm carrying a
current of 1 A. The resistivity of copper = 1.7 108   m .
3. The particles P shown in figure has a mass of 10 mg and a charge of –0.01 µC. Each plate has a
2
surface area 100 cm on one side. What potential difference V (in mV) should be applied to the
combination to hold the particle P in equilibrium?
4. Total charge – Q is uniformly spread along circumference of a fixed ring of radius R. A

small test charge +q of mass m is kept at the centre of the ring and is given a gentle push
(small displacement) along the axis of the ring. Find the time period of the motion of
Qq
charge +q in second (Given mass of test charge q is m  )
64 3 0 R 3
5. A and B are two points on a uniform ring of resistance R. The ACB = , where C is the
centre of the ring. Find the equivalent resistance (in ) between A and B (Given

 , R  4 )
2
6. Find the value of current (in ampere) passed through point ‘A’ 3 2
when the switch ‘S’ is pressed 12 V A 6V
1
PART II: CHEMISTRY

1.
O
C CH3 CH2 CH3
+
H2C CH2 NMe3 +
H2C CH2 NMe3
Above conversion can be achieved by :

(a) Wolff-Kishner reduction (b) Clemmensen reduction
(c) LiAlH4 (d) NaBH4
2. CH3
O
 H2 SO5 
(A)  H2 SO 4 . Major product (A) is :
monoperoxy
sulfuric acid
CH
H3C CH3
5  isopropyl
2  methyl cyclohexanone
(a) H3C (b) H3C

O
O O
(c) H3C (d) H3C

O O
O
3. Find out major product which is formed by the following reaction :
conc. H+/
NH NH
(a) (b) NH2

H2N NH2
NH2
(c) NH2 (d) NH2 NH2
N
H
 i  O3 SeO2 i Conc. KOH  Z

4. 2  Butene   X     Y    
ii  Me2S ii  Conc. H2SO4 / 
The end product [Z] is
O
O
C
(A) C (B) O
O C
O
O
O
O
(C) (D) O O
O
O
O
5. STATEMENT 1 : Diamine silver (I) hydroxide, [Ag(NH3)2]OH is used to distinguish
between formic acid and acetic acid
Because
STATEMENT 2 : Formic acid contains –CHO group also and hence it reduces Tollen’s
Reagent
(a) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for

Statement-1
(b) Statement-1 is True, Statement-2 is True ; Statement-2 is Not a correct explanation for
Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True.
6. STATEMENT 1 : During acid catalyzed esterification, oxygen atom of alcohol is generally

present in ester molecule.
Because
STATEMENT 2 : Esterification is a reversible reaction.
(a) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for

Statement-1
(b) Statement-1 is True, Statement-2 is True ; Statement-2 is Not a correct explanation for
Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True.

7. Which of the following will give yellow ppt of CHI3 when treated with NaOI.
O O
(a) (b)
CH3 C OC2H5 CH3 C Cl
O OH
(c) I 3C CH (d) O
8. Which of the following can reduce Fehling's solution

(a) Formic acid (b) 1-hydroxy-3-pentanone
(c) 1-methoxy ethanol (d) Acetaldehyde
9. Correct statement(s) among the following is/are
(a) Formic acid gives positive test with Tollen’s reagent

(b) Benzaldehyde gives positive test with Fehling’s solution
O
(c)
OH gives positive test with Benedict’s solution
(d) N-phenyl hydroxyl amine gives positive test with Tollen’s reagent.
Sn/HCl alc AgCN alc KCN Sn/HCl

10. B2   A 2   CH3  Br   A1   B1
B1 and B2 can be distinguished by
(a) HNO2 (b) CHCl3 + NaOH (c) CS2 and HgCl2 (d) Hinsberg reagent
11. CH3
H Cl NaI / acetone
H3C H  P
Cl
Correct option(s) is/are
(a) Reaction with Br2 / CCl4 ; P will form a meso compound
(b) Reaction with Cl2 / H2O ; P will form a diastereomer pair
(c) Reaction with OsO4 / NaHSO3, P will form a recemic mixture
(d) Reaction with Baeyer Reagent, P will form a meso compound
monochlorination
 monochlorinated products
12.
Correct statement(s) about the number of products formed is/are
(a) Number of diastereomeric pairs is 4
(b) Number of optically inactive compounds formed is 2
(c) Number of enantiomeric pairs is 4
(d) Number of total monochlorinated compounds formed is 7

1. Cyclopentyl ethanol is heated with Ca(OH)2 and iodine solution to produce a

compound(X) and a yellow precipitate. Calculate the ratio of molar mass of ‘X’ to its
degree of unsaturation (Round off your answer up to the second place of decimal]
2. Consider the following sequence of reaction :

