Professional Documents
Culture Documents
FLOOR CARE
Public
BU Additives
BL Waxes
2015
2 Public
BU Additives, BL Waxes, 2015
Outline
– Guide Formulations
3 Public
BU Additives, BL Waxes, 2015
GENERAL
INFORMATION
4 Public
BU Additives, BL Waxes, 2015
DOMESTIC FLOORS
Low level of wear on the floor, low traffic areas
e.g. at home
Achieve gloss without buffing
5 Public
BU Additives, BL Waxes, 2015
BUFFABLE PRODUCTS
gloss can be achieved by buffing,
DRY-BRIGHT EMULSIONS
DRY-BRIGHT EMULSIONS
for protective coating, or
for maintenance & care (diluted),
as sealer (for porous surfaces) or
for protective coating
for maintenance & care (diluted)
DRY-BRIGHT
EMULSIONS
8 Public
BU Additives, BL Waxes, 2015
WAX
FLOOR CARE PRODUCT
Temporary plasticizer
Permanent plasticizer
Wetting agents
FLOOR
Supplementary additives
(Detergents, Defoamers,
Preservatives, Antistatic agents, ...)
9 Public
BU Additives, BL Waxes, 2015
DRY-BRIGHT EMULSIONS
General
They contain waxes and/or polymers in finely dispersed form which dry to a bright
film after the evaporation of water. The ratio of wax to polymer should be geared to
the particular flooring. It influences the following properties of the protective film:
• non-slip properties
Guide formulations:
• adhesion N 13-153, N 35-453
IND 50-855, IND 50-863, IN 34-853
10 Public
BU Additives, BL Waxes, 2015
DRY-BRIGHT EMULSIONS
Polymer Content
LOW HIGH
11 Public
BU Additives, BL Waxes, 2015
DRY-BRIGHT EMULSIONS
with high-polymer and low wax-content
– Metal-salt-containing polymer dispersions (e.g. Licomer M 55- Michelman) lead to
readily removable protective films.
– Products based on metal-salt-free acrylate or styrene/acrylate dispersions such as
Licomer A 53 may be regarded as polymer sealants.
– The use of plasticizers/ coalescing aids are mandatory, with polymers.
– Wax emulsions have a matrix effect, prevent powdering of the relatively hard
protective film and provide the required non-slip properties.
– Licowax 371 FP, Licocene PPMA 1332 TP, Licowax KC 132 TP have a particularly
good non-slip effect.
– For solving adhesion problems on stone, modern pre-treated parquet and laminate
floorings the wax portion has to be increased.
– The given formulations can be prepared also as concentrates up to 32% solid
content, simply by reducing the water-content.
12 Public
BU Additives, BL Waxes, 2015
Waxes
in DRY-BRIGHT EMULSIONS
Clariant waxes LICOWAX®, LICOCENE® help for..
Appearance
Wear resistance
Slip-properties
Adhesion
Emulsifiers
in DRY-BRIGHT EMULSIONS
IONIC EMULSIFIERS : These emulsifiers are soaps derived during emulsification from oleic
acid and/or wax acids with volatile amines or inorganic bases, particularly potassium
hydroxide solution. Commonly used amines are 2-amino-2-methylpropanol (AMP),
Diethylaminoethanol (DEAE), 2-dimethylamino-2-methyl-1-propanol (DMAMP), 3-
methoxypropylamine (MPA), Morpholine (MOR), Triethanolamine (TEA).
14 Public
BU Additives, BL Waxes, 2015
Polymer dispersions
in DRY-BRIGHT EMULSIONS
*Clariant does not supply polymer dispersions anymore, as in the past with the
Licomer range. Licomer business is taken over by Michelman in 2011.
15 Public
BU Additives, BL Waxes, 2015
– Plasticizers are added to reduce the minimum film-forming temperature (MFT) and
also improve the wetting- and leveling properties.
– The type and amount of plasticizer depends on the polymer dispersion used.
Typically permanent and temporary plasticizers are combined.
TEMPORARY PLASTICIZERS are volatile and evaporate: e.g. Ethyl diglycol (EDG),
Methyl diglycol (MDG), (N-methyl)-2-pyrrolidone.
– For ionic emulsions, basic adjustment can be made with wetting resin solution,
e.g. with an ammoniacal Syncera 1464 (Paramelt) solution or Licomer T51
(Michelman) and the fine tuning with fluorosurfactants such as Zonyl FSJ (BYK)
or Silco FLW (Keim).
– Nonionic wax emulsions do not require these additives because Wax emulsifier
2106 and 4106 produce emulsions with good wetting and levelling properties. If
necessary, fluorosurfactants can be added.
