Scribd Logo
Upload

Welcome to Scribd!

  • Organic Chemistry - lesson8-II

    Uploaded by

    Kajal Gupta
    17 views6 pages
    This document provides an overview of modern spectroscopic techniques for structural elucidation of organic compounds. It discusses UV-Vis, IR, and NMR spectroscopy, which provide information on molecular structure by analyzing the absorption, emission, or scattering of electromagnetic radiation. Molecules can exist at different energy levels, and each spectroscopic region (UV, visible, IR, microwave, radio) probes a different type of molecular motion or property (electronic, vibrational, rotational, nuclear spin). The document outlines the basic principles and molecular interactions involved in each technique, and provides resources for further reading.

    Original Description:

    Class Notes

    Original Title

    Organic Chemistry- lesson8-II

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document
    This document provides an overview of modern spectroscopic techniques for structural elucidation of organic compounds. It discusses UV-Vis, IR, and NMR spectroscopy, which provide information on molecular structure by analyzing the absorption, emission, or scattering of electromagnetic radiation. Molecules can exist at different energy levels, and each spectroscopic region (UV, visible, IR, microwave, radio) probes a different type of molecular motion or property (electronic, vibrational, rotational, nuclear spin). The document outlines the basic principles and molecular interactions involved in each technique, and provides resources for further reading.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    17 views6 pages

    Organic Chemistry - lesson8-II

    Uploaded by

    Kajal Gupta
    This document provides an overview of modern spectroscopic techniques for structural elucidation of organic compounds. It discusses UV-Vis, IR, and NMR spectroscopy, which provide information on molecular structure by analyzing the absorption, emission, or scattering of electromagnetic radiation. Molecules can exist at different energy levels, and each spectroscopic region (UV, visible, IR, microwave, radio) probes a different type of molecular motion or property (electronic, vibrational, rotational, nuclear spin). The document outlines the basic principles and molecular interactions involved in each technique, and provides resources for further reading.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Flag for inappropriate content
    of 6

    Modern Techniques in Structural Elucidation of

    Organic Compounds
    Spectroscopic Techniques in Structural Elucidation

    Water (H2O)
    or
    Ethanol (C2H5OH)
    or
    Hexane (C6H14)

    a. UV-Vis- Spectroscopy

    b. IR-Spectroscopy

    c. NMR- Spectroscopy

    Books: Any book on organic spectroscopy


    Lectures mainly follow:
    Introduction to Spectroscopy by D. L. Pavia, G. M. Lampman, G. S. Kriz
    and J. R. Vyvyan
    Organic Chemistry by P. Y. Bruice
    Organic Chemistry by J. Clayden, N. Greeves and S. Warren
    Spectroscopy
    molecular spectroscopy is the study of the interaction of electromagnetic (EM)
    radiation with Molecule

    based on the analysis of EM radiation that is emitted, absorbed, or scattered by


    molecules
    Absorption spectroscopy:
    a photon is absorbed and the
    molecule is raised to a higher energy
    level.

    Emission spectroscopy:
    a photon is emitted and the
    molecule falls back to a lower energy
    level

    give information on: molecular structure (bond lengths, strengths, energy


    levels, etc...)
    Spectroscopy: Molecular Energy Levels
    Spectroscopy: Electromagnetic (EM) Radiation

    EM region Wavelength (nm) Energy (K cal/mole) Molecular Energy level


    UV 200-300 143-95 Electronic
    visible 400-700 71-41
    infrared 1000-10000 29-2.9 Vibrational
    microwave 107-109 3 X 10-3-3 X 10-4 Rotational
    radiowave 1011 3 X 10-6 Nuclear spin precession

    Ultraviolet → electronic (UV-Visible spectroscopy)


    Infrared → vibration (Infra red spectroscopy)
    Microwave → rotation (rotational spectroscopy)
    Radio → nuclear spin in magnetic field (NMR-spectroscopy)
    Looking forward

    UV spectroscopy:
    Basic principle, Beer–Lambert law, Chromophore, etc.

    Course material will be uploaded after 17:00 h on every Wednesday @

    http://www.iitg.ac.in/ckjana/ckjana/Teaching.html

    You might also like