ASAP 2420 V2.06 (V2.

06 J) Unit 1 Port 1 Serial #: 192 Page 1

Sample: 7
Operator:
Submitter:
File: C:\2420\DATA\VERIFI~1\000-726.SMP

Started: 02/08/2018 20:54:07 Analysis Adsorptive: N2

Completed: 03/08/2018 1:12:16 Analysis Bath Temp.: 77.350 K
Report Time: 03/08/2018 16:19:37 Thermal Correction: No
Sample Mass: 3.0574 g Warm Free Space: 15.6881 cm³ Measured
Cold Free Space: 47.0184 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

Summary Report

Surface Area
Single point surface area at P/Po = 0.249661682: 1.6605 m²/g

BET Surface Area: 1.7081 m²/g

Langmuir Surface Area: 2.4064 m²/g t-

Plot Micropore Area: 0.1588 m²/g

t-Plot External Surface Area: 1.5493 m²/g

BJH Adsorption cumulative surface area of pores

between 1.7000 nm and 300.0000 nm diameter: 1.309 m²/g

BJH Desorption cumulative surface area of pores

between 1.7000 nm and 300.0000 nm diameter: 1.5749 m²/g

Pore Volume
Single point desorption total pore volume of pores
less than 100.4395 nm diameter at P/Po = 0.980505084: 0.005660 cm³/g

t-Plot micropore volume: 0.000063 cm³/g

BJH Adsorption cumulative volume of pores

between 1.7000 nm and 300.0000 nm diameter: 0.006108 cm³/g

BJH Desorption cumulative volume of pores

between 1.7000 nm and 300.0000 nm diameter: 0.006293 cm³/g

Pore Size
Desorption average pore width (4V/A by BET): 13.25365 nm BJH

Adsorption average pore diameter (4V/A): 18.6667 nm BJH

Desorption average pore diameter (4V/A): 15.9841 nm

 Started: 02/08/2018 20:54:07 Analysis Adsorptive: N2
Completed: 03/08/2018 1:12:16 Analysis Bath Temp.: 77.350 K
Report Time: 03/08/2018 16:19:37 Thermal Correction: No
Sample Mass: 3.0574 g Warm Free Space: 15.6881 cm³ Measured
Cold Free Space: 47.0184 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

Isotherm Tabular Report

Relative Absolute Quantity Elapsed Time Saturation
Pressure (P/Po) Pressure Adsorbed (h:min) Pressure
(mmHg) (cm³/g STP) (mmHg)

00:41 758.832397
0.009756712 7.406727 0.2763 00:57 759.141663
0.032919422 24.992134 0.3332 01:00 759.191162
0.068011114 51.636658 0.3795 01:02 759.238525
0.079947142 60.696808 0.3907 01:04 759.211731
0.100143522 76.032722 0.4087 01:06 759.237549
0.120165396 91.232841 0.4248 01:08 759.227234
0.140140388 106.401863 0.4402 01:10 759.251953
0.160154226 121.603020 0.4539 01:12 759.286987
0.180132996 136.776169 0.4659 01:14 759.306580
0.200178741 151.999100 0.4781 01:16 759.316895
0.249661682 189.576965 0.5083 01:18 759.335449
0.300155415 227.922989 0.5399 01:20 759.349915
0.350205847 265.925873 0.5706 01:22 759.341614
0.399706176 303.523438 0.6015 01:24 759.366394
0.449715189 341.492096 0.6332 01:26 759.351929
0.499625976 379.406891 0.6665 01:29 759.381836
0.549638945 417.368286 0.7016 01:31 759.349915
0.599556205 455.277893 0.7405 01:33 759.358154
0.649530016 493.258026 0.7839 01:35 759.407593
0.699410162 531.156128 0.8353 01:37 759.434387
0.749295110 569.063660 0.8973 01:39 759.465332
0.799029551 606.846802 0.9748 01:41 759.479797
0.819694795 622.583862 1.0158 01:43 759.531311
0.849381554 645.178284 1.0827 01:46 759.585938
0.873985831 663.892578 1.1539 01:48 759.614807
0.898685900 682.685669 1.2487 01:51 759.648804
0.922837368 701.036133 1.3852 01:55 759.652954
0.945978896 718.671265 1.6004 02:00 759.711731
0.969659513 736.736633 2.1839 02:11 759.789001
0.976623535 742.106384 2.5976 02:20 759.869446
0.983699072 747.506165 3.2834 02:30 759.893127
0.988504291 751.122986 4.0826 02:42 759.858093
0.980505084 745.105347 3.6590 02:51 759.919922
0.975747961 741.481262 3.2425 02:59 759.910645
0.955679735 726.227295 2.1597 03:13 759.906555
0.926179485 703.867126 1.5583 03:23 759.968384
0.891250386 677.386414 1.2921 03:28 760.040527
0.860572048 654.089172 1.1642 03:31 760.063232
0.833651992 633.673767 1.0840 03:34 760.117859
0.807977782 614.159180 1.0241 03:36 760.118896
0.800720896 608.650513 1.0035 03:38 760.128174
0.750476757 570.481750 0.9163 03:40 760.159119
0.701482641 533.244934 0.8464 03:43 760.168396
 Started: 02/08/2018 20:54:07 Analysis Adsorptive: N2
Completed: 03/08/2018 1:12:16 Analysis Bath Temp.: 77.350 K
Report Time: 03/08/2018 16:19:37 Thermal Correction: No
Sample Mass: 3.0574 g Warm Free Space: 15.6881 cm³ Measured
Cold Free Space: 47.0184 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