17 Public
BU Additives, BL Waxes, 2015
PRESERVATIVES
Microorganisms introduced via air, water or contaminants often find favourable living
conditions in aqueous systems and multiply very rapidly. The metabolic products they
produce can cause unpleasant odours, discoloration and instability. Emulsions with a
low pH and those diluted with cold tap water (crash cooling method) are particularly at
risk. It is therefore advisable to preserve the emulsions against bacteria and moulds
(0.1 -0.2% preservative in the formulation).
18 Public
BU Additives, BL Waxes, 2015
FREEZE/THAWS RESISTANCE
The low-temperature resistance of nonionic emulsions can be improved needs to be
taken into consideration. One could add around 5% ethanol or other appropriate
products.
ELECTROSTATIC CHARGES
Many floor coverings, e.g. untreated, highly insulating PVC coverings, tend to
accumulate electrostatic charge as a result of traffic. It is advisable to treat such floor
coverings with nonionic dry-bright emulsions because the film formed by these products
accumulates only a relatively weak electrostatic charge. Hostaphat KL 304 or suitable
Hordaphos types from Clariant could be used to increase antistatic effect.
BUFFABLE PRODUCTS
(WATER-BASED)
20 Public
BU Additives, BL Waxes, 2015
BUFFABLE PRODUCTS
(SOLVENT-BASED)
22 Public
BU Additives, BL Waxes, 2015
– Protective coating
Waxes
in SOLVENT-BASED FLOOR POLISH
Clariant waxes LICOWAX®, LICOCENE® help for..
Gloss
Wear resistance
Soil repellency
Solvent-binding
Heat resistance
Rheology regulation
Other Ingredients
in SOLVENT-BASED FLOOR POLISH
SOLVENT
White spirit (boiling range between 140 and 200 °C) is the solvent mostly
used, sometimes mixed with turpentine (boiling range between 150 and
180 °C).
– For wet-mop daily maintenance a wash and wax product is Guide formulations:
RW 41 m, RW 48,
added to the cleaning water. Wet mop products are always used
RW 49, RW 65
diluted in water (solids content about 2 %).
28 Public
BU Additives, BL Waxes, 2015
– For the use with UHS machines a wax:polymer ratio of 1:1 is the best choice in
regard to adhesion, buffability and lubrication of the pad.
Guide formulations:
INA 1-655
29 Public
BU Additives, BL Waxes, 2015
– A cleaner is sprayed over the floor, one area at a time, and then a
polishing machine with pads cleans and polishes in one
operation until a thin, shiny film is obtained. Soil and traffic marks
are removed. The most commonly used products of this type are
emulsion cleaners.
Guide formulations:
RW 61
30 Public
BU Additives, BL Waxes, 2015
CRYSTALLIZERS
31 Public
BU Additives, BL Waxes, 2015
Crystallizers
Guide formulations:
JS 423h
32 Public
BU Additives, BL Waxes, 2015
Clariant Products
for Floor Care
33 Public
BU Additives, BL Waxes, 2015
These are pale, very hard waxes. They can be processed alone
and in combination with other waxes to form both nonionic and
ionic dry-bright emulsions. They can also be used to produce
wash & wax systems and floor cleaners.
GUIDE FORMULATIONS
(Dry-bright)
40 Public
BU Additives, BL Waxes, 2015
DRY-BRIGHT EMULSIONS
Wax-Based with low-polymer content
N13-353: Universal care product, neutal pH and readily buffable, excellent
adhesion on all substrates
DRY-BRIGHT EMULSIONS
with high-polymer and low wax-content
IND 50-855, IND 50-863: Dry-bright emulsion for large areas with extremely hardwearing
protective film (with metal-salt)
Formulation IND 50-855 IND 50-863
Water 44.9 36.0
Ammonia solution - 0.4
Ethyldiglycol 2.6 3.1
Hostaphat TBEP HQ 1.8 2.1
Syncera 1464 4.8 -
Licomer M 55 37.4 -
Licomer M 63 - 47.2
Wax emulsion 6.7 7.3
(e.g. Licomer W 19, IN 55, IN 31, IN 67, Lu 1029/2, N3-C)
DRY-BRIGHT EMULSIONS
Metal-salt-free formulations
IN 34-853: appr. 20% for industrial floors, polymer sealant, the protective film stands-up for machine polishing.
IN 50-8623: Dry-bright emulsion for the household field.