O
OEt
EtO (i) C 2H5ONa/C2H5OH,
(P)
O (ii) H 3O +, (major product)
(iii) dil.NaOH,
Calculate the ratio of molar mass of (P) to the degree of unsaturation of (P)
3. Methanal condenses with ammonia to form a compound (X). One-fifth of the total
number of C-N bonds present in a molecule of ‘X’ is ____
4. Ratio of the maximum number of moles of HI that can react with 1 mole of glycerol to
that of 1 mole of ethylene glycol, is _________
[Round – off the answer upto the second place of decimal]
5. OH
conc. H2SO4 Br2
No. of organic products (x) No. of organic products (y)
CCl4
Value of (y/x) is _________ (Round-off the answer upto 2nd place of decimal)
6.
(i) KCN/H+ (catalyst)
CH3CHO (P)
+
(ii) H 3O (major product)
(iii) conc, H 2SO4/
Ratio of different number of isomeric forms of ‘A’ to the number of
oxygen atoms present in a molecule of ‘A’ is _________
PART III: MATHEMATICS



1.
2x  2
2. Find the limits lim 3
x 1 26  x  3
3.
4.
 x  2  1  1
5. lim   is equal to ln5 , then value of K is ____________.
x  1 log x  2   K
 5 
2 2     5
6. If f(x) = sin x + sin  x  + cosx cos  x  3  and g  4  = 1 then gof(x) is ____________
 3     
(PANINI-eSANKALP022AP1A, AP1-AP8, CP1-DP1, PH1)
IIT – JEE, 2022

PAPER I (PHASE –V)
ANSWERS
PHYSICS (PART-I)
SECTION – 1
1. D
2. A
4. D
5. C
7. A, B, D
8. A, B, C
9. A, B, C
10. A, C, D
11. B, C
12. A, C
1. 8.4
2. 8.4 to 8.6
3. 42.50 to 43.50
4. 0.50
6. 3.80 to 3.85
CHEMISTRY (PART-II)
SECTION – 1
1. B
2. C
3. A
4. C
5. A
6. B
7. C, D
8. A,C,D
9. A,C, D
10. A,B,C,D
11. A, C
12. A, B, C
1. 55.33
2. 37.50
3. 2.40
4. 1.67
5. 1.67
6. 0.75
MATHEMATICS (PART-III)
SECTION – 1
1. D
2. A
3. D
4. C
5. A
6. A
SECTION – 2
7. A, B, D
8. A, D
9. A, B, D
10. A, C
11. A, B
12. A, C
SECTION – 3
1. 6.00
2. 54.00
3. 7.00
4. 2.00
5. 2.00
6. 1.00

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(PANINI-eSANKALP022AP1A, AP1-AP8, CP1-DP1, PH1)

IIT – JEE, 2022

A. Question Paper Format

Batch : . . . . . . . . . . . . . . . . . . . . . . .Session :. . . . . . . . . . . . . . . . . . . . . . Date:. . . . . . . . . . . . . . . .

2. Nine similar resistors of resistance R are connected as shown in the

3. The variation of electric field between the two charges q1 E

(B) q1 and q2 are positive charges and q1  q2

5. A large metallic plate is facing a charged sheet having charge 

6. Resistance of each part is ‘R’ and resistance of circumference

SECTION – 2: (One or More Than One Options Correct Type)

7. Inside an electrical conductor there is a cavity and a charge q is

(C) Sum of linear momentum of +q and q is zero in horizontal direction.

9. A conducting sphere of radius b has a spherical cavity with its Q

(C) Charge distribution of outer surface of conducting sphere is non uniform

(D) Charge distribution of outer surface of conducting sphere is uniform

10. A positively charged ring having uniform charge density is

(B) Net electric field at point A is zero

(C) The elements 1 and 2 produce same potential at A

(D) The direction of net electric field at A is towards 2

11. A positively charged particle of charge q and mass m is suspended from a O

(D) after long time is 3/4R

SECTION – 3: (Numerical Value Type)

1. What is the potential difference between the points M and N for E1

4. Total charge – Q is uniformly spread along circumference of a fixed ring of radius R. A

PART II: CHEMISTRY

Above conversion can be achieved by :

(a) H3C (b) H3C

(c) H3C (d) H3C

3. Find out major product which is formed by the following reaction :

(a) (b) NH2

(c) NH2 (d) NH2 NH2

 i  O3 SeO2 i Conc. KOH  Z

(a) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for

6. STATEMENT 1 : During acid catalyzed esterification, oxygen atom of alcohol is generally

(a) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for

SECTION – 2: (One or More Than One Options Correct Type)

8. Which of the following can reduce Fehling's solution

9. Correct statement(s) among the following is/are

(a) Formic acid gives positive test with Tollen’s reagent

Sn/HCl alc AgCN alc KCN Sn/HCl

SECTION – 3: (Numerical Value Type)

1. Cyclopentyl ethanol is heated with Ca(OH)2 and iodine solution to produce a

2. Consider the following sequence of reaction :

PART III: MATHEMATICS

SECTION – 2: (One or More Than One Options Correct Type)

SECTION – 3: (Numerical Value Type)

(PANINI-eSANKALP022AP1A, AP1-AP8, CP1-DP1, PH1)

IIT – JEE, 2022

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