Isotherm Tabular Report

Relative Absolute Quantity Elapsed Time Saturation
Pressure (P/Po) Pressure Adsorbed (h:min) Pressure
(mmHg) (cm³/g STP) (mmHg)

0.650465546 494.455292 0.7877 03:45 760.156006

0.600462210 456.449280 0.7374 03:47 760.163208
0.550426847 418.444305 0.6912 03:49 760.217834
0.500623565 380.594849 0.6491 03:51 760.241577
0.451060750 342.930939 0.6007 03:53 760.276611
0.381961738 290.396576 0.5535 03:55 760.276611
0.331637489 252.132462 0.5203 03:57 760.265259
0.281460661 213.979248 0.4869 03:59 760.245667
0.231327677 175.870636 0.4530 04:01 760.266296
0.181297683 137.839752 0.4173 04:03 760.295166
0.121570232 92.426003 0.3704 04:05 760.268372
 Started: 02/08/2018 20:54:07
Completed: 03/08/2018 1:12:16
Report Time: 03/08/2018 16:19:37
Sample Mass: 3.0574 g
Cold Free Space: 47.0184 cm³
Ambient Temperature: 22.00 °C
Automatic Degas: Yes
Analysis Adsorptive: N2
Analysis Bath Temp.: 77.350 K
Thermal Correction: No
Warm Free Space: 15.6881 cm³ Measured
Equilibration Interval: 10 s
Low Pressure Dose: None

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

Isotherm Linear Plot

7 - Adsorption
7 - Desorption
4.0

3.5

3.0
Quantity Adsorbed (cm³/g STP)

2.5

2.0

1.5

1.0

0.5

0.0
0.0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Relative Pressure (P/Po)
 ASAP 2420 V2.06 (V2.06 J) Unit 1 Port 1 Serial #: 192 Page 5

Sample: 7
Operator:
Submitter:
File: C:\2420\DATA\VERIFI~1\000-726.SMP

Started: 02/08/2018 20:54:07 Analysis Adsorptive: N2

Completed: 03/08/2018 1:12:16 Analysis Bath Temp.: 77.350 K
Report Time: 03/08/2018 16:19:37 Thermal Correction: No
Sample Mass: 3.0574 g Warm Free Space: 15.6881 cm³ Measured
Cold Free Space: 47.0184 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

