7/8/2021 2 PUC NEET 15 TH GROUP ELEMENTS

RVS PU College
2 PUC NEET 15 TH GROUP ELEMENTS
08 Jul 2021

1) The chemical used for cooling in refrigeration is

1)CO 2 2)N H 4 OH 3)N H 4 Cl 4)Liquid N H 3

2) The concentration of fluoride ions in drinking water upto 1 ppm make the enamel on teeth much harder by converting –X
–
into fluorapatite. What is –X
–
?
1)[3Ca 3 (P O4 ) . CaF2 ]
2
2)[3Ca 3 (P O4 ) . Ca(OH ) ]
2 2
3)[3Ca(OH ) 2
. Ca3 (P O4 ) ]
2
4)[Ca 3 (P O4 ) .3CaF2 ]
2

3) Which of the following is correct

1)Nitrogen forms multiple bonds 2)78% by volume of air 3)Only V group element present in the elementary state 4)All of the
between its atoms in nitrogen in Nature is Nitrogen above

4) Which of the following is both neutral and paramagnetic

1)N 2O 2)N O 3)NO 2 4)N 2 O2

5) Which of the following compounds give N H on heating?

3

(I) N H 4 N O3

(II) N H 4 N O2

(III) (N H 4 )2 Cr2 O7
(IV) (N H 4 )2 CO3

(V) M g(N H 4 )P O4

1)I, III, IV 2)II, III, V 3)IV only 4)IV, V

6) P4 O10 is the anhydride of the following

1)H 3P O2 2)H 3P O3 3)H 3P O4 4)H 3P O5

7) Which of the following oxide is most acidic?

1)As 2 O3 2)P 2 O5 3)Sb 2 O3 4)Bi 2 O3

8) When H 2S gas is passed through nitric acid, the product is

1)Rhombic S 2)Prismatic S 3)Amorphous S 4)None of these

9) When equal weights of the two fertilizers, urea and ammonium sulphate are taken, urea contains
1)Less nitrogen than 2)As much nitrogen as 3)Twice the amount of nitrogen 4)More than twice the amount of nitrogen
ammonium sulphate ammonium sulphate present in ammonium sulphate present in ammonium sulphate

10) The statement that is NOT correct is

1)hypophosphorus acid reduces 2)in solid state PCl exists 5 3)pure phosphine is 4)phosphorus acid on heating disproportionate to
+ −
silver nitrate to silver as [P Cl 4] [P Cl6 ] not inflammable give metaphosphoric acid and phosphine

11) C and D are

−1
1)BiOCl, Bi 2)Bi,BiOCl 3)Bi(OH ) 3
, Bi 4)(BiCl 4) Bi

12) Black coloured sulphide Aqua regia

⟶ A
DM G

⟶ B (rosy red colour complex) A + excess of KCN ⟶ C (complex)

Solution

The hybridisation and structure of complex ‘C’ is

1)dsp 2
, sq. planar 2)sp 3
, tetra hedral 3)dsp , trigonal bipyramidal
3
4)d 3
sp
3
pentagonal bi-pyramidal

13) What may be expected to happen when phosphine gas is mixed with chlorine gas
1)The mixture only 2)P Cl and H Cl are formed and the
3 3)P Cl and H Cl are formed and the
5 4)P H 3. Cl2 is formed with
cools down mixture warms up mixture cools down warming up
7/8/2021 2 PUC NEET 15 TH GROUP ELEMENTS

14) Nitric acid is used in the manufacture of:

1)TNT 2)picric acid 3)N H 4 N O3 4)all of these

15) Which statement is not correct for nitrogen

1)It has a small size 2)It does not readily react with O 2 3)It is a typical non-metal 4)d-orbitals are available for bonding

16) In the catalytic oxidation of ammonia an oxide is formed which is used in the preparation of H N O . This oxide is 3

1)N 2 O5 2)N 2 O4 3)N O 2 4)N O

17) Strong reducing behaviour of H PO is due to : 3 2

1)High oxidation state of phosphorus 2)Presence of two -OH groups 3)two P-H bonds 4)High electron gain enthalpy of phosphorus

18) Which of the following is not a conjugate acid - base pair?

1)H P O 2−

3
, PO
3−

3
2)H 2P O
−

4
, HP O
2−

4
3)H 2P O
−

4
, H3 P O 4 4)H 2P O
−

4
, PO
3−

19) Which is the correct statement for the given acids?

1)Phosphinic acid is a diprotic acid while 2)Phosphinic acid is a monoprotic acid while 3)Both are 4)Both are
phosphonic acid is a monoprotic acid. phosphonic acid is a diprotic acid. diprotic acids. triprotic acids

20) HgCl and I both when dissolved in water containing excess of I ions the pair of species formed is :
2 2
−

1)H gI 2, I
−

3
2)H gI 2, I
−
3)H gI 4
2−
, I
−

3
4)H g 2 I2 , I
−

21) Which statement is false?

