ASAP 2420 V2.06 (V2.

06 J) Unit 1 Port 5 Serial #: 192 Page 1

Sample: 6
Operator:
Submitter:
File: C:\2420\DATA\VERIFI~1\000-683.SMP

Started: 14/07/2018 8:01:53 Analysis Adsorptive: N2

Completed: 14/07/2018 11:42:26 Analysis Bath Temp.: 77.350 K
Report Time: 14/07/2018 22:03:05 Thermal Correction: No
Sample Mass: 3.5922 g Warm Free Space: 14.6928 cm³ Measured
Cold Free Space: 42.0125 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.6150 p3(d), p(a)

Summary Report

Surface Area
Single point surface area at P/Po = 0.250015959: 0.5626 m²/g

BET Surface Area: 0.5717 m²/g

Langmuir Surface Area: 0.7943 m²/g t-

Plot Micropore Area: 0.0942 m²/g

t-Plot External Surface Area: 0.4775 m²/g

BJH Adsorption cumulative surface area of pores

between 1.7000 nm and 300.0000 nm diameter: 0.443 m²/g

BJH Desorption cumulative surface area of pores

between 1.7000 nm and 300.0000 nm diameter: 0.5274 m²/g

Pore Volume
Single point desorption total pore volume of pores
less than 78.9761 nm diameter at P/Po = 0.975054162: 0.001450 cm³/g

t-Plot micropore volume: 0.000042 cm³/g

BJH Adsorption cumulative volume of pores

between 1.7000 nm and 300.0000 nm diameter: 0.002109 cm³/g

BJH Desorption cumulative volume of pores

between 1.7000 nm and 300.0000 nm diameter: 0.002135 cm³/g

Pore Size
Desorption average pore width (4V/A by BET): 10.14682 nm BJH

Adsorption average pore diameter (4V/A): 19.0264 nm BJH

Desorption average pore diameter (4V/A): 16.1957 nm

 Started: 14/07/2018 8:01:53 Analysis Adsorptive: N2
Completed: 14/07/2018 11:42:26 Analysis Bath Temp.: 77.350 K
Report Time: 14/07/2018 22:03:05 Thermal Correction: No
Sample Mass: 3.5922 g Warm Free Space: 14.6928 cm³ Measured
Cold Free Space: 42.0125 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.6150 p3(d), p(a)

Isotherm Tabular Report

Relative Absolute Quantity Elapsed Time Saturation
Pressure (P/Po) Pressure Adsorbed (h:min) Pressure
(mmHg) (cm³/g STP) (mmHg)

00:53 764.843445
0.010290347 7.871056 0.0937 01:01 764.897034
0.033761458 25.825222 0.1154 01:04 764.932068
0.068442498 52.359501 0.1321 01:06 765.014465
0.079948269 61.160099 0.1354 01:08 764.995911
0.099989132 76.493340 0.1409 01:10 765.016541
0.120022102 91.812088 0.1456 01:12 764.959839
0.140029888 107.117386 0.1501 01:14 764.960876
0.160073039 122.453735 0.1544 01:16 764.986633
0.180104365 137.768341 0.1579 01:18 764.936157
0.200143507 153.094330 0.1612 01:20 764.922791
0.250015959 191.237488 0.1723 01:22 764.901123
0.300353302 229.747086 0.1833 01:24 764.922791
0.350257596 267.901611 0.1941 01:26 764.870239
0.400026214 305.964020 0.2048 01:28 764.859924
0.450011256 344.185852 0.2163 01:30 764.838318
0.499946143 382.440796 0.2281 01:32 764.963989
0.550010377 420.709229 0.2409 01:34 764.911438
0.600009225 458.934143 0.2546 01:36 764.878479
0.649913820 497.131195 0.2704 01:38 764.918640
0.699966086 535.393311 0.2896 01:40 764.884644
0.749730621 573.486816 0.3126 01:42 764.923828
0.799728141 611.754150 0.3413 01:44 764.952637
0.820101089 627.286133 0.3570 01:46 764.888794
0.850162830 650.289673 0.3820 01:48 764.900146
0.874847030 669.158875 0.4082 01:51 764.886719
0.899733425 688.215454 0.4430 01:53 764.910400
0.924478862 707.153992 0.4914 01:55 764.921753
0.948581033 725.568787 0.5715 01:58 764.899109
0.970505071 742.387451 0.7361 02:02 764.949585
0.978260040 748.315552 0.8689 02:07 764.945435
0.985264438 753.735474 1.0978 02:13 765.008301
0.990415043 757.714478 1.4093 02:21 765.047424
0.983010668 752.073059 1.1889 02:26 765.071106
0.975054162 745.994812 0.9375 02:33 765.080383
0.964944772 738.233459 0.7721 02:38 765.052551
0.954446084 730.210266 0.6772 02:41 765.061829
0.929163828 710.865906 0.5539 02:45 765.059814
0.902590225 690.556885 0.4834 02:47 765.083496
0.876813286 670.867859 0.4367 02:49 765.120544
0.850885719 650.992493 0.4009 02:51 765.076294
0.825568165 631.633667 0.3733 02:53 765.089661
0.800416815 612.406311 0.3504 02:55 765.109253
0.750486783 574.195862 0.3148 02:57 765.097900
 Started: 14/07/2018 8:01:53 Analysis Adsorptive: N2
Completed: 14/07/2018 11:42:26 Analysis Bath Temp.: 77.350 K
Report Time: 14/07/2018 22:03:05 Thermal Correction: No
Sample Mass: 3.5922 g Warm Free Space: 14.6928 cm³ Measured
Cold Free Space: 42.0125 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.6150 p3(d), p(a)