Isotherm Log Plot

7 - Adsorption
7 - Desorption
4.0

3.5

3.0
Quantity Adsorbed (cm³/g STP)

2.5

2.0

1.5

1.0

0.5

0.0
0.01 0.05 0.1 0.5 1
Relative Pressure (P/Po)
 Started: 02/08/2018 20:54:07 Analysis Adsorptive: N2
Completed: 03/08/2018 1:12:16 Analysis Bath Temp.: 77.350 K
Report Time: 03/08/2018 16:19:37 Thermal Correction: No
Sample Mass: 3.0574 g Warm Free Space: 15.6881 cm³ Measured
Cold Free Space: 47.0184 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

BET Surface Area Report

BET Surface Area: 1.7081 ± 0.0113 m²/g
Slope: 2.530466 ± 0.016621 g/cm³ STP
Y-Intercept: 0.018058 ± 0.002573 g/cm³ STP
C: 141.130579
Qm: 0.3924 cm³/g STP
Correlation Coefficient: 0.9998490
Molecular Cross-Sectional Area: 0.1620 nm²
Relative Quantity 1/[Q(Po/P - 1)]
Pressure Adsorbed
(P/Po) (cm³/g STP)

0.068011114 0.3795 0.192284

0.079947142 0.3907 0.222398
0.100143522 0.4087 0.272281
0.120165396 0.4248 0.321474
0.140140388 0.4402 0.370220
0.160154226 0.4539 0.420130
0.180132996 0.4659 0.471600
0.200178741 0.4781 0.523498
0.249661682 0.5083 0.654536
 ASAP 2420 V2.06 (V2.06 J) Unit 1 Port 1 Serial #: 192 Page 7

Sample: 7
Operator:
Submitter:
File: C:\2420\DATA\VERIFI~1\000-726.SMP

Started: 02/08/2018 20:54:07 Analysis Adsorptive: N2

Completed: 03/08/2018 1:12:16 Analysis Bath Temp.: 77.350 K
Report Time: 03/08/2018 16:19:37 Thermal Correction: No
Sample Mass: 3.0574 g Warm Free Space: 15.6881 cm³ Measured
Cold Free Space: 47.0184 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

BET Surface Area Plot

7

0.6

0.5

0.4
1/[Q(Po/P - 1)]

0.3

0.2

0.1

0.0
0.00 0.05 0.10 0.15 0.20 0.25
Relative Pressure (P/Po)
 Started: 02/08/2018 20:54:07 Analysis Adsorptive: N2
Completed: 03/08/2018 1:12:16 Analysis Bath Temp.: 77.350 K
Report Time: 03/08/2018 16:19:37 Thermal Correction: No
Sample Mass: 3.0574 g Warm Free Space: 15.6881 cm³ Measured
Cold Free Space: 47.0184 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

t-Plot Report
Micropore Volume: 0.000063 cm³/g
Micropore Area: 0.1588 m²/g
External Surface Area: 1.5493 m²/g
Slope: 1.001643 ± 0.016299 cm³/g·nm STP
Y-Intercept: 0.040681 ± 0.006627 cm³/g STP
Correlation Coefficient: 0.999207
Surface Area Correction Factor: 1.000
Density Conversion Factor: 0.0015468 Total
Surface Area (BET): 1.7081 m²/g
Thickness Range: 0.35000 nm to 0.50000 nm
Thickness Equation: Harkins and Jura
t = [ 13.99 / ( 0.034 - log(P/Po) ) ] ^ 0.5

Relative
Statistical Quantity Fitted
Pressure (P/Po)
Thickness (nm) Adsorbed
(cm³/g STP)

0.009756712 0.26157 0.2763

0.032919422 0.30373 0.3332
0.068011114 0.34124 0.3795
0.079947142 0.35167 0.3907 *
0.100143522 0.36794 0.4087 *
0.120165396 0.38290 0.4248 *
0.140140388 0.39705 0.4402 *
0.160154226 0.41069 0.4539 *
0.180132996 0.42394 0.4659 *
0.200178741 0.43700 0.4781 *
0.249661682 0.46877 0.5083 *
0.300155415 0.50132 0.5399
0.350205847 0.53451 0.5706
0.399706176 0.56890 0.6015
0.449715189 0.60591 0.6332
0.499625976 0.64589 0.6665
0.549638945 0.68991 0.7016
0.599556205 0.73900 0.7405
0.649530016 0.79491 0.7839
 Started: 02/08/2018 20:54:07 Analysis Adsorptive: N2
Completed: 03/08/2018 1:12:16 Analysis Bath Temp.: 77.350 K
Report Time: 03/08/2018 16:19:37 Thermal Correction: No
Sample Mass: 3.0574 g Warm Free Space: 15.6881 cm³ Measured
Cold Free Space: 47.0184 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