1)N H is a Lewis base
3 2)N H molecule is triangular planar
3 3)N H does not act as reducing agent
3 4)N H (liquid ) is used as a solvent
3

22) Ammonia water is a good cleaning agent because it:

1)is weakly basic 2)emulsifies grease 3)leaves no residue when wiped out 4)all are true

23) Phosphine is not obtained by the reaction

1)White P is heated with N aOH 2)Red P is heated with N aOH 3)Ca 3 P2 reacts with water 4)Phosphorus trioxide is boiled with water

24) Which one of the following statements is true for H N O 2

1)It is very stable in aqueous 2)It cannot act both as an oxidant and as a 3)It cannot act as an oxidising 4)It cannot act as reducing
solution reductant agent agent

25) Which of the following statements about liquid nitrogen is true

1)It is unreactive 2)It is used in cryosurgery 3)It does not decompose organic compounds 4)It is very stable

26) On heating a mixture of N H 4 Cl and KN O we get 2

1)N H 4 N O3 2)N 2 3)N 2O 4)N O

27) Which of the following has highest boiling point

1)N H 3 2)P H 3 3)AsH 3 4)SbH 3

28) N O2 and N 2 O4 are two forms of nitrogen dioxide. One exists in gaseous state while other in liquid state. The nature of N O and N 2 2 O4 forms are:
1)both are 2)both are 3)N O is paramagnetic while N
2 2 O4 is 4)N O is diamagnetic while N
2 2 O4 is
paramagnetic diamagnetic diamagnetic paramagnetic

29) KOH

(A) ⟶ (B) (gas turns red litmus to blue)

Zn+KOH

(C) ⟶ (B) (gas)

H eat

(A) ⟶ (D) (does not sup port f or combustion)

gas

1)A = N H 4 N O3 ; B = N2 ; C = KN O3 2)A = N H 4 N O2 ; B = N H3 ; C = KN O2 3)A = (N H 4)

2
SO4 ; B = N H3 ; C = KN O2 4)A = N

30) NO
2

N H4 Cl(aq) ⟶ A(g)

(aq)

−
OH

N H4 Cl ⟶ B(g)

Correct statement w.r.t A and B

1)A is Lewis base, B is inert 2)A is more soluble in H 2O than B 3)In liquid form both A and B are used as refrigerant 4)All are correct

31) The number of P-O-P bridges in the structure of phosphorous pentoxide and phosphorous trioxide are respectively
7/8/2021 2 PUC NEET 15 TH GROUP ELEMENTS

1)6, 6 2)5, 5 3)5, 6 4)6, 5

32) The cyanide ion, CN −

and N are isoelectronic. But in contrast to CN
2
−
, N is chemically inert because of
2

1)Low bond 2)Absence of bond 3)Unsymmetrical electron 4)Presence of more number of electrons in bonding
energy polarity distribution orbitals

33) Number of oxygen atoms attached phosphorus atom in P O molecules are 4 6

1)6 2)4 3)3 4)2

34) The bonds present in P 4 O10 are

1)Ionic and covalent 2)Ionic and dative 3)Covalent and dative 4)Only covalent bonds

35) Which of the following compound does not produces oxyacid of central atom on hydrolysis
1)BF 3 2)N Cl 3 3)SCl 4 4)P Cl 5

36) P4 + 8SOCl2 → 4A + 4B + 2C , B is oxide, which of the following statements is wrong.

1)Aq solution of A 2)‘B’ acts as dry Bleaching agent and bleaching 4)In A and C central atom undergo
Δ

3)2C ⟶ SCl4 + 3S

conducts electricity property is due to reduction sp

3
hybridization.

37) Which of the following statements is true ?

1)Except N all elements of V 2)All V group elements 3)All V group elements except Bi 4)All V group elements except N and
group exhibit allotropy exhibit allotropy exhibit allotropy Bi exhibit allotropy

38) Which of the following is more acidic

1)P 4 O6 2) P 4 O1 0 3)As 4 O6 4)As 4 O1 0

39) Which of the following is not correct?

1)Hydrolysis of N Cl gives 3 2)N H is less stable
3 3)N H is a weak reducing reagent
3 4)Nitric oxide in solid state exhibits
N H3 and HOCl than P H 3 compared to P H 3 diamagnetic property

40) N H3 burns in dioxygen with a

1)pale yellow flame and give NO 2 2)pale yellow flame and gives N 2 3)pale yellow flame and gives H N O 3 4)green flame and gives N
2

41) N H4 N O2 ⟶ A + H2 O;
Δ

N H4 N O 3 ⟶ B + H2 O then
1)A = B = N 2 2)A = B = N 2O 3)A = N O 2; B = N2 O 4)A = N 2; B = N2 O

42) Some statements are given regarding Group 15 elements

a) Group 15 elements are commonly known as pnicogens

b) Arsenic, Antimony and Bismuth are found mainly as sulphide minerals

c) The general valence electronic configuration is ns 2

np
3

d) The formula of fluorapatite is Ca 9 (P O4 ) . CaF2

6
. Correct statements are
1)a, b, c, d 2)a, b only 3)c, d only 4)a, c, d only

43) ‘AIR BAG’ used in cars contain

1)N H 4 N O2 2)(N H 4 )2 Cr2 O7 3)N aN 3 4)N H 4 Cl + KN O2

44) Which of the following compounds will not give ammonia on heating?
1)(N H 4)
2
SO4 2)(N H 4)
2
CO3 3)N H 4 N O2 4)N H 4 Cl

45) Which acid is not formed by the action of water on phosphorus pentoxide
1)H P O 3 2)H 4 P2 O 7 3)H 3P O4 4)H 3P O3