Isotherm Tabular Report

Relative Absolute Quantity Elapsed Time Saturation
Pressure (P/Po) Pressure Adsorbed (h:min) Pressure
(mmHg) (cm³/g STP) (mmHg)

0.700498812 535.959534 0.2863 02:59 765.111267

0.650569430 497.755341 0.2627 03:01 765.107178
0.600696010 459.589386 0.2419 03:03 765.094788
0.531789936 406.887268 0.2164 03:05 765.127808
0.481661801 368.518433 0.1953 03:07 765.097900
0.431606857 330.208618 0.1760 03:09 765.068054
0.381471931 291.851196 0.1603 03:12 765.065979
0.331386356 253.531052 0.1454 03:14 765.061829
0.281389340 215.294739 0.1291 03:16 765.113342
0.231275985 176.946625 0.1126 03:18 765.088623
0.181081465 138.554001 0.0967 03:20 765.147339
0.121594822 93.038704 0.0714 03:27 765.153503
 Started: 14/07/2018 8:01:53
Completed: 14/07/2018 11:42:26
Report Time: 14/07/2018 22:03:05
Sample Mass: 3.5922 g
Cold Free Space: 42.0125 cm³
Ambient Temperature: 22.00 °C
Automatic Degas: Yes
Analysis Adsorptive: N2
Analysis Bath Temp.: 77.350 K
Thermal Correction: No
Warm Free Space: 14.6928 cm³ Measured
Equilibration Interval: 10 s
Low Pressure Dose: None

Comments: tubo + muestra sin desg = 52.6150 p3(d), p(a)

Isotherm Linear Plot

6 - Adsorption
6 - Desorption

1.4

1.2

1.0
Quantity Adsorbed (cm³/g STP)

0.8

0.6

0.4

0.2

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Relative Pressure (P/Po)
 ASAP 2420 V2.06 (V2.06 J) Unit 1 Port 5 Serial #: 192 Page 5

Sample: 6
Operator:
Submitter:
File: C:\2420\DATA\VERIFI~1\000-683.SMP

Started: 14/07/2018 8:01:53 Analysis Adsorptive: N2

Completed: 14/07/2018 11:42:26 Analysis Bath Temp.: 77.350 K
Report Time: 14/07/2018 22:03:05 Thermal Correction: No
Sample Mass: 3.5922 g Warm Free Space: 14.6928 cm³ Measured
Cold Free Space: 42.0125 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.6150 p3(d), p(a)

Isotherm Log Plot

6 - Adsorption
6 - Desorption

1.4

1.2

1.0
Quantity Adsorbed (cm³/g STP)

0.8

0.6

0.4

0.2

0.0
0.01 0.05 0.1 0.5 1
Relative Pressure (P/Po)
 Started: 14/07/2018 8:01:53 Analysis Adsorptive: N2
Completed: 14/07/2018 11:42:26 Analysis Bath Temp.: 77.350 K
Report Time: 14/07/2018 22:03:05 Thermal Correction: No
Sample Mass: 3.5922 g Warm Free Space: 14.6928 cm³ Measured
Cold Free Space: 42.0125 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.6150 p3(d), p(a)

BET Surface Area Report

BET Surface Area: 0.5717 ± 0.0032 m²/g
Slope: 7.585216 ± 0.041734 g/cm³ STP
Y-Intercept: 0.029926 ± 0.006461 g/cm³ STP
C: 254.463143
Qm: 0.1313 cm³/g STP
Correlation Coefficient: 0.9998941
Molecular Cross-Sectional Area: 0.1620 nm²
Relative Quantity 1/[Q(Po/P - 1)]
Pressure Adsorbed
(P/Po) (cm³/g STP)

0.068442498 0.1321 0.556094

0.079948269 0.1354 0.641928
0.099989132 0.1409 0.788608
0.120022102 0.1456 0.936808
0.140029888 0.1501 1.084510
0.160073039 0.1544 1.234568
0.180104365 0.1579 1.391603
0.200143507 0.1612 1.552083
0.250015959 0.1723 1.934577
 ASAP 2420 V2.06 (V2.06 J) Unit 1 Port 5 Serial #: 192 Page 7

Sample: 6
Operator:
Submitter:
File: C:\2420\DATA\VERIFI~1\000-683.SMP

Started: 14/07/2018 8:01:53 Analysis Adsorptive: N2

Completed: 14/07/2018 11:42:26 Analysis Bath Temp.: 77.350 K
Report Time: 14/07/2018 22:03:05 Thermal Correction: No
Sample Mass: 3.5922 g Warm Free Space: 14.6928 cm³ Measured
Cold Free Space: 42.0125 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.6150 p3(d), p(a)

BET Surface Area Plot

6

1.8

1.6

1.4

1.2
1/[Q(Po/P - 1)]

1.0

0.8

0.6

0.4

0.2

0.0
0.00 0.05 0.10 0.15 0.20 0.25
Relative Pressure (P/Po)