t-Plot
Harkins and Jura
7 Not Fitted Points
0.8

0.7

0.6
Quantity Adsorbed (cm³/g STP)

0.5

0.4

0.3

0.2

0.1

0.0
0.00 0.05 0.10 0.15 0.20 0.25 0.30 0.35 0.40 0.45 0.50 0.55 0.60 0.65 0.70 0.75 0.80
Thickness (nm)
 Started: 02/08/2018 20:54:07 Analysis Adsorptive: N2
Completed: 03/08/2018 1:12:16 Analysis Bath Temp.: 77.350 K
Report Time: 03/08/2018 16:19:37 Thermal Correction: No
Sample Mass: 3.0574 g Warm Free Space: 15.6881 cm³ Measured
Cold Free Space: 47.0184 cm³ Equilibration Interval: 10 s
Ambient Temperature: 22.00 °C Low Pressure Dose: None
Automatic Degas: Yes

Comments: tubo + muestra sin desg = 52.2022 p1(d), p1(a)

BJH Adsorption Pore Distribution Report

Faas Correction
Harkins and Jura
t = [ 13.99 / ( 0.034 - log(P/Po) ) ] ^ 0.5
Diameter Range: 1.7000 nm to 300.0000 nm
Adsorbate Property Factor: 0.95300 nm
Density Conversion Factor: 0.0015468
Fraction of Pores Open at Both Ends: 0.00
Pore Diameter Average Incremental Cumulative Incremental Cumulative
Range (nm) Diameter (nm) Pore Volume Pore Volume Pore Area Pore Area
(cm³/g) (cm³/g) (m²/g) (m²/g)

168.6 - 119.7 135.9 0.001306 0.001306 0.038 0.038

119.7 - 84.1 95.7 0.001142 0.002448 0.048 0.086
84.1 - 65.3 72.3 0.000700 0.003148 0.039 0.125
65.3 - 37.4 44.0 0.001021 0.004169 0.093 0.218
37.4 - 26.6 30.1 0.000374 0.004543 0.050 0.267
26.6 - 20.5 22.7 0.000236 0.004779 0.042 0.309
20.5 - 16.6 18.1 0.000162 0.004941 0.036 0.345
16.6 - 14.0 15.1 0.000120 0.005060 0.032 0.376
14.0 - 11.7 12.6 0.000111 0.005172 0.035 0.412
11.7 - 10.6 11.1 0.000069 0.005240 0.025 0.437
10.6 - 8.5 9.3 0.000128 0.005369 0.055 0.492
8.5 - 7.1 7.6 0.000102 0.005470 0.053 0.545
7.1 - 6.0 6.4 0.000084 0.005554 0.052 0.597
6.0 - 5.2 5.5 0.000068 0.005622 0.049 0.647
5.2 - 4.6 4.8 0.000062 0.005684 0.051 0.698
4.6 - 4.0 4.3 0.000056 0.005740 0.052 0.750
4.0 - 3.6 3.8 0.000054 0.005794 0.057 0.807
3.6 - 3.2 3.4 0.000052 0.005845 0.061 0.868
3.2 - 2.9 3.0 0.000052 0.005898 0.069 0.937
2.9 - 2.6 2.7 0.000052 0.005950 0.076 1.013
2.6 - 2.3 2.4 0.000055 0.006004 0.090 1.104
2.3 - 2.1 2.2 0.000048 0.006053 0.089 1.193
2.1 - 2.0 2.0 0.000018 0.006070 0.035 1.228
2.0 - 1.9 1.9 0.000015 0.006086 0.032 1.261
1.9 - 1.8 1.8 0.000022 0.006108 0.048 1.309