DRY-BRIGHT EMULSIONS
Wax emulsions
Formulation IN 55 IN 31 IN 67 Lu 1029/2 N3-C
Licowax PED 191 28.0 - - - -
Licowax PED 153 - 27.6 14.2 - -
Licowax 371 FP - - 14.2 - -
Licocene PPMA 1332 TP - - - 23.5 -
Licowax KC 132 TP - - - - 30.0
Genapol OX-100 6.9 6.0 - -
Dobanol 91/6, Shell or Synperonic 91/5 6.5 - - - -
Wax emulsifier 4106 - - - - 6.0
Imbentin C/091/040 - - - 5.0 -
Oleic Acid - - - 5.0 -
KOH (~86%) 0.2 0.2 0.3 0.9 -
Diethylaminoethanol 0.7 0.7 - 1.6 -
Sodium sulfite 0.2 0.2 0.2 0.2 -
Water 64.4 64.4 65.1 63.8 -
TOTAL 100 100 100 100 -
Very hard Slip resistant Very slip Slip resistant
Characteristic Hard film
film film resistant film film
44 Public
BU Additives, BL Waxes, 2015
GUIDE FORMULATIONS
(Buffable-WATER BASED)
45 Public
BU Additives, BL Waxes, 2015
ALLWAX Formulations
for all floors
Formulation INA 1-655 INA 2-755 INA 3-655
Water 61.9 49.0 55.0
Ethyldiglycol 1.4 2.4 0.9
Hostaphat TBEP HQ 0.5 1.6 0.6
Ammonia sol. (~ 25%) 0.4 0.5 -
Genapol X 080 - - 0.5
Syncera 1464 4.0 3.0 3.0
Licomer M 55 15.4 30.0 21.0
Wax Emulsion INA 1 15.4 - -
Wax Emulsion INA 2 - 13.0 -
Wax Emulsion INA 3 - - 18.0
Zonyl FSJ or Silco FLW
1.0 0.5 1.0
(1%)
TOTAL 100 100 100
46 Public
BU Additives, BL Waxes, 2015
WAX EMULSIONS
for ALLWAX Formulations
Formulation INA 1 INA 2 INA 3
Licowax KSL or
14.0 12.0 8.0
Licowax KC 132 TP
Licowax PED 153 14.0 13.0 -
Licowax PED 191 - - 20.0
Diethylaminoethanol 1.0 - 0.9
KOH (~86%) 0.2 0.6 0.3
Sodium sulfite 0.1 0.2 0.2
Emulsifier* 5.5 6.5 5.0
Water 65.2 67.7 65.6
TOTAL 100 100 100
GUIDE FORMULATIONS
(Buffable-SOLVENT BASED)
48 Public
BU Additives, BL Waxes, 2015
GUIDE FORMULATIONS
(Solvent-Based)
B 91: Paste floor polish for very high buffed gloss
BF 21: Liquid floor polish 12.5% for a hard protective film and high gloss
Formulation B 91 BF 21
Licowax O or OP 6.0 -
Licowax PE 520 1.5 -
Licowax R21 - 6.0
Dicera RT 0.5 -
Paraffin wax 13.5 3.0
Hard Microwax - 2.5
Soft Microwax - 1.0
White Spirit 78.5 87.5
TOTAL 100 100
49 Public
BU Additives, BL Waxes, 2015
GUIDE FORMULATIONS
(Wash & Wax)
50
BU Additives, BL Waxes, 2015
Formulation RW 48 RW 41 m
Water 64.0 42.0
Borax 2.0 -
(sodium tetraborate decahydrate)
Wax Emulsion
- 50.0
(30% Licowax KLE)
Genapol T-250 or T-500 - 5.0
Genapol OX 80 - 3.0
TOTAL 100 100
51 Public
BU Additives, BL Waxes, 2015
GUIDE FORMULATIONS
Wax emulsions for Wash & Wax
IN 67, Lu 1029/2: Wax emulsions with anti-slip properties
N3-C: Easy to prepare wax emulsion with self-shine and anti-slip properties
Formulation IN 67 Lu 1029/2 N3-C
Licowax PED 153 14.2 - -
Licowax 371 FP 14.2 - -
Licocene PPMA 1332 TP - 23.5 -
Licowax KC 132 TP - - 30.0
Genapol OX-100 6.0 - -
Wax emulsifier 4106 - - 6.0
Imbentin C/091/040 - 5.0 -
Oleic Acid - 5.0 -
KOH (~86%) 0.3 0.9 -
Diethylaminoethanol - 1.6 -
Sodium sulfite 0.2 0.2 -
Water 65.1 63.8 -
TOTAL 100 100 -
Slip resistant Very slip Slip resistant
Characteristic
film resistant film film
52 Public
BU Additives, BL Waxes, 2015
Formulation RW 61
Wax Emulsion
26.5
(30% Licowax KLE)
Genapol OX-060 2.0
White spirit 20.0
Hostapur SAS 60 0.1
Zonyl FSJ or Silco FLW (1%) 0.5
Water 50.9
TOTAL 100.0
54 Public
BU Additives, BL Waxes, 2015
CRYSTALLIZERS
55 Public
BU Additives, BL Waxes, 2015
CRYSTALLIZER
Formulation JS 423-h
Cationic Wax Emulsion
20.0
(e.g. based on Licowax KSL)
Magnesium-fluorosilicate-6-hydrate 20.0
Water 60.0
TOTAL 100.0
Cationic Wax
Emulsion
Licowax KSL 14.0
Genamin S 080 6.0
Acetic Acid 0.2