Name: _________________________________ Date:__________

Assessment: Acids, Bases and Salts

I. Write an equation for the dissociation (ionization) of the following acids and bases in water:
H2O
a) HClO4 H+ + ClO4-
H2O
b)H2SO4
H2O
c) HC2H3O2
H2 O
d) H2S
H2O
e) NaOH
H2 O
f) Ba(OH)2

II. Complete the following table: (first one is done as an example)

Acidic, Basic, or
[H3O+] [OH-] pH pOH
Neutral?
a 1.0 x 10-3 1.0 x 10-11 3.00 11.00 Acidic
b 1.0 x 10-5
c 10.00
d 6.00

III. Calculate the pH of each of the following substances:

a) 0.0010 M HCl __________

b) 0.010 M NaOH __________
c) 1.0 M HBr __________
d) 0.075 M KOH ___________
e) 0.000000000001M H2SO4 __________

IV. Identify the acids and bases found in each chemical equation. Write the answer below each of the
substance .

1. HCl(g) + H2O(l) H3O+(aq) + Cl-(aq)

2. H2SO4(l) + 2H2O(l)    2H3O+(aq) + SO42-(aq)

3. CH3COOH (aq) + H2O (l) H3O+ + CH3COO- (aq)

4. HCO3 – (aq) + H2O (l) H2CO3 (aq) + OH- (aq)

5. NH3 + HCO3-  NH4+ + CO3-2

Name: _________________________________ Date:__________

Assessment: Chemical Equilibrium

I. Analysis: Determine the unknown for each given problem below. (5 points)

For numbers 1 to 5, refer to the following equation:

2C (g) + 2D (g) 3E (g) + F(g) + heat
Predict the direction of the shift in equilibrium. Write the letter of your answer.
a. forward b. backward c. no effect
________1. Increase in pressure
________2. Addition of compound C
________3. Removal of compound E
________4. Decrease in temperature
________5. Addition of catalyst

II. Write the equilibrium expression, Keq, for each of the following reactions:
a) 2 NO(g) + O2(g) ⇌2 NO2(g)

b) 4 HCl(g) + O2(g) ⇌2 H2O(g) + 2 Cl2(g)

c) NOCl(g)⇌NO(g) + ½ Cl2(g)

d) Fe3+(aq) + SCN-(aq)⇌FeSCN2+(aq)

e) CaCl2(s) ⇌Ca2+(aq) + 2Cl-(aq)

f) HC2H3O2(aq) + H2O(l) ⇌ H3O+(aq) + C2H3O2-(aq)

g) MgO(s) + CO2(g) ⇌ MgCO3(s)

h) C(s) + CO2(g) + 2Cl2(g) ⇌ COCl2(g)

i) Ca3(PO4)2(s) ⇌ 3 Ca2+(aq) + 2 PO43-(aq)

j) ZnO(s) + CO(g) ⇌ Zn(s) +CO2(g)

III. Classify the following equilibria as heterogeneous or homogeneous, and write an equilibrium expression
for each.
 a) NH4NO2(s) ⇌N2(g) + 2 H2O(g)

b) H2O(l) ⇌ H2O(g)

c) SO2(g) + ½ O2(g) ⇌ SO3(g)

d) S8(s) + 8 O2(g) ⇌ 8 SO2(g)

e) MgO(s) + CO2(g) ⇌ MgCO3(s)

IV. Problem Solving: Determine the unknown in each given problem.

1. At the equilibrium point in the decomposition of phosphorus pentachloride to chlorine and phosphorus
trichloride, the following concentrations are obtained: 0.010 mol/L PCl 5, 0.15 mol/L PCl3 and 0.37 mol/L
Cl2. Determine the Keq for the reaction.
PCl5(g) ⇌ PCl3(g) + Cl2(g)